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MECS® SULFURIC ACID AND ENVIRONMENTAL

TECHNOLOGIES

requirements or solve crucial plant Key Benefits to Your Organization


operating bottlenecks. Our solutions can ■ Recovery of salable concentrated
help you increase process reliability and sulfuric acid
energy efficiency, even as you lower your
■ Recovery of valuable high-pressure
operating and maintenance costs.
steam for concentrated H2S feeds
Our experts bring a practical approach ■ Guaranteed ultra-low acid mist
to plant evaluations, troubleshooting, emissions exceed the most stringent
and new technology solutions. A high regulated values
percentage of MECS® personnel ■ Low SO2 emissions, custom-designed
—in process, design and solution per local regulations
engineering, as well as project and
■ Low operating costs
product management—have previous
plant operating, maintenance and start- ■ Easy and safe equipment inspection
up experience. Our design engineering and maintenance
group features all the disciplines needed ■ Reliable plant operation
to create world-class process-related
technology. To this end, we employ state- DynaWave® Wet Gas Scrubbers
MECS® IS THE LEADING PROVIDER OF of-the-art tools such as 3D CAD and CFD. DynaWave® is the only wet gas scrubbing
PROPRIETARY PROCESS TECHNOLOGY, Backed by nearly 100 years of experience, process that can use a variety of reagents
SPECIALTY PRODUCTS AND TECHNICAL our expert consultants can work closely and accomplish multiple functions—
SERVICES TO THE GLOBAL SULFURIC with your team to analyze, recommend, including SO2 acid gas absorption,
ACID INDUSTRY. engineer and implement a custom solution quenching, particulate removal, and
for your specific needs. oxidation—all in one scrubber. A unique,
MECS® has provided best-in-class sulfuric high-performance environmental
acid plant processes, clean technologies, World-Leading Sulfuric Acid Plant Processes technology, DynaWave® has been
and specialty products to a wide MECS® has a long and successful history implemented by MECS® in over 300
distribution of industries for over 80 years. in providing proven and reliable solutions solutions worldwide, in various industries.
Our proprietary solutions are engineered to the sulfuric acid industry. Our solutions
to perform and built to last. feature breakthrough technologies, many Most industry applications require a wet
of which have revolutionized performance, gas scrubber to perform two or more of
MECS® is the global leader in sulfuric acid the following functions.
plant design and technology licensing for quality and cost-effectiveness for the
sulfuric acid industry. We offer complete 1. Quench incoming gas
the phosphate fertilizer, oil refining, metal
smelting, and numerous other industries. processes and plant designs for sulfur 2. Remove acid gases
Our expert engineers apply the centuries burning, metallurgy, spent acid recovery,
3. Oxidize sulfites to sulfates
of combined experience MECS® and and wet gas sulfuric acid recovery
(SULFOX). 4. Eliminate particulate matter
DuPont have acquired in building over
1000 acid plants worldwide, as well as in In many conventional scrubbers or simple
SULFOX Wet Gas Sulfuric Acid Recovery
producing and safely handling numerous caustic scrubbers, each function occurs in
Process
compounds in our own facilities. a different area of the vessel, or outside
The SULFOX wet gas sulfuric acid process the scrubber altogether. The DynaWave®
ENGINEERED TO PERFORM AND is suitable for a wide range of applications Wet Gas Scrubber is different from
BUILT TO LAST in which wet waste gas, containing H2S, conventional scrubbers in that it handles
At the core of our technical expertise CS2 or SO2, must be desulfurized. Our all four of these functions in the same
are our commitment to quality and our expert engineers can deliver results vessel. Three of the functions take place
reputation for proven product innovation. for clients in a vast array of industries, in a unique area known as the Froth Zone.
Expert MECS® consultants can customize including metallurgical, general chemical, The fourth function, oxidation, is achieved
our technical services and proprietary coal gasification, coal-based fertilizer, in situ in the vessel sump. No other
technologies to achieve new performance natural gas processing, steel, power, scrubber is capable of this performance.
gains for your organization. We can viscose fibers, pigments production, and
help you meet and exceed regulatory refinery and petro-chemical, among others.
Our straightforward approach reduces hanging mist eliminator seal system and footprint. New installations may also
both capital and operating costs. design: deletion of stainless steel piping, benefit from using standard design vessel
Most importantly, it allows for minimal reduced field labor for installation, sizes with element blank offs for future
equipment inside the vessel, making enhanced safety and no need for future expansion capability.
