Page 1/23

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 21.09.2012 Version: 11 Revision: 21.09.2012

SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier
· Trade name: WINGSTAY® L
· Article number: WSLL
· CAS Number: 68610-51-5
· EC number:
271-867-2
· Registration number 01-2119496062-39-0002
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the preparation Antioxidant
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
OMNOVA Solutions SAS
14 Avenue des Tropiques,
Z.A. de Courtaboeuf 2, Villejust
F-91955 Courtaboeuf Cédex
FRANCE
msds@omnovasolutions.com
· Further information obtainable from: HSE.
· 1.4 Emergency telephone number:
CHEMTREC United States: +1.800.424.9300
CHEMTREC International: +1.703.527.3887
UK: +44 870 600 6266
GR: +30 10 779 3777
24/24 7/7: +33 1. 69.29.27.00

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
Aquatic Chronic 4 H413 May cause long lasting harmful effects to aquatic life.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
R53: May cause long-term adverse effects in the aquatic environment.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
· Hazard pictograms Void
· Signal word Void
· Hazard statements
H413 May cause long lasting harmful effects to aquatic life.
· Precautionary statements
P273 Avoid release to the environment.
· 2.3 Other hazards Dust can combine with air to form an explosive mixture.
· Results of PBT and vPvB assessment Not applicable.
· PBT: Not applicable.
· vPvB: Not applicable.
(Contd. on page 2)
GB

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 Page 2/23
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 21.09.2012 Version: 11 Revision: 21.09.2012

Trade name: WINGSTAY® L

(Contd. of page 1)

SECTION 3: Composition/information on ingredients

· 3.1 Substances
· CAS No. Description
68610-51-5
Phenol, 4-methyl-, reaction products with dicyclopentadiene and isobutylene.
Butylated reaction product of p-cresol and dicyclopentadiene.
· Identification number(s)
· EC number: 271-867-2

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray.
Water haze
Foam
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
· 5.3 Advice for firefighters
· Protective equipment: Wear self-contained respiratory protective device.
· Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures Avoid formation of dust.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Pick up mechanically.
Send for recovery or disposal in suitable receptacles.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling
Prevent formation of dust.
Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection:
Dust can combine with air to form an explosive mixture.
(Contd. on page 3)
GB

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 Page 3/23
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 21.09.2012 Version: 11 Revision: 21.09.2012

Trade name: WINGSTAY® L

(Contd. of page 2)
Protect against electrostatic charges.
Use explosion-proof apparatus / fittings and spark-proof tools.
All transfer and storage equipment should be metallised an earthed.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Store in dry conditions.
Store receptacle in a well ventilated area.
Protect from heat and direct sunlight.
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: See item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Immediately remove all soiled and contaminated clothing
· Respiratory protection: Suitable respiratory protective device recommended.
· Protection of hands: Protective gloves
· Material of gloves
PVC gloves
Rubber gloves
Plastic gloves
· Penetration time of glove material
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
· Eye protection: Safety glasses
· Body protection: Impervious protective clothing

* SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Powder
Colour: Whitish
· Odour: Uncharacteristic.
· Change in condition
Melting point/Melting range: 118°C
Boiling point/Boiling range: Undetermined.
· Flash point: > 280°C
· Flammability (solid, gaseous): Product is not flammable.
· Ignition temperature:
Decomposition temperature: >300°C
· Self-igniting: 445 °C (deposit)
· Danger of explosion: Product does not present an explosion hazard.
(Contd. on page 4)
GB

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 Page 4/23
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 21.09.2012 Version: 11 Revision: 21.09.2012

Trade name: WINGSTAY® L

(Contd. of page 3)

· Danger of explosion (Cloud): ST3

· EMI (Cloud): <10 mJ
· KST (Cloud): 349 bar.m.s-1
· P.max (Cloud): 9 bar
· LOC (Cloud): 8 %v/v O2/N2
· Explosion limits:
Lower: <60 g/m3
(Cloud)
Upper: >1500 g/m3
(Cloud)
· Density: Not determined.
· Bulk density at 20°C: 320 kg/m³
· Relative density at 20°C 1.0736
· Solubility in / Miscibility with
water at 25°C: <0.01 mg/l
· aromatic hydrocarbons: Fully miscible.
· Log Kow (n-octanol/water): 7.56 (30°C)
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: None
· 10.6 Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Phenolic type compounds.

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
Oral LD50 >5000 mg/kg (rat) (OECD Guideline 401)
Dermal LD50 >2000 mg/kg (rat) (OECD Guideline 402)
· Primary irritant effect:
· on the skin:
New Zealand White rabbits: The primary irritation score was 0.25.
This material is not irritating to the skin.
· on the eye: No irritating effect.
· Sensitization:
This substance was determined to be non-sensitizing by skin contact in the Guinea Pig test (OECD 406).

