176 i Succeed Chemistry Class 12th

Sample Question Paper 11

(Detailed Solutions)

and Reason are correct and Reason is the correct

1. (i) (a) explanation of Assertion. (1)
Melting NH3 PH3 AsH3 SbH3
(iii) (c) Benzene diazonium salts are soluble in water
point/K 195.2 139.5 156.7 185 because they are ionic in nature. Hence, Assertion is
correct but Reason is incorrect. (1)
So, the correct order is NH 3 > PH 3 < AsH 3 < SbH 3 (1)
Or
Or
CH 3 CH 3
(c) Complete reaction is as follows :
½ NH 3 ½
NH 4Cl (aq ) + NaNO 2(aq ) ¾® N 2(g ) + 2H 2O(l ) (d)H 3C — C — Br ¾¾¾¾¾¾® H 3C — C — NH 2
–HBr, substitution
A B
+ NaCl(aq) (1) ½ ½
CH 3 CH 3
Heat
(ii) (d) Ba(N 3 )2 ¾¾® Ba (s) + 3N 2(g )
tert-butyl bromide prefer to undergo elimination
Azide salt of barium can be obtained in purest form rather than substitution on treatment with a base.
as well as the decomposed product contain solid Ba The product is iso-butylene rather than
as by-product alongwith gaseous nitrogen, hence tert-butylamine. Hence, Assertion is incorrect but
no additional step of separation is required. Other Reason is correct. (1)
reactions are :
(iv) (b) CH 3NH 2 ¾¾¾® H 3CNHCH 2CH 2OH
Heat
NH 4NO 3 ¾¾® N 2O + 2H 2O [ b -amino alcohol]
Heat b-amino alcohol is less reactive than the starting
2NH 3 + 3CuO ¾¾® 3Cu + 3H 2O + N 2 amines. (1)
Heat
(NH 4 )2Cr2O7 ¾¾® Cr2O 3 + 4H 2O + N 2 (1) 3. (d) Acidic strength of oxides generally decreases with
decrease in oxygen content. Thus, the correct order for
(iii) (d) Dinitrogen is a colourless, odourless, tasteless
decreasing acidic strength of oxides of nitrogen is
and non-toxic gas. It has a very low solubility in
water. It is rather inert at room temperature. (1) N 2O 5 > N 2O 4 > N 2O 3 > NO > N 2O (1)
Heat Or
(iv) (d) 6Li + N 2 ¾¾® 2Li 3N
(a) Complete reactions are as follows :
Heat
3Mg + N 2 ¾¾® Mg 3N 2 3Cu +8HNO 3(dil.) ¾® 3Cu(NO 3 )2 + 2NO + 4H 2O
( X)
773 K 2NO + O 2 - 2NO 2
( X) (Y )
N 2(g ) + 3H 2(g ) 1 2NH 3(g ) ;
3NO 2 + H 2O ¾® 2HNO 3 + NO
D f H° = - 46.1 kJ mol -1 (1) (Y ) ( Z) ( X)
(1)
2. (i) (a) In acylation reaction of amines, equilibrium shifts 6 5 4 3 2 1
4. (c) CH 3 ¾ CH ¾ CH ¾ C ¾ C H 2 ¾ CH 3
to the right side in the presence of pyridine because ½
½ ½½
it is a stronger base than amine which removes HCl NH 2 OH O
so formed in the reaction. Hence, both Assertion
and Reason are correct and Reason is the correct \The IUPAC name of the given compound is
5-amino-4-hydroxyhexan-3-one. (1)
explanation of Assertion. (1)
(ii) (a) Aniline does not undergo Friedel Crafts reaction 5. (d) Infinite time will be taken for the 100% completion of
(alkylation and acetylation) due to salt formation with reaction as it is first order reaction. (1)
AlCl 3, (the Lewis acid) which is used as a catalyst. Or
Due to this nitrogen of aniline acquires positive
(d) When one reactant is present in large excess in a
charge and hence, act as a strong deactivating
chemical reaction between two substances, then
group for further reaction. Hence, both Assertion reaction is known as pseudo first order reaction. (1)
Sample Question Paper 11 177
6. (d) The cell representation of the given reaction is, 14. (a) The conductance is the property of the conductor
Cu(s)|Cu 2+ (aq )||Ag + (aq )|Ag(s)` which facilitates the flow of electricity through it however
