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Jsa Jis R 1701-4
Jsa Jis R 1701-4
Jsa Jis R 1701-4
INDUSTRIAL
STANDARD
Translated and Published by
Japanese Standards Association
ICS 81.060.30
Reference number: JIS R 1701-4 : 2016 (E)
© JSA 2016
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or
utilized in any form or by any means, electronic or mechanical, including photocopying and
microfilm, without permission in writing from the publisher.
Printed in Japan
HT/AT
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Contents
Page
5 Test piece···················································································································· 3
6 Test methods·············································································································· 3
6.1 General··············································· ...................................................... ···················3
6.2 Pretreatment of test piece························································································3
6.3 Preparation for measurement······················································· ···························4
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9 Test report·················································································································· 6
Annex JA (informative) Comparison table between JIS and corresponding
International Standard ...................................................... ···8
(i)
Foreword
This translation has been made based on the original Japanese Industrial Standard
revised by the Minister of Economy, Trade and Industry through deliberations at the
Japanese Industrial Standards Committee as the result of proposal for revision of
Japanese Industrial Standard submitted by Japan Fine Ceramics Association (JFCA)!
National Institute of Advanced Industrial Science and Technology (AIST)!Japanese
Standards Association (JSA) with the draft being attached, based on the provision of
Article 12 Clause 1 of the Industrial Standardization Law applicable to the case of
revision by the provision of Article 14.
Consequently JIS R 1701-4: 2008 is replaced with this Standard.
This JIS document is protected by the Copyright Law.
Attention is drawn to the possibility that some parts of this Standard may conflict with
patent rights, applications for a patent after opening to the public or utility model rights.
The relevant Minister and the Japanese Industrial Standards Committee are not
responsible for identifying any of such patent rights, applications for a patent after
opening to the public or utility model rights.
JIS R 1701 series consists of the following five parts under the general title "Fine
ceramics (advanced ceramics, advanced technical ceramics)-Test method for air
purification performance of photocatalytic materials":
Part 1: Removal of nitric oxide
Part 2: Removal of acetaldehyde
Part 3: Removal of toluene
Part 4: Removal of formaldehyde
Part 5: Removal of methyl mercaptan
(ii)
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Introduction
This Japanese Industrial Standard has been prepared based on the first edition of
ISO 22197-4 published in 2013, by modifying some of the technical contents to ensure
consistency among JIS R 1701-1 to JIS R 1701-5 and JIS R 1751-1 to JIS R 1751-5
which have been established after the publication of ISO 22197-4.
Sidelines and dotted underlines represent the parts modified from the correspond-
ing International Standard. A list of modifications with the explanations is given in
AnnexJA.
1 Scope
This Standard specifies the method to test the removal performance of formaldehyde
(HeHO), among air purification performances, of the photocatalytic materials supported
on the surface of building materials and other products.
This Standard is mainly intended for photocatalysts which are effective in ultravio-
let (UV) region within a wavelength range of 300 nm to 380 nm, under solar radiation.
To the testing of formaldehyde removal performance under visible light, the method
given in JIS R 1751-4 shall be applied instead of the method specified in this Standard.
NOTE: The International Standard corresponding to this Standard and the sym-
bol of degree of correspondence are as follows.
ISO 22197-4: 2013 Fine ceramics (advanced ceramics, advanced technical
ceramics)-Test method for air-purification performance of semiconduct-
ing photocatalytic materials-Part 4: Removal of formaldehyde (MOD)
In addition, symbols which denote the degree of correspondence in the
contents between the relevant International Standard and JIS are IDT
(identical), MOD (modified), and NEQ (not equivalent) according to ISO/
lEe Guide 21-1.
2 Normative references
The following standards contain provisions which, through reference in this text, con-
stitute provisions of this Standard. The most recent editions of the standards (includ-
ing amendments) indicated below shall be applied.
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4 Test equipment
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specified in 4.1 of JIS R 1701-1. Since low concentrations of formaldehyde are to be
tested, the equipment shall be constructed with materials of low adsorption so that there
is minimum loss due to adsorption that may influence the measurement.
