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Redox Reactions - JEE Notes
Redox Reactions - JEE Notes
OaidatioY -Numbet-
Otidahon Numlpe o ny elemunt in an
Compound is detinad as no t elactoons
ost'or 9aingd by,he ekomant duung
tS Convesio from foue State
tany panticulan Compound t i s
iven PPSitive Sgn whan electvpns
dun d given,Megative Si9n if
electyons Qo Gai ned.:
In Case of Tonic compound ON Sogo s
a l chagige lbut in Case Gt Covalnt
Compowndit ShowS Hupothetic al
Cho9e +t
Mn
FA
KMnOA
Combingo
STa Sta
Hud.7oge Non-Met
CON +1 ONH3, Pha HS ,etc
a) In Sup etOido, ion (O) tho 0N
OF 6y9en is (2)
K Oxidation et Sulphust in
Sulphide -2 ON -2
ON-2
I n compounds itn FuosAtnL 9- HS, CuS, FeS, NHHS
Ougen Shows poSitive O N Hald
Oida tim No of Halogen
in
, FaF
Metals S alw ays
ON of AQkali * Summation of ON of a elanmants is
+1) Zeto iy case of çonPons o r is
Cal t h not dhai9e on iOn iin
Cae of ions
merals Is
ON Cf ALKalina Eatth
aluwas (t2) 1 Detumine tha ON f h elhmant
9, r , Ka wndoi ngd in fha foWow ing Case
*Ihe maximum N h a t any K MnO
Can Showis tho no 0f elcT7ons
in its Valoncg Sho
ctoons O Nof Mn + 7
i SO b-2 L= t6
JRa Meral s- bUook
koL torth M O Nof S =
r6
OT0 a miuy
nEn Ca7oon omi ii) KaC O4 2+-8 O -tb
Orernnp) ye en am -oulock O N of Cr-+6
LDnreinfalogen eemt
ns np NirToen am? y +S iv) KaC ON dr -/4
O of+ Cr O =+6
=+6
* h minimwm ON 9f any elmant
is gfve by- Mga2 0 O Nd ef -14 +S
P-
Nor FoR 1min CoN) -(no of e in Oute
METALS Shall v(NH),O PO,N »(NH,) Po .
I-8 --3
Of
oTkon m
3 t 3 t -12 o
N Tro9e amuu
Oy9en Fomi
vi)LtgNa, ADFa
Hodoge ram t-8) O N 0f AS + =
AO
O A
Vin) ASO4
N 0f A
= +2 Egr C8 O ONof Os 8
So 2x b -0 Ru Q4 ON of Ru +8 =
ix) BSO,)3
O Nof 3= +3 Xe COH)
T
Pen xaniC Acid
0N 9f Sulphun -A -4 0 ONof Xe -+%
a) Detinmi the
inthafoouoin9 Compounds- A) Pen xandlo
O:N Ot Xe +8
Lon XeO%
Ha SOs d1-6 0
Nof - +4 v HS2 Os Peroxy dt slphuc acid Marshalls
HSOD 2 Acid J
ON OF Sb I ON OF
H-0-S
SO-O-S-O-H Sulphusi =r6
ON of S rb
O 0-2
O-93 93 has ee
Caloulata tha ) of Fe în Fe,O,
3(100- 0 0 7 J00- - 200xu
Fe.OFe,O Fe oo 13
1e2 Fe
y00 33 33 Thus o f Fe
o f Fe
-Total (Fe)
A Ca.leuIato the / of Sn" in Sn O
Calaulatt ha. () of Po" tn P'bs +8x E2) O - +400
Pumbie Orda 4 A4T Sn
O Avenage ON 6
t200 8
PO+P60, Po,O 42t200-2 36 -
00
T S 0 N ON et NProge
L+S
L-3
ON of A,8,C,D,t in
ii)+ooth ha elomonts aste Same, 8) Ca.leulato. the
e n Chck fo D+2
o ihem
hybidi Satiav E N
OTdo ef
Tf hybmdi Sation a Sama, than Ne
Ta,ON
NO ON of ofiAa, t 1 ,
and gafng
of, Ca, Joose,dolD OridationAnd Roduction
)6 mo mine
0 mo Jos of,elctronS, PTOduct
ON Of (CJ.) in inal Oxi dah0m
9oin 0t O N t O2 2NO
Oxfdarov /No
JoSS 9t 2 NH N2t3H
Y X LoSS OF elactaan S calWg d oxidahon,
PGain3 S i n whan an elemant dooses (e)
6 ) C . + 10e c0rs'OC tho ON inGO aços incuqse in
0e O N i8 also caWod. 0xidaion
Loo8eg LEO Loosing of Elecnon is Qxfdatian
SPnca CI
on uining (e onS.