° ° + ° 2+ resistance resists the flow of electricity. Hence, both
Ecell = EAg / Ag
- ECu /Cu Assertion and Reason are correct and Reason is the
Anode Cu(s) ¾® Cu 2+ (aq ) + 2e - and correct explanation of Assertion. (1)
Cathode 2 Ag + (aq ) + 2e - ¾® 2Ag(s). (1) 15. (d) Ester hydrolysis is slow in the beginning and
7. (d) Statement (d) is not correct. Corrected statement is becomes fast after sometime because a small amount
for ideal solution, DHmix = 0, DVmix = 0. (1) of dilute sulphuric acid is added in the begining to start
the reaction. As the reaction proceeds, RCOOH is
Or
produced. The rate of ester hydrolysis increases with
(d) In case of ideal solution, the intermolecular forces of the increase in the amount of carboxylic acid produced.
attraction between A¾A and B¾B types are nearly
equal to that between A¾B type. Hence, DVmix = 0, i.e. Hence, Assertion is incorrect but Reason is correct. (1)
volume of solution = sum of volumes of two 16. (d) Order of basicity of amines in gaseous phase
components and DHmix = 0, i.e. no heat is absorbed or follows the order:
evolved. (1) Tertiary amine >secondary amine >primary amine >NH3
CH 3 The basic nature of aliphatic amines increases with increase
½ Alc. KOH
in the number of alkyl groups (in gaseous phase).
8. (d)CH 3C ¾ CH 2 ¾ CH 3 ¾ ¾ ¾¾® Hence, Assertion is incorrect but Reason is correct. (1)
D
½ Or
Cl The angle C—N—C is less than 109.5°, i.e. 108° due to
CH 3 CH 3 the presence of unshared pair of electrons.
½ ½
CH 3 ¾ C == CHCH 3 + CH 2 ==C ¾ CH 2CH 3 17. (a) Conversion of 3-methyl aniline into 3-nitrotoluene is
( a) ( b) as follows:
Hence, both (a) and (b) are formed as product. (1) +
NH2 N2BF4–
9. (a) This figure represents fcc unit cell, therefore, it has 273 K
(Diazotisation)
74% packing efficiency. (1)
CH3 NaNO2/HBF4
CH3
Or (a) In the given crystal structure, equal number of
cations and anions are missing (two K + and two Cl - )
3-methyl aniline Diazonium salt
NO2
from their normal lattice sites and the crystal maintains
its electrical neutrality. Hence, this is Schottky defect. NaNO2/Cu
(1) N2 + NaBF4 + Heat
CH3
10. (c) Mn (manganese) can show oxidation state upto + 7 3-nitrotoluene
(2)
and hence, exhibit maximum number of oxidation states. Or
a-carbon (1)
18. (i) When alkyl group is same, the reactivity of alkyl
11. (a) Lysine, H2N ¾ (CH2)4 ¾ CH ¾ COOH halide is decided by the halogen present. Larger the
NH2 size of halogen atom, higher is the R—X bond length,
and weaker is the bond. Thus, more reactive is the
It is a basic amino acid. It is an a-amino acid because
alkyl halide.
¾ NH 2 group is present on the a-carbon atom bonded
to the ¾ COOH. (1) Hence, order of size is, F < Cl < Br < I.
12. (a) In solution, the surface has both solute and solvent Thus, the order of reactivity is R — Cl < R —Br < R —I.
molecules, thereby the fraction of the surface has (1)
covered by the solvent molecules get reduced. (ii) The compound CH 3CH(Cl)CH 2CH 3 is more reactive
Consequently, the number of solvent molecules than CH 3CH 2CH 2CH 2Cl as the former one gives more
escaping from the surface is reduced, thus vapour stable carbocation intermediate.
pressure of the solution is also reduced.
