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Reiner Eisenring | Michiel van Ettinger | 29-11-2017

Commissioning
Training
www.berghofmembranes.com
Page 2

Agenda

Berghof introduction
Product range
Basics of Cross-flow Ultrafiltration
BioFlow & BioPulse system
Control philosophy
Biopulse operation in detail
Case study
Commissioning Training | www.berghofmembranes.com
Page 3

Commissioning Training | www.berghofmembranes.com


Page 4

Products & instruments

Automation &
Fluoroplastics control

Membranes

Engineering & management

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Products & instruments
Page 5

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Page 6

Product range
• Tubular membranes
• Low solids (5 mm)
• High solids (8 mm)
• Chemical Resistant
• Membrane skids
• Pilot units/ piloting
• Engineering & Commissioning
• Project management
Commissioning Training | www.berghofmembranes.com
Page 7

What is a membrane doing?


Permeate

Feed Concentrate

Membranes separats a Feed (stream) into a higher concentrated


Retentate (or Concentrate) and a lower concentrated Permeat

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Page 8

How can a membrane do this?

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Page 9

How can a membrane do this?

Source: Visual Encyclopedia of


Chemical Engineering

Membranes are simple walls with many holes!

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Page 10

How can a membrane do this?

Source: Visual Encyclopedia of


Chemical Engineering

Very tiny holes!

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Page 11

How can a membrane do this?

Source: Visual Encyclopedia of


Chemical Engineering

The holes are called pores!

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Page 12

Membrane types

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Page 13

How does membranes looks like?

Flatsheet (outside – in)

Hollow fibre (outside – in)

Tubular (inside – out)

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Page 14

How are membranes operated?

2 basic principels: Dead-end and Cross-flow Filtration


Page 15

How are membranes operated?

2 basic principels: Dead-end and Cross-flow Filtration

Dead-end
Page 16

How are membranes operated?

2 basic principels: Dead-end and Cross-flow Filtration

Dead-end Cross-flow
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For MBR-application only Cross-flow-Filtration is


suitable. Why?

1. Dead-end-Filtration is a discontinuous filtration mode

2. Only cross-flow filtration guarantees control of the filter cake

3. High solid content of Bioreactor would immediately bloc Dead-end


filtration membranes

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Page 18

Control of filter cake – cross-flow velocity

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Page 19

Function of membranes in Bioprocess

Bioreactor Secundary Sand filters &


Pre- Primary
Clarifier Desinfection
treatment Clarifier

Influent Effluent

Thickener

Dehydration
system

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Page 20

Membrane Bioreactor treatment

Pre- Bioreactor
Treatment

Influent Effluent

Membrane filtration
system
Dehydration
system

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Page 21

MBR treatment (submerged and external)

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Page 22

MBR treatment (submerged and external)

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Page 23

Submerged Influent
Permeate

Bioreactor

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Waste sludge
Page 24

External Influent Retentate Recycle

Bioreactor
Permeate

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Waste sludge
Page 25

External
EXTERNAL ULTRA FILTRATION
BASED ON
Influent Retenate Recycle
INSIDE-OUT PRINCIPLE.
The solution for
fouling sensitive
Bioreactor applications
Permeate

Waste sludge

Commissioning Training | www.berghofmembranes.com


Page 26

External
EXTERNAL ULTRA FILTRATION
BASED ON
Influent Retenate Recycle
INSIDE-OUT PRINCIPLE.
The solution for
fouling sensitive
Bioreactor applications
Permeate
Easy accessibility for
cleaning & maintenance

Waste sludge

Commissioning Training | www.berghofmembranes.com


Page 27

External
EXTERNAL ULTRA FILTRATION
BASED ON
Influent Retenate Recycle
INSIDE-OUT PRINCIPLE.
The solution for
fouling sensitive
Bioreactor applications
Permeate
Easy accessibility for
cleaning & maintenance

Higher fluxes with


a smaller footprint
Waste sludge

Commissioning Training | www.berghofmembranes.com


Page 28

Comparison
Design Advantages Disadvantages
Flat Sheet Wide choice of membranes High costs
(Submerged)
Can be dissembled and cleaned Membrane replacement process is time
consuming
Low energy requirement
Hollow Fiber Very compact system Can get fouled with particulates
(Submerged)
Low liquid hold up Not suitable for viscous liquids

