08-08-19 Sri Chaitanya-Jr - Chaina-I Jee-Adv (2014 P2) WTA-13 Q.P

Sri Chaitanya IIT Academy., India.
AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sri Chaitanya-Jr. Chaina-I Jee-Adv Date: 08-09-19
Time: 3 Hr’s 2014_P2 Max. Marks:180
Name of the Student: ___________________ H.T. NO:

2014_PAPER-II
08-09-19_Sri Chaitanya-Jr.Chaina-I_WTA-13_Syllabus
MATHS:
Vector Algebra: upto linear combination of vectors, linearly dependent &
independent vectors
PHYSICS:
GRAVITATION: Introduction, Newton’s law of gravitation, gravitational field due to
point mass and distributed mass, Variation of g with different factors.(EXCLUDE
Gravitational Potential)
CHEMISTRY:
Chemical Equilibrium
Sri Chaitanya IIT Academy, India 08-09-19_Sri Chaitanya- Jr.Chaina-I_Jee-Adv(2014_P2)_WTA-13_Q.P
JEE-ADVANCE-2014-P2-Model
Time: 03: 00 Hrs IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec– I(Q.N: 01 – 10) Questions with Single Correct Choice 3 -1 10 30
Questions with Comprehension Type
Sec– II(Q.N: 11 – 16) 3 -1 6 18
(3 Comprehensions – 2 +2+2 = 6Q)
Sec– III(Q.N: 17 – 20) Matrix Matching Type 3 -1 4 12
Total 20 60
CHEMISTRY:
Sec – I(Q.N : 21 – 30) Questions with Single Correct Choice 3 -1 10 30
Sec – II(Q.N : 31 – 36) 3 -1 6 18
Sec – III(Q.N : 37 – 40) Matrix Matching Type 3 -1 4 12
Total 20 60
MATHEMATICS:
Sec – I(Q.N : 41 – 50) Questions with Single Correct Choice 3 -1 10 30
Sec – II(Q.N: 51 – 56) 3 -1 6 18
Sec – III(Q.N : 57 – 60) Matrix Matching Type 3 -1 4 12
Total 20 60
Sec: Jr.Chaina-I Space for Rough Work Page 2

PHYSICS Max Marks: 60
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
1. Consider a uniform circular arc AB of mass M, which subtends an angle  at its center
of curvature ‘O’. Radius of curvature is R.
A
B
Find gravitational field intensity at ‘O’.

GM  2GM  GM  2GM 
A) sin   B) sin   C) co s   D) sin  
R 2 2 R 2 2 R 2 2 R 2 2
2. Consider a uniform ring of mass M and radius R. A semi-infinite wire of linear mass
density  coincides with axis of the ring with one end at its center.
M
Gravitational force of interaction between ring and the wire has magnitude
GM 2GM 2GM 4GM
A) B) C) D)
R R R R
3. Consider an equilateral triangle of side length  made of three identical uniform thin rods
each having linear mass density  . A point ‘P’ is located on a straight line passing
through centroid of the triangle and perpendicular to the plane of the triangle, at a

distance form centroid of the triangle. Magnitude of gravitational field intensity at P is
2
6 3 G 9 3 G 9 G 9 G
A)  B)  C)  D) 
7  7  2  2 7 
4. A thin wire of uniform linear mass density  and of infinite length is arranged on a
plane as shown in the figure. PQR section is quarter-circle of radius a and c is the
curvature center.
P C
Q
R
Magnitude of gravitational field intensity due to the entire wire at C is
2G 2 2G 2G G

A) B) C) D)
a a a 2a
5. Consider a thin uniform spherical shell of radius R and mass per unit area  .
Gravitational force exerted on one half of the shell by other half is
A) 22 G 2 R 2 B) 4 2 G 2 R 2 C)  2 G 2 R 2 D) 82 G 2 R 2

