AJAY BEHL ACADEMY SINCE 2005

Premier institute for Engineering and Medical Entrance Exam

TEST: Thermodynamics DPP 1

1. Which one of the following statements is false? 9. During compression of a spring the work done is
(a) Work is a state function. 10 kJ and 2 kJ escaped to the surroundings as heat.
(b) Temperature is a state function. The change in internal energy, "U (in kJ)” is:
(c) Change in the state is completely defined (a) 12 (b) 8
when the initial and final states are specified (c) 8 (d) 12
(d) None of the above 10. Which one of the following equations does not
2. According to the first law of thermodynamics correctly represent the first law of thermodynamics
which of the following quantities represents for the given processes involving an ideal gas?
change in a state function? (Assume nonexpansion work is zero)
(a) qrev (b) qrev  wrev (a) Cyclic process : q  w
(c) qrev / w rev (d) qrev  wrev (b) Adiabatic process : U  w
3. When 110g of manganese (At. mass=55) dissolves (c) lsochoric process: U  q
in dilute HNO3 at 27°C under atmospheric (d) Isothermal process: q  w
pressure, the work done in the process is : 11. One mole of an ideal gas at 300 K is expanded
(a) 2494.2 J (b) – 2494.2 J isothermally from an initial volume of 1 litre to 10
(c) – 4988.4 J (d) 4988.4 J litres. The E for this process is (R =2 cal. mol1
4. Temperature of 5 moles of a gas is decreased by K1)
2K at constant pressure. Indicate the correct (a) 163.7 cal (b) zero
statement. (c) 1381.1 cal (d) 9 lit. atm
(a) work done by the gas = 5 R 12. In a closed insulated container, a liquid is stirred
(b) work done by the gas = 10 R with a paddle to increase the temperature, which of
(c) work done over the gas = 10 R the following is true?
(d) work done = 0 (a) E  W  0, q  0 (b) E  W  q  0
5. Workdone for the conversion of 0.5 mole of water
(c) E  0,W  q  0 (d) W  0, E  q  0
at 100°C to steam at 1 atm pressure is (heat of
vaporisation of water at 100°C is 40670 J mol-1) 13. The work done during the expansion of a gas from
3 3
(a) –1.54 kJ (b) 1.54 kJ a volume of 4 dm to 6 dm against a constant
(c) 1.25 kJ (d) –1.35 kJ external pressure of 3 atm is (1 L atm  101.32 J )
6. Work out the heat change (cal) when 40g of He
(a) 6 J (b) 608 J
gas at 27°C undergoes isothermal and reversible
(c) + 304 J (d) 304 J
compression from initial pressure of 1 atm to
14. A well stoppered thermos flask contains some ice
10 atm, (R = 2 cal K1 mol1).
cubes. This is an example of a
(a) 13.818 k cal (b) 13.818 k cal (a) closed system (b) open system
(c) 55.272 k cal (d) 55.272 k cal (c) isolated system
7. An ideal gas is allowed to expand from 1 L to 10 L (d) nonthermodynamic system
against a constant external pressure of 1 bar. The 15. Calculate the work done (in Joules) when 0.2 mole
work done in kJ is of an ideal gas at 300 K expands isothermally and
(a)  9.0 (b) + 10.0 reversibly from an initial volume of 2.5 litres to
(c)  0.9 (d)  2.0 the final volume of 25 litres.
8. Among the following, the set of parameters that (a) 996 (b) 1148
represents path functions, is: (c) 11.48 (d) 897
(A) q + w (B) q
(C) w (D) HTS
(a) (B) and (C) (b) (B), (C) and (D)
(c) (A) and (D) (d) (A), (B) and (C)

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