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity:
EC50 (48 h) >0.2 mg/l (daphnia) (OECD Guideline 202)
EC50 (96 h) >0.2 mg/l (fish) (OECD Guideline 203)
(Contd. on page 5)
GB

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 Page 5/23
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 21.09.2012 Version: 11 Revision: 21.09.2012

Trade name: WINGSTAY® L

(Contd. of page 4)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: No toxicity demonstrated at limit of solubility.
· Additional ecological information:
· General notes:
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation Must be specially treated adhering to official regulations.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, ADN, IMDG, IATA Void
· 14.2 UN proper shipping name
· ADR, ADN, IMDG, IATA Void
· 14.3 Transport hazard class(es)
· ADR, IMDG, IATA
· Class Void
Not classified.
· ADN/R Class: Void
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· UN "Model Regulation": -

* SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· This material is included in or exempt from:
· Australia: AICS
· Canada: DSL
· China: IECSC
· Europe: EINECS
· Japan: ENCS
· South Korea: ECL
· New Zealand: TSA
· Philippines: PICCS
· United States: TSCA
(Contd. on page 6)
GB

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 Page 6/23
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 21.09.2012 Version: 11 Revision: 21.09.2012

Trade name: WINGSTAY® L

(Contd. of page 5)
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has been carried out.

* SECTION 16: Other information

The information provided above is intended as guidance relating to the safe handling, use, processing,
storage, transportation, disposal and release of the material listed. Nothing contained herein is to be
considered as an express or implied warranty or performance or quality specification. The information relates
only to the specific material designated and may not apply for such material when used in combination with
any other materials or in any process, except as otherwise specified herein. The information contained herein
is believed to be true and correct as of the date that this Material Safety Data Sheet was issued. The material
described herein is produced for commercial and industrial use and unless otherwise specifically designated
by the manufacturer in writing have not received any specific regulatory approvals including, without
limitation, approvals for food contact or medical/surgical applications, such as medical devices.
· Department issuing MSDS: HSE.
· Contact: msds@omnovasolutions.com
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organization
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
· * Data compared to the previous version altered.
GB

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APPENDIX: EXPOSURE SCENARIOS

Contents

1. Formulation of aqueous dispersions or emulsions

SU3; SU10; ERC2; PROC3, PROC8b, PROC9

2. Industrial use in the production of solid rubber products

SU3; SU11; ERC3, ERC5, ERC12a; PROC5, PROC6, PROC8b, PROC9, PROC14, PROC21

3. Industrial use in the production of latex dipped articles

SU3; SU10, SU11; ERC3, ERC5; PROC5, PROC8b, PROC9, PROC13, PROC14

4. Industrial use in the production of impact modified plastics and thermoplastics

SU3; SU10, SU11, SU12; ERC2, ERC3, ERC5; PROC3, PROC5, PROC8b, PROC9, PROC14, PROC21,
PROC24

5. Industrial use in the production of low/medium voltage cross-linked polyethylene cables

SU3; SU12; ERC2, ERC3; PROC3, PROC5, PROC8b, PROC9, PROC14, PROC24

6. Industrial use in the production of articles based on rubber foams

SU3; SU5; ERC2, ERC3, ERC5, ERC12a; PROC3, PROC5, PROC8b, PROC9, PROC13, PROC21

7. Industrial use in the production of coated paper

SU3; SU6b; ERC2, ERC3; PROC3, PROC5, PROC8b, PROC9, PROC14

8. Professional use in R&D

SU22; SU24; ERC8b; PROC15

9. Professional and consumer use of solid rubber products, latex-based products, low- and medium-
voltage cables
SU21; SU22; ERC10a, ERC11a; PROC21

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1. Formulation of aqueous dispersions or emulsions

1. Title of exposure scenario

Sector of use SU3: Industrial use
Sector of end-use SU10: Formulation of preparations and/or repackaging
Market sector PC32: Polymer preparations and compounds
Environment: ERC2: Formulation of preparations
Worker: PROC3: Use in closed batch process (synthesis or formulation)
PROC8b: Transfer of substance or preparation (charging/discharging)
from/to vessels/large containers at dedicated facilities
PROC9: Transfer of substance or preparation into small containers
(dedicated filling line, including weighing)

2. Conditions of use affecting exposure

2.1 Control of environmental exposure: Formulation of aqueous dispersions or emulsions (ERC2)
Amounts used
Max. 1000 tonnes per year; max. 50% of Wingstay L in the dispersion/emulsion
Frequency and duration of use
Max. 300 days per year
Environment factors not influenced by risk management
Flow rate of receiving surface water: 18000 m3/d (default)
Other given operational conditions affecting environmental exposure
Not applicable
Technical conditions and measures at process level (source) to prevent release
Spill containment measures:
E11.01 Closed sinks/basins to prevent discharge to waste- and/or surface water
E11.02 Hard impervious surfaced areas to prevent spillages to soil
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Reduction and cleaning of air emissions:
E12.03 Air filtration – fabric filter (recovery and abatement technique for particulates)
Reduction and cleaning of waste water:
E13.04 Oil-water separation (Mechanical separation of insoluble contaminants)
Disposal of waste:
E14.02 Hazardous waste incineration
Ventilation control:
W18.01 Receptor hood (Extraction of contaminant at source by use of air pulled through one or
more fixed points of extraction) or W19.01 Push pull systems (Combination of positively displaced air
used to capture and push contaminants towards a balanced extraction ventilation system) and/or W20.01
Dilution ventilation(Flow of air into and out of a working area so that contaminants are diluted by
adding fresh air)
Organizational measures to prevent/limit release from site
Not applicable
Conditions and measures related to municipal sewage treatment plant
Incineration of sewage sludge
Conditions and measures related to external treatment of waste for disposal
E14.02 Hazardous waste incineration
Additional good practice advice beyond the REACH CSA
Note: The measures reported in this section have not been taken into account in the exposure estimates related to the
exposure scenario above. They are not subject to obligation laid down in Article 37(4) of REACH. Thus, the
downstream user is not obliged to i) carry out an own CSA and ii) to notify the use to ECHA, if he does not implement
these measures.
Not applicable
2.2 Control of worker exposure
Although the substance is found to be not hazardous to human health, the recommendations as given in the
ETRMA (European Tyre & Rubber Manufacturers Association) General Rubber Goods manufacturing GES
(version 1.1) using the CEFIC Risk Management Measures Library Codes should be followed.

