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  • Solution de Série de TD1

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    ياسمين لقراف
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    The document contains solutions to 6 exercises: 1. It calculates concentrations using given phase equilibrium equations. 2. It calculates a mass transfer rate using given mass transfer and reaction rate coefficients. 3. It calculates a global mass transfer coefficient by equating the inverse of rates. 4. It demonstrates an equation for a mass transfer coefficient in terms of the diffusion coefficient and thickness. 5. It demonstrates an equation relating global mass transfer coefficients between two phases using equilibrium and rate relationships. 6. It derives a relationship between the global mass transfer coefficients of the two phases.

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    Solution de série de TD1

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    The document contains solutions to 6 exercises: 1. It calculates concentrations using given phase equilibrium equations. 2. It calculates a mass transfer rate using given mass transfer and reaction rate coefficients. 3. It calculates a global mass transfer coefficient by equating the inverse of rates. 4. It demonstrates an equation for a mass transfer coefficient in terms of the diffusion coefficient and thickness. 5. It demonstrates an equation relating global mass transfer coefficients between two phases using equilibrium and rate relationships. 6. It derives a relationship between the global mass transfer coefficients of the two phases.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    18 views4 pages

    Solution de Série de TD1

    Uploaded by

    ياسمين لقراف
    The document contains solutions to 6 exercises: 1. It calculates concentrations using given phase equilibrium equations. 2. It calculates a mass transfer rate using given mass transfer and reaction rate coefficients. 3. It calculates a global mass transfer coefficient by equating the inverse of rates. 4. It demonstrates an equation for a mass transfer coefficient in terms of the diffusion coefficient and thickness. 5. It demonstrates an equation relating global mass transfer coefficients between two phases using equilibrium and rate relationships. 6. It derives a relationship between the global mass transfer coefficients of the two phases.

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    of 4

    Solution exo 1 :

    Phase I (G) Phase II (L)

    A1
    C1I* C1II*

    ∗ ∗
    C1I = m C1II +p ,p = 0
    ∗
    ∗
    C1I 0.1
    C1II = = = 0.285 mol/l
    m 0.35

    Solution exo 2 :
    Données :

    DA1,L = 1.83 10−9 m2 . s −1


    k1II = 5. 10−5 m. s −1
    ∗
    C1II = 38.4 10−3 kmol/m3
    ∗
    On a: N1 = k1II (C1II − C1IIb )

    C1IIb = 0
    Donc :
    ∗
    N1 = k1II C1II = 5. 10−5 ∗ 38.4 10−3 = 1,92. 10−3 mol/m2 . s ≅ 2. 10−3 mol/m2 . s

    Solution exo 3 :
    Données :

    D1II = 1.83 10−9 m2 . s−1


    k1I = 5. 10−4 m. s−1
    k1II = 5. 10−5 m. s −1
    m=0.53

    On a :
    1 1 m
    = +
    k GI k1I k1II
    AN :
    1 1 0.53
    = −4
    +
    k GI 5. 10 5. 10−5
    1 1
    = 12600 ⟹ k GI = = 7,93. 10−5 m/s
    k GI 12600

    Solution exo 4 :
    Démontrer :
    D1I
    k1I =
    δI
    Selon le cours on a :
    ∗ )
    N1 = k1I (C1Ib − C1I (1)

    dC1
    N1 = −D1 (2)
    dx

    De (2) on a :
    ∗ )
    (C1Ib − C1I ∗ )
    (C1Ib − C1I
    ∆C ∗ )
    N1 = −D1I = −D1I = D1I = k1I (C1Ib − C1I
    ∆x −δI − 0 δI
    Alors :

    D1I
    k1I =
    δI

    Solution exo 5 :
    Démontrer :
    1 1 1
    = +
    k GII mk1I k1II

    m : c’est le coefficient de partage, il représente la pente de la courbe d’équilibre


    On a :
    ∗ ) ∗
    N1 = k1I (C1Ib − C1I = k1II (C1II − C1IIb )

    E E
    N1 = k GI (C1Ib − C1Ib ) = k GII (C1IIb − C1IIb )

    E ∗ ) ∗
    k GII (C1IIb − C1IIb ) = k1I (C1Ib − C1I = k1II (C1II − C1IIb )
    E ∗ ) ∗
    (C1IIb − C1IIb ) (C1Ib − C1I (C1II − C1IIb )
    = =
    1 1 1
    k GII k1I k1II
    E ∗ )⁄ ∗
    (C1IIb − C1IIb ) (C1Ib − C1I m (C1II − C1IIb )
    ⟺ = =
    1 1 1
    ⁄m
    k GII k1I k1II
    ∗
    C1Ib C1I
    ( − m)
    E ∗
    (C1IIb − C1IIb ) m (C1II − C1IIb )
    ⟹ = =
    1 1 1
    k GII mk1I k1II
    En math on a :
    a c e a c+e
    = = ⟺ =
    b d f b d+f
    Donc :
    ∗
    C1Ib C1I
    ( − m ) (C1II
    E ∗
    (C1IIb − C1IIb ) m − C1IIb )
    = +
    1 1 1
    k GII mk1I k1II
    ∗
    E
    C1Ib C1I ∗
    (C1IIb − C1IIb ) − +C1II − C1IIb
    = m m
    1 1 1
    +
    k GII mk1I k1II
    ∗
    ∗ ∗
    C1I ∗
    C1I = mC1II ⟹ = C1II
    m
    E C1Ib E
    C1Ib = mC1IIb ⟹ = C1IIb
    m
    E
    C1Ib
    (C1IIb − C1IIb ) −C1IIb
    = m
    1 1 1
    +
    k GII mk1I k1II
    Donc :
    E E
    (C1IIb − C1IIb ) (C1IIb −C1IIb )
    =
    1 1 1
    +
    k GII mk1I k1II
    1 1
    =
    1 1 1
    +
    k GII mk1I k1II
    1 1 1
    = +
    k GII mk1I k1II

    Solution exo 6 :

    La relation entre k GII 𝑒𝑡 k GI

    On a :
    1 1 m
    = +
    k GI k1I k1II
    Et
    1 1 1
    = +
    k GII mk1I k1II
    Donc :
    1 m. 1 m. 1 1
    m∗ = + =
    k GII mk1I k1II k GI
    Donc :
    m 1
    =
    k GII k GI

    Donc :

    k GII = mk GI

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