Ygggbhhr DD d7

FIITJEE
Solutions to JEE(Main)-2020
Test Date: 5th September 2020 (First Shift)
PHYSICS, CHEMISTRY & MATHEMATICS

Paper - 1
Time Allotted: 3 Hours Maximum Marks: 300

 Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
Important Instructions:
1. The test is of 3 hours duration.
2. This Test Paper consists of 75 questions. The maximum marks are 300.
3. There are three parts in the question paper A, B, C consisting of Physics, Chemistry and Mathematics
having 25 questions in each part of equal weightage out of which 20 questions are MCQs and 5
questions are numerical value based. Each question is allotted 4 (four) marks for correct response.
4. (Q. No. 01 – 20, 26 – 45, 51 – 70) contains 60 multiple choice questions which have only one correct
answer. Each question carries +4 marks for correct answer and –1 mark for wrong answer.
5. (Q. No. 21 – 25, 46 – 50, 71 – 75) contains 15 Numerical based questions with answer as numerical
value. Each question carries +4 marks for correct answer. There is no negative marking.
6. Candidates will be awarded marks as stated above in instruction No.3 for correct response of each
question. One mark will be deducted for indicating incorrect response of each question. No deduction
from the total score will be made if no response is indicated for an item in the answer box.
7. There is only one correct response for each question. Marked up more than one response in any
question will be treated as wrong response and marked up for wrong response will be deducted
accordingly as per instruction 6 above.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2020 (5th September-First Shift)-PCM-2
PART –A (PHYSICS)
1. A hollow spherical shell at outer radius R floats just submerged under the water surface.
The inner radius of the shell is r. If the specific gravity of the shell material is 27 w.r.t
8
water, the value of r is.
2 4 1 8
(A) R (B) R (C) R (D) R
3 9 3 9
2. A balloon is moving up in air vertically above a

point A on the ground. When it is at a height h1, a
girl standing at a distance d (point B) from A (see
figure) sees it at the angle 450 with respect to the
vertical. When the balloon climbs up a future height
h2, it is seen at the angle 600 with respect to the
vertical if the girl moves further by a distance 2.464
d (point C). Then the height h2 is (given tan 300 =
0.5774):
(A) 0.464 d (B) 0.732 d
(C) 1.464 d (D) d
2
2 3
3. A physical quantity z depends on four observables a, c, c and d, as z = a b . The
c d3
percentages of error in the measurement of a, b, c and d are 2%, 1.5%, 4% and 2.5%
respectively. The percentage of error in z is:
(A) 13.5% (B) 16.5%
(C) 12.25% (D) 14.5%
4. Three different processes that can occur in an ideal

monoatomic gas are shown in the P vs V diagram.
The paths are labeled as A  B, A  C and A 
D. The change in internal energies during these
process are taken as EAB, EAC and EAD and the work
done by W AB, W AC and W AD. The correct relation
between these parameters are:
(A) E AB  E AC  E AD ,WAB  0, WAC  WAD
(B) E AB  E AC  E AD , WAB  0,WAC  0, WAD  0
(C) E AB  E AC  E AD , WAB  WAC  WAD
(D) E AB  E AC  E AD , WAB  0, WAC  0, WAD  0
5. A wheel is rotating freely with an angular speed  on a shaft. The moment of inertia of
the wheel is I and the moment of inertia of the shaft is negligible. Another wheel of
moment of inertia 3I initially at rest is suddenly coupled to the same shaft. The resultant
fractional loss in the kinetic energy of the system is:
3 5 1
(A) (B) (C) (D) 0
4 6 4
6. In a resonance tube experiment when the tube is filled with water up to a height of 17.0
cm from bottom, it resonates with a given tuning fork. When the water level is raised the
next resonance with the same tuning fork occurs at a height of 24.5 cm. If the velocity of
sound in air is 330 m/s, the tuning fork frequency is:
(A) 1100 Hz (B) 2200 Hz
(C) 3300 Hz (D) 550 Hz
7. An electron is constrained to move along the y – axis with a speed of 0.1 c (c is the
speed of light) in the presence of electromagnetic wave, whose electric field is

E  30ˆj sin 1.5  107 t  5  102 x V / m. The maximum magnetic force experienced by
 
the electron will be: (given c  3  108 ms1 and electron charge = 1.6  1019 C )
(A) 3.2  10 18 N (B) 1.5  10 19 N
(C) 2.4  1018 N (D) 4.8  1019 N
8. With increasing biasing voltage of a photodiode, the photocurrent magnitude:

(A) remains constant
(B) increases initially and after attaining
(C) increases linearly
(D) increases initially and saturates finally
9. A bullet of mass 5 g, traveling with a speed of 210 m/s, strikes a fixed wooden target.
One half of its kinetic energy is converted into heat in the bullet while the other half is
converted into heat in the wood. The rise of temperature of the bullet if the specific heat
 0

of its material is 0.030 cal / g  C 1cal  4.2  10 ergs close to:
7

0 0
(A) 83.3 C (B) 38.4 C
(C) 87.50 C (D) 119.20 C
R
10. The value of the acceleration due to gravity is g1 at a height h  (R= radius of the
2
earth) from the surface of the earth. It is again equal to g1 at a depth d below the surface
d
of the earth. The ratio   equals:
R
 