4.2 Test gas supply The test gas supply shall be in accordance with 4.2 of JIS R
1701-1. The test gas supply provides air polluted with formaldehyde at a predetermined
concentration, temperature and water-vapour concentration by using formaldehyde
mixed standard gas contained in a gas cylinder, and supplies it continuously to the
photoreactor. It consists of a mass-flow controller, a humidifier, gas mixers, etc.
Instead of standard gas in a gas cylinder, formaldehyde gas generated by a suitable
method may be used. In this case, however, it shall have been confirmed beforehand
that the method is capable of supplying a constant concentration of formaldehyde gas
during the test, and that impurities (e.g. methanol) are not contained in the generated
gas in such an amount as may influence the test results.
4.3 Photoreactor The photoreactor shall be in accordance with 4.3 of JIS R 1701-1.
4.4 Light source The light source shall be in accordance with 4.4 of JIS R 1701-1.
The distance between the light source and the photoreactor shall be adjusted so that the
UV irradiance at the test piece surface is 10.0 W/m 2 ± 0.5 W/m2 • A calibrated UV irra-
diance meter specified in JIS R 1709 shall be used for measurement of UV irradiance.
5 Test piece
The test piece shall be a flat or filter-type photocatalytic material ~~_._9__~~_~}~~__Il?:~
wide and ---------------------------------
99.0 mm ± 1.0 mm long. If there is a play inside the photo reactor, e.g. between
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the test piece and the auxiliary plate, the test piece shall be moved toward the upstream
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~~~_~? __~_~~_~_~J~~~~~})X_~~~!?:~__?r~_~~~~~~_?_~__~!?_~J~~~_~~_~~q~~?:~~:_ If flat test pieces are to
be tested, the thickness of the test piece shall ideally be less than 5 mm, in order to
minimise the photocatalytic contribution from the side faces and to facilitate the collec-
tion of washings. Thicker materials can be tested, provided that these test conditions
are satisfied. Test pieces with a thickness 5 mm or greater can be tested by a
photoreactor with a sufficient depth, in which case, however, the side faces of the test
piece shall be sealed before testing to avoid possible adsorption thereon. In the case of
filter-type test pieces, the test piece thickness shall be 20 mm or under.
-----------------------------
6 Test methods
6.1 General
The test for formaldehyde removal shall be carried out by following procedures given
in 6.2 to 6.5 and the quantity removed under light irradiation shall be measured. Fig-
ure 1 shows a typical trace of formaldehyde concentration in this process. In the case
where the formaldehyde removal quantity is excessively small and a more certain result
is demanded, the test conditions may be altered as described in clause 8.
S0- 1.2
Irradiation Irradiation
0-
~ / start V stop
.S 1.0
t;
ell
• 0 •
~
S 0.8
0
;j
"0
~ 0.6
~
.S
-.i-J
~ 0.4 0 0
0 0 0
~
<ll
U
~ o Outlet
8 0.2
o • Inlet
::c:
~ 0.0
-60 o 60 120 180 240 300 360
Time (min)
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The test piece may be dried by heating within a temperature range, at a maxi-
mum of 120°C, that does not cause physical and chemical changes to the test piece.
In either case, dryness is confirmed when a constant mass is reached. Record any
observations, such as the presence of sediment, and method used for drying.
b) Removal of organic matter Irradiate the test piece with UV lamp for 12 h or
longer but shorter than 24 h. The UV irradiance at the catalyst surface shall be
10 W/m 2 to 20 W/m 2 • The test piece shall be irradiated in zero-calibration gas or in
a clean airtight container. If contamination due to lipophilic property is expected,
the procedure in b) may be performed first, and then followed by the procedure in
a). If washing is expected to have adverse effect on the characteristics of the test
piece, the washing procedure in a) may be omitted.
6.4 Pretest
If the concentration of formaldehyde cannot be obtained instantaneously, the time
of the adsorption of formaldehyde reaching saturation in a dark condition cannot be con-
firmed during the test. For this reason, the following pretest shall be carried out. If
the concentration can be determined immediately, there is no need for the pretest.
After pretreatment of the test piece in 6.2 and preparation for the test in 6.3, intro-
duce the test gas into the photoreactor. Measure the formaldehyde concentration under
the dark condition for 90 min at the intervals of 15 min. The time of the dark condition
shall be the time when the concentration exceeds 90 % of the supply concentration for
the first time, and the concentration of the dark condition shall be the concentration at
that time. When the concentration of formaldehyde is still less than 90 % of the supply
concentration after 90 min, then this test method shall not apply.
