/ a) hex 2- ene - 4A ) B ,

µ
H H
B :
I 1
b) 2,5 -

methyl hex -2 -
ene b) A : I CH }
cl
Hf C CH }
-

c
-

- - -

c) 3- chloro but 1- ene -

I
1 I
'" ""2
d) cis -

hex 2. ene-
A CI

e) 3-
methylcyolopent-l-eneq.tt it D:
CH , H
1 I
Hf -
C -
C -
CH }
2A ) CHECHCHZCHZCH } I 1 CI -
C -
C -
H

"
1 I
b) H
CH }CH=cc1=cHcH } OH , A

c)
cHz=cH=cHCH }
ci )
f
"
}
F ai ;)
CHI
HO -
C- c- OH ,H YH } it
Br l l d- c- c- c-
3)
-

Br CH H
,
t.it , It IH } It
in b- a) ilvlight
for chain initiation
b) :

" "

ini ctfu →
zu
c chain propagation :

Ga ) CHBRCHBR CH4-1.cl-s.CH , -111-4

b) shake the test tube with CH , -142 →
CHilt.cl
•

the alkene and Brzlaq) in

the dark The orange Biscay)

.
chain termination :

dewloun.se rapidly .
.
•
CH } -1 all → [ Hit
c) It c) No asif there is a plentiful snppiyofclz
it it
it , ,

- d -
c
-
c -
d - further substitution of ohlonmethanewilltafe
It It It It plaoetogiveacnixtuneofpndnutsof
CHUI , Chili , Cltcbandccly .

Tail Free Radical Substitution Tbi ) Electrophilic Addition

aii ) Ñu →
2. a bii )
CHECK, -1 Br, → ( HzBrCHzBr
CHKHst.cl-s.CH ,cH , -111-4 biii) The Brzlaq) dewlouvise rapidly
orange . .

aiii )
.CH }CH , -142 →
CHzcttilt.cl
air ) .cl/-zlHztaCl-sCHzCHil1
 8A ) button -12
107

4%-4+-5
A
b)
it it it
cracking
1

c) skeletal formula I 1 I 1

dilly Hit

¥-4 I
dii) H H H H
l l l I

am Brian
hexane : no color change CHIH }
hex -2 -
ene :
The orange Bring) dewlouvise rapidly . .

bit
H#%=y
"

/ \
H CHIH }

bii )

Hail UV light
air ) substitution reaction
bit Kmnoycaqlldilltzsoy
bii )
CHECK ,
last
→
cH¥qHz :( 1-
→
CHUAN

fat
c) make chloro ethane from ethane and a
large excess of this used .

Most of the products formed are at }CHil .

:& ! ;É¥:É+ :*
di' diii ) cost

impact to environment
H H H H
dii) l l l l
-
c -
c - c -
u -

l l l l
Cl H 4 It