DynaWave® an extremely reliable and seal system inspection or maintenance
low-maintenance scrubber. repairs. In addition, plate and vessel Innovative Heat Exchange Technologies
savings from a smaller diameter tower MECS® gas-to-gas heat exchangers offer
Brink® Mist Eliminators design may be realized, should that option one of the most efficient means on the
MECS® offers the industry’s broadest be pursued. market for recovering heat from energy-
range of products designed to remove consuming applications in a wide range
virtually any type of mist from any gas For existing plants, all of the benefits noted of industries. Both our fully welded plate
stream, including elusive submicron- above can be realized, except the option and non-welded “floating” plate units have
sized aerosol mists. Thousands of our for smaller tower design. In addition, delivered results in sulfuric acid plant,
systems have been installed in hundreds for new Brink® element replacement in fertilizer, refining, non-ferrous metals,
of applications: from sulfuric acid to existing facilities, the extra height available general chemicals, and coal gasification
asphalt manufacturing, plastic extrusions, can allow for longer functional process installations, as well as many others.
metalworking, and beyond. length on the Brink® AutoDrain™ elements,
resulting in de-bottlenecking opportunities. All MECS® gas-to-gas heat exchangers
®
From the invention of Brink Fiber Bed Lower pressure drop and/or increased feature a compact, modular design and
Mist Eliminators in 1958, MECS® has plant rates may be realized. Fast track long service life. The units are shop-
set the standard for offering the widest turnarounds can be achieved due to less fabricated to ensure quality, and trucked
array of designs and materials in mist field work required. as individual blocks or complete modules.
eliminators worldwide. Today, we meet With their compact size and weight,
the needs of global clients in a broad For retrofits/re-packs, the same benefits installation and field setup are much
range of industries, from sulfuric acid to noted for existing plants can be realized. simpler than with conventional shell and
asphalt manufacturing, plastic extrusion, Modification to element screen cages tube heat exchangers.
metalworking, and many other industries. and the addition of proprietary embedded
Brink® Fiber Bed Mist Eliminators feature drainage devices will be installed to MECS® gas-to-gas heat exchangers are
the latest technology, to effectively remove incorporate the Brink® AutoDrain™ design available in both cross-flow and counter-
fine aerosol mists, submicron oil smoke, during an element re-pack. The retrofit flow configurations. Our modular approach
and soluble solids from process gas elements will operate like new Brink® enables us to offer one of the most
streams and stack effluents. Our solutions AutoDrain™ mist eliminators without the flexible and efficient flow arrangements
protect valuable downstream equipment, need for filling seal cups, materials and available, as well as the flexibility to
optimize operations, and minimize labor for seal cups and/or drain piping. expand to accommodate future increases
environmental impact, while delivering the in capacity. This modular approach also
Brink® eXtra Performance XP™ enables significant design and operational
highest efficiency, lowest pressure drop,
and longest effective life available today. Following a decade of research and customization, including the freedom to
over 5 years of commercial acid plant select distinct materials of construction
Brink® mist elimination solutions for over experience, MECS® now designs and for each heat transfer zone. Each module
300 applications have been installed in builds the eXtra Performance XP™ for all can be fabricated from a variety of heavy-
over 5000 facilities around the globe. acid towers. The eXtra Performance offers gauge carbon steel and stainless steel
Our engineers can help your organization the lowest pressure drop available in one plates, including COR-TEN®, 304L, 316L,
select and optimize a Brink® solution to one match-ups when compared to and 309S. Heavy-duty MECS® gas-to-
for your application needs, whether you other elements. The pressure drop per XP gas heat exchangers, built with robust
wish to improve process equipment element is 1/3 less than a typical element materials, can deliver reliable and efficient
design, operation, and product quality, of the same size and efficiency. As a performance in the most demanding,
or seek to reduce stack opacity to avoid result, a sulfuric acid plant may use up to corrosive, and high-temperature
environmental citations. one third fewer filter elements at the same applications, up to 1500 °F (816 °C).
delta P, and fewer filter elements means
Brink® AutoDrain™ Fiber Beds for Sulfuric lower life-cycle maintenance costs. New Heat Recovery System
Acid Plants installations can benefit from lower initial The MECS® Heat Recovery System
® ®
New from MECS is Brink AutoDrain ™
capital cost due to smaller vessel size is a proven technology that is well
providing effective draining of acid from positioned for today’s value, energy and
Brink® mist eliminators without the environmentally conscious world and few
use of expensive and complex seal leg industrial process investments can both
piping systems. save money plus reduce greenhouse
gases. The MECS® HRS captures and
For new installations, Brink® AutoDrain™ re-uses waste heat from the sulfuric
offers a significant initial cost reduction acid process and converts it to medium
and life cycle maintenance cost and a pressure steam. In addition to producing
shortened project schedule. Additional
value can be realized by eliminating the COR–TEN® is a registered trademark of U.S. Steel Corporation.