H H
Hence, both Assertion and Reason are correct and H 3C H 3C
½ ½ -
OH
Reason is the correct explanation of Assertion. (1) CCl ¾® C+ ¾¾®
13. (c) Halogen atom due to –I-effect has some tendency H 3CCH 2 H 3CCH 2
to withdraw electron from benzene ring. So, the ring 2-chlorobutane (Carbocation)
gets deactivated as compared to benzene. Hence, H
H 3C ½
electrophilic substitution reactions in haloarene occur
C —OH
slowly and require more drastic conditions as
H 3CH 2C
compared to those in benzene. Hence, only Assertion
2-hydroxybutane (1)
is correct but Reason is incorrect. (1)
178 i Succeed Chemistry Class 12th

19. CuSO 4 solution cannot be stored in zinc vessel (ii) In Cottrell precipitator, smoke particles (charged) are
because Zn displaces Cu from CuSO 4 solution giving passed through a chamber containing plates with
ZnSO 4 and Cu metal. The reaction is as follows : charge opposite to the smoke particles.
Smoke particles lose their charge on the plates and
Zn + CuSO 4(aq ) ¾® ZnSO 4(aq ) + Cu
get precipitated. (1)
Here, zinc is anode and Cu is cathode.
° ° ° 22. In butane, only weak van der Waals’ forces of attraction
Therefore, Ecell = ECu 2+ - EZn 2+
/Cu / Zn exist, whereas in propanol, polar —OH group is present,
= 0.34 - (- 0.76) = 110
. V due to which strong intermolecular hydrogen bonding
° exists between its molecules. Thus, large amount of
Hence, Ecell is positive, so, DG will be negative this
energy is required to break the strong intermolecular
reaction is feasible. (2)
H-bonding. Therefore, propanol has higher boiling point
20. Inner orbital complexes When the complex formed (391 K) as compared to butane (309 K).
involves the use of inner (n - 1)d -orbitals for d+ d- d+ d- d+ d-
hybridisation (d 2sp3 ), the complex is called inner orbital K H ¾ O K.. H ¾ O K.. H ¾ O K..
complex. This type of complex is also called low spin ½ ½ ½
C 3H7 C 3H7 C 3H7
complex. e.g. [ V (H 2O )6 ]3+ , [Co(NH 3 )6 ]3+ , etc. (1)
(2)
Or
Outer orbital complex When the complex formed
Mechanism It involves following three steps :
involves the use of outer nd-orbitals for hybridisation,
Step I Protonation of alkene.
(sp3d 2 ), the complex is called outer orbital complex,
having large number of unpaired electrons. This type of H 2 O + H+ ¾® H 3 O+
complex is also called high spin complex. H H
3- 3- H H + H
e.g. [CoF6 ] , [MnCl 6 ] , etc. (1) C C
+
+H¾O¾H H¾C¾C + H 2O
Or H H H
H
(i) Compound [ Pt(NH 3 )2 Cl (NO 2 )]
Step II Nucleophilic attack of water forming carbocation.
IUPAC name Diamminechloridonitrito-N-platinum (II)
H H H H
Electronic configuration + H +
H¾C¾C + H2 O H¾C¾C¾O¾H
[Pt(NH3)2(Cl)(NO2)] H
H H H
5d 6p
2+ Step III Deprotonation to form corresponding alcohol.