6. Two equal masses each m are hung from a balance whose scale pans differ in vertical
height by ‘h’. The error in weighing in terms of density of the earth  is
1 8 4
A)  Gmh B)  G  mh C)  G  mh D)  G  mh
3 3 3
7. Consider a cube of uniform mass density as shown in figure-I. Point P is on the vertex.
Let magnitude of gravitational field intensity at P is E o .
Now a cubical section having edge length half that of original cube is scooped out, as
shown in figure-II.
What is the magnitude of gravitational field strength at the same point P in the new
situation?
Eo 3E o Eo 3E o
A) B) C) D)
2 2 8 8
R
8. A spherical planet of radius R is made of a spherical core of radius and density 0 ,
2
R
over and above the core is a layer of thickness and density  .
2
R
o
2
1
If acceleration due to gravity at a height R from the surface of the planet is times that at
8
R 
a depth from the surface then is
2 0
2 1 3 6
A) B) C) D)
3 7 8 7
9. A uniform wire of mass M and length   R , is held vertically above pole with one end
just touching the surface of earth at pole. R is radius of earth and g be acceleration due to
gravity at pole. Considering only gravitational force of earth on the wire, tension at the
midpoint of the wire is
Mg 2Mg Mg Mg
A) B) C) D)
2 3 3 6
10. Choose the wrong statement
A) According to Newton, inertial mass and gravitational mass are equal.
B) In a satellite, an astronaut feels weightless-ness because satellite is freely falling
C) Center of mass and center of gravity of a symmetrical object (say a uniform disc)
must, always coincide.
D) If a concentric spherical cavity is made in a uniform solid sphere, gravitational field in
the cavity is zero.
SECTION - II
(PARAGRAPH TYPE)
This section contains 3 Paragraph of questions. Each paragraph has 2 multiple choice questions based on
a paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE IS correct.
Paragraph for Question Nos. 11 & 12
A fixed sphere of radius R and uniform density ‘  ’ has spherical cavity of radius R/2
such that the surface of the cavity passes through the centre of the sphere . A particle of
mass ‘m’ is located at the centre (A) of the cavity and released from rest.

11. The velocity with the mass “m” hits the centre ‘O’.
2 2 2 3G
A) v  R  G B) v  R  G C) v  R  G D) R
3 5 7 2
12. The time taken by the mass to hit the centre “O”.
2 3 5 7
A) B) C) D)
3 G 2 G 2 g 2 G
Paragraph for Question Nos. 13 to 14
Let’s consider a regular hexagon of side length ‘a’ on a plane with its vertices named
A,B,C,D,E and F. Let there are six identical particles each of mass M fixed at the
vertices of this hexagon.
A
F B
E
C
Lets take a straight line passing through the center of the hexagon and perpendicular to
the plane of hexagon as axis of the hexagon.
13. At what distance from center of the hexagon, on the axis of the hexagon, a particle of
mass m be placed so that particle experiences maximum gravitational force?
a a a
A) B) 2a C) D)
2 3 2 2

14. Now two particles (one at B and the other at E) are removed, and a particle of mass m is
placed on the axis of the hexagon and released. What can be its maximum acceleration
due to gravitational force of masses at the vertices?
2 GM 4 GM 8 GM 4 GM
A) B) C) D)
3 a2 3 3 a2 3 3 a2 3 a2
A uniform metal sphere of radius a and mass M is surrounded by a thin uniform spherical
shell of equal mass and radius 4a. The centre of the shell falls on the surface of the inner
sphere.
15. Find the gravitational field intensity at point P1 .

GM GM GM GM
A) B) C) D)
16 a 2 8a 2 2a 2 4a 2
16. Find the gravitational field intensity at point P2 .
21GM 61GM 61GM 61GM

