SAFETY DATA SHEET

T-BUTYL MERCAPTAN

1 IDENTIFICATION

PRODUCT IDENTIFIER
Product Name: T-BUTYL MERCAPTAN
RECOMMENDED USE AND RESTRICTIONS OF USE
Recommended Use: Odorant for gas products
Restrictions of Use: no information available
NAME, ADDRESS, AND TELEPHONE NUMBER OF THE RESPONSIBLE PARTY
Company: M Chemical Company, Inc.
Address: 825 Colorado Boulevard, Suite 214
Los Angeles, CA 90041 USA
Telephone: (323) 254-3600
EMERGENCY TELEPHONE NUMBER
CHEMTREC: 1 (800) 424-9300 [Contract number 225543]
Contact only in the event of chemical emergencies involving spill,
leak, exposure, or accident involving this chemical.

2 HAZARD(S) IDENTIFICATION

CLASSIFICATION OF THE SUBSTANCE

This product is classified as hazardous according to the 2012 OSHA Hazard Communication
Standard (29 CFR §1910.1200) and GHS.
Hazard(s): SENSITIZATION – SKIN (CATEGORY 1A)
FLAMMABLE LIQUID (CATEGORY 2)
HAZARDOUS TO THE AQUATIC ENVIRONMENT – LONG-TERM (CHRONIC)
HAZARD (CATEGORY 2)
SIGNAL WORD, HAZARD STATEMENTS, SYMBOLS, & PRECAUTIONARY STATEMENTS
Signal Word: DANGER
Hazard Statement(s): May cause an allergic skin reaction
Highly flammable liquid and vapor
Toxic to aquatic life with long lasting effects
Hazard Pictograms(s):

Precautionary Statements:
• Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/
ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures
against static discharge.
• Avoid breathing fumes/vapors/spray. Wear protective gloves/ eye protection/ face
protection. Contaminated work clothing must not be allowed out of the workplace.

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• IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin
with water/ shower. Wash contaminated clothing before re-use. If skin irritation or rash
occurs: Get medical advice/attention.
• IN CASE OF FIRE: Use dry sand, dry chemical or alcohol-resistant foam for extinguishing.
• Avoid release to the environment. Collect spillage.
• Store in a well-ventilated place. Keep cool.
• Dispose of contents/container in accordance with local/regional/national/international
regulations.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC)
• Static accumulating flammable liquid. Can become electrostatically charged even in bonded
and grounded equipment. Sparks may ignite liquid and vapor.
• Objectionable odor may cause nausea, headache or dizziness. Vapor is heavier than air and
can cause suffocation by reducing oxygen available for breathing.
OTHER CLASSIFICATIONS
NFPA

3 COMPOSITION / INFORMATION ON INGREDIENTS

This product contains the following component(s) which are present at concentrations sufficient
to result in the classification of the product as hazardous to health (i.e. above the relevant cut-off
value for any particular health hazard) according to the 2012 OSHA Hazard Communication
Standard (29 CFR §1910.1200).

CHEMICAL NAME CAS NUMBER W T. %

2-Propanethiol, 2-methyl 75-66-1 > 99
Synonym:
tert-Butyl mercaptan

4 FIRST AID MEASURES

DESCRIPTION OF NECESSARY MEASURES

Eyes In case of contact with eyes, rinse immediately with water for several minutes.
Remove contact lenses if present and easy to do so. Continue rinsing. Get
medical attention if irritation occurs.
Inhalation Remove to fresh air and keep comfortable for breathing. If not breathing, give
artificial respiration and get immediate medical attention.
Skin Rinse immediately with water/shower. Remove contaminated clothing and shoes
and wash before re-use. Get medical attention if irritation or rash occurs.
Ingestion Rinse mouth. Do not induce vomiting. If vomiting occurs naturally, have person
lean forward to reduce the risk of aspiration. Get medical attention immediately.
MOST IMPORTANT SYMPTOMS / EFFECTS, ACUTE AND DELAYED

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Eyes May cause eye irritation.
Inhalation May be harmful if inhaled. Objectionable odor may cause nausea, headache or
dizziness. Vapor is heavier than air and can cause suffocation by reducing
oxygen available for breathing.
Skin May be harmful if absorbed through the skin. May cause an allergic skin
reaction. May cause skin irritation.
Ingestion Potential aspiration hazard: May be harmful if swallowed and enters airways.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF NECESSARY
Notes to Physician: None known

