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MONTHLY ASSESSMENT TEST (IIT-2019)

FIITJEE MONTHLY ASSESSMENT


TEST PHYSICS, CHEMISTRY & MATHEMATICS
MONTHLY ASSESSMENT
CM - TEST CODE: 105458

Time Allotted: 3 Hours Maximum Marks: 240

 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examina tion Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
BATCHES – 79

2. This question paper contains Three Parts.


3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into three sections: Section-A , Section-B & Section-C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment No.
and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.
(i) Section-A (01 – 8) contains 8 multiple choice questions which have only one correct answer. Each
question carries +3 marks for correct answer and – 2 mark for wrong answer.

Section-A (09 – 12) contains 4 multiple choice questions which have one or more than one correct
answer. Each question carries +4 marks for correct answer. There is no negative marking.

(ii) Section-B (01 – 02) contains 2 Matrix Match Type questions containing statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. Each question
carries +8 marks for all correct answer. For each correct row +2 marks will be awarded and –1 mark for
each row matched incorrectly.

(iii) Section-C (01 – 06) contains 6 Numerical based questions with single digit integer as answer, ranging from
0 to 9 and each question carries +4 marks for correct answer and – 1 mark for wrong answer.

Name of the Candidate :__________________________________________

Batch :___________________ Date of Examination :___________________

Enrolment Number :______________________________________________

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Corp. off. : FIITJEE House 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi – 16. Ph : 46106000/10/13/15, Toll Free No. 1800114242.
Fax : 011-26513942, Web:www.fiitjee.com
MONTHLY ASSESSMENT TEST (IIT-2019)

Section – I (Physics)
PART – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

1. A soap film of thickness h is formed in a wire loop of radius r. Surface tension and density of the
soap solution are σ and ρ respectively. The soap film is now punctured at the centre. The time it
takes to disappear is
2 h h
(A) r (B) 2r
 
h h
(C) r (D) r
4 2

2. A slit is cut at the bottom, along the right bottom edge of a rectangular
tank. The slit is closed by a wooden wedge of mass m and apex angle θ
as shown in the figure. The vertical plane surface of wedge is in
contact with the right vertical wall of container. Coefficient of static
h
friction between these two surfaces is μ. To what maximum height
water can be filled in the tank without leakage from slit? (Assume that 
the width of wedge inside the paper is b)

2m 4m
(A) (B)
btan     b tan    
2m 2m cos 
(C) (D)
bsin    cos  bsin    cos 

3. A large lake consists of two immiscible fluids of densities ρ and


2ρ as shown. A ball of mass m and radius r is placed at the 
bottom and its material is of density 2ρ. It is taken very slowly to
the top of the interface as shown, with the help of some external h
r 2
force. Then the total work done by the external force in the
process is

(A) –mg(r+h) (B) mgr

(C) mg(h+r) (D) mg2r


space for rough work

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Corp. off. : FIITJEE House 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi – 16. Ph : 46106000/10/13/15, Toll Free No. 1800114242.
Fax : 011-26513942, Web:www.fiitjee.com
MONTHLY ASSESSMENT TEST (IIT-2019)

4. A bubble of radius r is made of soap solution at the end of a long capillary tube with its other end
closed. When the closed end is opened, the bubble collapses in time t0. Estimate the time taken for
a bubble of radius ηr to collapse under the following assumptions:
(i) that the air flow inside capillary is laminar
(ii) the process is sufficiently slow so that we can regard the process as a quasi-static one and can
disregard the effects of viscosity of the soap solution and the time required for liquid in the wall
of the bubble to readjust its shape.
3 1
(A)  2 t0 (B)  2 t0
5 7
(C)  2 t0 (D)  2 t0

5. A non-uniform cylinder of mass m, length l and radius r is having its centre at a distance of l/4
from the centre on its axis. The cylinder is kept in a liquid of uniform density ρ. The moment of
inertia of the cylinder about its COM is I. The angular acceleration of point A relative to point B
just after release from shown position is

 gl 2 r 2  gl 2 r 2
(A) (B)
I 4I
 gl 2 r 2 3 gl r 2 2
(C) (D)
2I 4I

6. The figure shows a semi cylindrical gate pivoted at the point O completely surrounded by a
stationary liquid of density ρ on the left. A force F is applied at the bottom end as shown to keep
the gate in equilibrium. The magnitude of this force F is
9  gR 2 3 gR 2
(A) (B)
2 2
(C)  gR 2 (D) none of these

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Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Corp. off. : FIITJEE House 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi – 16. Ph : 46106000/10/13/15, Toll Free No. 1800114242.
Fax : 011-26513942, Web:www.fiitjee.com
MONTHLY ASSESSMENT TEST (IIT-2019)

7. A rectangular container of dimensions 3mX3√3mX1m(inside depth)


as shown is sliding down smoothly on an inclined plane of angle of 3m
inclination 300, holding the maximum possible volume of water. The 3 3m
container is now made to come to a gradual rest very slowly, to avoid
3m
unnecessary spillage. The percentage of water that still remains inside 30o
now is

(A) 100% (B) 50%


(C) 45% (D) 75%

8. Two identical cylindrical containers connected by a thin tube near their


bottoms contain a little water. When an ice block of volume 100cm3 is A
B
gently put inside container A, it gets half submerged inside the water.
How much water will flow through the connecting tube in the process
of melting of ice cube? Assume density of ice as 900kg/m3 and water as
1000kg/m3.

