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George Et Al. 2005 - Mastodon Dates Monteverde
George Et Al. 2005 - Mastodon Dates Monteverde
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Previous 14Cdeterminationsobtained on two segmentsof a single mastodonbone recoveredfrom Monte Verde,Chile, were
highly discordant,differingby more than 5,000 years. Because of the significance of this site in discussions concerning the
earliest peopling of the WesternHemisphere,additional 14Cand new 813Cvalues have been obtained on organicfractions
isolatedfrom both segments.Theconstituentamino acid profiles indicate that both bone segmentsretainsignificantamounts
of protein (mostly collagen) residues. Four accelerator mass spectrometry-basedI4Cvalues obtained on total amino acids
and ultrafilteredgelatinfractions- twofrom each segment- are statistically identical and indicate an age of 12,460 (± 30)
BP for the mastodon. This value is concordant with 14Cvalues obtained on other culturally affiliated organics associated
with the MV-IIlevels at this site.
766
Table 1. Radiocarbonand 513CData on Two Segments of a Single MastodonBone from Monte Verde,Chile.
Table 1 lists the previouslypublishedages for The new 14Cvalues obtainedon all four frac-
the two bone fragments (Dillehay and Pino tions fromthe two bone fragmentsarestatistically
1997a:43^4) and our new results.Foreach frag- identical.Although the weighted averageof the
ment,two differentorganicfractions- totalamino fourvalues(12,460[± 30] B.R) appearsto be older
acids and ultrafilteredgelatin- were chemically than the previously reported age for TX-3760
isolated,and 14Cand 813Cvalues were measured. ( 11,990 ± 200 B.P.),thelargeuncertaintyin theear-
Afterthefragmentswerefirstexaminedundermag- lier value makesit difficultto determinea precise
nificationandthe surfaceswerephysicallycleaned offset. However,it is clear that the original age
andthentreatedwith .2N HC1andddH2Opriorto assigned to the segment of the mastodon bone
the acid hydrolyses,the totalaminoacid fractions recoveredfromthesurfaceof thesite(BETA-7834)
were isolated using an ion-exchangechromatog- was seriouslyincorrect.Wehaveno explanationfor
raphy procedure described in detail by Burky this anomaly,unless the portionof the bone dated
(1996). These fractionswere combustedto CO2, as BETA-7834 was far more biogeochemically
and the CO2was convertedto catalyticallycon- degradedthanthe samplessuppliedto us. Unfor-
densed graphiteat the RadiocarbonLaboratory, tunately,we have no datato confirmor refutethis
Universityof California,Riverside.The 14Ccon- possibility.
tentwasmeasuredattheKeckCarbonCycleAccel-
eratorMass SpectrometryLaboratory,University
Summary
of California,Irvine(UCIKeckAMS Laboratory).
Ultrafilteredgelatinfractionswere preparedusing The5,000-yeardiscrepancyin the 14Cages fortwo
an approachsimilarto thatof Brownet al. (1988). segmentsof a single mastodonbone from Monte
Physically cleaned and subsequentlydemineral- Verdewas initiallyattributedto massivecontami-
izedbonewashydrolyzed,andthefiltratewasultra- nation. Another explanation for the age offset
filtered(Amicon™Centriprep10) to yield a >10 invokedvery poor preservationof the collagenin
kD fraction,which was lyophilized,dried,com- at least one of the two fragments.However,we
bustedto CO2,andgraphitized.Similarlyprepared foundthatcollagenpreservationin bothbones far
samples from 14C-deadBeaufortSea whalebone exceededtheminimumtypicallyrequiredforaccu-
wereusedas processblanks.Theultrafiltered frac- rate 14Cvalues. The redatingof both fragments
tions were prepared,andthe 14Cwas measuredat using, in each case, two differentorganicextracts
the UCI KeckAMS Laboratory. The >10 kD frac- yieldedfourstatisticallyidentical14Cage estimates
tion yields from both bones were 13-14 percent, averaging12,460 (± 30) B.R, consistentwith the
and the finalproductswere a very light tan color, observationthat the two segmentsbelong to the
indicativeof very good preservationand minimal samebone.Forundetermined reasons,the original
cross-linkingof the collagento exogenouscarbo- datefor the fragmentfoundon the surface(BETA-
hydratesor otherchemicalmoieties. 7824) was incorrect.The 14Cage of this Monte
1994 Volcanoesof the World.2nd ed. Geoscience Press, Taylor,R. E., C. VanceHaynesJr.,DonnaL. Kirner,andJohn
Tucson. Southon
Stafford,ThomasW., K. Brendel,andRobertC. Duhamel 1999 RadiocarbonAnalysisof ModernOrganicsat Monte
1988 Radiocarbon,13Cand 15NAnalysis of Fossil Bone: Verde,Chile:No Evidencefor a Local ReservoirEffect.
Removalof Humateswith XAD-2 Resin. Geocehmicaet AmericanAntiquity64:455-460.
CosmochimicaActa 52:2197-2206. Taylor,R. E., C. VanceHaynesJr.,andMinze Stuiver
Stafford,ThomasW., P. EdgarHare,L. Currie,A. J. Timothy 1996 ClovisandFolsomAge Estimates:Stratigraphic Con-
Jull,andDouglasJ. Donahue text andRadiocarbonCalibration.Antiquity70:515-525.
1990 Accuracyof NorthAmericanHumanSkeletonAges. Taylor,R. E., David GlennSmith,andJohnSouthon
QuaternaryResearch34:111-120. 2001 The KennewickSkeleton: Chronologicaland Bio-
Stafford,ThomasW.,A. J. TimothyJull,K. Brendel,RobertC. molecularContexts.Radiocarbon43:965-976.
Duhamel,andDouglasJ. Donahue Tuross,Noreen
1987 Study of Bone RadiocarbonDatingAccuracyat the 1997 OrganicPreservation atMonteVerde.InMonteVerde:
University of Arizona NSF Accelerator Faculty for A LatePleistoceneSettlementin Chile,Vol.2: TheArche-
RadioisotopeAnalysis.Radiocarbon29:24-44. by ThomasD. Dille-
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Taylor,R. E. hay,pp.73-83. SmithsonianInstitutionPress,Washington,
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1992 Radiocarbon Datingof Bone:ToCollagenandBeyond.
In RadiocarbonafterFourDecades:An Interdisciplinary
Perspective,editedby R. E.Taylor,AustinLong,andRenee
Kra,pp. 375-402. SpringerVerlag,New York. Received February23, 2005; Accepted February24, 2005.