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General measures:
W27.01 General good hygiene and housekeeping (regular cleaning etc.)
W27.02 Personal hygiene (no eating, drinking and smoking in contaminated areas)
Ventilation:
W17.01 Local exhaust ventilation systems where energy is required to ensure that
contaminant-laden air is drawn in and captured by the hood
W20.01 Dilution ventilation (Flow of air into and out of a working area so that contaminants are
diluted by adding fresh air)
Hand protection:
W29.01 Chemical resistant protective gloves

3. Exposure estimation and reference to its source

3.1 Environment
A qualitative approach has been used as PNEC values could not be properly derived. The substance has a
very low water solubility (<0.01 mg/L) and a very high octanol-water partition coefficient (log Kow>7.56).
Therefore the bioavailability and the bioaccumulation potential, which decreases with increasing log Kow,
will be low. If the above technical measures are taken into account, risks to environmental compartments are
deemed to be negligible.
3.2 Worker / Consumer
No occupational exposure estimations and risk characterizations have been performed as the substance is
found to be not hazardous to human health.

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2. Industrial use in the production of solid rubber products

1. Title of exposure scenario

Sector of use SU3: Industrial use
Sector of end-use SU11: Manufacture of rubber products
Market sector PC32: Polymer preparations and compounds
Article category AC10: Rubber articles
Environment: ERC3: Formulation in materials
ERC5: Industrial use resulting in inclusion into or onto a matrix
ERC12a: Industrial processing of articles with abrasive techniques
(low release)
Worker: PROC5: Mixing or blending in batch processes for formulation of
preparations and articles (multistage and/or significant contact)
PROC6: Calendering operations
PROC8b: Transfer of substance or preparation (charging/discharging)
from/to vessels/large containers at dedicated facilities
PROC9: Transfer of substance or preparation into small containers
(dedicated filling line, including weighing)
PROC14: Production of preparations or articles by tabletting,
compression, extrusion, pelletisation
PROC21: Low energy manipulation of substances bound in materials
and/or articles

2. Conditions of use affecting exposure

2.1 Control of environmental exposure: Production of solid rubber products (ERC3, ERC5, ERC12a)
Amounts used
Max. 500 tonnes per year; max. 1% of Wingstay L in the rubber product
Frequency and duration of use
Max. 240 days per year
Environment factors not influenced by risk management
Flow rate of receiving surface water: 18000 m3/d (default)
Other given operational conditions affecting environmental exposure
Not applicable
Technical conditions and measures at process level (source) to prevent release
Spill containment measures:
E11.01 Closed sinks/basins to prevent discharge to waste- and/or surface water
E11.02 Hard impervious surfaced areas to prevent spillages to soil
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Reduction and cleaning of air emissions (especially during Banbury mixing):
E12.03 Air filtration – fabric filter (recovery and abatement technique for particulates)
Reduction and cleaning of waste water:
E13.04 Oil-water separation (Mechanical separation of insoluble contaminants)
Disposal of waste:
E14.02 Hazardous waste incineration
Ventilation control during Banbury mixing:
W17.01 Captor hood (Local exhaust ventilation systems where energy is required to ensure
that contaminant-laden air is drawn in and captured by the hood)
Ventilation control during curing:
W18.01 Receptor hood (Extraction of contaminant at source by use of air pulled through one or
more fixed points of extraction) or W19.01 Push pull systems (Combination of positively displaced air
used to capture and push contaminants towards a balanced extraction ventilation system) and/or W20.01
Dilution ventilation(Flow of air into and out of a working area so that contaminants are diluted by
adding fresh air)
Organizational measures to prevent/limit release from site
Not applicable

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Conditions and measures related to municipal sewage treatment plant

Incineration of sewage sludge
Conditions and measures related to external treatment of waste for disposal
E14.02 Hazardous waste incineration
Additional good practice advice beyond the REACH CSA
Note: The measures reported in this section have not been taken into account in the exposure estimates related to the
exposure scenario above. They are not subject to obligation laid down in Article 37(4) of REACH. Thus, the
downstream user is not obliged to i) carry out an own CSA and ii) to notify the use to ECHA, if he does not implement
these measures.
Not applicable
2.2 Control of worker exposure
Although the substance is found to be not hazardous to human health, the recommendations as given in the
ETRMA (European Tyre & Rubber Manufacturers Association) General Rubber Goods manufacturing GES
(version 1.1) using the CEFIC Risk Management Measures Library Codes should be followed.
General measures:
W27.01 General good hygiene and housekeeping (regular cleaning etc.)
W27.02 Personal hygiene (no eating, drinking and smoking in contaminated areas)
Hand protection during Banbury mixing:
W29.01 Chemical resistant protective gloves
Dilution ventilation during Banbury mixing and shaping:
W20.01 Dilution ventilation (Flow of air into and out of a working area so that contaminants are
diluted by adding fresh air)
Ventilation control during Banbury mixing:
W17.01 Captor hood (Local exhaust ventilation systems where energy is required to ensure
that contaminant-laden air is drawn in and captured by the hood)
Ventilation control during curing:
W18.01 Receptor hood (Extraction of contaminant at source by use of air pulled through one or
more fixed points of extraction) or W19.01 Push pull systems (Combination of positively displaced air
used to capture and push contaminants towards a balanced extraction ventilation system) and/or W20.01
Dilution ventilation (Flow of air into and out of a working area so that contaminants are diluted by
adding fresh air).
Limiting concentration and change of physical state (if appropriate):
CW1.06 Dilution by user prior to application
CW2.01 Control of physical form (product design, under control of the producer and
therefore applicable for quantitative considerations: e.g. tablets vs. powder, or inclusion in
matrices)

