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DP UNIT 10 & 20.

ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

Summary

DP UNIT 10 & 20. ORGANIC CHEMISTRY

Subject Year Start date Duration


Chemistry Grade 11, Grade 12 Week 4, September 10 weeks

Course Part
Organic Chemistry

Description
Organic chemistry is the study of carbon-containing compounds. It is called ‘organic’ because it used to be thought that carbon
compounds only came from living things, but now we know that is not true. In this topic we will learn about a wide range of types
of organic compounds, learning how to name them and some of the reactions they undergo. We will also look at the mechanisms
for some of these reactions. At HL, there is a particular focus on the fine details of isomerism, and the importance of the shape
of molecules.

Inquiry & Purpose

Essential Understandings

Today, we may be starting to experience the consequences of using fossil fuels as our main source of energy. There is a vast
range of

products that can be derived from fossil fuels as a result of carbon’s rich chemistry. This raises the question “are they too
valuable to

burn?”

Inquiry Questions

Type Inquiry Questions

Content-based What are the main classes of organic chemicals, their structures and uses?

Content-based How can we convert one organic chemical to another using reaction pathways?

Skills-based Can you demonstrate your practical skills in using reaction pathways to make and purifying
organic compounds?

Debatable Should we reserve crude oil solely for the purpose of obtaining raw materials, especially now that
it is getting to be in short supply world-wide?

Transfer goals

• Organic chemistry focuses on the chemistry of compounds containing carbon.

• Structure, bonding and chemical reactions involving functional group inter-conversions are key strands in organic

Sekolah Victory Plus


Page 1 of 18
DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

chemistry.

Missed concepts/misunderstandings

Students tend to get mixed up with names of classes of organic chemicals and functional groups. They also struggle with
memorising

the interconversion pathways, conditions and reactants needed.

Curriculum

Aims

Appreciate scientific study and creativity within a global context through stimulating and challenging opportunities

Acquire a body of knowledge, methods and techniques that characterize science and technology

Develop an ability to analyse, evaluate and synthesize scientific information

Become critically aware, as global citizens, of the ethical implications of using science and technology

Objectives

Demonstrate knowledge and understanding of

facts, concepts, and terminology

communicating scientific information

Apply

facts, concepts, and terminology

methodologies and techniques

methods of communicating scientific information

Formulate, analyse and evaluate

hypotheses, research questions and predictions

methodologies and techniques

Syllabus Content

Core

10. Organic chemistry

10.1 Fundamentals of organic chemistry

Nature of science:

Serendipity and scientific discoveries - PTFE and superglue.

Sekolah Victory Plus


Page 2 of 18
DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

Ethical implications - drugs, additives and pesticides can have harmful effects on both people and the
environment.

Understandings:

A homologous series is a series of compounds of the same family, with the same general formula, which differ
from each other by a common structural unit.

Structural formulas can be represented in full and condensed format.

Structural isomers are compounds with the same molecular formula but different arrangements of atoms.

Functional groups are the reactive parts of molecules.

Saturated compounds contain single bonds only and unsaturated compounds contain double or triple bonds.

Benzene is an aromatic, unsaturated hydrocarbon.

Applications and skills:

Explanation of the trends in boiling points of members of a homologous series.

Distinction between empirical, molecular and structural formulas.

Identification of different classes: alkanes, alkenes, alkynes, halogenoalkanes, alcohols, ethers, aldehydes,
ketones, esters, carboxylic acids, amines, amides, nitriles and arenes.

Identification of typical functional groups in molecules eg phenyl, hydroxyl, carbonyl, carboxyl, carboxamide,
aldehyde, ester, ether, amine, nitrile, alkyl, alkenyl and alkynyl.

Construction of 3-D models (real or virtual) of organic molecules.

Application of IUPAC rules in the nomenclature of straight-chain and branched-chain isomers.

Identification of primary, secondary and tertiary carbon atoms in halogenoalkanes and alcohols and primary,
secondary and tertiary nitrogen atoms in amines.