Pt =
H H H H H
dsp2-hybridisation + +
H ¾ C ¾ C ¾ O ¾ H + H2O H ¾ C ¾ C ¾ OH + H3O
Structure Square planar
H H H H
Magnetic behaviour Diamagnetic Ethyl alcohol (2)
(as all the electrons are paired). (1) - + Br2
(ii) Compound [Co(NH 3 )4Cl 2 ]Cl 23. (i) CH 3CH 2COO Ag ¾ ¾
¾® CH 3CH 2Br
( A)
IUPAC name Tetraamminedichloridocobalt (III) chloride Alc.KOH
Electronic configuration ¾¾¾® CH 2 == CH 2
( B) (1)
[Co(NH3)4Cl2]Cl Red P/Br2
3d (ii) CH 3 ¾ CH ¾ CH 3 ¾¾¾¾® CH 3 ¾ CH ¾ CH 3
½ ½
Co3+ = OH Br
( A)
d 2sp3 -hybridisation HBr
Alc. KOH
Structure Octahedral (1) ¾¾¾® CH 3 CH == CH 2 ¾¾¾® CH 3CH 2CH 2Br
peroxide
( B)
Magnetic behaviour Diamagnetic (1)
21. (i) Positively charged ions coagulate the negatively 24. (i) Deacon's process Chlorine can be manufactured by
charged sol and negatively charged ion coagulate Deacon’s process in which oxidation of HCl gas is
the positively charged sol. Positively charged sol of done by atmospheric O 2 in the presence of CuCl 2
hydrated ferric oxide is formed when FeCl 3 is added (catalyst) at 723 K.
in excess of hot water. On adding excess of NaCl to CuCl
this sol, negatively charged Cl – ions coagulate the 4HCl + O 2 ¾¾®
2
2Cl 2 + 2H 2O (1)
positively charged sol of hydrated ferric oxide. (1)
Sample Question Paper 11 179
(ii) Chlorine is used these five electrons is t 23g e g2 , i.e. all the electrons remain
(a) for bleaching wood pulp (required for the unpaired to form a high spin complex.
manufacture of paper and rayon), bleaching
eg
cotton and textiles.
(b) in the manufacturing of dyes, drugs and some dz2 dx2–y2
organic compounds like DDT, carbon Do
tetrachloride, refrigerants, etc. (1) d5 t2g
25. In the solution, the surface has both solute and solvent dxy dyz dzx (1½)
molecules. Due to this, effective surface area for the
However, in the presence of CN - , the distribution of
vaporisation of water molecules decreases.
these electrons is t 25g , e g0 , which the third t 2g orbital
Consequently, the vapour pressure of the solution of
glucose in water is lower than that of water. (2) contains one unpaired electron.
Or eg
Given,
Mass of ethanoic acid = 2.5 g Do
Mass of benzene = 75 g d5
t2g (1½)
Moles of solute (CH 3 COOH)
Q Molality = 28. (i) (a) Ethylamine (primary amine) gives carbylamine
Mass of solvent (in kg) (benzene,C 6 H 6 ) test. Because, this test is only given by primary
Molar mass of CH 3COOH = 24 + 4 + 32 amines, it gives a foul odour when heated with
chloroform and alc. KOH. Diethylamine
= 60 g mol -1 (secondary amine) does not give this test.
2.5 g D
Moles of CH 3COOH = CH 3CH 2NH 2 + CHCl 3 + 3KOH ¾®
60 g mol -1
CH 3CH 2NC + 3KCl + 3H 2O (1)
75 g (b) Acetamide when heated with NaOH/KOH gives
Mass of benzene in kg = = 0.075 kg
1000 g kg -1 a smell of ammonia. Ethylamine does not
evolve NH 3 and gives carbylamine reaction,
Moles of CH 3COOH
Molality = while acetamide does not give this test.