(A) no water flows (B) 45g


(C)50g (D) 20g
space for rough work

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Corp. off. : FIITJEE House 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi – 16. Ph : 46106000/10/13/15, Toll Free No. 1800114242.
Fax : 011-26513942, Web:www.fiitjee.com
MONTHLY ASSESSMENT TEST (IIT-2019)

(Multi Correct Choice Type)


This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.

9. A container contains three liquids as shown in the figure. The specific


gravity of liquid 1 and liquid 2 are 0.8 and 1.2 respectively. There is a small
hole of area 10-6m2 at point P. initially the hole is closed. The cross sectional
area of the container is 50cm2. Assume all liquids are ideal and neglect any
friction between liquids and container. Take g=9.8m/s2 and h=28cm.

(A) The value of h2/h1 is 40/7


(B) The value of h2/h1/ is 40/21
(C) The speed of water efflux just after opening of hole at P is 3.92m/s
(D) The speed of water efflux just after opening of hole at P is 1.96m/s

10. A spherical tank with 1.2 m radius is half filled with oil of relative density 0.8. It is given a
horizontal acceleration of 10m/s2. Assume g as 10m/s2.
(A) The free surface of the liquid will be a plane surface making an angle of 450 with horizontal
(B) The free surface will assume a bulge due to the sphericity of vessel and have a mean deflection
angle of 450
9600
(C) The maximum gauge pressure on the surface of sphere is N/m2
2
(D) The maximum gauge pressure on the surface of sphere is 9600 2 N/m2
space for rough work

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Corp. off. : FIITJEE House 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi – 16. Ph : 46106000/10/13/15, Toll Free No. 1800114242.
Fax : 011-26513942, Web:www.fiitjee.com
MONTHLY ASSESSMENT TEST (IIT-2019)

11. A specially designed container has its bottom inclined at an angle θ and a hemispherical dent of
radius r is also made at the centre of the bottom as shown. A liquid of density ρ is filled in the
container to a height h above the highest point of the dent.

2r

(A) The magnitude of pressure force on dent is


1
 2 r 3  g 2  2 r 3  g  2
    3   
2
   r 2
 g ( h  r )  2  r 2
 g ( h  r ) cos 
 3    
(B) The magnitude of pressure force on dent is
1
 2 r 3  g 2  2 r 3  g  2
    3   
2
   r 2
 g ( h  r )  2  r 2
 g ( h  r ) cos 
 3    
(C) The net force may not necessarily pass through the centroid of the hemispherical dent
(D) The net force must necessarily pass through the centroid of the hemispherical dent

12. A liquid is kept in static equilibrium in a cylindrical container upto a


certain height h as shown in figure. Now, its made to rotate with a
gradually increasing angular velocity about the central axis of container.
Pick the correct alternatives regarding the motion of free surface. H
h
(A) For H=3h/2, the liquid will reach the topmost surface before
touching bottom
(B) For H=4h/3, the liquid will touch topmost surface before touching
bottom
(C) For H=21h/10, the liquid will touch bottom before reaching
topmost surface
(D) For H=5h/2, the liquid touches bottom and top simultaneously
space for rough work

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Corp. off. : FIITJEE House 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi – 16. Ph : 46106000/10/13/15, Toll Free No. 1800114242.
Fax : 011-26513942, Web:www.fiitjee.com
MONTHLY ASSESSMENT TEST (IIT-2019)

PART – B
(Matrix Match Type)

1. A cubical box is completely filled with mass m of a liquid and is E F


given horizontal acceleration a as shown match the force due
to fluid pressure on the faces of the cube with their appropriate A B
values (assume zero pressure at minimum pressure). a

G H

Column – I Column – II
(A) force on face ABFE ma
(P)
2
(B) force on face BFHD mg
(Q)
2
(C) force on face ACGE ma mg
(R) +
2 2
(D) force on face CGHD ma
(S) + mg
2

space for rough work

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Corp. off. : FIITJEE House 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi – 16. Ph : 46106000/10/13/15, Toll Free No. 1800114242.
Fax : 011-26513942, Web:www.fiitjee.com
MONTHLY ASSESSMENT TEST (IIT-2019)

2. A cuboid is filled with liquid of density 2 upto height h and with B


liquid of density 1, also upto height h as shown. A

h 1 D
C
2
h F
t
E

Column – I Column – II
(A) Force on face ABCD due to liquid of density 1 (P) zero
(B) Force on face ABCD due to liquid of density 2  gh 2 
(Q) 1
2
(C) Force on face CDEF due to liquid of density 1 (R) 1gh 2

(D) Force on face CDEF due to liquid of density 2   gh 


(S) 1gh  2  h
 2 

(T) 101gh 2 2

PART – C
(Numerical Based)
This section contains 06 multiple choice questions. The answer to each question is a single digit integer,
ranging from 0 to 9 (both inclusive)

1. A cube with a mass m = 20g wettable by water floats on the surface of water. Each face of the cube a is
30cm long. If the distance between the lower face of the cube and the surface of the water is represented
X
as (in mm. approx.), then x = ?
10
2
[S.T of water = 70 dyn/cm, g = 10 m/sec , assume angle of contact with water is zero.]