3. Exposure estimation and reference to its source

3.1 Environment
A qualitative approach has been used as PNEC values could not be properly derived. The substance has a
very low water solubility (<0.01 mg/L) and a very high octanol-water partition coefficient (log Kow>7.56).
Therefore the bioavailability and the bioaccumulation potential, which decreases with increasing log Kow,
will be low. If the above technical measures are taken into account, risks to environmental compartments are
deemed to be negligible.
3.2 Worker / Consumer
No occupational exposure estimations and risk characterizations have been performed as the substance is
found to be not hazardous to human health.

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3. Industrial use in the production of latex dipped articles

1. Title of exposure scenario

Sector of use SU3: Industrial use
Sector of end-use SU10: Formulation of preparations and/or repackaging
SU11: Manufacture of rubber products
Market sector PC32: Polymer preparations and compounds
Article category AC5: Fabrics, textiles and apparel
AC10: Rubber articles
Environment: ERC3: Formulation in materials
ERC5: Industrial use resulting in inclusion into or onto a matrix
Worker: PROC5: Mixing or blending in batch processes for formulation of
preparations and articles (multistage and/or significant contact)
PROC8b: Transfer of substance or preparation (charging/discharging)
from/to vessels/large containers at dedicated facilities
PROC9: Transfer of substance or preparation into small containers
(dedicated filling line, including weighing)
PROC13: Treatment of articles by dipping and pouring
PROC14: Production of preparations or articles by tabletting,
compression, extrusion, pelletisation

2. Conditions of use affecting exposure

2.1 Control of environmental exposure: Production of latex dipped articles (ERC3, ERC5)
Amounts used
Max. 500 tonnes per year; max. 1% of Wingstay L in the rubber product
Frequency and duration of use
Max. 240 days per year
Environment factors not influenced by risk management
Flow rate of receiving surface water: 18000 m3/d (default)
Other given operational conditions affecting environmental exposure
Not applicable
Technical conditions and measures at process level (source) to prevent release
Spill containment measures:
E11.01 Closed sinks/basins to prevent discharge to waste- and/or surface water
E11.02 Hard impervious surfaced areas to prevent spillages to soil
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Reduction and cleaning of air emissions:
E12.03 Air filtration – fabric filter (recovery and abatement technique for particulates)
Reduction and cleaning of waste water:
E13.04 Oil-water separation (Mechanical separation of insoluble contaminants)
Disposal of waste:
E14.02 Hazardous waste incineration
Ventilation control:
W18.01 Receptor hood (Extraction of contaminant at source by use of air pulled through one or
more fixed points of extraction) or W19.01 Push pull systems (Combination of positively displaced air
used to capture and push contaminants towards a balanced extraction ventilation system) and/or W20.01
Dilution ventilation(Flow of air into and out of a working area so that contaminants are diluted by
adding fresh air)
Organizational measures to prevent/limit release from site
Not applicable
Conditions and measures related to municipal sewage treatment plant
Incineration of sewage sludge
Conditions and measures related to external treatment of waste for disposal
E14.02 Hazardous waste incineration
Additional good practice advice beyond the REACH CSA

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Note: The measures reported in this section have not been taken into account in the exposure estimates related to the
exposure scenario above. They are not subject to obligation laid down in Article 37(4) of REACH. Thus, the
downstream user is not obliged to i) carry out an own CSA and ii) to notify the use to ECHA, if he does not implement
these measures.
Not applicable
2.2 Control of worker exposure
Although the substance is found to be not hazardous to human health, the recommendations as given in the
ETRMA (European Tyre & Rubber Manufacturers Association) General Rubber Goods manufacturing GES
(version 1.1) using the CEFIC Risk Management Measures Library Codes should be followed.
General measures:
W27.01 General good hygiene and housekeeping (regular cleaning etc.)
W27.02 Personal hygiene (no eating, drinking and smoking in contaminated areas)
Dilution ventilation during extrusion:
W20.01 Dilution ventilation (Flow of air into and out of a working area so that contaminants are
diluted by adding fresh air)
Ventilation control during curing:
W18.01 Receptor hood (Extraction of contaminant at source by use of air pulled through one or
more fixed points of extraction) or W19.01 Push pull systems (Combination of positively displaced air
used to capture and push contaminants towards a balanced extraction ventilation system) and/or W20.01
Dilution ventilation (Flow of air into and out of a working area so that contaminants are diluted by
adding fresh air).
Limiting concentration and change of physical state (if appropriate):
CW1.06 Dilution by user prior to application
CW2.01 Control of physical form (product design, under control of the producer and
therefore applicable for quantitative considerations: e.g. tablets vs. powder, or inclusion in
matrices)

3. Exposure estimation and reference to its source

3.1 Environment
A qualitative approach has been used as PNEC values could not be properly derived. The substance has a
very low water solubility (<0.01 mg/L) and a very high octanol-water partition coefficient (log Kow>7.56).
Therefore the bioavailability and the bioaccumulation potential, which decreases with increasing log Kow,
will be low. If the above technical measures are taken into account, risks to environmental compartments are
deemed to be negligible.
3.2 Worker / Consumer
No occupational exposure estimations and risk characterizations have been performed as the substance is
found to be not hazardous to human health.

