Practical Chemisty

144
solution.
thiosulphate
of sodium N
B. Strength solution
thio solution
= 10 ml. of 50 KCr0, n

9.5 ml of
10xN=
Normality5y 0.021 N.
s00.021 N.

Amount of Free Chlorine

C. N hypo solution
2.0 ml of 0.021
50 ml. of water
sample=
2 x 0.021
Normality 50

Strength
2 x 0.021 x 35.5 gm./litre
50
0.0298 x 10 DDI
Ppm.
10
= 29.8 ppm.

6. Result:
Free chlorine = 29.8 ppm.

7. Precautions:
used.
starch solution should be
(i) Freshly prepared titration.
water should be used throughout the
(ii) Distilled
be added just near end point.
(ii) Starch solution should
solution should be kept in
between 7-
(iv) The pH of the sample
solution.
by adding acid/alkali to the sample
the teacher.
(iv) Any special instruction by

EXPERIMENT NO. 8.7

1. Object le
To estimate the percentage of available
chlorine in a given sanip
of bleaching powder.
. Apparatus flask
Burette (25 ml), Pipette (10ml), conical flask, volume
(100ml), watch glass, bleaching powder, sodium thiosulphate. olution olution

starcu
(N/40). potassium iodide (10%). glacial acetic acid,
(Freshly prepared).
3. Theory b l e a c h i n g

of
Available chlorine which is a measure of qualitydilute
powder refers to the chlorine iberated by the action of T h e l i b e r a t e d

Is
expressed in percentage by weight of bleaching P
 a p s Á so f W a t e r

ironm bleaching powder

hhrne
iron

biich is titrated against

iodine titrat
which oxidizes KI and
Xidizes
is
145

standardizedliberates
of
unt
(aO1, 2CH,COOH
+
equivalent
hypo solution:
CI.+2 KI = 2 KCI +
(CH,COO),Ca H,O+ Cl,
I,
+

1.+2Na,S, O,
Starch + 1, Na,SO 2
Deep blue colour Nal
+

Significance:

Growth of the
th of
living organisms
aund abundanco such as
hh are found in
uscd
abundance in the
for any industrial
algac,
surface, drainagefungi and bacteria
hen

surface film of slime

face as film purpose. These water is harmful
along with organisms adhere to the
he water. The
growth
of the suspended matter present in
mussels in the
s capacity. The growth of the
organisms pipelines seriously affects
emperature range of 10-
35
in water takes place
pathogens presentgenerally
C. The
watCr are the carriers for diseases
like the in
lrination of the water
supplies chloera, dysentery etc. The
and industrial
deactivate disease causing water serves
bacterias is also achieved. It bacterias and the mainly to
also control of algae, fungi
sult of reaction of
chlorine with improves the quality of water
28 Organic substances. ammonia, sulphides, as

. Procedure: manganese and

i) To
standardize intermediate,
solution, prepare a standard sodium thiosuphate
thiosuphate (hypo)
(hypo)
solution
strength. Follow the procedure to of
KCr^0, N/30
of
hypo solution as standardize the intermediate
described in previous
10
prepare the experiment No. 8.6
0.4
gm of
bleaching powder solution, weigh accurately
10 a bleaching
mortar.
powder on watch
glass and transfer in
Crush with pestle and add
make thin paste of the
a little water, carefully
wn water. Transfer the powdered
paste into
blcaching powder sample
100 ml volumetric flask
sing small
quantity of water. Wash the mortar and
with distilled pesle
and transfer the washing to volumetric
flask. When allwater
the bleachin
100 ml
volumetric
powder paste is transferred to
flask then
ii)
water ke upto the mark with distiled
Wash the
buretté, pipette and conical flask
water thoroughly. with distilled
 146 Practical Chemistry
iv) Rinse the burette with standardized hypo solution and s
d fl the
burette with hypo solution. Note down the initial readin
burette.
ading of
(v) Rinse the pipette with the homogeneous solution of bleachi
powder. Pipette out 10 ml of homogenous (after shaking well) aching
solution, transfer it to conical flask. Add 10 ml of KI (10%)
solution and 3-4 ml of glacial acetic acid. Solution turns brown
wn.
vi) Titrate the liberated iodine against the thiosulphate solution
n
turns to pale yellow colour.
(vii) Now add 2-3 drops of freshly prepared starch solution. Solution
turns to blue colour.
(vii) Continue adding hypo solution till blue colour disappears. The
disappearance of blue colour, indicates the end point. Note
down the burette reading.
(ix) Repeat the titration procedure to get the concordant reading
Note down the burette reading.
6. Observation:
Table 1
Titration of Standard K,Cr,O, with intermediate hypo solution

S.No. Volume of K,Cr,0, Burette reading Volume of hypo

Initial Final Solution consumed
Solution
(ml) (ml) (ml) (ml)
1. 10.0 0.0 9.2 9.2
0.0 9.0 9.0
2. 10.0
9.0 9.0
3 10.0 0.0

Table 2 olution

itration of bleaching powder sample with standardised hypo so

Volume of hypo
S.No. Volumd of Bleaching Burette reading Solution consumed

powder Solution Initial Final

(ml)
(ml) (ml) (ml)
11.1
1. 10.0 0.0 11.
2. 11.0
11.0
10.0 0.0
11.0
3. 10.0 0.0 11.0
 147
n s t h s i s
o fW
ter
a t e

Calculation:
Hypoo:
of
N, V2
Strength
=

A.
N, V,
Hypo
KCr,O
N10=
30 9.0 0.037 N
N
powder
Bleaching
of
Strength
N,V2 N, V
Bleaching powder
Hypo
o.037 x 11.00.0407 N
N 10
C. Available Chlorine

= 35.5 x 0.0407 1.4448 gm./litre of suspension

= .14448 gm/100 ml suspension

available chlorine
D. % of
14448 x 100 36.12%
.4

3. Result in a given sample

of bleaching
available chlorine
percentage of
powder is 36.12%.
9. Precautions: care.
solution should be prepared with
Bieaching powder paste
carefully noted.
()) End point should be

(1) Use distilled water in the titration.

(Iv) Any special instruction by the teacher

EXPERIMENT NO. 8.8

1. Object
dioxide (CO,)
of a given sample
of water. determine the dissolved carbon
4.
Apparatus and Reagents: voumetric
tlask

(25 ml), pipctte (25 ml). Conical flask.

0 t
100 ml) e
Na,CO, solution (N/50).
nenolphthalein.