A) B) C) D)
900 a 2 450a 2 900a 2 1800a 2

SECTION - III
(Matching List Type)
This section contains four questions, each having two matching lists (List-1 & List-II). The options for
the correct match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
17. In list-I, there is an arrangement of identical particles each of mass m on x – y plane. In
each case, there is an additional particle of same mass m at ( o, o, h).
List-II, is the force this particle i.e. at ( o, o, h) experiences due to system of particles on x
– y plane.
List- I List- II
Three particles are on x –y plane on the
vertices of an equilateral triangle of side 8 2 Gm 2
P) 1)
length ‘a’ . The vertices lie on a circle of 15 a 2
radius R, with centre at origin. Given h = R
Four particles are on x – y plane on the
vertices of a square of side length ‘a’. The 9 Gm 2
Q) corners of the square are on a circle of radius 2)
2 2 a2
R with its centre at origin. Given h  3R.
Five particle are on x –y plane, on the
vertices of a regular pentagon of side length
‘a’.
3 3 Gm 2
R) The vertices of the pentagon lie on a circle of 3)
radius R with its centre at origin. Given 4 a2
4
h  2 2R ( Take cos 36o  )
5
Six particles are on x – y plane on the vertices
of a regular hexagon of side length a. The 3Gm 2
S) vertices of hexagon lie on a circle of radius R 4)
a2
with its centre at origin . Given h  3R
A) P – 3, Q – 4, R – 1, S - 2 B) P – 2, Q – 4, R – 1, S - 3
C) P – 2, Q – 1, R – 1, S - 3 D)P – 3, Q – 4, R – 2, S - 3

18. Lets consider a uniform sphere of radius a made of a material of density  . Center of the
a
sphere ‘C’ is at origin and the there are two spherical carities of radii each. C1 and
2
a   a 
C2 are centers of the cavities and located at  , o, o  and   , o, o  respectively. A
2   2 
a   3a 
and B are two points with in cavity-1 with positions  , o, o  and  , o, o 
4   4 
respectively.
Cavity-1
Cavity-2
A B
C2 C1
C
Let E A , E B , E C1 and E C represent strength of gravitational field at points

A, B, C1, and C respectively.
List- I List- II
If cavity-2 is filled with a material of same density
P) EA 1) 0.041
 then is
EB
If cavity-2 is filled with a material of density 2  , then
Q) EA 2) 1
is
EB
R) If cavity-2 is filled with a material of density 2  then 3) 1.245

EC
E C1
If cavity-1 is filled a material of same density  then

S) EA 4) 1.60
EB
A) P – 2, Q – 3, R – 4, S - 2 B) P – 2, Q – 4, R – 3, S - 1
C) P – 1, Q – 3, R – 4, S - 2 D) P – 2, Q – 3, R – 4, S - 1
19. Two concentric shells of masses M1 and M2 are situated as shown in the figure. Match the
column. ‘r’ represents distance of particle from common centre.
Column – I Column – II
(A) Force on a particle of mass m (P) Zero
when the particle is at A
(B) Force on a particle of mass m (Q) GM 2 m / r 2
when the particle is at B
(C) Force on a particle of mass m (R) Gm  M1  M 2  / r 2
when the particle is at C
(D) Magnitude of net force on outer (S) GM 1M 2
shell due to inner shell. r22
A) A-R,B-Q,C-P,D-P B) A-Q,B-R,C-P,D-R
C) A-R,B-Q,C-R,D-P D) A-R,B-P,C-Q,D-R

20. A solid sphere of mass m and radius r is placed inside a hollow thin spherical shell of
mass m and radius 4r as shown in fig. A particle P of mass m ' is placed on the line
joining the two centers at a distance x from the point of contact of the sphere and the shell
(OP=x). If g denotes the magnitude of the resultant gravitational force on this particle due
to the sphere and shell, then match the following:
Column – I Column – II
A) 3r P) Gmm '  1 1 
x g   
2 r 2  52 82 
B) x  4r Q) Gmm '
g
2r 2
C) x  9r R) Gmm '  1 1 
g   
r 2  62 92 
D) x  10r S) 1 Gmm '

g
9 r2
A)A-Q, B-s, C-p, D-r B) A-s, B-q, C-p, D-r

C) A-Q, B-s, C-r, D-p D) A-Q, B-p, C-s, D-r

CHEMISTRY Max Marks: 60
SECTION – I
21. The equilibrium N 2   3H 2   2NH 3  is established in a cylinder with a movable piston.
g g g
If He g is now introduced into the vessel and the system is allowed to attain equilibrium
again, then which of the following statements is correct in regards to the new equilibrium
A) Pressure of NH 3 has increased
B) Molar concentration of NH 3 has increased
C) Molar concentration of N 2 has increased
D) Molar concentration of N 2 has decreased
22. Making of NH 3 g  by Habers process using suitable catalyst is an exothermic process
N 2 g  3H 2 g  2NH 3 g ; H   ve Assuming that equilibrium has been established, select
the incorrect statement, on increasing the pressure on the system at constant temperature.
A) Reaction shifts forward to attain new equilibrium
B) Average molar mass of gaseous mixture increases
C) Partial pressure of NH3 , N 2 , H 2 will increase
D) Concentration of NH 3 increases whereas concentration of N 2 and H 2 decreases
23. If 10 moles of A and 4 moles of B are mixed in a 2 lit container and allowed to reach
equilibrium, then calculate the moles of B left in the container at equilibrium
A  2B  C; k  1010 M 2
A) 2.5  1011 B) 5  106 C) 105 D) None