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4. Industrial use in the production of impact modified plastics and thermoplastics

1. Title of exposure scenario

Sector of use SU3: Industrial use
Sector of end-use SU10: Formulation of preparations and/or repackaging
SU11: Manufacture of rubber products
SU12: Manufacture of plastic products, including compounding and
conversion
Market sector PC32: Polymer preparations and compounds
Article category AC13: Plastic articles
Environment: ERC2: Formulation of preparations
ERC3: Formulation in materials
ERC5: Industrial use resulting in inclusion into or onto a matrix
Worker: PROC3: Use in closed batch process (synthesis or formulation)
PROC5: Mixing or blending in batch processes for formulation of
preparations and articles (multistage and/or significant contact)
PROC6: Calendering operations
PROC8b: Transfer of substance or preparation (charging/discharging)
from/to vessels/large containers at dedicated facilities
PROC9: Transfer of substance or preparation into small containers
(dedicated filling line, including weighing)
PROC14: Production of preparations or articles by tabletting,
compression, extrusion, pelletisation
PROC21: Low energy manipulation of substances bound in materials
and/or articles
PROC24: High (mechanical) energy work-up of substances bound in
materials and/or articles

2. Conditions of use affecting exposure

2.1 Control of environmental exposure: Production of impact-modified plastics and thermoplastics
(ERC2, ERC3, ERC5)
Amounts used
Max. 400 tonnes per year; max. 0.5% of Wingstay L in the plastic product
Frequency and duration of use
Max. 300 days per year
Environment factors not influenced by risk management
Flow rate of receiving surface water: 18000 m3/d (default)
Other given operational conditions affecting environmental exposure
Not applicable
Technical conditions and measures at process level (source) to prevent release
Spill containment measures:
E11.01 Closed sinks/basins to prevent discharge to waste- and/or surface water
E11.02 Hard impervious surfaced areas to prevent spillages to soil
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Reduction and cleaning of air emissions:
E12.03 Air filtration – fabric filter (recovery and abatement technique for particulates)
Reduction and cleaning of waste water:
E13.04 Oil-water separation (Mechanical separation of insoluble contaminants)
Disposal of waste:
E14.02 Hazardous waste incineration
Ventilation control:
W18.01 Receptor hood (Extraction of contaminant at source by use of air pulled through one or
more fixed points of extraction) or W19.01 Push pull systems (Combination of positively displaced air
used to capture and push contaminants towards a balanced extraction ventilation system) and/or W20.01
Dilution ventilation(Flow of air into and out of a working area so that contaminants are diluted by

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adding fresh air)

Organizational measures to prevent/limit release from site
Internal recycling of plastic waste (PROC24)
Conditions and measures related to municipal sewage treatment plant
Incineration of sewage sludge
Conditions and measures related to external treatment of waste for disposal
E14.02 Hazardous waste incineration
Additional good practice advice beyond the REACH CSA
Note: The measures reported in this section have not been taken into account in the exposure estimates related to the
exposure scenario above. They are not subject to obligation laid down in Article 37(4) of REACH. Thus, the
downstream user is not obliged to i) carry out an own CSA and ii) to notify the use to ECHA, if he does not implement
these measures.
Not applicable
2.2 Control of worker exposure
Although the substance is found to be not hazardous to human health, the recommendations as given in the
ETRMA (European Tyre & Rubber Manufacturers Association) General Rubber Goods manufacturing GES
(version 1.1) using the CEFIC Risk Management Measures Library Codes should be followed.
General measures:
W27.01 General good hygiene and housekeeping (regular cleaning etc.)
W27.02 Personal hygiene (no eating, drinking and smoking in contaminated areas)
Dilution ventilation during extrusion:
W20.01 Dilution ventilation (Flow of air into and out of a working area so that contaminants are
diluted by adding fresh air)
Ventilation control during curing:
W18.01 Receptor hood (Extraction of contaminant at source by use of air pulled through one or
more fixed points of extraction) or W19.01 Push pull systems (Combination of positively displaced air
used to capture and push contaminants towards a balanced extraction ventilation system) and/or W20.01
Dilution ventilation (Flow of air into and out of a working area so that contaminants are diluted by
adding fresh air).
Limiting concentration and change of physical state during curing and extrusion (if appropriate):
CW1.06 Dilution by user prior to application
CW2.01 Control of physical form (product design, under control of the producer and
therefore applicable for quantitative considerations: e.g. tablets vs. powder, or inclusion in
matrices)

3. Exposure estimation and reference to its source

3.1 Environment
A qualitative approach has been used as PNEC values could not be properly derived. The substance has a
very low water solubility (<0.01 mg/L) and a very high octanol-water partition coefficient (log Kow>7.56).
Therefore the bioavailability and the bioaccumulation potential, which decreases with increasing log Kow,
will be low. If the above technical measures are taken into account, risks to environmental compartments are
deemed to be negligible.
3.2 Worker / Consumer
No occupational exposure estimations and risk characterizations have been performed as the substance is
found to be not hazardous to human health.