2. A piston of 20 cm diameter and 20cm long moves down in a cylinder of diameter 20.0628cm. The oil filling
the annular space has a viscosity of 10 poise and the weight of piston is 1kg. If the speed is x/10 cm s 1
2
with which the piston slides down. Then x/5 is [g = 1000 cm/sec ]
space for rough work

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Corp. off. : FIITJEE House 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi – 16. Ph : 46106000/10/13/15, Toll Free No. 1800114242.
Fax : 011-26513942, Web:www.fiitjee.com
MONTHLY ASSESSMENT TEST (IIT-2019)

3. Length of horizontal arm of a uniform cross-section U-section


U-tube is 1 = 21 cm and ends of both of the vertical arms are
2
open to surrounding of pressure 10500 N/m . A liquid of
density  = 103 kg/m3 is poured into the tube such that liquid
just fills the horizontal part of the tube. Now one of the open
ends is sealed and the tube is then rotated about a vertical 6cm
axis passing through the other vertical arm with angular
velocity o = 10 rad/sec. If length of each vertical arm be a =
6cm. Calculate the length of air column in the sealed arm in
2
cm. [g = 10 m/sec ]
21cm

4. A vessel with a symmetrical hole in its


bottom is fastened on a cart. The mass of
the vessel and the cart is 1.5 kg. With what L
force F (in  10 N) should the cart be pulled
2

so that the maximum amount of water b


remains in the vessel. The dimensions of the
vessel are as shown in the figure. Given that
b = 50cm, c= 10cm, area of base A = 40 C
2 2
cm , L = 20cm, g = 10m/s . F

5. A solid cylinder of height h and mass m is floating in a liquid of density 


2 h/4
as shown in the figure. Find the acceleration of the vessel (in m/s )
containing liquid for which the relative downward acceleration of the
completely immersed cylinder w.r.t vessel becomes equal to one-third of m
2
that of the vessel. (Take g = 10m/s )

6. A wooden plank of length 1m and uniform cross section is hinged at


one end to the bottom of a tank as shown in the figure. The tank is
filled with water up to a height of 0.5m. the specific gravity of the
plank is 0.5. If the angle  by the inclination of that the plank is 0.5. If
the angle  by the inclination of that the plank makes with the vertical
in the equilibrium position (exclude the case  = 0). Find the value of 0.5 m 
1
.
cos 2 
space for rough work

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Corp. off. : FIITJEE House 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi – 16. Ph : 46106000/10/13/15, Toll Free No. 1800114242.
Fax : 011-26513942, Web:www.fiitjee.com
MONTHLY ASSESSMENT TEST (IIT-2019)

Section – II (Chemistry)
PART – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

1. One mole of an ideal gas initially at a pressure of 2.0 bar and a temperature of 300K is taken to a
P
final pressure of 4.0 bar by reversible path defined by = constant (Cv =12.5J mol1k1 and it is
V
independent of temperature ) which of the following is incorrect.
(A) The final temperature is 1200K (B) Heat interaction is 14.99kJ
(C) Work done by the gas is 450R (D) E = 11.2 kJ

 5 
2. One mole of an ideal gas  c v, m  R  at 300K and 5atm is expanded adiabatically to a final
 2 
pressure of 2atm against a constant pressure of 2 atm. The final temperature of the gas is
35 3
(A) T1 (B) T1
29 5
5 29
(C) T1 (D) T1
3 35

3. PV plot for two ideal gases during adiabatic process are given in the figure. Plot A and plot B
should not represent the gases respectively are.

A
B

V
(A) He and H2 (B) H2 and He
(C) SO3 and CO2 (D) N2 and Ar

4. 10 g of ice at 0oC is added to 20g of water at 90oC in a thermally insulated flask of negligible heat
capacity. The heat of fusion of ice is 6kJ/mol. Then Ssystem (JK1) is
[Cp = 75.42 JK1 mol1, log(306) = 2.485, log(273) = 2.436 log (363) = 2.559 ]
(A) 4.9 (B) 2.7
(C) 15.8 (D) 4.9
space for rough work

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Corp. off. : FIITJEE House 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi – 16. Ph : 46106000/10/13/15, Toll Free No. 1800114242.
Fax : 011-26513942, Web:www.fiitjee.com
MONTHLY ASSESSMENT TEST (IIT-2019)

5. The normal boiling point of liquid ‘X’ is 400 K. Which of the following is incorrect about the
process X () 
 X (g )
(A) G  0 at 400K and 1atm (B) G  ve at 400K and 0.1atm
(C) G  ve at 400K and 2atm (D) G  ve at 410K and 1atm

1atm
6. A () A(g ) ; H vapourisation  460.6 Cal/mol and boiling point is 50K. The boiling point
of
liquid at 10atm is
(A) 150K (B) 75K
(C) 100K (D) 500K

7. Which of the following is incorrect


(A) Graphite has higher electrical conductivity than diamond
(B) Graphite has higher CC bond order than diamond
(C) Molten cryolite is added to alumina in the extraction of ‘Al’ for increasing electrical
conductivity and melting point of alumina
(D) AlCl3 exists as dimer but not AlF3

8. Which of the following compound is used to stop the growth of silicones at any stage
(A) (CH3)3SiOH (B) (CH3)2Si(OH)2
(C) (CH3)Si(OH)3 (D) (CH3)4Si
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Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Corp. off. : FIITJEE House 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi – 16. Ph : 46106000/10/13/15, Toll Free No. 1800114242.
Fax : 011-26513942, Web:www.fiitjee.com
MONTHLY ASSESSMENT TEST (IIT-2019)

(Multi Correct Choice Type)


This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.