Discussion of the structure of benzene using physical and chemical evidence.

10.2 Functional group chemistry

Nature of science:

Use of data - much of the progress that has been made to date in the developments and applications of scientific
research can be mapped back to key organic chemical reactions involving functional group interconversions.

Understandings:

Alkanes: Alkanes have low reactivity and undergo free-radical substitution reactions.

Alkenes: Alkenes are more reactive than alkanes and undergo addition reactions. Bromine water can be used to
distinguish between alkenes and alkanes.

Alcohols: Alcohols undergo nucleophilic substitution reactions with acids (also called esterification or
condensation) and some undergo oxidation reactions.

Halogenoalkanes: Halogenoalkanes are more reactive than alkanes. They can undergo (nucleophilic) substitution

Sekolah Victory Plus


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DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

reactions. A nucleophile is an electron-rich species containing a lone pair that it donates to an electron-deficient
carbon.

Polymers: Addition polymers consist of a wide range of monomers and form the basis of the plastics industry.

Benzene: Benzene does not readily undergo addition reactions but does undergo electrophilic substitution
reactions.

Applications and skills:

Alkanes: Writing equations for the complete and incomplete combustion of hydrocarbons. Explanation of the
reaction of methane and ethane with halogens in terms of a free-radical substitution mechanism involving
photochemical homolytic fission.

Alkenes: Writing equations for the reactions of alkenes with hydrogen and halogens and of symmetrical alkenes
with hydrogen halides and water. Outline of the addition polymerization of alkenes. Relationship between the
structure of the monomer to the polymer and repeating unit.

Alcohols: Writing equations for the complete combustion of alcohols. Writing equations for the oxidation reactions
of primary and secondary alcohols (using acidified potassium dichromate(VI) or potassium manganate(VII) as
oxidizing agents). Explanation of distillation and reflux in the isolation of the aldehyde and carboxylic acid
products. Writing the equation for the condensation reaction of an alcohol with a carboxylic acid, in the presence
of a catalyst (eg concentrated sulfuric acid) to form an ester.

Halogenoalkanes: Writing the equation for the substitution reactions of halogenoalkanes with aqueous sodium
hydroxide.

Additional higher level

20. Organic chemistry

20.1 Types of organic reactions

Nature of science:

Looking for trends and discrepancies - by understanding different types of organic reactions and their
mechanisms, it is possible to synthesize new compounds with novel properties which can then be used in several
applications. Organic reaction types fall into a number of different categories.

Collaboration and ethical implications - scientists have collaborated to work on investigating the synthesis of new
pathways and have considered the ethical and environmental implications of adopting green chemistry.

Understandings:

Nucleophilic Substitution Reactions: SN1 represents a nucleophilic unimolecular substitution reaction and SN2
represents a nucleophilic bimolecular substitution reaction. SN1 involves a carbocation intermediate. SN2
involves a concerted reaction with a transition state. For tertiary halogenoalkanes the predominant mechanism
is SN1 and for primary halogenoalkanes it is SN2. Both mechanisms occur for secondary halogenoalkanes. The
rate determining step (slow step) in an SN1 reaction depends only on the concentration of the halogenoalkane,
rate = k[halogenoalkane]. For SN2, rate = k[halogenoalkane][nucleophile]. SN2 is stereospecific with an inversion
of configuration at the carbon.

SN2 reactions are best conducted using aprotic, non-polar solvents and SN1 reactions are best conducted using
protic, polar solvents.

Sekolah Victory Plus


Page 4 of 18
DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

Electrophilic Addition Reactions: An electrophile is an electron-deficient species that can accept electron pairs
from a nucleophile. Electrophiles are Lewis acids. Markovnikov’s rule can be applied to predict the major
product in electrophilic addition reactions of unsymmetrical alkenes with hydrogen halides and interhalogens. The
formation of the major product can be explained in terms of the relative stability of possible carbocations in the
reaction mechanism.