5 FIRE FIGHTING MEASURES

SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA

Suitable Use foam, dry chemical, or carbon dioxide (CO2) to extinguish fire.
Unsuitable Do high volume water jet as it may scatter and spread the fire.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL
Extremely flammable liquid and vapor. Vapors are heavier than air and may travel along the
ground or be moved by ventilation and ignited by heat, pilot lights, and other flames and ignition
sources at locations distant from material handling point. Burning or thermal decomposition of
this material in a fire may produce hazardous products, including carbon monoxide, carbon
dioxide, oxides of sulfur, and other toxic gases.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS
Standard protective equipment for fighting chemical fires should be used, including self
contained breathing apparatus (SCBA) and full fire fighting turn-out gear.
Caution: CO2 used for extinguishing will displace air in confined spaces and may cause an
oxygen deficient atmosphere.
Closed containers of this material may explode when subjected to heat from surrounding fire.
After a fire, wait until the material has cooled to room temperature before initiating clean-up
activities. Do not approach containers suspected to be hot. Cool endangered containers with
water spray from a protected location. Move undamaged containers from the hazard area if it
can be done safely.
Water used for extinguishing a fire must be prevented from draining into sewers or being
released to the environment. Decontaminate fire-fighting equipment after use.

6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES

Prevent further leakage or spillage if you can do so without risk. Ventilate the area. Eliminate all
ignition sources. Avoid generation of vapors. Do not breathe vapors or fumes. Avoid personal
contact. Wear personal protective equipment (See Section 8: Exposure Controls / Personal
Protection). Isolate the hazard area and evacuate unnecessary and unprotected personnel.
Ventilate area only if odor control is not an issue.
ENVIRONMENTAL PRECAUTIONS
Do not release to the environment. Do not allow substance to enter into surface water or drains.
Collect spillage. Contaminated water must be retained and disposed of in accordance with all
local, regional, national, and international regulations. Consult a regulatory specialist to

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determine appropriate state or local reporting requirements, for assistance in waste
characterization and/or hazardous waste disposal and other requirements listed in pertinent
environmental permits.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP
Contain and collect spillage with non- combustible absorbent material such as sodium
bicarbonate, sodium carbonate, calcium carbonate, clean sand or non-acidic clay and then wet
down (dampen) the mixture with water. Sweep or scoop up using non-sparking tools and place
into suitable properly labeled containers for prompt disposal. The sweepings should be wetted
down further with water (see Section 13: Disposal Considerations).

7 HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING

Do not breathe vapors or fumes and avoid personal contact. Use only with adequate ventilation.
Do not eat, drink, or use tobacco products while working. Keep away from heat, sparks and
flames: No smoking. Keep container tightly closed. Do not enter confined spaces unless
adequately ventilated. Wash thoroughly after handling. Wash contaminated clothing before re-
use. Check that all equipment is properly grounded and installed to satisfy electrical
classification requirements.
Static electricity may accumulate when transferring material. All metal and groundable storage
containers, including but not limited to drums, cylinders, Returnable Intermodal Bulk Containers
(RIBCs) and Class C Flexible Intermodal Bulk Containers (FIBCs) must be bonded and
grounded during filling and emptying operations. To minimize static charge accumulation, flow
rate should be restricted to less than 1 m/s (3 ft/s). When adding product to a hot reactor, closed
system addition is recommended due to product volatility and flammability.
Emptied container retains vapor and product residue and is hazardous when empty, follow label
warnings even after container is emptied. RESIDUAL VAPORS IN CONTAINERS MAY
EXPLODE ON IGNITION. DO NOT CUT, DRILL, GRIND, OR WELD ON OR NEAR THE
CONTAINER. Improper disposal or reuse of the container may be dangerous and/or illegal.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Keep in a dry, cool place. Keep away from direct sunlight. Keep container closed when not in
use. Store in closed containers, in a secure area to prevent container damage and subsequent
spillage. Store in well ventilated area away from heat and sources of ignition such as flame,
sparks and static electricity. Ensure that all storage and handling equipment is properly
grounded and installed to satisfy electrical classification requirements. Observe all local,
regional and national regulations and National Fire Protection Association (NFPA) Codes that
pertain to the specific local conditions of storage and use.
Store away from oxidizing agents, strong acids, strong bases, and reducing agents.