9. Consider an ideal gas contained in a cylinder and separated by frictionless adiabatic piston into
two sections ' A' and ' B' . Section B is in contact with a water bath that maintains it at constant
temperature. Initially TA  TB  300K , VA  VB  2.0 L and n A  n B  2.0 mole . Heat is
supplied in section ' A' and the gas expands, moving the piston to the right i.e, Compressing
section ' B' until the final volume in section ' B' is 1.0L. [C v, m  20JK 1mol 1 ,
log10 (3)  0.4771, log10 (2)  0.3010]
Which of the following is/ are correct
(A) ' Q' in the section ' B' is  3.45kJ
(B) ' Q' in the section ' A' is  27.45kJ
(C) 'S' of surroundings is  35.35 Jk 1
 q system
(D) 'S' of surrounding in this process is determined by the equation Ssurrounding 
T

10. Which of the following statement(s) is/ are correct


(A) Heat capacity of CO 2 increases with temperature but heat capacity of ' He' remains constant
(B) In reversible adiabatic expansion of different gases, If initial and final volumes in each case is
same then WHe  WH2  WNH3
(C) Entropy can be created but not destroyed
(D) At a given temperature internal energy of ' He' is greater than O 3
space for rough work

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Corp. off. : FIITJEE House 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi – 16. Ph : 46106000/10/13/15, Toll Free No. 1800114242.
Fax : 011-26513942, Web:www.fiitjee.com
MONTHLY ASSESSMENT TEST (IIT-2019)

11. Which of the following statement(s) is / are correct


(A) In Borazine, nitrogen is better   acceptor than   donor
(B) Borazine is the inorganic benzene due to its similar chemical properties with benzene
(C) Unsymmetrical cleavage of B2H6 generates B3N3H6 at a certain temperature when heated with
NH3
(D) Due to symmetrical cleavage of B2H6 gives H3PBH3 with phosphine

12. Which of the following is/ are correct


H2 O
(A) AlN (P) + (Q)

coke NaOH
(R) (X) + (S) (Q)
 NaNO2
Cl2 NaOH
(B) (S) (T) (U)
(dry)

Then ‘U’ is soluble in excess of NH4OH


(C) SnO and SnO2 are amphoteric oxides, forms SnO 22 and SnO 32  ions respectively in alkali
(D) SrC2 is an acetylide but B4C is a methanide
space for rough work

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MONTHLY ASSESSMENT TEST (IIT-2019)

PART – B
(Matrix Match Type)

1. Match the following column-I and column-II


Column-I Column-II
(A) Melting of solids at normal melting points (P) Suniv  0
(B) Effusion of a gas from gas cylinder (Q) G  0
(C) Freezing point of water at 0oC and 2.0 atm (R) Ssys  0
(D) Vaporization of H 2O() at 373 K and 0.9 (S) Ssur  0
atm
(T) G  ve

2. Match the following column-I and column-II


Column-I Column-II
(A) coke
( Z) LiH
(P) ' Y' is B 2 H 6
B2 O3  
 X 
(Y)  LiBF4

(B)  (Q) ' Q' is BN
(Y)  NH3 
  B3 N 3 H 6  H 2
(C)  (R)
Boron + (R) 
(Q) 
 Na 2 B4 O 7  NH 4 Cl ' R ' is N 2
(D) NH3  F2 
(R )  (W) (S) ' W' is HF
(T) ' Z' is F2
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MONTHLY ASSESSMENT TEST (IIT-2019)

PART – C
(Numerical Based)
This section contains 06 multiple choice questions. The answer to each question is a single digit integer,
ranging from 0 to 9 (both inclusive)

1. About 1 dm3 gastric juice are produced per day in the human body from other body fluids such as
blood, whose pH is 7.6021 at 53oC. Calculate the minimum work (in kJ) required to produce 1 dm3
gastric juice whose pH may be taken as unity. [ log(4) = 0.6021].

2. When a current of ' X' ampere from a 20.9 V battery is used for 4.0 sec to heat 100g water, its
temperature increased by 1oC. Heat capacity of water is 4.18Jk 1g 1 . If all the electrical energy is
converted into thermal energy, then the value of ' x ' is

3. B5H9 acts an excellent rocket fuel because of the enormous amount of energy released when this
compound burns as 2B5 H 9 (g)  12O 2 (g)   5B2 O3(s)  9H 2 O (g)
If 0.1 g of this compound is treated with excess of oxygen in a bomb calorimeter with heat
capacity of 0.92kJ/oC then the temperature of 852 g of water present in the calorimeter increases
by 1.57oC. If the molar enthalpy of combustion of B5H9(g) is  4.5 10 x kJ / mol , then the value of
‘x’ is

4. One mole of an ideal gas Cp= 4R at 300K is expanded adiabatically to ‘n’ times to the original
volume. What is the value of ‘n’ if temperature falls by 150o

5. How many of the following statement(s) is/are correct


(1) ‘Si’ forms diamond type allotropy but not graphite type allotropy
(2) Carbon forms more stable complexes than silicon
(3) Borate salt forms white fumes after heating with conc. H2SO4, but forms white precipitate
with conc. HCl
Ca (OH)2
dilHCl
(4) Salt 
 colourless gas   white turbidity
Solution
Then the salt must be carbonate.