Electrophilic Substitution Reactions: Benzene is the simplest aromatic hydrocarbon compound (or arene) and has
a delocalized structure of π bonds around its ring. Each carbon to carbon bond has a bond order of 1.5. Benzene
is susceptible to attack by electrophiles.

Reduction Reactions: Carboxylic acids can be reduced to primary alcohols (via the aldehyde). Ketones can be
reduced to secondary alcohols. Typical reducing agents are lithium aluminium hydride (used to reduce carboxylic
acids) and sodium borohydride.

Applications and skills:

Nucleophilic Substitution Reactions: Explanation of why hydroxide is a better nucleophile than water. Deduction
of the mechanism of the nucleophilic substitution reactions of halogenoalkanes with aqueous sodium hydroxide
in terms of SN1 and SN2 mechanisms. Explanation of how the rate depends on the identity of the halogen (ie the
leaving group), whether the halogenoalkane is primary, secondary or tertiary and the choice of solvent.

Outline of the difference between protic and aprotic solvents.

Electrophilic Addition Reactions: Deduction of the mechanism of the electrophilic addition reactions of alkenes
with halogens/interhalogens and hydrogen halides.

Electrophilic Substitution Reactions: Deduction of the mechanism of the nitration (electrophilic substitution)
reaction of benzene (using a mixture of concentrated nitric acid and sulfuric acid).

Reduction Reactions: Writing reduction reactions of carbonyl containing compounds: aldehydes and ketones to
primary and secondary alcohols and carboxylic acids to aldehydes, using suitable reducing agents. Conversion
of nitrobenzene to phenylamine via a two-stage reaction.

20.2 Synthetic routes

Nature of science:

Scientific method - in synthetic design, the thinking process of the organic chemist is one which invokes retro-
synthesis and the ability to think in a reverse-like manner.

Understandings:

The synthesis of an organic compound stems from a readily available starting material via a series of discrete
steps. Functional group interconversions are the basis of such synthetic routes.

Retro-synthesis of organic compounds.

Applications and skills:

Deduction of multi-step synthetic routes given starting reagents and the product(s).

20.3 Stereoisomerism

Nature of science:

Transdisciplinary - the three-dimensional shape of an organic molecule is the foundation pillar of its structure and

Sekolah Victory Plus


Page 5 of 18
DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

often its properties. Much of the human body is chiral.

Understandings:

Stereoisomers are subdivided into two classes—conformational isomers, which interconvert by rotation about a
σ bond and configurational isomers that interconvert only by breaking and reforming a bond.

Configurational isomers are further subdivided into cis-trans and E/Z isomers and optical isomers.

Cis-trans isomers can occur in alkenes or cycloalkanes (or heteroanalogues) and differ in the positions of
atoms (or groups) relative to a reference plane. According to IUPAC, E/Z isomers refer to alkenes of the form
R1R2C=CR3R4 (R1 ≠ R2, R3 ≠ R4) where neither R1 nor R2 need be different from R3 or R4.

A chiral carbon is a carbon joined to four different atoms or groups.

An optically active compound can rotate the plane of polarized light as it passes through a solution of the
compound. Optical isomers are enantiomers. Enantiomers are non-superimposeable mirror images of each other.
Diastereomers are not mirror images of each other.

A racemic mixture (or racemate) is a mixture of two enantiomers in equal amounts and is optically inactive.

Applications and skills:

Construction of 3-D models (real or virtual) of a wide range of stereoisomers.

Explanation of stereoisomerism in non-cyclic alkenes and C3 and C4 cycloalkanes.

Comparison between the physical and chemical properties of enantiomers.

Description and explanation of optical isomers in simple organic molecules.

Distinction between optical isomers using a polarimeter.