8 EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROL LIMITS

tert-Butyl mercaptan Not applicable (N/A)
CAS No. 75-66-1

APPROPRIATE ENGINEERING CONTROLS

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Work in well ventilated areas. The use of local exhaust ventilation is recommended to control
air contaminants. Provide mechanical ventilation for confined spaces. Use explosion-proof
ventilation equipment. Use mechanical handling to reduce human contact with materials.
Monitor carbon monoxide and oxygen levels in tanks and enclosed spaces. Consult ACGIH
ventilation manual or NFPA Standard 91 for design of exhaust systems.
INDIVIDUAL PROTECTIVE MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT
General Hygiene Do not breathe vapors or fumes. Avoid contact with eyes and
skin. Wash thoroughly after handling and before eating, drinking,
or using tobacco products. Wash contaminated clothing before re-
use. Eye wash station and safety shower should be available in
the immediate work area.
Eye/Face Protection Wear safety goggles or equivalent protection.
Skin Protection Wear protective gloves impervious to the conditions of use and
protective clothing. Suitable materials for gloves have not been
determined for this product. The penetration time of the glove
material must be determined by the glove manufacturer and be
observed. This recommendation is advisory only and must be
evaluated by an Industrial Hygienist familiar with the specific
situation of anticipated use by the customer.
Respiratory Protection Where airborne exposure is likely use NIOSH-approved
respiratory protection equipment appropriate to the material and/or
its components. Full face-piece equipment is recommended and,
if used, replaces need for face shield and/or chemical goggles.
Consult respirator manufacturer to determine appropriate type
equipment for a given application. Observe respirator use
limitations specified by NIOSH or the manufacturer. For
emergency and other conditions where there may be a potential
for significant exposure, use an approved full-face positive-
pressure, self-contained breathing apparatus or positive-pressure
airline with auxiliary self-contained air supply.

9 PHYSICAL AND CHEMICAL PROPERTIES

Appearance colorless liquid

Odor mercaptan odor
Odor Threshold 0.1 ppb
Physical State liquid
pH value no information available
Freezing Point 1.1oC
Boiling Point 64oC
Flash Point – 26oC (closed cup)
Evaporation Rate no information available
Flammability no information available
Upper Flammability Limit no information available
Lower Flammability Limit no information available
Vapor Pressure 305 mm Hg (38oC)
Vapor Density 3.11 kg/m3

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Specific Gravity 0.806 (15.5oC)
Solubility in water no information available
Partition Coefficient (octanol/water) no information available
Autoignition Temperature no information available
Decomposition Temperature no information available
Viscosity no information available

10 STABILITY AND REACTIVITY

REACTIVITY
No reactivity hazards are known under normal conditions of storage and use.
CHEMICAL STABILITY
This substance is expected to be stable under normal conditions of storage and use.
POSSIBILITY OF HAZARDOUS REACTIONS
Risk of violent reaction with oxidizing agents, strong acids, strong bases, and reducing agents.
CONDITIONS TO AVOID
Sparks, flames, ignition sources, and static discharges.
INCOMPATIBLE MATERIALS
Oxidizing agents, reducing agents, strong acids, strong bases
HAZARDOUS DECOMPOSITION PRODUCTS
Burning may produce hazardous combustion products, including carbon monoxide, carbon
dioxide, oxides of nitrogen, and other toxic gases.

11 TOXICOLOGICAL INFORMATION

SIGNS AND SYMPTOMS OF OVEREXPOSURE, ACUTE AND DELAYED

Eyes May cause eye irritation.
Inhalation May be harmful if inhaled. Objectionable odor may cause nausea,
headache or dizziness. Vapor is heavier than air and can cause
suffocation by reducing oxygen available for breathing.
Skin May be harmful if absorbed through the skin. May cause an
allergic skin reaction. May cause skin irritation.
Ingestion Potential aspiration hazard: May be harmful if swallowed and
enters airways.
Target Organ Effects no information available
Chronic Effects no information available
ACUTE TOXICITY
Oral Rat, LD50 = 4,729 mg/kg
Inhalation Rat, LC50 (4 hr, vapor) = 97.5 mg/L
Dermal Rabbit, LD50 > 2,000 mg/kg
SKIN CORROSION / IRRITATION
Not classified as a skin irritant based on available data.
EYE DAMAGE / IRRITATION
Not classified as an eye irritant based on available data.