T P OduCT 9fKxnI (DPO Raduction
oe 1o baan
OC Must oe o e a i d, oss ef O
t aande (C), SCl2 must have gain t eloctronS
H:
OCT ed 1 Ghain ef is callod SQduc tion
Kn L te balon ca Sina uwhn i S 9auned 0N
i8
Cha qe, CL thoPOduct muust
e 2c0 Oduct doc.aaco deC.S0ase in ON
be C 2CJ° u s tho n IO:- CalWa d d u c tian
aduc fion
CO+ IOe
C2 dCI*+I0e
1OCO 2 H2HT
OxPd ahion
accompon feol
Thus h diffetont ON, 9f(C.L) * Oxdatign is always
by Roduction -
in h PTQduct foSimadd aL
(+S) ond. C-1)
S0dahon Halk RxnRan
> Ra,duchon Ha
8+Se
mola of
1) 1moJo of Ha Nooses
2moJos oj NaH
ooses,Q0.molos
cton3,,thon o , O a T i O with
olowTng elactrong eténmine inal 0 N of
Ougen whicn ot TN, TOUOwing
PoddS iSlasa poSSTolo:- Inus 1moe loose Lomo las ofes"S
aO, t
Calculatiam of'n-factoa
) Zn +H2S0, ~n
H
ogmS et a ComPouund dopendls
6S h gm n-acto
m H 6S 43m
uPon tho natHA af hin a Substanca
a given
uwhidh it is Showing
9Qoc tion
AoPA ,Rachucins Aqent
HCa O +HC,O 6Na,0 + Ha30g NaS0 t Ho
H lon
abs07 bS H tcnS, Acfdity =2
2 Con ralea)e vaia ble
gPo)3 H,0
Hene n-tacto7 Gt a SinGJe substane
Cases V
wi be, dutteuntinOuFreun wt AcidPty no et H
o
duul le which tS eV vaUonT
no otmohs
a SubS tana iS Vasu alole
CaoH) +HCI CaloH)CL + H2O
n factov 1
Actdiy
It is deftnid foot base and is detimad CaCoH) +dHCA CaC2 2H,0
-nfactor =
no et moles ot (OHJion 9fven by
NaCo2 +2HC0 2NaC COt+ HaO
no 9t moles,et CH*) ion t a n uP Acidf ty=
by On mols OF base
Actdlity +'n factor
aNa HGT22-1
Acfdrty
Na SO +2 Cat2 HO
E Base MWe
Actdty
Basi ci
1 NoOH Na OH M1
It is dafinad fon acds Ond is dafirao
CoCOH
AD.CoM)
Co 3 2COH)
Co) M/2
NHL OH NH OH no 9t mok ot Hion given up by
On modo G}Ocrd 0Y
NaOH +HCJ
NaC +H,O, Actolt-1 2) no ot OH on takon up by imole
1mp Ja Obsorbs iH* 9acid
Basiaty Basicfty of HPo,dsens R3salts ef HPO
EAtd
ol_M
BaSicity
n-factoa ) HPO, +NaOH
PO, +2Na0H
Na HPO, +HaO E=M/1
Naa HPO4. ++2H0,E M/2
Hg PO4 +3MOR, Na PO4 3H0, E=M/3
H + C E -M/1
9 HCJ Q H t + QO
E =M2
)Ha dO 8) CO+ alOH) Ca COs t H0sEco 2
H+ HPO2 basictty -L NOt+2NaOH
EW ofN,OF
2NaNOg3 t Ha0
E 9 HPo. -M/2
4. HaPO3 2HT + HPos Bas fc?ty
HaPO 3Ht + P04 Basicity - l0)NH,CI tNaOOH NHOH +NaCI (o7)
NH,CU rNaOH NHat Na Cl + H0
r) Bosuc Acid BCOH) Bas/city=1 Bàsic?ty of NH, CA= 1
EKCphon,
BCOH)a,tH0BCOH) +H* 1) Ca leuat tho n-facton sf SocI
Leuwis Acfd. in tho 9iven uaChon
OCQ2+NaOH Na SO tNoaCd
-Ha PO2 -O-P-H1 Actoke Hydryan OC 4Na OH Na,S0gtaNaC +2H0
Srructuoa/ 'n- factor 4 4 NaOH o7iS 40H
HPOHPO
Dependon
-o-?-0)& Actd e wsed u ao
Eton M
Chasge on i0n
Na, Po +BaCl2 NaC& +8a,Po,)
Na3 PO, +3daCA, t NaC& Baz CPo,)
E M/2 3 n-1
HTE M/1 /3
a E /1, PO * hor BPnany_Com?ounda 9t the
etc
AL toam Az By 5 we ave
) SaltES
Esalt M Wsad
lotal +ve -'ve chançe on Salt n - 2x3 -6S+
Eg Al2 SO) =>
or
AQ6O), - ML =S42
-
Na +CA EM/1
NaC&
Ma SO, E M/2 1 b . =S*
A PO > A* Po =M/3 EAC+Eso,
E M/1
CA B-
EM/2
EM/3
7EALso) EA+Es:
TO
e9vivalant weiqht ot tauin
Tha