24. 2 moles of He and 3 moles of N 2O 4 are introduced into a 10 lit vessel and heated to
227o C . The total pressure at equilibrium is 24.63 atm. Assuming ideal behaviour, K p of
the reaction N 2O 4  2NO 2 is

A) 0.2 B) 2 C) 8.21 D) 2.18
25. In a 5 litre vessel, the following equilibrium partial pressures are measured:
SO 2  2atm, O 2  4 atm and SO 3  4 atm . O 2 is removed from the vessel at constant
temperature until the pressure of SO 3 drops to 2 atm. The new equilibrium partial
pressure of O 2 is
A) 1 atm B) 0.5 atm C) 0.25 atm D) none
26. Which of the following will be effected by changing temperature at constant pressure
(terms have their usual meaning)?
o
A) H B) G o C) So D) All the above
27. In which of the following hypothetical reaction K p  K c at 10 K temperature?
A) A g   Bg   C g  B) 2A g   Bg   Cg 
C) A g   3B g   2C g  D) Pred  Pwhite
28. 2X 6 g  4X 3 g
A 20 L vessel containing X 6 and X 3 at 1500K. K p  4  1018 atm. Assuming Px 3  Px 6
and total pressure is 10 atm, what will be the partial pressure of X 6 ?

10
A) 5  108 atm B) 5  106 atm C) 2  108 atm D) 5  10 atm
29. Two equilibria AB(g )  A(g )  B(g) and AB(g)  B(g)  AB2(g ) are simultaneously
maintained in a closed vessel with equilibrium constants K1 and K 2 respectively. If [A]

and [ AB2 ] are y & x respectively, from equilibrium produced by taking only AB initially.
K1
Then is equal to:
K2
2
y 2 y 2  x  y y 2  x  y x
A)  y  x  B) C) D)  x  y 2
x x x y
30. If two moles of N 2O4 at 1 atm pressure is placed in a container at 300 K and temperature
is raised to 600 K at constant volume. The molecular weight at equilibrium was 76.67.
Then, the final pressure in the container at equilibrium at 600 K is
A) 1.2 atm B) 2.4 atm C) 1.4 atm D) 3.5 atm
SECTION - II
(PARAGRAPH TYPE)
Equilibrium constants are given in atm  n  g

 for the following reactions at 18 C
o
SrCl2 .6H 2O(s)  SrCl2 .2H 2Os  4H 2O g ; K p  10 12
Na 2HPO4 .12H 2O(s)  Na 2HPO4 .7H 2O(s)  5H 2O(g) ; K p  2.43 1013

Na 2SO4 .10H 2O(s)  Na 2SO 4s  10H 2O(g) ; K p  1.024  10 27
The vapour pressure of water at 18o C is 15.2 torr
31. The three salts are placed in containers at 18o C as shown and connected to manometers
(all similar). If height of Hg column recorded in the manometers are x1 , x 2 , x 3
respectively, then the relation between x1 , x 2 , x 3 is

x1 x2 x3
(I) (II) (III)

SrCl2 .6 H 2O( s ) Na2 HPO4 .12 H 2O( s ) Na2 SO4 .10 H 2O
A) x1  x 2  x 3 B) x 2  x 3  x1 C) x 3  x 2  x1 D) x1  x 3  x 2
32. At what relative humidity will Na 2SO 4 be deliquescent at 18o C ?