Low capital costs Comparatively limited range of products

Tubular Can tolerate feeds with high suspended solids High energy requirements?
(External)
Can work with viscous liquids High capital costs?
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Easy to clean Requires large space?
Page 29

Important parameters
Pressures
• Pressure drop over a module: ∆P = Pin – Pout
• Permeate pressure: Pperm
• Av. Pressure over a module: Pav = (Pin + Pout)/2
• TMP = Pav - Pperm
Keep it constant in the range of 1 – approx. 2.5 bar
During backwash: negative TMP!

Concentration factor
• Flow feed/ Flow concentrate: Cf = Ffeed/Fconcentrate
Keep it 1.1-1.15 or maybe 1.2 depending on application
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Page 30

Important parameters
Flux
• Flux = Qpermeate/Amembrane (L/m² x h)
Typical values: 55 – 100 L/m²*h

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Page 31

Berghof tubular membranes

Operation parameter:
pH-Value: 5–9
Max. Inlet Pressure (inside): 7 bar
Max. negative TMD: - 0,6 bar (during Back-wash)
Max. Temperature: 40 °C

No use of silica containing Anti-foam agents in Bioreactor!

Commissioning Training | www.berghofmembranes.com


Page 32

Berghof tubular membranes

Parameter during cleaning:


pH-Value: 2 – max. 10 (exceptional 11)
Max. Inlet Pressure (inside): 7 bar
Max. Temperature: 40 °C
Max. concentration of free chlorine: 200 ppm (Natriumhypochlorite contents
59% aktive Chlorine!)

Caution: Operation outside the defined parameter will lead in loss of guarrantee!

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Page 33

Berghof solution for tubular MBR external systems

BioFlow

BioPulse

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Page 34

BioFlow technology

High turbulent flow parallel among the membrane surface


Excellent fouling control results in high flux rates
Efficient and easy to clean
Reliable and robust process
Optimized energy consumption due to optimization of process and membrane – and module
design.

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Membrane Technology Page 35

External Berghof MBR concepts


Bioflow: robust, high reliability

• Treatment of liquids with extremely high fouling potential


• Low investment cost (high permeate flux rate 75 – 120 l/m²h)
• Small footprint
• Easy cleaning & maintenance

Waste water Berghof BioFlow

BIO-
High Energy Consumption
5m
Reactor 2,2 - 7,0 kWh/m³ permeate
Permeate
Feed Recirculation
pump pump
3,5 - 4,5 m/s
Commissioning Training | www.berghofmembranes.com
Page 36

Bioflow
Flux: 75- 120 l/m2h
Permeate

Feed Concentrate
3.5 – 4.5 m/s

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Membrane Technology Page 37

External Berghof MBR concepts


Biopulse: Low energy, high flexibility

• Innovative self-regulating side stream concept


• Most economical treatment at any time
• Intelligent fouling control software

Waste water Berghof BioPulse

Permeate

BIO-
Permeate Low Energy Consumption
5m suction pump
Reactor 0,4 – 1,0 kWh/m³ permeate

Feed pump Backwash


1,0 - 2,0 m/s pump

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Page 38

Berghof Biopulse system

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Page 39

Biopulse technology
Modular design
Engineering innovation by smart control:
System checks the individual TMP of the membranes
If TMP is changing the system automatically reacts with:
1. Increasing crossflow
2. Permeate backwash
3. Permeate backwash + chemicals
4. Flushing (after every stop, periodically)
5. Cleaning In Place