ZeCor® replacement parts and sulfuric proper type of catalyst to maximize value
acid plant equipment help our clients for your sulfuric acid plant.
quickly and cost-effectively strengthen
weak links. We offer a complete line of High-Performance GEAR™ Series
ZeCor®-fabricated major components and Our latest catalysts feature a hexa-lobed
accessories. ring shape and higher activity to reduce
■ Nozzle assemblies or sleeves are pressure drop and improve performance.
available in ZeCor®-Z, ZeCor®-310M The GEAR™ Series’ distinctive design helps
and ZeCor®-C to repair damage and increase energy savings, extend operating
significantly reduce the safety hazards time, boost acid production, and reduce
of acid leaks. overall plant SO2 emissions.
electricity in turbine-generators, for sale This innovative sulfuric acid catalyst is
■ Inline Strainers are available, as well as
or use, the HRS supplemental steam may characterized by its:
side and bottom Outlet Nozzles with
be utilized within the process, in the plant
Vortex Breakers. ■ Geometrically optimized shape
proper and adjacent facilities with no net
consumption of fossil fuel or energy. ■ Packing Support Grids in ZeCor -Z and
®
■ Enhanced surface area
ZeCor®-310M are designed with more ■ Activity improvement
The newest breakthrough is the than 80% open flow area, resulting
■ Reduced pressure drop
SteaMax HRS™ System. It provides in excellent gas distribution, and can
for a significant increase in medium replace ceramic grid bars and locks. Designated as GR-330 and GR-310,
pressure steam, adding to the flexibility ■ Prefabricated Grating makes handling GEAR™ catalysts allow interchangeable
of the steam’s use and customization and installation easier, while providing use in all passes of the converter.
for site specific energy requirements enhanced performance over ceramic GR-330 is produced in a 13 mm diameter
and other local conditions. When the systems. size, while GR-310 is 12 mm in diameter.
unit cost for energy is high, and if the
■ TowerGARD® Mesh Pads offer Extended Surface Area — XLP Series
local requirements for steam are met,
outstanding mesh pad mist elimination
commercial opportunities for production Our XLP Series enables low pressure
with a longer service life.
of electricity can provide electrical grid drop and high conversion performance
offsets or a revenue stream from the sale ■ UniFlo® Acid Distributors ensure in all beds of the converter. XLP catalyst
of the electrical energy. Sulfuric acid plants uniform acid distribution and less is the industry standard in sulfuric acid
throughout the world can utilize and profit pressure drop. plants today.
from the recovered heat and enhanced ■ Towers and Pump Tanks can be shop-
steam generation provided by the MECS® fabricated prior to plant shutdown, Rings — LP Series
SteaMax HRS™ System. and staged on site for insertion of This series offers moderate pressure drop
UniFlo® Acid Distributors, Brink® Mist and high activity.
Engineered Alloy Products Eliminators, and tower packing such
We revolutionized the sulfuric acid industry as WavePak™, which dramatically Pellet Type
with a full line of corrosion-resistant increases efficiency. Our pellet design is ideal for low gas
equipment in our cost-effective ZeCor® velocity converters and applications where
■ Piping Systems and Fittings come
family of alloys, exclusively available from maximum durability is required for lower
standard or custom-fabricated in various
MECS®. All of our specialty products, from screening losses.
sizes, to quickly and cost-effectively
high-performance alloys to innovative
upgrade or repair acid piping systems. Cesium Promoted
tower packing, join distinctive materials
with MECS® process and design expertise, ■ Replacement Acid Cooler parts and our This catalyst series enables low plant stack
to deliver solutions that keep plants FILMGARD® 5 system can upgrade emissions and lower ignition temperatures
operating safely and smoothly. any existing anodic protection (AP) for faster plant start-ups.
acid coolers with a common, centrally
Controlling corrosion in sulfuric acid controlled system that monitors up Sulfuric Acid Plant Services and Solutions
equipment ranks among the top concerns to three coolers with one operator Whether you’re considering an acid plant
of every acid plant owner. MECS® ZeCor® interface. expansion, or seek to improve plant
products apply our decades of acid plant reliability or optimize plant operation,
experience and technology innovation High-Performance Catalyst for Sulfuric Acid
our Global Engineered Solutions (GES)
to solve the problem of corrosion. The Plant Applications professionals are an integral extension of
superiority of our designs resides in High quality MECS® catalyst, derived from the MECS® sulfuric acid technology teams.
our attention to fine details and our our research and development efforts, Backed by over two centuries of combined
quality fabrication. The superiority of our balance and optimize the key attributes experience, the design and construction
performance lies in our exclusive ZeCor® of activity, pressure drop, hardness, and of over 1000 acid plants, and the current
alloys. This unique line of specialty metal service life. MECS® has the complete operation and ownership of ten acid
alloys is proven to provide long-lasting technical expertise, proven catalyst plants, DuPont and MECS® bring real-life,
resistance to corrosion and durable performance, and overall sulfuric acid proven solutions to your facility.
service against the unforgiving abuse of plant production knowledge to specify the
sulfuric acid.