Content

10.1. Fundamentals of organic chemistry

10.2. Functional group chemistry

20.1. Types of organic reactions (HL ONLY)

20.2. Synthetic routes (HL ONLY)

20.3. Stereoisomerism (HL ONLY)

Skills
• Explanation of the trends in boiling points of members of a homologous series.
• Distinction between empirical, molecular, and structural formulas.
• Identification of different classes: alkanes, alkenes, alkynes, halogenoalkanes, alcohols, ethers, aldehydes, ketones, esters,
carboxylic acids, amines, amides, nitriles, and arenes.
• Identification of typical functional groups in molecules eg phenyl, hydroxyl, carbonyl, carboxyl, carboxamide, aldehyde,
ester, ether, amine, nitrile, alkyl, alkenyl, and alkynyl.
• Construction of 3-D models (real or virtual) of organic molecules.
• Application of IUPAC rules in the nomenclature of straight-chain and branched-chain isomers.
• Identification of primary, secondary, and tertiary carbon atoms in halogenoalkanes and alcohols and primary, secondary, and

Sekolah Victory Plus


Page 6 of 18
DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

tertiary nitrogen atoms in amines.


• Discussion of the structure of benzene using physical and chemical evidence.

Alkanes:

• Writing equations for the complete and incomplete combustion of hydrocarbons.


• Explanation of the reaction of methane and ethane with halogens in terms of a free-radical substitution mechanism involving
photochemical homolytic fission.

Alkenes:

• Writing equations for the reactions of alkenes with hydrogen and halogens and of symmetrical alkenes with hydrogen
halides and water.
• Outline of the addition polymerization of alkenes.
• Describe the relationship between the structure of the monomer to the polymer and repeating unit.

Alcohols:

• Writing equations for the complete combustion of alcohols.


• Writing equations for the oxidation reactions of primary and secondary alcohols (using acidified potassium dichromate(VI) or
potassium manganate(VII) as oxidizing agents).
• Explanation of distillation and reflux in the isolation of the aldehyde and carboxylic acid products.
• Writing the equation for the condensation reaction of an alcohol with a carboxylic acid, in the presence of a catalyst (eg
concentrated sulfuric acid) to form an ester.

Halogenoalkanes:

• Writing the equation for the substitution reactions of halogenoalkanes with aqueous sodium hydroxide.

(HL ONLY)

Nucleophilic Substitution Reactions:

• Explanation of why hydroxide is a better nucleophile than water.


• Deduction of the mechanism of the nucleophilic substitution reactions of halogenoalkanes with aqueous sodium hydroxide
in terms of SN1 and SN2 mechanisms.
• Explanation of how the rate depends on the identity of the halogen (ie the leaving group), whether the halogenoalkane is
primary, secondary or tertiary and the choice of solvent.
• Outline of the difference between protic and aprotic solvents.

Electrophilic Addition Reactions:

• Deduction of the mechanism of the electrophilic addition reactions of alkenes with halogens/interhalogens and hydrogen
halides.

Electrophilic Substitution Reactions:


• Deduction of the mechanism of the nitration (electrophilic substitution) reaction of benzene (using a mixture of concentrated
nitric acid and sulfuric acid).

Reduction Reactions:
• Writing reduction reactions of carbonyl-containing compounds: aldehydes and ketones to primary and secondary alcohols and
carboxylic acids to aldehydes, using suitable reducing agents.

Sekolah Victory Plus


Page 7 of 18
DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

• Conversion of nitrobenzene to phenylamine via a two-stage reaction.

• Deduction of multi-step synthetic routes given starting reagents and the product(s).
• Construction of 3-D models (real or virtual) of a wide range of stereoisomers.
• Explanation of stereoisomerism in non-cyclic alkenes and C3 and C4cycloalkanes.
• Comparison between the physical and chemical properties of enantiomers.
• Description and explanation of optical isomers in simple organic molecules.