A) above 10% B) below 10% C) above 20% D) below 20%
The shown “film strip” represents five molecular level scenes of a gaseous mixture as it
reaches equilibrium over the time.
Reaction : X 2 g  Y2 g  2XYg
Gas X 2 : Solid colour Gas XY :

Gas Y2 : colourless
33. If each particle represents 0.2 moles of particles then what will be the value of reaction
quotient (Q) for scene B ?
A) 0.16 B) 0.08 C) 16/9 D) 20/9

34. In scene ‘A – E ’ if each particle represents 0.1 moles of particles, then on introducing 0.5
moles each of particles of X2and Y2 additionally in scene A, then equilibrium stage can
be represented by which of the picture ?
A) B)
C) D)
Thermodynamic stability is often used in chemical reactions to predict extent of reactions
or to predict the preferred product in some reactions. Thermodynamically a more stable
substance will be the one which has lower Gibbs free energy. In various cases, it might be
decided on the basis of enthalpy. However, that may not always be true. The
thermodynamic data, therefore can be used for predicting stability among phases and to
decide the possible transformation. Based on this information and the data given below,
answer the questions that follow.
Data: H f o of Sn  white  0 H f o of Sn  grey  2.1 kJ / mole
So of Sn  white   0 J / mole  K So of Sn grey   44 J / mole  K
All the above data at 300 K

Density of Sn  white  7.36 g / ml

Density of Sn  grey  5.769 g / ml
One such transformation is ‘tinpest’ which is an autocatalytic, allotropic transformation

of the element tin, causing deterioration of tin objects at low temperatures.
35. Which of the following is correct for the allotropic transition Sn  white   Sn  grey  at
1 bar and 300K?

A) Transition is spontaneous
o
B) G  0
C) Equilibrium exists between white tine & grey tin
D) all the above
36. What are the favorable conditions for transforming Sn white to Sn  grey ?
A) High pressure, low temperature B) Low pressure, low temperature

C) Low pressure, high temperature D) High pressure, high temperature
SECTION - III
This section contains four questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
37. Match the following
COLUMN-I COLUMN-II
P) SO 2 g  O 2 g  SO3 g 1) shifts equilibrium in the forward direction
Addition of He g at constant volume
Q) I3 aq  I 2 aq  Iaq 2) Increases pressure of the system
Addition of H 2Ol at eqm
R) A s  2B g 3) Concentration of product increases
Increase of volume
S) N 2O 4 g  2NO 2 g 4) Concentration of product remains same
Addition of NO 2 g at constant volume
P Q R S
A) 1 2 4 3
B) 2 1 4 3
C) 3 2 4 1
D) 4 1 2 3
38. For the given endothermic reaction: A  g  2B g , the variation in concentration due to
different changes is plotted. Match the changes in column II with the effect in column I
COLUMN-I COLUMN-II
P) Effect I 1) Addition of inert gas at constant pressure
Q) Effect II 2) Addition of only B at constant volume
R) Effect III 3) Decrease in Temperature at constant volume
S) Effect IV 4) Addition of inert gas at constant volume
Effect-I Effect-II Effect-III Effect-IV

P Q R S
A) 1 2 3 4
B) 2 4 1 3
C) 2 3 4 1
D) 3 2 1 4

COLUMN-I COLUMN-II
(Reactions)     1, initial conc  1
P) 2X  g  Y g  Z g 1)   2 K c
Q) X g  Y g  Z g 2)   3 K c
1/3
R) 3X  g  Y g  Z g 3)    2K c 
S) 2X  g  Y g  2Z g 4)   K c
P Q R S
A) 4 2 1 3
B) 3 2 4 1
C) 1 4 2 3
D) 1 2 4 3
1
40. If the equilibrium constant for N 2  O 2  2NO is K1 and NO  O2  NO2 is K 2 ,
2
then match the equations in column I with the equilibrium constants in Column II
COLUMN-I COLUMN-II
P) 2NO 2  2NO  O 2 1) K1/2
1 .K 2
1 1
Q) N 2  O 2  NO 2 2) 2
2 K . K1
2
1 1 1
R) NO  N 2  O2 3)
2 2 K 22
S) 2NO 2  N 2  2O 2 4) K11/2
P Q R S
A) 1 2 3 4
B) 3 1 4 2
C) 2 1 3 4
D) 4 1 2 3