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SENSITIZATION
Respiratory Sensitization no information available
Skin Sensitization Classified as sensitizing (Category 1A) based on available data.
GERM CELL MUTAGENICITY
Not classified based on available data (in vitro, in vivo).
CARCINOGENICITY
Not classifiable due to lack of data. None of the components in this product at concentrations
greater than 0.1% are listed by IARC, NTP, OSHA, or ACGIH as a carcinogen.
REPRODUCTIVE TOXICITY
Not classified as toxic to reproduction or development based on available data.
TARGET ORGAN TOXICITY
Single Exposure Not classifiable due to lack of data.
Repeat/Prolonged Exposure Not classified as STOT – RE based on available data.
ASPIRATION HAZARD
May present an aspiration hazard due to viscosity.

12 ECOLOGICAL INFORMATION

ECOTOXICITY
Acute toxicity – fish Rainbow trout, LC50 (96 hr) = 34 mg/L
Acute toxicity – algae Green algae, ErC50 (72 hr) = 24 mg/L
Acute toxicity – invertebrates Daphnia magna, EC50 (48 hr) = 6.7 mg/L
Acute toxicity – bacteria no information available
This product is toxic to aquatic life with long lasting effects.
PERSISTENCE AND DEGRADABILITY
not readily biodegradable (6% after 63 days in water)
BIOACCUMULATIVE POTENTIAL
no information available
MOBILITY IN SOIL
no information available
OTHER ADVERSE EFFECTS
no information available

13 DISPOSAL CONSIDERATIONS

Disposal by incineration is recommended. Dispose of contents and container in accordance

with local, regional, national, and international regulations. Consult a regulatory specialist to
determine appropriate state or local reporting requirements, for assistance in waste
characterization and/or hazardous waste disposal and other requirements listed in pertinent
environmental permits. Note: Chemical additions to, processing of, or otherwise altering this
material may make this waste management information incomplete, inaccurate, or otherwise
inappropriate. Furthermore, state and local waste disposal requirements may be more
restrictive or otherwise different from federal laws and regulations.

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14 TRANSPORT INFORMATION

UN NUMBER
2347
UN PROPER SHIPPING NAME
BUTYL MERCAPTANS
TRANSPORT HAZARD CLASS(ES)
3
PACKING GROUP
II
ENVIRONMENTAL HAZARD(S)
Marine pollutant
TRANSPORT IN BULK
no information available

15 REGULATORY INFORMATION

INVENTORY STATUS
Australia (AICS) Components listed or exempt
Canada (DSL) Components listed or exempt
China (IECSC) Components listed or exempt
European Union (EINECS) Components listed or exempt
Japan (ENCS) Components listed or exempt
New Zealand (NZIoC) Components listed or exempt
Philippines (PICCS) Components listed or exempt
South Korea (ECL) Components listed or exempt
Taiwan (TCSI) Components listed or exempt
United States (TSCA) Components listed or exempt
USA FEDERAL SARA TITLE III RULES
Section 302 The components of this material are either not regulated under SARA Title III,
Section 302, or are regulated but are present in negligible concentrations.
Section 304 The following components of this material are regulated under SARA Title III,
Section 304 as extremely hazardous chemicals for emergency release
notification (“CERCLA” list): tert-Butyl mercaptan, CAS No. 75-66-1, RQ 100 lb;
Benzene, CAS No. 71-43-2; RQ 10 lb.
Section 313 This material does not contain any chemical components with known CAS
numbers that exceed the threshold (De Minimis) reporting levels established by
SARA Title III, Section 313.
Section 311/312 Hazards: Acute health hazard, fire hazard
USA STATE REGULATIONS
CA WARNING! This product contains a chemical known to the State of California to
Cause Cancer and/or Reproductive Toxicity.

16 OTHER INFORMATION

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REVISION DATE
October 29, 2015
REASONS FOR REVISION
New version compliant with 29 CFR §1910.1200 and GHS

M Chemical Company Inc. provides the information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the
material by a properly trained person using this product. Individuals receiving the information must exercise their independent
judgment in determining its appropriateness for a particular purpose. M CHEMICAL COMPANY INC. MAKES NO
REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY
WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION
SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, M CHEMICAL
COMPANY INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS.

End of SDS

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