Concepts
• "A homologous series is a series of compounds of the same family, with the same general formula, which differ from each
other by a common structural unit."
• "Structural formulas can be represented in full and condensed format."
• "Structural isomers are compounds with the same molecular formula but different arrangements of atoms."
• "Functional groups are the reactive parts of molecules."
• "Saturated compounds contain single bonds only and unsaturated compounds contain double or triple bonds."
• "Benzene is an aromatic, unsaturated hydrocarbon."

Alkanes:

• "Alkanes have low reactivity and undergo free-radical substitution reactions."

Alkenes:

• "Alkenes are more reactive than alkanes and undergo addition reactions. Bromine water can be used to distinguish between
alkenes and alkanes."

Alcohols:

• "Alcohols undergo nucleophilic substitution reactions with acids (also called esterification or condensation) and some
undergo oxidation reactions."

Halogenoalkanes:

• "Halogenoalkanes are more reactive than alkanes. They can undergo (nucleophilic) substitution reactions. A nucleophile is
an electron-rich species containing a lone pair that it donates to an electron-deficient carbon."

Polymers:

• "Addition polymers consist of a wide range of monomers and form the basis of the plastics industry."

Benzene:

• "Benzene does not readily undergo addition reactions but does undergo electrophilic substitution reactions."

(HL ONLY)

Nucleophilic Substitution Reactions:

• "SN1 represents a nucleophilic unimolecular substitution reaction and SN2 represents a nucleophilic bimolecular
substitution reaction. SN1 involves a carbocation intermediate. SN2 involves a concerted reaction with a transition state."
• "For tertiary halogenoalkanes the predominant mechanism is SN1 and for primary halogenoalkanes it is SN2. Both
mechanisms occur for secondary halogenoalkanes."

Sekolah Victory Plus


Page 8 of 18
DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

• "The rate determining step (slow step) in an SN1 reaction depends only on the concentration of the halogenoalkane, rate =
k[halogenoalkane]. For SN2, rate = k[halogenoalkane][nucleophile]. SN2 is stereospecific with an inversion of configuration
at the carbon."
• "SN2 reactions are best conducted using aprotic, non-polar solvents and SN1 reactions are best conducted using protic,
polar solvents."

Electrophilic Addition Reactions:

• "An electrophile is an electron-deficient species that can accept electron pairs from a nucleophile. Electrophiles are Lewis
acids."
• "Markovnikov's rule can be applied to predict the major product in electrophilic addition reactions of unsymmetrical alkenes
with hydrogen halides and interhalogens. The formation of the major product can be explained in terms of the relative
stability of possible carbocations in the reaction mechanism."

Electrophilic Substitution Reactions:

• "Benzene is the simplest aromatic hydrocarbon compound (or arene) and has a delocalized structure of π bonds around its
ring. Each carbon to carbon bond has a bond order of 1.5. Benzene is susceptible to attack by electrophiles."

Reduction Reactions:

• "Carboxylic acids can be reduced to primary alcohols (via the aldehyde). Ketones can be reduced to secondary alcohols.
Typical reducing agents are lithium aluminium hydride (used to reduce carboxylic acids) and sodium borohydride."

• "The synthesis of an organic compound stems from a readily available starting material via a series of discrete steps.
Functional group interconversions are the basis of such synthetic routes."
• "Retro-synthesis of organic compounds."
• "Stereoisomers are subdivided into two classes—conformational isomers, which interconvert by rotation about a σ bond
and configurational isomers that interconvert only by breaking and reforming a bond. Configurational isomers are further
subdivided into cis-trans and E/Z isomers and optical isomers."
• "Cis-trans isomers can occur in alkenes or cycloalkanes (or heteroanalogues) and differ in the positions of atoms (or groups)
relative to a reference plane. According to IUPAC, E/Z isomers refer to alkenes of the form R1R2C=CR3R4 (R1 ≠ R2, R3 ≠
R4) where neither R1 nor R2 need be different from R3 or R4."
• "A chiral carbon is a carbon joined to four different atoms or groups."
• "An optically active compound can rotate the plane of polarized light as it passes through a solution of the compound.
Optical isomers are enantiomers. Enantiomers are non-superimposeable mirror images of each other. Diastereomers are not
mirror images of each other."
• "A racemic mixture (or racemate) is a mixture of two enantiomers in equal amounts and is optically inactive."