MATHS Max Marks: 60
SECTION – I
41. ABCDEF is a regular hexagon in the xy plane with vertices in the anticlock wise
 
direction. If AB  2i then CD is
A) i  3 j B) i  3j C) i  3j D) 3i  j
42. If points 1,2,3  ,  0, 4,3  ,  2,3,5  and 1, 5, 3 are vertices of tetra-hedron. Then the
points where lines joining the mid-points of opposite edges are concurrent is
A) 1, 1,2  B)  1,1,2  C) 1,1, 2 
D)  1,1, 2 
     
43. Orthocentre of an equilateral triangle ABC is the origin O. If OA  a;OB  b;OC  c then
  
AB  2BC  3CA is equal to
   
A) 3c B) 3a C) 0 D) 3b
44. A unit tangent vector at t = 2 on the curve x  t 2  2; y  4t  5 and z  2t 2  6t is
1    1 1    1
A) 
i  j k B) 2i  2j  k
  C)  
2i  j  k D) i  j  k
  
3 3 6 3
    
45. Let a  i  j  k ;b  5i  3j  3k and c  3i  j  2k .If r is collinear with c and
  has
 
ab 
length then r equals
2
 3  2
A) 3c B)  c C)  c D)  c
2 3

46. A line passes through the points whose position vectors are iˆ  ˆj  2kˆ and iˆ  3 ˆj  kˆ .The
position vector of a point on it at unit distance from the first point can be
1   1  
A) 5i  j  7k
  B) 4i  9 j  15k 
5 5
1   

C) î  4jˆ  3kˆ  D)
5

i  4 j  3k 
     
47. The base vectors a1,a 2 and a 3 are given interms of base vectors b1 ,b 2 and b3 as
   
a1  2b1  3b 2  b3
   
a 2  b1  2b2  2b3 and
   
a 3  2b1  b 2  2b3
       
If F  3b1  b 2  2b3 , Then vector F in terms of a1,a 2 and a 3 is
       
A) F  3a1  2a 2  5a 3 B) F  2a1  5a 2  3a 3
       
C) F  3a1  5a 2  2a 3 D) F  3a1  2a 2  5a 3
1
48. If a1 and a2 are two values of a for which the unit vector aiˆ  bjˆ  kˆ is linearly
2
1 1
dependent with î  2ˆj and ˆj  2kˆ , then  is equal to
a1 a 2
1 11 16
A)1 B) C) D)
8 16 11
 
49. In the OAB , M is the midpoint of AB, C is a point on OM, such that 2OC  CM . X is
 
a point on the side OB such that OX  2XB . The line XC is produced to meet OA in Y.
OY
Then is equal to
YA
1 3 2 2
A) B) C) D)
3 2 7 5

50. On the xy plane where ‘O’ is the origin, given points A(1,0), B(0,1) and C(1,1). Let P, Q
and ‘R’ be moving points on the line OA,OB,OC respectively such that
     
     
OP  45 x OA , OQ  60 x OB ; OR  1  x  OC with  x  0  . If the three points P,Q
and R are collinear then the value of ‘ x ’ is equal to

7 1 1 1
A) B) C) D)
187 106 100 187
SECTION - II
(PARAGRAPH TYPE)
       
Three points A,B and C have position vectors 2a  3b  5c , a  2b  3c and 7a  c with
reference to an origin O.
Now, answer the following
51. Which of the following is correct.

       
A) 2OA  3OB  OC  O B) 2OA  7OB  9OC  O
       
C) OA  OB  OC  O D) OA  3OB  2OC  O
52. ‘B’ divided AC in ratio
A) 2:3 B) 2:5 C) 1:2 D) 2:1

Let A,B,C,D,E represent vertices of a regular pentagon ABCDE. given the position
     
vector of these vertices be a,a  b, b, a and  b respectively.