Mass of solvent (C 6H 6 ) in kg -+
D
CH 3CONH 2 + KOH ¾® CH 3COOK + NH 3 ­(1)
2.5 / 60 mol
= = 0.556 mol kg -1 (molal)
0.075 kg (ii) In order to check the activation of benzene ring by
(2)
amino group, first it is acetylated with acetic
M ´Z
26. a3 = anhydride or acetyl chloride in the presence of
d ´ NA pyridine to form acetanilide which can be further
Z ´M nitrated easily by nitrating mixture.
d =
a3 ´ N A NH2 NHCOCH3 NHCOCH3
2 ´ 93 (CH3CO)2O Conc×HNO3+
8.55 =
a3 ´ 6.023 ´ 10 23 Pyridine conc×H2SO4,
228 K
1/ 3 Aniline Acetanilide
æ 2 ´ 93 ö NO2
a = çç ÷
23 ÷ p-nitroacetanilide
è 8.55 ´ 6.023 ´ 10 ø (Major)
a = 3.306 ´ 10 - 8 cm NHCOCH3
+
3 NO2
r= ´ 3.306 ´ 10 - 8
4
1732
. ´ 3.306 ´ 10 - 8 o-nitroacetanilide
= = 14.31 pm (Minor)
(1)
4 (3) Or
27. Because of the presence of six ligands, the complex is (i) Hofmann’s ammonolysis reaction In the presence
octahedral and thus, d-orbital split up into lower energy of methyl iodide and sodium carbonate, aniline forms
t 2 g orbitals and higher energy e g orbitals. CN - is a N,N-dimethyl aniline as:
strong field ligand and H 2O is a weak field ligand. ·· +
Mn(II) ion has 3d 5 configuration. C 6H 5 NH 2 + CH 3 ¾ I ¾® [C 6 H 5 N H 2CH 3 ]I -
Aniline Methyl iodide N - methyl anilinium iodide
In the presence of H 2O molecules, the distribution of
180 i Succeed Chemistry Class 12th
+ belonging to adjacent turn is responsible for making
2[C 6H 5 NH 2CH 3 ] I- + Na 2CO 3 ¾®
the a-helix structure stable. (1)
2C 6H 5NHCH 3 + 2NaI + CO 2 ­ + H 2O
N- methyl aniline (iii) Glucose on reaction with acetic anhydride produces
·· CH 3 I glucose pentaacetate.
C 6H 5 NHCH 3 ¾¾¾® C 6H 5N(CH 3 )2 CHO CHO
Na 2CO 3 N,N-dimethyl aniline (1) ½ Acetic anhydride ½
(ii) (a) Intermolecular hydrogen bonding is present in (CHOH)4 ¾ ¾ ¾ ¾ ¾ ¾® (CHOAc)4
primary amines but not in tertiary amines (H-atom ½ ½
is absent in amino group), so primary amines CH 2OH CHOA c
Glucose G lucose pentacetate
have higher boiling point than tertiary amines.
R R R This reaction explains the presence of five ¾ OH groups
½ d - d+ ½ d - d+ ½d - in glucose. (1)
H¾ N - - - H — N - - - H — N
½ ½ ½ 2.303 a
30. For first order reaction, t = log
H H H k a- x
Hydrogen bonding in primary amines (1) a
(b) Amines are less acidic than alcohols of Here, a - x = ; k = 60 s -1
16
comparable molecular mass, because N—H
On putting the values,
bond in amines is less polar than O—H that
2.303 a ´ 16 2.303
causes hydrogen bonding in alcohols. t = log = log16
Hence, amines release H + ion with more 60 a 60
2.303
difficulty as compared to alcohols. (1) = ´ 4 log 2
60
29. DNA molecule has two strands in which the four = 4.62 ´ 10 - 2s
complementary bases pair to each other, i.e. cytosine (3)
(C) pairs with guanine (G), while thymine (T) always 31. (i) k = 0.693 = 0.693 = 4779
. ´ 10 - 2 min - 1
pairs with adenine (A). When DNA molecule is t 1/ 2 14.5 min
hydrolysed, the molar mass of cytosine is always equal
to that of guanine and the molar mass of adenine is Let decrease in pressure of CH 3OCH 3 in 12 min
equal to that of thymine. (1½) = p atm
In RNA, there is no relationship between the quantities a = 0.40 atm, a - x = 0.40 - p atm
of four bases (C, G, A and U) obtained, i.e. the base 2.303 a