Assessment

Formative assessment

• MCQ Problem Set with Answer Key


• Structured Questions

Note: These activities are given below.

Summative assessment
NOV TOPIC 10 Summative PAPER 1
23 HL SL Summative Paper 1 Tuesday at 8:30 AM

Sekolah Victory Plus


Page 9 of 18
DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

NOV TOPIC 10 Summative PAPER 2


30 HL SL Summative Paper 2 Tuesday at 8:45 AM

Learning Experiences

Prior learning experiences

Students should already understand the following:

• Students should
• Students should

Pedagogical approaches

Introduction to Unit

Learning objectives: Assess students' prior learning.

Students .

Students

Topic - Fundamentals of organic chemistry

Learning Objectives

10.1.1. U10: Serendipity and scientific discoveries - PTFE and superglue.

10.1.2. U10: Ethical implications - drugs, additives and pesticides can have harmful effects on both people and the
environment.

• Describe homologous series in organic compounds


• Describe structural formulas of hydrocarbons
• Describe the skeletal formulas of hydrocarbon
• Describe the stereochemical formula of hydrocarbons

Topic - Functional group chemistry

Learning Objectives:

10.2.1. U10: Use of data - much of the progress that has been made to date in the developments and applications of scientific
research can be mapped back to key organic chemical reactions involving functional group interconversions.

• Differentiate the types of functional groups


• Identify the types of funtional groups in a hydrocarbon
• Naming alkanes, alkenes, alkynes and branched-chain hydrocarbons
• Explain structural isomerism
• Differentiate the types of isomerism
• Classify organic compounds
• Classify the types of alcohol
• Classify the types of halogenoalkanes
• Classify the types of amines
• Name alcohols, carboxylic acids, aldehydes, ketones, and halogenoalkanes

Sekolah Victory Plus


Page 10 of 18
DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

• Describe esters
• Name esters, ethers, and amides
• Classify the types of amines
• Describe the properties of esters
• Determine the factors that affect the boiling points of organic compounds
• Differentiate homolytic and heterolytic bond fission

1. Practice Exercise: Identifying functional groups


2. Video Presentation: (1591) Testing for unsaturated hydrocarbons - YouTube

AHL

Topic - Types of organic reactions

Learning Objectives:

19.1.1. U19: Looking for trends and discrepancies - by understanding different types of organic reactions and their
mechanisms, it is possible to synthesize new compounds with novel properties which can then be used in several applications.
Organic reaction types fall into a number of different categories.

19.1.2. U19: Collaboration and ethical implications - scientists have collaborated to work on investigating the synthesis of new
pathways and have considered the ethical and environmental implications of adopting green chemistry.

• Explain the free radical substitution reactions of the alkanes


• Explain the combustion reactions of the alkanes
• Describe the test for unsaturation
• Explain the addition reactions for the alkenes
• Explain the addition polymerization
• Explain the combustion reactions of alcohols
• Explain the oxidation reactions of alcohols
• Explain the reactions of halogenoalkanes
• Explain the evidence for the structure of benzene
• Describe the reactions of benzene
• Describe the organic acids and bases

1. Video Presentation: (1634) 10.2 Reactions of benzene (SL) - YouTube


2. Video Presentation: (1634) Oxidation of Alcohols | Using Potassium Dichromate - YouTube

Topic - Synthetic routes

Learning Objectives:

19.2.1. U19: Scientific method - in synthetic design, the thinking process of the organic chemist is one which invokes retro-
synthesis and the ability to think in a reverse-like manner.