AD
53. The ratio is equal to
BC
 3  3  2  
A)  1  cos  : cos B)  1  2cos  : cos
 5  5  5  5
     
C)  1  2cos  : 2cos D)  1  2cos  : 2cos
 5 5  5 5
54. AD divides EC in the ratio
2 3 
A) cos :1 B) cos :1 C)1: 2cos D) 1: 2
5 5 5
‘A’ particle in equilibrium is subjected to four forces
  4 12 3 
F1  10kˆ; F2  u  iˆ  ˆj  kˆ 
 13 13 13 
  4 12 3 
F3    iˆ  ˆj  kˆ 
 13 13 13 


F4  W cos î  sin ˆj 
Answer the following
55. The value of u is
65 65
A)  65cot  B)  65cot 
3 3
65
C)  40cos ec D) 40cos ec
3
56. The value of  is
65 65
A)  65cot  B)  65cot  C) 40cos ec D) 40cos ec
3 3

SECTION - III
This section contains four questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
COLUMN-I COLUMN-II
A) ABCD is a parallelogram and A1 and B1 are the P) 6
midpoint of sides BC and CD respectively. If
  
AA1  AB1   AC then ‘  ’is equal to
B) ABCD is quadrilateral ‘E’ is the point of Q) 3
intersection of the line joining the midpoints of 4
the opposite sides. If ‘O’ is point and

    
OA  OB  OC  OD  OE then ‘  ’is equal to
C) If the resultant of three forces R) 4
  
F1  piˆ  3jˆ  k;F
ˆ ˆ ˆ ˆ ˆ ˆ
2  5i  j  2k;F3  6i  k acting
on a particle has a magnitude equal to 5 units,

then modulus of difference of the values of ‘p’
is ---
D)        S) 3
Let a, b,c be unit vectors such that a  b  c  o .
2
If the area of triangle formed by the vectors
 
a and b is A, then the value of 4A 2 is…
A) A-S,B-Q,C-P,D-R B) A-S,B-R,C-P,D-Q
C) A-Q,B-R,C-P,D-S D) A-P,B-Q,C-P,D-S

Column I Column II
A) The vector î  x ˆj  3kˆ is rotated through an angle P) 1
'  ' and is doubled in magnitude. It now becomes

4iˆ   4x  2  ˆj  2kˆ . If  &  are the values of x

then is equal to     

B)   Q) 2
Given three non-zero, non-coplanar vectors a, b
        
and c , r1  pa  qb  c and r2  a  pb  qc . If the
   
vector r1  2r2 and 2r1  r2 are collinear, then
p  q is equal to

C) If b is a vector whose initial point divides the R) 3
join of 5iˆ and 5 ˆj in the ratio K : 1 and whose


terminal point is the origin and b  37 . If ‘K’
lies in the interval  ,    ,   . Then  .  is

equal to
D) If '  ' is the number of distinct real value of '  ' S) 4
for which the vectors  2 î  ˆj  k,

ˆ î   2ˆj  kˆ and
î  ˆj   2 kˆ are coplanar then    2  is equal to
A) A-P, B-QR, C-P, D-S B) A-R, B-Q, C-P, D-S

C) A-R, B-P, C-P, D-S D) A-R, B-S, C-Q, D-R

 
59. a and b form the consecutive sides of a regular hexagon PQRSTU
Column I Column II
  
A) If RS  xa  yb , then P) x  2
  
B) If RT  xa  yb , then Q) x  1
  
C) If PT  xa  yb , then R) y 1
 
D) If PS   xb , then S) y2
A) A-R, B-PR, C-S, D-Q

B) A-QR, B-PR, C-RS, D-P
C) A-QR, B-PR, C-QS, D-P
D) A-QR, B-PR, C-PS, D-P
Column I Column II
A) If points A(60iˆ  3 ˆj ), B(40iˆ  8 ˆj ) and C (aiˆ  52 ˆj ) are P) 1
a
collinear then is equal to…
10
 
B) Let OA = iˆ  3 ˆj  2kˆ and OB  3iˆ  ˆj  2kˆ, The vector Q) 4

OC bisecting the angle AOB and ‘C’ being a
point on the line AB. is  ( iˆ  ˆj  kˆ) Then    is

equal to

C) If the vector iˆ  ˆj  kˆ bisects the angle between R) 3

the vector c and the vector 3iˆ  4 ˆj . If unit vector

in the direction of c is
1 ˆ    
 ( i   ˆj   kˆ) Then   is ([ .] is G.I.F.)
15   

D) The vector c , directed along the internal bisector S) 10

of the angle between the vectors a  7iˆ  4 ˆj  4kˆ
 
and b  2iˆ  ˆj  2kˆ with c  5 6 is
 (iˆ  7 ˆj  2kˆ).Then ,[  ] is equal to .. ([.] is G.I.F.)
A) A-S , B-R , C-Q , D-P B) A-Q , B-P , C-S , D-R

C) A-P , B-Q , C-S , D-P D) A-Q , B-R , C-S , D-P

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Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

Name of the Student: ___________________ H.T. NO:

Sec: Jr.Chaina-I Space for Rough Work Page 2

Find gravitational field intensity at ‘O’.