(5) Alkali metal bicarbonates are less soluble than those carbonates due to intermolecular
hydrogen bonds between bicarbonate ion
(6) I2O5 is used in the quantitative estimation of the blue gas
(7) BF3 is completely hydrolysed in water due to formation of BF4 ion
(8) H3BO3 is a 3D polymer due to hydrogen bonds
(9) Aqueous solution of Borax acts as buffer

6. A white coloured inorganic salt gives the following reactions


(1) It is soluble in H2O and the solution has sweet taste. The solution forms black ppt with H2S
(2) The salt when heated gives acetone and a yellow coloured residue which is used during
paiting
(3) The solution of the salt gives a white ppt. with HCl which is soluble in hot water.
(4) When the yellow coloured residue dissolves in excess of NaOH solution then forms
Na X MOy .
The value of (X+Y) is ………..
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MONTHLY ASSESSMENT TEST (IIT-2019)

Section – III (Mathematics)


PART – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

1. Let ao, a1, a2 ……………., an be a sequence of numbers satisfying (3  an+1). (6 + an) = 18 and ao = 3. If

 a i   2n   n  3 then    is
n
1 1

i 0
(A) 3 (B) 4
(C) 5 (D) 7

511
 3 K 2  3 KK  1  3 K  12 is
1
2. The value of
K 1
1 1
(A) (B)
3 511
(C) 3 (D) 7

3. The number of points on the line x + 2y = 5 from where the angle between the tangents drawn from it to the
x 2 y2
hyperbola   1 are at right angle is
9 4
(A) 0 (B) 1
(C) 2 (D) Infinite

x 2 y2
  1 in the
2 2
4. Tangents are drawn at the point of intersection P of ellipse x + 2y = 50 and hyperbola
16 9
first quadrant. The area of the circle passing through point P which cuts the intercept of 2 unit length each
from these tangents is

(A) SQ. unit (B) 2 SQ. unit
3 3
4
(C) 3 3  SQ units (D) SQ. unit
3
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MONTHLY ASSESSMENT TEST (IIT-2019)

x2 y2
  1 cuts the circle x + y = a at the points
2 2 2
5. If the tangent at the point P(h, k) on the hyperbola
2 2
a b
1 1
P1(x1, y1) and P2(x2, y2) then  is equal to
y1 y 2
2
(A) (B) 2h
h
2
(C) (D) 2k
k

x 2 y2
6. Tangents drawn from the point (6, 5) to the hyperbola   1 touch the hyperbola in
9 4
st th st nd
(A) 1 and 4 quadrants (B) 1 and 2 quadrants
rd th st nd rd th
(C) 3 and 4 quadrants (D) 1 , 2 , 3 and 4 quadrants

7. An ellipse and a hyperbola have their principal axes along the coordinate axes and have foci separated by a
distance of 2 13 of each individual. The difference of their focal semi-axes is equal to 4. If the ratio of their
eccentricities is 3:7, then the absolute difference of square of their radii of director circle is
(A) 16 (B) 20
(C) 75 (D) 80

k
r  m!   
 n  m
n k 
8. If m, n, r, k are non negative integers and   
m! k! r 1 r  2 
m 0
Then the value of ‘’ using induction or otherwise will be
(A) r  k  1 ! (B) n  k !
(C) n  r  k  1 ! (D) n  r  k  !
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MONTHLY ASSESSMENT TEST (IIT-2019)

(Multi Correct Choice Type)


This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.

 
m2n
  3m n.3m  m.3n  = q
p
9. If (m, n are natural numbers)
m 1 n 1
Where p and q are relatively prime then
(A) p + q = 41 (B) p  q  23
(C) 3p < q (D) q is divisible by 2

x2 y2
10. A tangent is drawn at any point on the hyperbola 
 1 . If this tangent is intersected by the tangents
a 2 b2
at the vertices at points P and Q then which of the following statement(s) is/are true?
(S, S are the foci of the hyperbola)

(A) S, S, P and Q are concyclic


4
PQ2
2 2 2 2
(B) PS + PS + QS + QS <
3
(C) S, S, P and Q forms a rhombus

(D) S, S, P and Q forms a parallelogram such that <PSQ + <PSQ =
2

11. An incident ray y = 3 coming parallel from negative x-axis strikes the curve x = 1  y 2 and gets reflected.
The reflected ray will pass through point(s)
(A) (0, 9 3 ) (B) ( 2 , 0)
3
(C) (4, 3 3 + 6) (D) ( , 3 3 )
2