• Explain the Sn2 mechanisms


• Explain the Sn1 mechanisms
• Describe the stereochemistry of Sn reactions
• Determine the solvent of Sn1 and Sn2 reactions
• Differentiate between Sn1 and Sn2 reactions
• Explain the electrophilic addition reactions
• Explain the Markovnikov's rule

Sekolah Victory Plus


Page 11 of 18
DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

• Describe the nitration of benzene


• Describe the reduction of carbonyl compounds
• Explain the reduction of nitrobenzene
• Explain the retro-synthesis
• Explain the organic reaction pathways

1. Video Presentation: Making Medicines - YouTube


2. Video Presentation: 20.2 Organic reaction pathways (HL) - YouTube

Topic - Stereoisomerism

Learning Objectives:

19.3.1. U19: Transdisciplinary - the three-dimensional shape of an organic molecule is the foundation pillar of its structure and
often its properties. Much of the human body is chiral.

• Explain cis-trans isomerism


• Describe E/Z isomerism
• Explain stereoisomerism
• Describe the cyclic molecules
• Describe the chemical properties of isomers
• Describe the optical isomerism of simple organic molecules
• Differentiate the enantiomers and diastereoisomers
• Distinguish the enantiomers of a chiral compound e

1. Practice Exercise: Drawing and naming the stereoisomers of hydrocarbons

Feedback
• for improvement of teaching
• for improvement of learning

Student expectations
• practice exercises and problem sets
• formative and summative assessments
• acceptable evidence of understanding should depend on the marking schemes

Support materials

Examples
Sample Exam Questions
Mark Schemes

Learning Process

Lecture
PowerPoint lecture/notes

Sekolah Victory Plus


Page 12 of 18
DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

Activities

Problem Set with Answer Key

Problem_Set_10.1__with_Answer_Key_.pdf

Problem_Set_10.1.pdf

Problem_Set_10.2__with_Answer_Key_.pdf

Problem_Set_10.2.pdf

Practice Exercises with Answer Key

_1__Functional_Groups.pdf

_2__Nomenclature_of_Alkanes__Alkenes___Alkynes.pdf

_3__Classification_of_Organic_Compounds.pdf

_4__Alcohols_and_Carboxylic_Acids_Nomenclature.pdf

_5__Aldehydes_and_Ketones_Nomenclature.pdf

_6__Addition_Reactions_of_Alkenes.pdf

_7__Addition_Polymerization.pdf

_8__Reactions_of_Alcohols.pdf

_9__Esters.pdf

Practice Exercises with Answer Key (AHL)

_1__Markovnikov_s_Rule_with_Answers.pdf

_2__Synthetic_Routes_with_Answers.pdf

Problem Set with Answer Key (AHL)

PROBLEM_SET__ANSWER_KEY_.pdf

Problem_Set_1-7.jpg

Problem_Set_8-10.jpg

Differentiation

Value prior knowledge


Scaffold learning

Reflections & Evaluation

General Reflections & Evaluation

Prior to studying the unit

Sekolah Victory Plus


Page 13 of 18
DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

Dea Sukrisna, S.Pd . Jan 13, 2022 at 9:40 PM

the knowledge of chemical bonding is used to determine students readiness. When planning the learning experience,
teacher prepare a self assessment on the chemical bonding.

During the unit

Dea Sukrisna, S.Pd . Jan 13, 2022 at 9:43 PM

What did we find compelling? the students struggle with organic reaction and functional group. This is indeed because of
the weak understanding in chemical bonding. Students with stronger understanding of chemical bonding able to understand
the content easier.

Notes/changes/suggestions:

Dea Sukrisna, S.Pd . Jan 13, 2022 at 9:43 PM

There is a possibility of move the unit right after chemical bonding

What worked well

Dea Sukrisna, S.Pd . Jan 13, 2022 at 9:44 PM

naming compound probably is the most successful part of the unit

What didn’t work well

Dea Sukrisna, S.Pd . Jan 13, 2022 at 9:45 PM

The planning went longer that it was planned due to the additional time needed to review chemical bonding

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Page 14 of 18
DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

Stream & Resources

Resources

Regine Alfonso Balagtas, BSCT .


