log C log C log C log C log C

pH Fe 3+ Fe(OH) 2+ Fe(OH)2 + Fe(OH)4 - Total Fe

0 4 1.84 -2.74 -19 4.00299432
0.5 2.5 0.84 -3.24 -18.5 2.50939966
1 1 -0.16 -3.74 -18 1.02905948 0
0 2
1.5 -0.5 -1.16 -4.24 -17.5 -0.41401121
2 -2 -2.16 -4.74 -17 -1.77117616
-2
2.5 -3.5 -3.16 -5.24 -16.5 -2.99404209
3 -5 -4.16 -5.74 -16 -4.09149998
3.5 -6.5 -5.16 -6.24 -15.5 -5.10735022 -4
4 -8 -6.16 -6.74 -15 -6.05364548
4.5 -9.5 -7.16 -7.24 -14.5 -6.89604816 -6
5 -11 -8.16 -7.74 -14 -7.59988825
5.5 -12.5 -9.16 -8.24 -13.5 -8.19067075
6 -14 -10.16 -8.74 -13 -8.72376943 -8

6.5 -15.5 -11.16 -9.24 -12.5 -9.23457377

7 -17 -12.16 -9.74 -12 -9.73598086 -10
7.5 -18.5 -13.16 -10.24 -11.5 -10.2162718
8 -20 -14.16 -10.74 -11 -10.5496904
-12
8.5 -21.5 -15.16 -11.24 -10.5 -10.4273855
9 -23 -16.16 -11.74 -10 -9.99216789
9.5 -24.5 -17.16 -12.24 -9.5 -9.49921042 -14
10 -26 -18.16 -12.74 -9 -8.99992098
10.5 -27.5 -19.16 -13.24 -8.5 -8.4999921
-16
11 -29 -20.16 -13.74 -8 -7.99999921
11.5 -30.5 -21.16 -14.24 -7.5 -7.49999992
12 -32 -22.16 -14.74 -7 -7 -18

12.5 -33.5 -23.16 -15.24 -6.5 -6.5

13 -35 -24.16 -15.74 -6 -6 -20
13.5 -36.5 -25.16 -16.24 -5.5 -5.5
14 -38 -26.16 -16.74 -5 -5
 Chart Title
0
0 2 4 6 8 10 12 14

-2

-4

-6

-8

-10

-12

-14

-16

-18

-20

Fe 3+ Fe(OH) 2+ Fe(OH)2 + Fe(OH)4 - Total Fe

 12 14

al Fe
pH log Fe log Fe(OH) 1+ log Fe(OH)3 - log Total Fe(OH)
0 13.5 4.6 -19.1 13.5000000005
0.5 12.5 4.1 -18.6 12.5000000017 C
1 11.5 3.6 -18.1 11.5000000055
-1
1.5 10.5 3.1 -17.6 10.5000000173 0 2 4 6
2 9.5 2.6 -17.1 9.50000005467
2.5 8.5 2.1 -16.6 8.5000001729 -2
3 7.5 1.6 -16.1 7.50000054674
3.5 6.5 1.1 -15.6 6.50000172895
4 5.5 0.6 -15.1 5.50000546741 -3

4.5 4.5 0.1 -14.6 4.50001728923

5 3.5 -0.4 -14.1 3.50005467099
-4
5.5 2.5 -0.9 -13.6 2.50017286134
6 1.5 -1.4 -13.1 1.50054640049
6.5 0.5 -1.9 -12.6 0.50172552503 -5
7 -0.5 -2.4 -12.1 -0.4945666858
7.5 -1.5 -2.9 -11.6 -1.4830457107
-6
8 -2.5 -3.4 -11.1 -2.448503057
8.5 -3.5 -3.9 -10.6 -3.3544595122
9 -4.5 -4.4 -10.1 -4.146097626 -7
9.5 -5.5 -4.9 -9.6 -4.8026702807
10 -6.5 -5.4 -9.1 -5.3667241109
10.5 -7.5 -5.9 -8.6 -5.8883812976 -8
11 -8.5 -6.4 -8.1 -6.3880508639
11.5 -9.5 -6.9 -7.6 -6.8200817602
-9
12 -10.5 -7.4 -7.1 -6.9234499802
12.5 -11.5 -7.9 -6.6 -6.5787563916
13 -12.5 -8.4 -6.1 -6.0978286358 -10
13.5 -13.5 -8.9 -5.6 -5.5997823862
14 -14.5 -9.4 -5.1 -5.0999782341 log Fe log Fe(OH) 1
 Chart Title

2 4 6 8 10 12 14

log Fe log Fe(OH) 1+ log Fe(OH)3 - log Total Fe(OH)