12. If a, b, c  N such that a(7, 16) and a, b, c are in harmonic progression as well as b, a, (a + c), …………
are in geometric progression then which of the following statement(s) is/are correct?
(A) Number of integral terms in G.P will be 6
(B) Number of even integral terms in G.P will be 3
(C) b < ac
865
(D) The harmonic mean of first four terms in G.P is .
64
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MONTHLY ASSESSMENT TEST (IIT-2019)

PART – B
(Matrix Match Type)

1. Match the following column :

Column – I Column – II
(A) If x, y, z  R+, x > 3 and x + y +z = 60 then the (P) 1 + 3
1024

maximum value of (x  3) (y + 1) (z + 5) is
(B) If x, y, z  R+, x > 3 and x + y +z = 60 then the (Q) 2160
maximum value of (x  3) (2y + 1) (3z + 5) will be
(C) If x, y, z  R+ and x+ y +z = 60 then the (R) 213

x y z
1

4 9

minimum value of     6x 2  3y 2  2z 2 will be


(D) The sequence {an} is defined by formula ao = 4
(S)
3553
and an+1 = a 2n  2a n  2 (n  0, n I) then a10 will be 33  6 2
(T) an even integer

2. Consider the hyperbola xy = 10!. Let Ti and Ti (i = 1, 2, 3 …… n) be the feet of perpendiculars
drawn from foci S1 and S2 respectively on the tangents to the hyperbola at all ‘n’ points Pi
(i = 1, 2, …… n) on the curve with integral coordinates.
Also Let Mi and Mi (i = 1, 2, ………. n) be the feet of perpendiculars from points Pi (i = 1, 2,
……… n) with integral coordinates on the pair of asymptotes. Now match the following.

Column – I Column – II
n (P) 2040  10!
(A) S1Ti  S2Ti ' 
i 1

(B) Sum of areas of all the ‘n’ triangles made by pair (Q) 540  10!
of asymptotes and tangent at integral point =
n (R) 1080  10!
(C)  Pi M i  Pi mi ' 
i 1
(D) The sum of abscissae and ordinates of all ‘n’ (S) 4020  10!
integral points on the hyperbola is
(T) an even number

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MONTHLY ASSESSMENT TEST (IIT-2019)

PART – C
(Numerical Based)
This section contains 06 multiple choice questions. The answer to each question is a single digit integer,
ranging from 0 to 9 (both inclusive)

2 2 20
 1  1
 ai
1
1. If an = 1  1    1  1   , n  1 then the value of is
 n  n
i 1
a3 b 1 c p
Let a, b, c R . If the least value of  
+
2. can be expressed as (where p and q are relatively
4b 2 2a q
8c
prime) then p + q is

The tangent at point P (4, 3 3  1 ) to the hyperbola 9x  y  36x + 2y + 26 = 0 meets the asymptotes at A
2 2
3.
and B whose abscissae are  and  then  +  is equal

 a 4  32b 4  81c 4 
If a, b, c R such that 2ab c = 1 then the least value of   is
+ 2
4.
 3 
 

3 x  C , C  R cuts the hyperbola (same branch) 2x + 12xy  7y  16x + 2y  3 = 0 at


2 2
5. If the line y =
 PQ' PQ 
points P, P and the asymptotes at Q, Q then the value of   is
 P ' Q P ' Q' 
([.] represents greatest integer function)

x2 y2
6. If the locus of perpendicular from centre upon normal to the hyperbola  1 is
a2 b2

x 2  y2   xa22  by22   a 2  b2  then ( +  + ) equals


 
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FIITJEE MONTHLY ASSESSMENT TEST
MONTHLY PHYSICS, CHEMISTRY & MATHEMATICS
ASSESSMENT

CM – TEST-79 CODE: 105458


ANSWERS
PHYSICS [PART I] CHEMISTRY [PART II] MATHEMATICS [PART III]
Q. CONCEPT Q. Q. CONCEPT
ANSWER ANSWER CONCEPT CODE ANSWER
NO. CODE NO. NO. CODE
C111902 &
1 C P111026 1 1 C M110518
(B) C111903
2 A P111014 2 (D) C111902 2 D M110509

3 B P111014 3 (A) C111902 3 B M111110

4 D P111030 4 (B) C111906 4 B M111106


5 B P111015 5 (C) C111907 5 C M111106
6 D P111015 6 (C) C111903 6 C M111110
P111007
7 B 7
(C) C113207 7 D M111103
P111008
8 D P111005 8 (A) C113209 8 A M111801

9 B,C P111010 9 (A,B,C) C111901&C111906 9 A, B, C, D M110518

10 A,D P111008 10 (A,C) C111903&C111906 10 A M111114

11 B,C P111014 11 (A,C,D) C113206 11 A, D M111119


12 A,B,C P111008 12 (A,C) C113208 12 B, C M110513
(A)P, Q, M110514,
A  P; R, S A  R; M110517
B  Q; B  S;
1 P111008 1 (B)R, S C111906&C111907 1
C  R; C  Q, T;
D  S (C) T D  P, T
(D) R, S
A  Q; (A) P,T M111130
A  R, T;
B  P;
(B) P B  R, T;
2 C  R; P111014 2 2
D  (C) Q,R C  Q, T;
(D) R,S D T
S C113206
1 3 P111025 1 1 7 M110518
4 C111902
2 5 P111009 2 2 9 M110514
5 C111903
3 5 P111008 3 3 8 M111130
3 C111909
4 1 P111008 4 4 8 M110514
8 C111903
5 P111019 5
5 5 C113206&C113207 5 2 M111130
6 2 P111015 6 6 3 M111107
4 C113206