Magnitude of gravitational field intensity due to the entire wire at C is

2G 2 2G 2G G

Sec: Jr.Chaina-I Space for Rough Work Page 4

Sec: Jr.Chaina-I Space for Rough Work Page 6

Sec: Jr.Chaina-I Space for Rough Work Page 7

15. Find the gravitational field intensity at point P1 .

16. Find the gravitational field intensity at point P2 .

21GM 61GM 61GM 61GM

Sec: Jr.Chaina-I Space for Rough Work Page 8

Sec: Jr.Chaina-I Space for Rough Work Page 9

Let E A , E B , E C1 and E C represent strength of gravitational field at points

Sec: Jr.Chaina-I Space for Rough Work Page 10

If cavity-1 is filled a material of same density  then

Sec: Jr.Chaina-I Space for Rough Work Page 11

D) x  10r S) 1 Gmm '

A)A-Q, B-s, C-p, D-r B) A-s, B-q, C-p, D-r

Sec: Jr.Chaina-I Space for Rough Work Page 12

N 2 g  3H 2 g  2NH 3 g ; H   ve Assuming that equilibrium has been established, select

A) 2.5  1011 B) 5  106 C) 105 D) None

Sec: Jr.Chaina-I Space for Rough Work Page 13

the reaction N 2O 4  2NO 2 is

A) A g   Bg   C g  B) 2A g   Bg   Cg 

C) A g   3B g   2C g  D) Pred  Pwhite

A 20 L vessel containing X 6 and X 3 at 1500K. K p  4  1018 atm. Assuming Px 3  Px 6

and total pressure is 10 atm, what will be the partial pressure of X 6 ?

maintained in a closed vessel with equilibrium constants K1 and K 2 respectively. If [A]

Sec: Jr.Chaina-I Space for Rough Work Page 14

Equilibrium constants are given in atm  n  g

SrCl2 .6H 2O(s)  SrCl2 .2H 2Os  4H 2O g ; K p  10 12

Na 2HPO4 .12H 2O(s)  Na 2HPO4 .7H 2O(s)  5H 2O(g) ; K p  2.43 1013

Sec: Jr.Chaina-I Space for Rough Work Page 15

(I) (II) (III)

32. At what relative humidity will Na 2SO 4 be deliquescent at 18o C ?

Reaction : X 2 g  Y2 g  2XYg

Gas X 2 : Solid colour Gas XY :

A) 0.16 B) 0.08 C) 16/9 D) 20/9

Sec: Jr.Chaina-I Space for Rough Work Page 16

So of Sn  white   0 J / mole  K So of Sn grey   44 J / mole  K

All the above data at 300 K

Sec: Jr.Chaina-I Space for Rough Work Page 17

One such transformation is ‘tinpest’ which is an autocatalytic, allotropic transformation

1 bar and 300K?

A) High pressure, low temperature B) Low pressure, low temperature

Addition of He g at constant volume

Q) I3 aq  I 2 aq  Iaq 2) Increases pressure of the system

Addition of H 2Ol at eqm

R) A s  2B g 3) Concentration of product increases

Addition of NO 2 g at constant volume

Effect-I Effect-II Effect-III Effect-IV

Sec: Jr.Chaina-I Space for Rough Work Page 19

Sec: Jr.Chaina-I Space for Rough Work Page 20

A) i  3 j B) i  3j C) i  3j D) 3i  j

44. A unit tangent vector at t = 2 on the curve x  t 2  2; y  4t  5 and z  2t 2  6t is

Sec: Jr.Chaina-I Space for Rough Work Page 21

Sec: Jr.Chaina-I Space for Rough Work Page 22

and R are collinear then the value of ‘ x ’ is equal to

Now, answer the following