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ing to Equation (3). The calculated value shall be rounded to two decimal places accord-
ing to JIS Z 8401.
The observed concentration of formaldehyde before water vapour correction shall be
used for calculation. For test gas flow rate J, the actually measured value converted to
the standard state of 0 °C and 101.3 kPa shall be used. When the removal percentage,
RF , is either below 5.0 % or more than 95.0 %, the removal percentage is calculated by
assigning 5.0 or 95.0 for R p , respectively, and expressed by attaching "below" or "more
than" to the obtained value.
For the test piece of removal percentage, R F , of below 5.0 %, the test conditions may
be altered in accordance with clause 8.
RF =
c -c
F,O F xl 00 ................................................................ (2)
CF,o
C Fo xf x 60
QF = RF X 100x 22.4 ............................................................. (3)
_~g_ ~_ ~ ~ _~}~~~)_
~~_~_~~ _\9__ ~9 ~ _
9 Test report
The test report shall include the following information.
a) General matters
1) Number of this Standard
2) Test date
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b) Testing establishment
1) Name and address of the testing establishment
2) N arne of the person in charge of the testing
c) Information on the test piece
1) Type, serial number, etc.
2) Material, shape and size
3) Process of selecting the test piece (e.g. sampling method)
4) Date of arrival of material at the testing establishment, date and time of removal
of material from the packaging, and date and time of preparation of test piece
d) Test results
1) Quantity of formaldehyde removed by the test piece during the last 1 h
2) Removal percentage of formaldehyde (optional)
e) Test conditions
1) Method of supplying formaldehyde
2) Supply concentration of formaldehyde, test gas flow rate, water-vapour concen-
tration, temperature
3) Whether the test method in clause 8 (alteration of test gas flow rate and number
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(1) Requirements in JIS (II) Inter- (III) Requirements in Interna- (IV) Classification and details of (V) Justification for the
national tional Standard technical deviation between JIS and technical deviation and
Standard the International Standard by clause future measures
number
No. and title Content No. of Content Classifi- Detail of technical
"'0
~ of clause clause cation by deviation
o~ clause
M
(1 1 Scope 1 Identical
~
M 2 Normative
U
references
t:d
~
3 Terms and 3 Identical
(1
definitions
o
~ - - 4 A list of symbols used Deletion Delete the list of sym- Change of the definition of
~ for calculation. Gas boIs. flow rate j will be sug-
S flow ratejis given on gested at the time of revi-
::r: Delete the provision of
~ dry-gas basis. dry-gas basis for flow sion of ISO. See 6.3 for
ratej(see 6.3). justification.
- - 5 Descri ption of the pur- Deletion Delete the description The description need not
pose and principle of of test purpose and be provided in the main
the test principle. text of the standard.
4.2 Test gas Test gas supply in ac- 6.2 The gas flow rate con- Alteration Delete the provision of Modification regarding
supply cordance with JIS R verted to standard state dry-gas basis (see 6.3). this matter will be sug-
1701-1. (0 °C, 101.3 kPa, and gested at the time of revi-
dry-gas basis). sion of ISO (see 6.3).
number ~
No. and title Content No. of Content Classifi- Detail of technical
l'V
of clause clause cation by deviation o
f-L
clause m
6.3 Prepara- The mass-flow control- 8.3 The mass-flow control- Alteration Add tolerance of Add tolerance of 5 %,
tion for mea- ler is set so that the ler is set so that the ± 0.15 L/min to the flow which is considered neces-
surement flow rate is 3.00 L/min flow rate is 3.0 L/min rate specification. Both sary. This results in the
±0.15 L/min (under the (under the standard JIS and ISO proce- difference of 1.6 % in
standard state of 0 °C, state of 0 °C, 101.3 kPa dures use flow rate water-vapour concentra-
101.3 kPa) and dry-gas basis) converted to standard tion, but since its influ-
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Errata for JIS (English edition) are printed in Standardization and Quality Conti'oJ, published
monthly by the Japanese Standards Association, and also provided to subscribers of JIS
(English edition) in Monthly InfOl'mation.