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5. Industrial use in the production of low/medium voltage cross-linked polyethylene

cables

1. Title of exposure scenario

Sector of use SU3: Industrial use
Sector of end-use SU12: Manufacture of plastic products, including compounding and
conversion
Market sector PC32: Polymer preparations and compounds
Article category AC13: Plastic articles
Environment: ERC2: Formulation of preparations
ERC3: Formulation in materials
Worker: PROC3: Use in closed batch process (synthesis or formulation)
PROC5: Mixing or blending in batch processes for formulation of
preparations and articles (multistage and/or significant contact)
PROC8b: Transfer of substance or preparation (charging/discharging)
from/to vessels/large containers at dedicated facilities
PROC9: Transfer of substance or preparation into small containers
(dedicated filling line, including weighing)
PROC14: Production of preparations or articles by tabletting,
compression, extrusion, pelletisation
PROC24: High (mechanical) energy work-up of substances bound in
materials and/or articles

2. Conditions of use affecting exposure

2.1 Control of environmental exposure: Production of low/medium voltage cross-linked polyethylene
cables (ERC2, ERC3)
Amounts used
Max. 200 tonnes per year; max. 0.3% of Wingstay L in the cable
Frequency and duration of use
Max. 300 days per year
Environment factors not influenced by risk management
Flow rate of receiving surface water: 18000 m3/d (default)
Other given operational conditions affecting environmental exposure
Not applicable
Technical conditions and measures at process level (source) to prevent release
Spill containment measures:
E11.01 Closed sinks/basins to prevent discharge to waste- and/or surface water
E11.02 Hard impervious surfaced areas to prevent spillages to soil
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Reduction and cleaning of air emissions:
E12.03 Air filtration – fabric filter (recovery and abatement technique for particulates)
Reduction and cleaning of waste water:
E13.04 Oil-water separation (Mechanical separation of insoluble contaminants)
Disposal of waste:
E14.02 Hazardous waste incineration
Ventilation control:
W18.01 Receptor hood (Extraction of contaminant at source by use of air pulled through one or
more fixed points of extraction) or W19.01 Push pull systems (Combination of positively displaced air
used to capture and push contaminants towards a balanced extraction ventilation system) and/or W20.01
Dilution ventilation(Flow of air into and out of a working area so that contaminants are diluted by
adding fresh air)
Organizational measures to prevent/limit release from site
Not applicable
Conditions and measures related to municipal sewage treatment plant
Incineration of sewage sludge

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Conditions and measures related to external treatment of waste for disposal

E14.02 Hazardous waste incineration
Additional good practice advice beyond the REACH CSA
Note: The measures reported in this section have not been taken into account in the exposure estimates related to the
exposure scenario above. They are not subject to obligation laid down in Article 37(4) of REACH. Thus, the
downstream user is not obliged to i) carry out an own CSA and ii) to notify the use to ECHA, if he does not implement
these measures.
Not applicable
2.2 Control of worker exposure
Although the substance is found to be not hazardous to human health, the recommendations as given in the
ETRMA (European Tyre & Rubber Manufacturers Association) General Rubber Goods manufacturing GES
(version 1.1) using the CEFIC Risk Management Measures Library Codes should be followed.
General measures:
W27.01 General good hygiene and housekeeping (regular cleaning etc.)
W27.02 Personal hygiene (no eating, drinking and smoking in contaminated areas)
Dilution ventilation during extrusion:
W20.01 Dilution ventilation (Flow of air into and out of a working area so that contaminants are
diluted by adding fresh air)
Ventilation control during curing:
W18.01 Receptor hood (Extraction of contaminant at source by use of air pulled through one or
more fixed points of extraction) or W19.01 Push pull systems (Combination of positively displaced air
used to capture and push contaminants towards a balanced extraction ventilation system) and/or W20.01
Dilution ventilation (Flow of air into and out of a working area so that contaminants are diluted by
adding fresh air).
Limiting concentration and change of physical state during curing and extrusion (if appropriate):
CW1.06 Dilution by user prior to application
CW2.01 Control of physical form (product design, under control of the producer and
therefore applicable for quantitative considerations: e.g. tablets vs. powder, or inclusion in
matrices)

In addition, the Plastic Exposure Scenario Team (PEST), which developed scenarios for chemicals used in
plastics manufacturing, recommended in the PEST ‘Masterbatching’ Excel sheet:
Eye protection (goggles) should be worn at any time. Respiratory protection should be used only during
mixing when dust formation is possible. Gloves should be used only during mixing when dermal contact is
possible.

3. Exposure estimation and reference to its source

3.1 Environment
A qualitative approach has been used as PNEC values could not be properly derived. The substance has a
very low water solubility (<0.01 mg/L) and a very high octanol-water partition coefficient (log Kow>7.56).
Therefore the bioavailability and the bioaccumulation potential, which decreases with increasing log Kow,
will be low. If the above technical measures are taken into account, risks to environmental compartments are
deemed to be negligible.
3.2 Worker / Consumer
No occupational exposure estimations and risk characterizations have been performed as the substance is
found to be not hazardous to human health.