xed
A J A
n-fac 6 elament 8 a
ABa /Asb
A B/ AB n-fac2 1E9 Wt 0f H 1
SaJts Ew of 25 S
wt o C
AL by n-Fac' Ly Eg
3 1) EnE,E gmS Egvivalnt Weisht ct Ouidising,Raducing
2EHC Ey+E ms Aent
3) E+E 8S9ms ChangebS Ozidation no
in
Foat 1mous of
a Su tanQ
ENa so, -ENt +Es2t9ms
1) Egvivalont weight of a mita Ofde 1n-factod £ (in oN) x(no of atoms)
iS 0 , calcula tha, evivalont
wight, Ot tho metalOnd also its 2) No et(e)S Jost or Gainad oy 1mous
Chdoude, Sulpnala, nitHaL, phosphal F a Subst an OA 0zdisng Agent
RARaducing Agent
EM,o Emead - g m s t4gms = 2gmS Egwt o t = Malwt a f OAIRA
OA/RA Chongein ON| e"gainad or dost
Ent 2+ 35 s -47 S3ms
EM-60 Etts 2 t A8 60 gmS E9- MnO, Mn a-facto
'
-
-2)x1
MNO EMtENo 12+6 2-+h 9mS
EPoy E+EPs12t32 44 9mS 9mS TEwt ot(Mn O) - M , 0N MMod
S
2) 1gm 9t motalnjtnatg, ave O86gm
e m ta Suphao.s Cal ailale the Se+MnO4+8H Mnt+ AH2O
evivalwnt weht o Metal n-factor EWt Mw mo thood
M (NOg)z Ma CSo4)x
1gm O%6Gm List ot impontant DA, RA
Egvi valinQ ot
(MNOa) Es of(M, (S0, )x)
=
OxidiSi ng Agents
E 62 ThuL
E+4% 1) KMnO Oxidsing a9ent in alL
medrumS
+2
"n'= 5 Acidic Di-nromac
Acicdi c Mn O >
) BaSi c ChTomat e
K MnOn'
=
1
Medum
KMnO, Basic Stabi y
BAN Neutoal MhOn'-3
fac a) k CrQ Pottassium Chaomate
K C1, Opottasium Di Chromal Ka CrO, BasicC3n 3x1-3 ,
+b
K, C,0, Aetdic Co CC,CzS0,)
LCT PO Cr(NOs)3
HaOa HOHyd7oger,
H Paoi I2 -22
n':Ix2
n- 3x2 =63n':6 PossfbbProducts
5HN0a >
Nitric Acid
1Ln,oasic madium KCva Op wil NH,T n 8 7.
A
not act ad 0Udising, agent
beccuSe Lt,i8 wnsta lola, in basie PNO n : 4 ossible
madum Ond Conyents inte ahromatü Procucts
NOp No n3
trom
CHNOg No,
CrO.
On
Cr0,2
balaunang Th Lachan
n' 1 NOJ
-
Co,0-2 H
OH1
CaO2
tybm betw en
ehtomota and a) KI Pottasiwm
lodids
Ovonge
Yellouo dt chomra
in diff medtum . n-2 : n- k3
a) HaC2 Ozac Acad Evi Giuen Mass., Ewt ML
xola 1a EMaSS nfact
no of moda
E m m
CO HOy EM MuDnfot
mx n'tactod
MW.
(CooH)2 E no ef mole x 'n' factor LMass
4) NaaSOs icsuWphaltr Siven
1E-N XVCin4) Voluma
a **4x 2 2 GiveV
Na S,0s C
let ra-thionate 1M N- E='n factor x Malaity
-2%=1 V
NNoT mali ty
Naoncy his is dafinad fo elomunts N-Mxnac tor M-Mo lonity
Eu A:L
Valancy
1 No ef mi e Nx VCinmu)D
Noumalty
(N)= M x 4 n facto = 2
ha no 9t
It is.dufinud as 320 2 0 HSO4
Ps epyiyaluncg 9+ Subs tanc&
en t Pet TL OF Sodution N=Mx 'n' -
2/s O4N
fN no VCin
at eg staSule
Sul i) t4 gmS of a (OH), in l0o m
M -x
thlO =1 DiJuin
Law
NV NV
MW V Ca+4
CoH), 22 -
nfoctO
ntacto
2
N = Mx'n' =2N
of,
Novmaluty in »1 Na YN
0t acidi c
miing9
ii) 316,9m KMnQ, in SoomL
So u hiom
) Fil in tha blanks
xii) CaOCcl,-C0
Feo Fe,03 /2x
18
A0 N- 1
np 1x&-& np a X2 9
AON 2
xiv SO HaSO nk n\P 2 Sn CO 2u2 n O +Co
40N 2x1-2
xv) FeS A-2xt- 4 nfactor ot nC204
Fec- AON- n 1xt=* +2
h -
e
ND HO +Co*
vi) Fe S Fe,O +SO +NO dic
2V2
2X6= 12
n (ix )+ 2) n of FeS= 1s
n-factoas ot Hg, CCN), -
KviFe CC 1X1=
Fer Cos*+ No Rlo foH Ocalatu Lon:
2Xh= 12
V C Ig > Cr O2+IO.