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Hints & Solutions
Physics
SINGLE OPTION CORRECT:
1. The soap film will disappear in a circular symmetric manner from the centre of the circular wire. Apply energy
concept(loss of surface energy=gain of elemental film’s KE)

2. Apply concept of equilibrium of wedge under limiting friction conditions

3. Consider any small element of the spherical object. No work is to be done on it as long as its in liquid of density 2.
Calculate work to be done on it when its in upper fluid.

4. Apply bernoulli’s equation for laminar fluid flow inside the pipe and excess pressure concept for soap bubble.

5. Apply torque equations about COM to find actual accelerations of A and B. Then apply relative acceleration concept.

6. Apply rotational torque equations

7. When sliding down freely on incline, free surface will be parallel to incline. When stopped, the free surface will be
horizontal

8. Total ice block isn’t submerged initially. After melting, apply mass conservation equations

9. Simple bernoullis equation concept

10. Free surface will be plane surface because of translational motion. Go perpendicular to free surface for maximum
pressure gradient

11. Consider a water hemisphere at bottom of tank with an extremely thin film of water below it. It will be in equilibrium.
From there we get force on the curved surface

12. The height that the liquid rises up on sides will be the same as the depression at mid point by volume conservation
equations(can you prove it?)

Matrix-Match Type:

1. Apply pressure difference concept due to horizontal acceleration

2. Simple pressure force concept

Integer Type:
1. Surface tension force and self weight is balanced by the buoyant force of liquid

2. Apply equation of continuity

3. Calculate pressure difference along the horizontal length of tube because of rotational effect of the tube

4. For retaining maximum water, there should not be any water present above the orifice of the base of container

5. Apply concept of buoyant force for accelerated fluids

6. Apply rotational equilibrium concept by equating torque about the hinge point

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Chemistry
Single option correct:

1. Hints / Solution: (B) Stage 1 : P1  2.0 bar , T1  300 K


Stage 2 : P2  4.0 bar , T2  ?
P
Given  k  P1  k.V1 & P2  k. V2
V
PV P V
Also 1 1  2 2
T1 T2
P  P 
P1  1  P2  2 
    
k k
T1 T2
From T2  1200K
E  nC v T  112.5(1200  300)  11.2kJ
v2 v2
w    P.dV  k  V.dV
v1 v1
P1V1  P2 V2

2
RT1  RT2

2
=  450R
 q  E  (w)  14.99kJ

2. Hints / Solution: (D) Given process is Irreversible adiabatic expansion


Q0
 U  W
T T 
nC v T2  T1    Pex  2  1  nR
 P2 P1 
 P .R   P .R 
T2 C v  ex   T1 C v  ex 
 P2   P1 
 P .R 
 T2 C v  R   T1 C v  2   Pex  P2
 P1 
29
 T2  T1
35

3. Hints / Solution: (A) Slope of reversible adiabatic process


dP P
  .
dV V
 | slope |  ||

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4. Hints / Solution: (B) Let final temperature Tf  T

H2O(s) step I step II


H2O(l) H2O(l)
10g ,
q1 10g , q2 10g ,
0 °C
0 °C at 'T'

H2O(l) step III


H2O(l)
20 g q3 20 g
at 90oC at 90oC
q1  n.H f   3333.3J
q 2  nCp T = 42 (T-273)
q 3  nCpT = 84 (t-363)
In adiabatic process q net  0
 T  306K
 H f 3333.3 1
 S1   JK
T 273
T 
S2  nCp n  2   4.78JK 1
 T1 

S3  14.3JK 1
Ssystem  S1  S2  S3
= 2.68 JK 1

5. Hints / Solution: (C) If pressure increases then boiling point of liquid also increases

p  H 1 1
6. Hints / Solution: (C) log 2     
 p1  2.303R  T1 T2 

7. Hints / Solution: (C) Na 3 AlF6  is added to Al2 O3 for decreasing the melting point and increasing
conductivity

8. Hints / Solution: (A) R 3Si  OH forms dimer only

Multiple Correct Option:


9. Hints / Solution: (A,B,C) Section A Section B
Initial Initial
n A  2.0 n B  2.0
VA  2.0L VB  2.0L
TA  300K TB  300K
(2)(R )(300)
PA  PB  300R
2
= 300R
Final Final
n A  2.0 n B  2.0

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VA  3.0L VB  1.0L
PA  600R p A  p B  TB  300K
TA  900K PB  600R

 w A   WB
1
 w B  2.303  2  8.314  300  log 
2
 3.45kJ
WA  3.45kJ
 q B  UB   w B 
 0  3.45
 q B  3.45kJ
q A  UA   w A 
 nC v T   w A 
 27.45kJ
 q system
Ssur 
T
But we cannot determine by this formula because we don’t know the temperature of
Heat source. But given process is reversible
 Suni  0
 Ssur  Ssystem