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6. Industrial use in the production of articles based on rubber foams

1. Title of exposure scenario

Sector of use SU3: Industrial use
Sector of end-use SU5: Manufacture of textiles, leather, fur
Market sector PC32: Polymer preparations and compounds
Article category AC5: Fabrics, textiles and apparel
Environment: ERC2: Formulation of preparations
ERC3: Formulation in materials
ERC5: Industrial use resulting in inclusion into or onto a matrix
ERC12a: Industrial processing of articles with abrasive techniques
(low release)
Worker: PROC3: Use in closed batch process (synthesis or formulation)
PROC5: Mixing or blending in batch processes for formulation of
preparations and articles (multistage and/or significant contact)
PROC8b: Transfer of substance or preparation (charging/discharging)
from/to vessels/large containers at dedicated facilities
PROC9: Transfer of substance or preparation into small containers
(dedicated filling line, including weighing)
PROC13: Treatment of articles by dipping and pouring
PROC21: Low energy manipulation of substances bound in materials
and/or articles

2. Conditions of use affecting exposure

2.1 Control of environmental exposure: Production of articles based on rubber foams (ERC2, ERC3,
ERC5, ERC12a)
Amounts used
Max. 400 tonnes per year; max. 1% of Wingstay L in the rubber foam articles
Frequency and duration of use
Max. 240 days per year
Environment factors not influenced by risk management
Flow rate of receiving surface water: 18000 m3/d (default)
Other given operational conditions affecting environmental exposure
Not applicable
Technical conditions and measures at process level (source) to prevent release
Spill containment measures:
E11.01 Closed sinks/basins to prevent discharge to waste- and/or surface water
E11.02 Hard impervious surfaced areas to prevent spillages to soil
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Reduction and cleaning of air emissions:
E12.03 Air filtration – fabric filter (recovery and abatement technique for particulates)
Reduction and cleaning of waste water:
E13.04 Oil-water separation (Mechanical separation of insoluble contaminants)
Disposal of waste:
E14.02 Hazardous waste incineration
Ventilation control:
W18.01 Receptor hood (Extraction of contaminant at source by use of air pulled through one or
more fixed points of extraction) or W19.01 Push pull systems (Combination of positively displaced air
used to capture and push contaminants towards a balanced extraction ventilation system) and/or W20.01
Dilution ventilation(Flow of air into and out of a working area so that contaminants are diluted by
adding fresh air)
Organizational measures to prevent/limit release from site
Not applicable
Conditions and measures related to municipal sewage treatment plant
Incineration of sewage sludge

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Conditions and measures related to external treatment of waste for disposal

E14.02 Hazardous waste incineration
Additional good practice advice beyond the REACH CSA
Note: The measures reported in this section have not been taken into account in the exposure estimates related to the
exposure scenario above. They are not subject to obligation laid down in Article 37(4) of REACH. Thus, the
downstream user is not obliged to i) carry out an own CSA and ii) to notify the use to ECHA, if he does not implement
these measures.
Not applicable
2.2 Control of worker exposure
Although the substance is found to be not hazardous to human health, the recommendations as given in the
ETRMA (European Tyre & Rubber Manufacturers Association) General Rubber Goods manufacturing GES
(version 1.1) using the CEFIC Risk Management Measures Library Codes should be followed.
General measures:
W27.01 General good hygiene and housekeeping (regular cleaning etc.)
W27.02 Personal hygiene (no eating, drinking and smoking in contaminated areas)
Dilution ventilation during extrusion:
W20.01 Dilution ventilation (Flow of air into and out of a working area so that contaminants are
diluted by adding fresh air)
Ventilation control during curing:
W18.01 Receptor hood (Extraction of contaminant at source by use of air pulled through one or
more fixed points of extraction) or W19.01 Push pull systems (Combination of positively displaced air
used to capture and push contaminants towards a balanced extraction ventilation system) and/or W20.01
Dilution ventilation (Flow of air into and out of a working area so that contaminants are diluted by
adding fresh air).
Limiting concentration and change of physical state during curing and extrusion (if appropriate):
CW1.06 Dilution by user prior to application
CW2.01 Control of physical form (product design, under control of the producer and
therefore applicable for quantitative considerations: e.g. tablets vs. powder, or inclusion in
matrices)

3. Exposure estimation and reference to its source

3.1 Environment
A qualitative approach has been used as PNEC values could not be properly derived. The substance has a
very low water solubility (<0.01 mg/L) and a very high octanol-water partition coefficient (log Kow>7.56).
Therefore the bioavailability and the bioaccumulation potential, which decreases with increasing log Kow,
will be low. If the above technical measures are taken into account, risks to environmental compartments are
deemed to be negligible.
3.2 Worker / Consumer
No occupational exposure estimations and risk characterizations have been performed as the substance is
found to be not hazardous to human health.

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7. Industrial use in the production of coated paper

1. Title of exposure scenario

Sector of use SU3: Industrial use
Sector of end-use SU6b: Manufacture of pulp, paper and paper products
Market sector PC26: paper and board dye, finishing and impregnation products:
including bleaches and other processing aids
Article category AC8: Paper articles
Environment: ERC2: Formulation of preparations
ERC3: Formulation in materials
Worker: PROC3: Use in closed batch process (synthesis or formulation)
PROC5: Mixing or blending in batch processes for formulation of
preparations and articles (multistage and/or significant contact)
PROC8b: Transfer of substance or preparation (charging/discharging)
from/to vessels/large containers at dedicated facilities
PROC9: Transfer of substance or preparation into small containers
(dedicated filling line, including weighing)
PROC14: Production of preparations or articles by tabletting,
compression, extrusion, pelletisation