CO3 2- a2 H+
2.16E-20 2.16E-17 1 0 8.9655464442816 0.0655464442815
2.16E-19 2.16E-16 0.316227766
2.15999E-18 2.15999E-15 0.1
2.15997E-17 2.15997E-14 0.031622777
2.1599E-16 2.1599E-13 0.01
2.15969E-15 2.15969E-12 0.003162278
2.15903E-14 2.15903E-11 0.001
2.15693E-13 2.15693E-10 0.000316228
2.15032E-12 2.15032E-09 0.0001
2.12969E-11 2.12969E-08 3.162278E-05
2.06699E-10 2.06699E-07 1E-05
1.89091E-09 1.89091E-06 3.162278E-06
1.48963E-08 1.48963E-05 1E-06
8.91368E-08 8.91368E-05 3.162278E-07
3.92573E-07 0.00039257 1E-07
1.41622E-06 0.00141622 3.162278E-08
4.67371E-06 0.00467371 1E-08
1.48492E-05 0.01484919 3.162278E-09
4.57046E-05 0.04570461 1E-09
0.00013171 0.13170531 3.162278E-10
0.00032428 0.32427563 1E-10
0.00060283 0.60282575 3.162278E-11
0.00082758 0.82758304 1E-11
0.00093819 0.93819082 3.162278E-12
0.00097959 0.97959179 1E-12
0.00099346 0.99345504 3.162278E-13
0.00099792 0.997921 1E-13
0.00099934 0.99934163 3.162278E-14
0.00099979 0.99979171 1E-14
pH log Fe 2+ log Fe(OH) +
0.5 7.9655468668605 -0.4344531331395
1 6.9655482031699 -0.9344517968302
1.5 5.9655524289239 -1.4344475710761
2 4.9655657916611 -1.9344342083389
2.5 3.9656080456414 -2.4343919543586
3 2.9657416374162 -2.9342583625838
3.5 1.9661638215184 -3.4338361784816
4 0.9674961908672 -3.9325038091328
4.5 -0.0283171826409 -4.4283171826409
5 -1.0153373709358 -4.9153373709358
5.5 -1.9766718046727 -5.3766718046727
6 -2.8730792794739 -5.7730792794739
6.5 -3.6500571522083 -6.0500571522083
7 -4.2939205358521 -6.1939205358521
7.5 -4.8511312408293 -6.2511312408293
8 -5.3696613966176 -6.2696613966176
8.5 -5.8717027196243 -6.2717027196243
9 -6.3599600338546 -6.2599600338546
9.5 -6.8196032968258 -6.2196032968258
10 -7.2109143174941 -6.1109143174941
10.5 -7.4801917984469 -5.8801917984469
11 -7.6178115798523 -5.5178115798523
11.5 -7.6722911784302 -5.0722911784302
12 -7.6910451376512 -4.5910451376512
12.5 -7.6971482154843 -4.0971482154843
13 -7.6990961608011 -3.5990961608011
13.5 -7.6997139775744 -3.0997139775744
14 -7.6999095314044 -2.5999095314044

a2 = 1/ (H^2/Ka1/Ka2 + 1 + H/Ka2)
Ka1 4.5E-07
Ka2 4.8E-11
Ct (fixed) 0.001
log Fe(OH)3 - log Total FeCO3
-23.634453555719 8.9655464448283 Chart Title
-23.13445313314 7.9655468685895
0
-22.63445179683 6.9655482086373 0 2 4 6 8 10 12
-22.134447571076 5.9655524462135
-21.634434208339 4.9655658463356 -1
-21.134391954359 3.9656082185371
-20.634258362584 2.9657421841602
-2
-20.133836178482 1.9661655504725
-19.632503809133 0.9675016582764
-19.128317182641 -0.0282998934103 -3
-18.615337370936 -1.0152826999411
-18.076671804673 -1.9764989433317
-4
-17.473079279474 -2.8725328789811
-16.750057152208 -3.6483316271794
-15.893920535852 -4.288487221631 -5

-14.951131240829 -4.8341769515166
-13.969661396618 -5.3181644536234 -6
-12.971702719624 -5.7261622318407
-11.959960033855 -6.006057659883
-7
-10.919603296826 -6.1222735775068
-9.8109143174941 -6.0776384283756
-8.5801917984469 -5.8685730960259 -8
-7.2178115798523 -5.5058624437507
-5.7722911784302 -4.9923729385975
-9
-4.2910451376512 -4.1144951178099
-2.7971482154843 -2.7759046071008
-1.2990961608011 -1.2969247966035 -10
0.2002860224256 0.2005036362136
log Fe 2+ log Fe(OH) + log Fe(OH)3 - log Total FeCO3
1.7000904685956 1.7001122345081
itle

8 10 12 14

log Fe(OH)3 - log Total FeCO3

pH log Total FeC log Total Fe(OH)
0 8.96554644 13.5 Chart Title
0.5 7.96554687 12.5
1 6.96554821 11.5 0
0 2 4 6 8 10
1.5 5.96555245 10.5
2 4.96556585 9.50000005
2.5 3.96560822 8.50000017 -1

3 2.96574218 7.50000055
3.5 1.96616555 6.50000173
4 0.96750166 5.50000547 -2

4.5 -0.02829989 4.50001729

5 -1.0152827 3.50005467
5.5 -1.97649894 2.50017286 -3

6 -2.87253288 1.5005464
6.5 -3.64833163 0.50172553
-4
7 -4.28848722 -0.49456669
7.5 -4.83417695 -1.48304571
8 -5.31816445 -2.44850306
-5
8.5 -5.72616223 -3.35445951
9 -6.00605766 -4.14609763
9.5 -6.12227358 -4.80267028
-6
10 -6.07763843 -5.36672411
10.5 -5.8685731 -5.8883813
11 -5.50586244 -6.38805086
-7
11.5 -4.99237294 -6.82008176
12 -4.11449512 -6.92344998
12.5 -2.77590461 -6.57875639
-8
13 -1.2969248 -6.09782864
13.5 0.20050364 -5.59978239 log Total FeCO3 log Total Fe(OH)
14 1.70011223 -5.09997823
 Chart Title

6 8 10 12 14

otal FeCO3 log Total Fe(OH)