Consulting services for sulfuric acid
plants and acid handling systems
■ Turnaround consulting, planning and
management
www.mecsglobal.com
■ Commissioning support
■ Mechanical integrity assessments North America
MECS Headquarters
■ Acid plant design, performance and
Chesterfield, Missouri 63017 USA
reliability studies Tel: +1-314-275-5700
■ Acid handling, storage, and transfer northamerica@mecsglobal.com
systems design and performance
Europe/Africa
reviews Brussels, Belgium
GES offers operational consulting and ■ HAZOP and troubleshooting services MECS Europe/Africa BVBA
equipment designs, supplies, and repairs ■ Startup and shutdown consulting Tel: +32-2-658-2620
focused on reliability, operability, the europe-africa@mecsglobal.com
environment, and safety. Our experts Process-critical equipment design, Milan, Italy
can help your sulfuric acid facility with supply and repair MECS Europe/Africa BVBA
everything from throughput and yield ■ Proprietary equipment supply and repair Phone: +39-02-8969-0658
optimization to uptime and reliability italy@mecsglobal.com
■ Specialized instrumentation and
improvements. We offer turnaround,
analyzers Johannesburg, South Africa
revamp and troubleshooting services, as
MECS Europe/Africa BVBA
well as mechanical integrity assessments, ■ Alloy valves and acid gas damper valves
Tel: +27-11-708-9860
process-critical equipment replacements, ■ Steaming equipment and boiler ferrules southafrica@mecsglobal.com
process troubleshooting, energy ■ Plate heat exchangers
optimization, capital project effectiveness, Asia/Pacific
■ Burners and burner management Hong Kong, China
safety assessments, operator training,
systems (BMS) MECS Far East Limited
and more.
Tel: +852-2734-5388
■ Specialized pumps, hoses, expansion
Our comprehensive consulting programs hongkong@mecsglobal.com
joints, bellows, and tower internals
are designed to follow a progressive Shanghai, China
three-phased approach, improving your Training products, services and solutions MECS Chemical Plants
organization’s performance and maximizing ■ Operator training simulators Equipment (Shanghai) Co., Ltd
asset utilization until world-class programmed with real-life scenarios Tel: +86-21-6182-1111
performance is obtained. Our team works shanghai@mecsglobal.com
■ Interactive training sessions
with you every step of the way to sustain Mumbai, India
■ Customized training programs
and build on your gains. We can help your MECS India Private Ltd.
unit operations to quickly start realizing Tel: +91-22-6744-9500
these benefits: india@mecsglobal.com
■ Step-change improvements in acid South America
plant reliability and uptime Barueri, Sao Paulo, Brazil
■ Significant reductions in annual MECS, Inc.
DuPont Sustainable Solutions
maintenance and capital expenses
Tel: +55-11-4166-8000
■ Reduction of sulfur oxide (SOx) and brazil@mecsglobal.com
nitrogen oxide (NOx) emissions

Worldwide DuPont Sales and Support


The information set forth herein is furnished free of charge and is based on technical data that DuPont believes to be For additional information contact:
reliable. It is intended for use by persons having technical skill and at their own discretion and risk. Because conditions of
use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use MECS® Sulfuric Acid and
of this information. Nothing herein is to be taken as a license to operate under or a recommendation to infringe any patents. Environmental Technologies
14522 South Outer Forty Road, Suite 100
Copyright © 2012 DuPont. The DuPont Oval Logo, DuPont™, The miracles of science™, Brink®, Brink® AutoDrain™ , DynaWave®,
eXtra Performance XP™, FILMGARD®, GEAR™, SteaMax HRS™, TowerGARD®, UniFlo®, WavePak™, ZeCor®, and MECS® are Chesterfield, Missouri USA 63017
registered trademarks or trademarks of E.I. du Pont de Nemours and Company or its affiliates. All rights reserved. Phone: +001 314-275 5700
K-25707 (01/12) Printed in the U.S.A.
www.cleantechnologies.dupont.com

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