k= log
pairing principle is not followed. t a- x
2.303 0.40
That is why, unlike DNA, RNA is single stranded. (1½) 4.779 ´ 10 - 2 = log
12 0.40 - p
Or
(i) a-amino acid forms polypeptide chain by elimination 0.40 4.779 ´ 10 - 2 ´ 12
log = = 0.2490
of water molecules. 0.40 - p 2.303
a 0.40
a -amino acid ¾® R — CH — COOH = Antilog (0.2490)
½ 0.40 - p
NH 2 = 1.774
nR — CH — COOH ¾® 0.40 - p =
0.40
½ 1.774
NH 2 R æO ö R 0.40
ç½½ ÷ p = 0.40 -
½ ç ÷ ½ 1.774
H 2N —CH —ç C — NH ÷ —CH — COOH
p = 0.175 atm
ç ÷
è ø Total pressure = (0.4 - p) + p + p + p
­ = 0.4 + 2p = 0.4 + 2 ´ 0.175
½
Peptide linkage
= 0.4 + 0.350
(1)
= 0.750 atm (3)
(ii) a-helix is a secondary structure of protein formed
by twisting of polypeptide chain to right handed (ii) From the relation, half life,
0.693 0.693
screw, like structure. Hydrogen bonds formed t 1/ 2 = =
between —NH— group of amino acids in one turn k 7.39 ´ 10 - 5s - 1
with the C == O groups of amino acids = 156.3 min - 1 (2)
Sample Question Paper 11 181
Or (e) Oxidation states These elements exhibit
(i) For the decomposition of N 2O 5, variable oxidation states.
Given, e.g. Cu shows two oxidation states (+ 1and + 2)
and Mn shows oxidation states from + 2 to + 7.
(f) Magnetic properties These elements show
1 diamagnetism and paramagnetism.
Conc. (g) Formation of coloured salts The compounds of
transition elements form coloured ions. e.g.
t (1) Mn 3 + : violet; Fe 2 + : green, etc.
This graph is valid only when reaction is of second
(ii) (a) The E° value for Cu/Cu 2+ electrochemical
order and it is explained below:
couple is positive (+ 0.34 V). Therefore, it cannot
For second order reaction, the integrated rate displace hydrogen from acids or Cu does not
equation is given as, reduce H + to H 2. (1)
1 æ 1 1ö
k = ´ çç - ÷÷ (b) A transition metal exhibits higher oxidation
t è a - x a ø states in oxides and fluorides because oxygen
On comparing the equation (i) with equation of and fluorine are of small size and high
straight line ( y = mx + c ), we get that electronegativity and hance can readily
æ 1 ö oxidise the metals for example
t vs ç ÷ plot is linear with a slope K and
è conc. ø O 3F6[Os(VI)] V2O 5[V(V)].
(1)
intercept 1/a.
(1) (c) The E° values for Mn, Ni and Zn are more
(ii) For first order reaction, negative them expected. The negative E°
0.693 0.693 2.303 [ A] values for Mn 2+ and Zn 2+ are related to the
k= = Þ t = log 0 stability of half-filled and fully-filled
t 1/ 2 3.0 h k [ A]
configuration. For Ni 2+ , the E° value is related to
[ A]0 k ´ t
log = its highest negative enthalpy of hydration.
[ A] 2.303 (1)
[ A]0 Or
= antilog 0.8024 = 6.345
[ A] (i) As the oxidation number increases, size of the ion of
[ A]0 = 1 M the transition element decreases. According to
[ A]0 1M Fajan’s rule, as the size of metal ion decreases,
[ A] = = = 0.1576 M covalent character of the bond formed increases.(1)
6.345 6.345
After 8h, sucrose left = 0.1576 M (3) (ii) (a) It is because of the formation of a complex
compound, [Cu(NH 3 )4] SO 4.
32. (i) Characteristics of the transition elements (d-block) CuSO 4 + 4NH 4OH ¾® [Cu(NH 3 )2 ]SO 4 + H 2O
(a) Electronic configuration General configuration (2)
of these elements is (n - 1) d 1-10ns1-2.