10. Hints / Solution: (A,C) # Polyatomic gas has both rotational and vibrational degree of freedom at high
Temperature. But monoatomic gas has only translational degree of freedom
# For adiabatic process
P2 V2  P1V1
W
 1
1
# 
|W|
# U
f
nRT  f = no of degree of freedom
2
11. Hints / Solution: (A,C,D) # Due to more E.N character of nitrogen, in Borazine nitrogen is better
  acceptor than  - donor
# Benzene and Borazine have different chemical properties
# With hard bases (NH3), B2H6 undergoes unsymmetrical cleavage
# With soft bases (PH3), B2H6 undergoes symmetrical cleavage

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12. Hints / Solution: (A,C)
H2 O
AlN Al(OH)3 + NH3
(P) (Q)


coke
Al2O3 Al + CO
(R)  (S) (X)

NaOH / NaNO2

NH 3
(Q)
dry NaOH
Al AlCl3 Al(OH)3
(S) Cl2 (T ) (U)

(U) is insoluble in NH4OH

NaOH
SnO Na 2SnO2
excess
NaOH Na 2SnO3
SnO2
excess

B4C is a covalent carbide

Matching Type:

1. Hints / Solution: ((A)P, Q, R, S (B)R, S (C) T, (D) R, S)


At equilibrium S universe= 0 and G  0
In the melting process Ssys  0 & Ssur  0
During effusion , randomness of the system increases
At 0o C , 2 atm freezing of water is non spontaneous
Vaporization of water at 373 K, 0.9 atm is spontaneous

2. Hints / Solution: ((A) P,T (B) P (C) Q,R (D) R,S)


LiH
B  F2 
 BF3 
 B2 H 6  LiBF4
(Z) (X) (Y)

B2 H 6  NH3  B3 N3H 6  H 2
(Y)
2B  N 2 
 2BN
(R) (Q)
NH3  F2 
 N 2  HF
(R ) ( W)

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Single integer type:

1. Hints / Solution: (4)


It is a slow process and hence change may be considered as reversible
v 
w  2.303nRT log 2 
 v1 
C   1
 2.303nRT log 1   v  
 C2   C
 4  10 8 
=  2.303  0.1  8.314  10 3  326 log 
 0.1 
 
=  4.0kJ

2. Hints / Solution: (5)


(X) (4) (20.9)  100  4.18 1
418
( X)  5
4  20.9
3. Hints / Solution: (3)
4.184  1.57  852
Heat absorbed by water 
1000
 5.596kJ
Heat absorbed by calorimeter  1.57  0.92  1.444kJ
Net heat given by B5H9  7.04kJ
0.1g B5H9 
 7.04 kJ
64gB 5H9 
 4505.6 kJ
 H o combustion of B5H9  4506kJ / mol
 4.5  103 kJ / mol
4. Hints / Solution: (8)

C p  4R ; C v  3R
   1.33
 1
 v2  T 
    1 
 V1   T2 
 1
 nv1   300 
    
 v1   150 
n 8

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5. Hints / Solution: (5)
# P  P bond is not formed between silicon atoms
# Due to lack of empty d- orbitals, carbon does not form complexes
# H3BO3 forms H- bonding with H2SO4 but H- bonding is not possible between
H3BO3 and HCl
# Sulphites also give same observation
# CO32  ions form H- bonds with H2O but HCO3 ions have intermolecular
H- bonds
# I 2O5  CO 
 I 2  CO2 I 2  Na 2S2O3 
 NaI  Na 2S4O6

# BF3 is partially hydrolysed due to formation of B F4 ion


BF3  H 2O B(OH)3 + HF
BF3+HF HBF4
# H3BO3 is a 2D sheet polymer due to hydrogen bonds
# Due to salt hydrolysis, aqueous solution of borax contains weak acid and its
conjugate base.

6. Hints / Solution: (4)


H2S PbS + CH3COOH
Pb(CH3COO)2
(black)

O
H3C C CH3 + PbCO3
(yellow)

HCl PbCl2 + CH3COOH


Pb(CH3COO)2
(White)

(partially soluble in cold 2HO, completely soluble in HOT 2HO)

NaOH
PbCO3 Na 2[Pb(OH)4] Na 2PbO2
(excess) -2H2O

X= 2 & Y=2

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MATHEMATICS
Single Option Correct:

1 2 1
1.  
a n 1 a n 3

2. a3  b3 = (a  b) (a2 + b2 + ab)

3. write equation of any tangent & passing through the point on line x + 2y = 5 & use m 1m2 = 1

4. Find equation of both tangents & tangents are perpendicular.

5. Write equation of tangent at P(h, k) & then make quadratic in y with equation of circle.

6. Check position of points with respect to hyperbola

7. Write equation of both ellipse & hyperbola then equation of director circle

8. Use induction and put k = 1

Multi Option Correct:


9. Put m in place of n and n in place of m and add

10. Write equation of tangent

11. Use properties of reflection

12. Apply condition of HP & GP

Matrix-Match Type:
1. Use AM, GM

2. Write factor of n!

Single Integer Type:


1. Rationalise an

2. Use AM, GM

3. Write equation of tangent and find point of intersection with asymptotes

4. Use AM, GM

5. Use PQ = PQ

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