Posted 7 files on Jun 2, 2021 at 3:01 PM

Organic Chemistry (AHL) topics

_1__Sn1_and_Sn2_Mechanism.pdf
3 MB PDF Document

_2__Markovnikov_s_Rule__Nitration_of_Benzene___Reduction_of_Carbonyl_Compounds.pdf
2 MB PDF Document

_3__Reduction_of_Nitrobenzene___Synthetic_Routes__Retro-synthesis_.pdf
2 MB PDF Document

_4__Isomerism__Intro_to_cis-trans__E-Z_.pdf
4 MB PDF Document

_5__Configurational_Isomerism.pdf
1 MB PDF Document

_6__Optical_Isomerism.pdf
2 MB PDF Document

_7__Conformational_Isomers.pdf
900 KB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:30 PM

Problem Set 10.2 with Answer Key

Problem_Set_10.2__with_Answer_Key_.pdf
200 KB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:29 PM

Problem Set 10.1 with Answer Key

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DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

Problem_Set_10.1__with_Answer_Key_.pdf
100 KB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:28 PM

Practice Exercises on Esters

_9__Esters.pdf
400 KB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:27 PM

Practice Exercises on Reactions of Alcohols

_8__Reactions_of_Alcohols.pdf
400 KB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:26 PM

Practice Exercises on Addition Polymerization

_7__Addition_Polymerization.pdf
300 KB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:25 PM

Practice Exercises on Addition Reactions of Alkenes

_6__Addition_Reactions_of_Alkenes.pdf
300 KB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:24 PM

Practice Exercises on Aldehydes and Ketones Nomenclature

_5__Aldehydes_and_Ketones_Nomenclature.pdf
200 KB PDF Document

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DP UNIT 10 & 20. ORGANIC CHEMISTRY
DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:21 PM

Practice Exercises on Alcohols and Carboxylic Acids Nomenclature

_4__Alcohols_and_Carboxylic_Acids_Nomenclature.pdf
200 KB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:20 PM

Practice Exercises on Classification of Organic Compounds

_3__Classification_of_Organic_Compounds.pdf
300 KB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:19 PM

Practice Exercises on Nomenclature of Alkanes, Alkenes, and Alkynes

_2__Nomenclature_of_Alkanes__Alkenes___Alkynes.pdf
300 KB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:18 PM

Practice Exercises on Functional groups

_1__Functional_Groups.pdf
200 KB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:13 PM

Slides on Organic Reactions and Benzene (continuation)

_5__Continuation_of_Organic_Reactions_and_Benzene.pdf
5 MB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:12 PM

Slides on Organic Reactions, Factors Affecting Boiling Points of Organic Compounds

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DP UNIT 10 & 20. ORGANIC CHEMISTRY
Sekolah Victory Plus Regine Alfonso Balagtas, BSCT ., Dea Sukrisna, S.Pd .

IB DP Chemistry (Grade 12) Line 6

_4__Organic_Reactions___Factors_Affecting_Boiling_Points_of_Organic_Compounds.pdf
7 MB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:11 PM

Slides on Nomenclature and Classification of Organic Compounds (continuation)

_3__Continuation_of_Nomenclature_and_Classification_of_Organic_Compounds.pdf
2 MB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:09 PM

Slides on Structural Isomerism, Nomenclature and Classification of Organic Compounds

_2__Structural_Isomerism__Nomenclature_and_Classification_of_Organic_Compounds.pdf
8 MB PDF Document

Regine Alfonso Balagtas, BSCT .


Posted 1 file on May 31, 2021 at 6:08 PM

Slides on Homologous Series, Functional Groups, Nomenclature of Alkanes, Alkenes, Alkynes

_1__Homologous_Series__Functional_Groups___Nomenclature_of_Alkanes__Alkenes___Alkynes_.pdf
8 MB PDF Document

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