2. Conditions of use affecting exposure

2.1 Control of environmental exposure: Formulation of preparations (ERC2)
Amounts used
Max. 500 tonnes per year; max. 1.5% of Wingstay L in paper
Frequency and duration of use
Max. 300 days per year
Environment factors not influenced by risk management
Flow rate of receiving surface water: 18000 m3/d (default)
Other given operational conditions affecting environmental exposure
No information available
Technical conditions and measures at process level (source) to prevent release
No information available
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Hazardous waste incineration
Organizational measures to prevent/limit release from site
No information available
Conditions and measures related to municipal sewage treatment plant
Incineration of sewage sludge
Conditions and measures related to external treatment of waste for disposal
No information available
Additional good practice advice beyond the REACH CSA
Note: The measures reported in this section have not been taken into account in the exposure estimates related to the
exposure scenario above. They are not subject to obligation laid down in Article 37(4) of REACH. Thus, the
downstream user is not obliged to i) carry out an own CSA and ii) to notify the use to ECHA, if he does not implement
these measures.
Not applicable
2.2 Control of worker exposure
No information available

3. Exposure estimation and reference to its source

3.1 Environment
A qualitative approach has been used as PNEC values could not be properly derived. The substance has a
very low water solubility (<0.01 mg/L) and a very high octanol-water partition coefficient (log Kow>7.56).
Therefore the bioavailability and the bioaccumulation potential, which decreases with increasing log Kow,

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 21/23

will be low. If the above technical measures are taken into account, risks to environmental compartments are
deemed to be negligible.
3.2 Worker / Consumer
No occupational exposure estimations and risk characterizations have been performed as the substance is
found to be not hazardous to human health.

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8. Professional use in R&D

1. Title of exposure scenario

Sector of use SU22: Professional uses
Sector of end-use SU24: Scientific research and development
Market sector PC21: Laboratory chemicals
Environment: ERC8b: Wide dispersive indoor use of reactive substances in open
systems
Worker: PROC15: Use as laboratory reagent

2. Conditions of use affecting exposure

2.1 Control of environmental exposure: Formulation of preparations (ERC2)
Amounts used
Max. 1 kg present at workplace
Frequency and duration of use
Not applicable
Environment factors not influenced by risk management
Not applicable
Other given operational conditions affecting environmental exposure
Not applicable
Technical conditions and measures at process level (source) to prevent release
Not applicable
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
General laboratory practices and measures should be taken into account.
Hazardous waste incineration.
Organizational measures to prevent/limit release from site
C6.04 Avoid release to the environment. Refer to special instructions/safety data sheet.
C14.07 Disposal – This material and its container must be disposed of as hazardous waste.
Conditions and measures related to municipal sewage treatment plant
Not applicable
Conditions and measures related to external treatment of waste for disposal
Hazardous waste incineration
Additional good practice advice beyond the REACH CSA
Note: The measures reported in this section have not been taken into account in the exposure estimates related to the
exposure scenario above. They are not subject to obligation laid down in Article 37(4) of REACH. Thus, the
downstream user is not obliged to i) carry out an own CSA and ii) to notify the use to ECHA, if he does not implement
these measures.
Not applicable
2.2 Control of worker exposure
W27.01 General good hygiene and housekeeping (General measures such as: - Regular cleaning of
contaminated walls, surfaces etc. - Provision of adequate facilities for washing, changing and storage of
clothing, including arrangements for laundering contaminated clothing).
W27.02 Personal hygiene (Prohibition of eating, chewing, drinking and smoking in contaminated areas).
Use suitable personal protective equipment. Refer to safety data sheet.

3. Exposure estimation and reference to its source

3.1 Environment
No environmental exposure calculations and risk characterizations have been performed as it can be
reasonably assumed that releases to the environment are negligible.
3.2 Worker / Consumer
No occupational exposure estimations and risk characterizations have been performed as the substance is
found to be not hazardous to human health.

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9. Professional and consumer use of solid rubber products, latex-based products,

low- and medium-voltage cables

1. Title of exposure scenario

Sector of use SU21: Consumer uses
SU22: Professional uses
Article category AC2: Machinery, mechanical appliances, electrical/electronic articles
AC5: Fabrics, textiles and apparel
AC8: Paper articles
AC10: Rubber articles
AC13: Plastic articles
Environment: ERC10a: Wide dispersive outdoor use of long-life articles and
materials with low release
ERC11a: Wide dispersive indoor use of long-life articles and materials
with low release
Worker: PROC21: Low energy manipulation of substances bound in materials
and/or articles

2. Conditions of use affecting exposure

2.1 Control of environmental exposure: Professional and consumer use of articles containing
Wingstay L (ERC10a, ERC11a)
Wingstay L is incorporated in the articles and no release is expected. Releases to the environment will be
negligible, if any, and wide dispersive. Control of environmental exposure is thus not needed.
2.2 Control of worker or consumer exposure
Control of worker or consumer exposure is not needed as Wingstay L is incorporated in the articles and no
release is expected.

3. Exposure estimation and reference to its source

3.1 Environment
No environmental exposure calculations and risk characterizations have been performed as it can be
reasonably assumed that releases to the environment are negligible.
3.2 Worker / Consumer
No occupational exposure estimations and risk characterizations have been performed as the substance is
found to be not hazardous to human health.

Quick-FDS [16573-69775-23074-010826] - 2013-05-16 - 19:22:55