(b) Electronic configuration of Mn 2+ is [Ar]3 d 5
(b) Physical properties These elements have
which is half-filled and hence, it is stable.
metallic properties such as metallic lustre, high
Therefore, third ionisation enthalpy is very high,
tensile strength, ductility, malleability, high
i.e. third electron cannot be easily removed. In
thermal and electrical conductivity, high melting
case of Fe 2+ , the electronic configuration is 3d 6.
point (except Zn, Cd, Hg), hardness, etc.
Therefore, Fe 2+ can easily lose one electron to
(c) Atomic and ionic size In a given series, radii acquire 3d 5 stable electronic configuration. (2)
decrease with increasing atomic numbers.
K 2Cr2O 7 /H 2SO 4
CaCO 3
(d) Ionisation enthalpies Due to an increase in 33. (i) (a) C 6H 5CHO ¾¾¾¾¾¾® C 6H 5COOH ¾¾®
nuclear charge which accompanies the filling of Benzaldehyde Benzoic acid
inner d-orbitals, there is an increase in ionisation Dry distillation
(C 6H 5COO)2Ca ¾ ¾ ¾ ¾ ¾ ¾® C 6H 5COC 6H 5
enthalpy along each series of the transition Calcium benzoate - CaCO 3 Benzophenone
elements from left to right. (1)
182 i Succeed Chemistry Class 12th
COOH (ii) The compound F is monobasic having molecular
CH3Cl,
weight 60. Therefore, it is acetic acid CH 3COOH.
(CaO + NaOH), D Anhyd. AlCl3
(b) Therefore, the compound D which has given F on
–CO2
oxidation acetic acid is CH 3CHO.
Benzoic Benzene (1/2)
acid
(iii) Since, the compound D has been obtained by
CH3 CH3 COOH oxidation of the compound B. Therefore, B is an
Conc. HNO3 K2Cr2O7,
+ conc. H2SO4, D
alcohol having formula CH 3CH 2OH.
H2SO4 (1/2)
(iv) The compound A which gives CH 3CH 2OH on
Toluene reduction with LiAlH 4 will be CH 3COOC 4H 9 (n-butyl
NO2 NO2 acetate).
p-nitrotoluene p-nitrobenzoic acid (1/2)
H 2O,
(1) The reactions may be given as:
Dil.H 2SO 4 NaBH 4 LiAlH 4
(c)CH ºº CH ¾ ¾ ¾ ¾® CH 3CHO ¾¾® CH 3COOC 4 H 9 ¾¾¾® CH 3CH 2OH
Acetylene HgSO 4 , in ether
Acetaldehyde ( A) Ethyl alcohol
333 K ( B)

CH 3CH 2OH ¾ ¾
2 2 7 2K Cr O /H SO
¾ ¾ ¾¾4
® CH 3COOH + CH 3CH 2CH 2CH 2OH
n-butyl alcohol
Ethanol Acetic acid (C )
(1)
COONa CH 3CH 2OH ¾
¾® CH 3CHO
Ethyl alcohol Acetaldehyde
( D)
CaO
(ii) (a) + NaOH + Na2CO3 aq . alkali
630K 2CH 3CHO ¾¾¾® CH 3 CH 2 ¾ CH 2CHO
Benzene ( D) |
(A) OH
(1)
(i) O3 Heat
(b) 2 O ¾¾¾® CH 3 == CHCHO
(ii) Zn-H2O - H 2SO 4 Acetaldehyde
( E)
Cyclohexanone
(B) H 2 /Ni
(1) CH 3CH ==CHCHO ¾¾® CH 3CH 2CH 2CH 2OH
( E) (C )
Or
Oxidation
(i) The compound A molecular formula C 6H 12O 2 gives CH 3CHO ¾¾¾¾® CH 3COOH
two compounds upon reduction with LiAlH 4. ( D) Acetic acid
Therefore, it is an ester. (1/2) (3)