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Page 40

Biopulse
Flux: 40 - 80 l/m2h
Permeate

Feed Concentrate
1 - 2 m/s

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Page 41

Bioflow energy consumption

10,00
60 l/m²h
9,00 l/m²h
8,00
BioFlow 70 l/m²h

80 l/m²h
7,00
90 l/m²h
6,00
100 l/m²h
kWh/m³

5,00

4,00

3,00

2,00

1,00

0,00
2,5 3 3,5 4 4,5 5
m /s

Commissioning Training | www.berghofmembranes.com


Page 42

Biopulse energy consumption

7 45 l/m²h
50 l/m²h
6
55 l/m²h
60 l/m²h
5
Biopulse 70 l/m²h
80 l/m²h
kWh/m³

4
90 l/m²h
3 100 l/m²h

0
0,5 1 1,5 2 2,5 3 3,5 4

m/s

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Page 43

Fouling sources

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Page 44

Fouling process

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Page 45

Actions for maintaining permeate production

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Page 46

1. Increase crossflow
Permeate

Feed Concentrate
2 - 3 m/s ↑

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Page 47

2 Backwash
Backwash

Feed Concentrate
1.0 - 1.5 m/s

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Page 48

3. Chemical Enchanted Backwash (CEB)


Backwash

Feed Concentrate
1.0 - 1.5 m/s

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Page 49

4. Flushing

Water Water
2 - 3 m/s ↑

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Page 50

5. Cleaning in Place (CIP)


Permeate

Circulation 1.0 - 3.0 m/s


TMP 0.5 – 3.0 bar Concentrate

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Page 51

CIP procedure

1. Drop down of Flux (permeat flow)


Increase of TMP:
Reason: Blocking of the pores Action: -> Cleaning at higher Baseline
Build up of Filter cake pressure (> 1 – 1,5 bar)
Stronger infiltration of cleaning
agent through pores

2. Increase of pressure drop/ module


Reason: accumulation of biomass Action: -> Cleaning at low Baseline
inside of tubes pressure and high flow rate
(high turbulence)

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Page 52

Cleaning

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Page 53

Cleaning Transmembrane Pressure

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Page 54

Focus of operators
In order to prevent decreasing membrane performance and/or taking the right
actions operators should monitor and always b informed about development of

1. permeate Flux (permeat flow)


2. pressure drop/ Module
3. TMP
4. spec. energy consumption

Commissioning Training | www.berghofmembranes.com


Page 55

Cleaning Agents

Type of Foulant Cleaning Agents


Mineral Deposits/Precip. Salts Acids
Organic Foulants Alkalis
Micro-organisms Enzymes
Oils, Fat and Grease Detergents

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Page 56

Matten

• BioPulse
• 6 modules + 1 dummy = 7 module positions
• Feed/ Bleed
• Permeate flow: 20 m3/h
• Circulation flow: 96 - 240 m3/hr (crossflow 1.0 - 2.5 m/s) estimated
• Pressure drop/ module: approx. 0.5 bar
• pH: 2 - 10 (max!) during cleaning

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Page 57

Feed skid

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Page 58

UF skid
Page 59

CIP skid

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Page 60

Operation Mods/Sequences:

Filtration -> Production of clear water/ Product


Flushing -> Removing sludge from membrane
Preparing Stand-by situation
Special Flushing -> Emergency flushing in case of blocked
strainer
Back-wash -> Filtration with periodical displacement of filter
cake from permeate side
can be done with or without chemicals
Cleaning in Place (CIP)-> indroduction of cleaning agends from concentrate
side to membranes
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Page 61

Filtration

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Operation sequences:
Filtration

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Operation sequences:
Filtration

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Operation sequences:
Filtration

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Operation sequences:
Filtration

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Operation sequences:
Filtration

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Filtration
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Filtration
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Filtration
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Filtration
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Filtration
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Filtration
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Filtration
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Filtration
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Filtration
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Filtration
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Filtration
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Filtration
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Filtration
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Filtration
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Flushing

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Page 82

Operation sequences:
Flushing

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Operation sequences:
Flushing

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Operation sequences:
Flushing

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Operation sequences:
Flushing

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Operation sequences:
Flushing

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Operation sequences:
Flushing

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Operation sequences:
Flushing

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Page 89

Operation sequences:
Flushing

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Flushing
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Flushing
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Flushing
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Flushing
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Flushing
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Flushing
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Flushing
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Flushing
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Flushing
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Flushing
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Flushing
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Flushing
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Flushing
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Filtration with Back-wash

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Page 104

Filtration
with BW
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Filtration
with BW
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Filtration
with BW
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Filtration
with BW
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Filtration
with BW
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Questions?

Commissioning Training | www.berghofmembranes.com

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