2) HCO Na,C,Oacks c. acid., RA
IY=24
RA 4catom3
-4-
nfac of Col5 t n22adtdr-
xix) Fe O4 Ix Fe,O +CO beiHCO Na,CO4
3 FeC. O,
Rec: Agent
Ix22
n-416)+3
nfac of FeC204 n-IC
How many (m sf O 2M
Law o Eg.vivalence- a LAu
wi th SOmL
Ked acidhed kMmc
M acidfe-
net
femangana in
0 HO So So+ 2HT+2e
HCA,
i n Case of HCL i n t o G 2 qnd Calulat yaluma of Semimolal acdi fhed
Oxidi Se
wiu p e u m a n g a n a piu not
ha
KMnO4 &oluthia 0wSLd &oxidiSe
Q ayailaole fo titSian O 3O4 g oF FeS Fe Fer2
oe
HCI C2
Oxidise
Cey of KMnO,=e FeSO
eOT e q
In Case ot HNO,LE,it8 wi
CSeLJ a
XXV
Ln fac S2 n fac
The titsjatqs agenT,Und
yey good OXidu Sina, LoiW not
Mo anu
Shm
- mL
novtc a the tit sta
t i t rand
oe oxidiSed y the
Sample Containing
penanganau titjation,Mnq dS99t FebotHOis dissoved in
s dSSo Svedin du
Ca0 C10 CO t2e aince gmS of hiS
fSodution
m N
N - Cq eg Jar thr be oF CaCo H in
egot he Sompla, honco
Va L 2
me. ofeSo, +Ha0 =me of KNn0 ey of Ca CoH)) mo lk3 x °n x2
y 1
n'=S AcPdic med
NV NaV2xV, eOf Na OH N, V, 0= 3 x 1 O 3 x O-2
5 xip 1000
8 e of HCL= N= S Sox2 =2Sxio
d+3X2 = t8x8 Hena
aSxIo = 0 3x10 + => 22 xIO 3
3t
ot FeàO *H20 AtXR x L9O4 8-161 =
-4 of FeSo HO -96/
puty of sample = 16-28
4 59 Sampla. o CaCoH) ig dissoJved
in Om Ot OSN,
HCI SoJuhons Dichaomai taatian
HCL is ba ck itrolid
wih 0 3N NaOH md !OmL ot Ka Cr0 act as Oxi disin9 madium in
Na
NaOH , Ued fO This PuiPo8e acidic modium ony Cd HaSoL
Thon adhg. 1, Put Ty
Ca COH)2 în tho
Diphany & Qmmi@
inducato which o@comes, b Juo
in
iS ed,as M
Sampl gt ven
CodouT Tpm Pink at end oF ef
Here ainta Tho 0 to uSed fo7 ,tho a t i o n
Ihis S
at e P t ohages ; Ferou t ,Oxala te aalt, H202, KL,
e of HCI, -
eq o NoOH Moh7s &alE etc
+ e9 of CalOH)L
+ tH,O hus, o O0 t
H b e
Ca given, thenco
*Fe 2- - O O18t
+e A+I6 A+ 24
CO
So+H0 &CO 2+2H t.
So+2H+2e 2
AO AO
mixtutUot AO
n-2x4=8
Samplc containing
)A
a d LAOs has weighT d:29.
LAO mqos Of K2T0 e ot A0 +e of 4,0, =
es ot K2C7, O
Tf i t takes 0 O1S (
T thaSamplo Complote 5 [22-x\x 8 OOISX6, reg- rmol in
ortd
To Orfdse_,Tha,
f OO187
in toLA QA fomodhen CalcwJati
mods At16 At48 'ot Ka,%
V8
Mx°n'= /gl->M=16
H02 Can) 2H,Oa) +Oacs) NH.O
=
=>
:2
ERalahiom betutan Malanty/Nonmakty_and lolu ma Strengh Val Sfrength =I:2x M 6
avaj Jabal
/f 3:SS x Mx V VmL
Chdonn