7 1
(A) (B)
9 3
5 4
(C) (D)
9 9
11. For a concave lens of focal length f, the relation between object and image distances u
and is , respectively, from its pole can best be represented by (u -  is the reference
line):
(A) (B)
(C) (D)
12. A solid sphere of radius R carries a charge Q + q

distributed uniformly over its volume. A very small point
like piece of it of mass m gets detached from the
bottom of the sphere and falls down vertically under
gravity. This piece carries charge q. If it acquires a
speed  when it has fallen through a vertical height h
(see figure), then: (assume the remaining portion to be
spherical)
 qQ   qQ 
(A) v 2  y  2
 g (B) v 2  2y   g
 4 0 R ym   4 0 R R  y  m 
 qQ   QqR 
(C) v 2  y   g (D) v 2  2y   g 
 4 0 R R  y  m
3
  4 0 R  y  m 
13. A galvanometer of resistance G is converted into a voltmeter of range 0 – IV by

connecting a resistance R1 in series with it. The additional resistance that should be
connected in series with R1 to increase the range of the voltmeter to 0 – 2V will be:
(A) R1 + G (B) R1
(C) G (D) R1 – G
14. Number of molecules in a volume of 4 cm3 of a perfect monoatomic gas at some

temperature T and at a pressure of 2 cm of mercury is close to? (Given, mean kinetic
energy of a molecule (at T) is 4 x 10–14 erg, g = 980 cm / s2, density of mercury = 13.6 g /
cm3)
(A) 5.8  1018 (B) 4.0  1016
(C) 5.8  1016 (D) 4.0  1018
15. A square loop of side 2a, and carrying current I, is kept in XZ plane with its centre at
origin. A long wire carrying the same current I is placed parallel to the z – axis and
passing through the point (0, b, 0), (b > > a). The magnitude of the torque on the loop
about z – axis is given by:
20I2a3 0I2a2 0I2a3 20I2a2
(A) (B) (C) (D)
b2 2b 2b2 b
16. Assume that the displacement (s) of air is proportional to the pressure difference  p 
created by a sound wave. Displacement (s) further depends on the speed of sound (v),
density of air () and the frequency (f). If p  10Pa,   300 m/ s,   1 lg / m3 and
f  1000 Hz , then s will be of the order of (take the multiplicative constant to be 1)
1
(A) mm (B) 10 mm
10
3
(C) mm (D) 1 mm
100
17. A helicopter rises from rest on the ground vertically upwards with a constant acceleration
g. A food packet is dropped from the helicopter when it is at a height h. The time taken
by the packet to reach the ground is close to [g is the acceleration due to gravity]:
h 2h
(A) t  1.8 (B) t 
g 3g
h 2 h
(C) t  3.4   (D) t   
 g 3  g
18. Activities of three radioactive substances A, B and C are

represented by the curves A, B and C in the figure. Then
their half lives T1  A  : T1 B  : T1  C  are in the radio:
2 2 2
(A) 3:2:1 (B) 2:1:3
(C) 4:3:1 (D) 2:1:1
19. An electrical power line, having a total resistance of 2, delivers 1 kW at 220 V. The
efficiency of the transmission line is approximately:
(A) 96% (B) 72%
(C) 91% (D) 85%
20. Two capacitors of capacitances C and 2C are charged to potential differences V and 2V,
respectively. These are then connected in parallel in such a manner that the positive
terminal of one is connected to the negative terminal of the other. The final energy of this
configuration is:
3 9
(A) CV 2 (B) CV 2
2 2
25
(C) CV 2 (D) zero
6

21.    
A force F  î  2ˆj  3kˆ N acts at a point 4iˆ  3 ˆj  kˆ m. Then the magnitude of torque
 
about the point î  2ˆj  kˆ m will be x N-m. The value of x is __________.
22. A particle of mass 200 MeV/c2 collides with a hydrogen atom at rest. Soon after the
collision the particle comes to rest, and the atom recoils and goes to its first excited
state. The initial kinetic energy of the particle (in eV) is N . The value of N is: (Given the
4
mass of the hydrogen atom to be 1 GeV / c2) __________.
23. Two concentric circular coils, C1 and C2 are placed in the XY plane. C1 has 500 turns,
and a radius of 1 cm. C2 has 200 turns and radius of 20 cm. C2 carries a time dependent
 2

current I  t   5t  2t  3 A where t is in s. The emf induced in C1 (in mV), at the
instant t = 1 s is 4 . The value of x is __________.

x
0
24. A beam of electrons of energy E scatters from a target having atomic spacing of I A . The
first maximum intensity occurs at   600 . Then E (in eV) is __________.
(Planck constant h = electron mass m = 9.1 10 31kg )
25. A compound microscope consists of an objective lens of focal length 1 cm and an eye
piece of focal length 5 cm with a separation of 10 cm. The distance between an object
n
and the objective lens, at which the strain on the eye is minimum is cm. The value of
40
n is __________.
PART –B (CHEMISTRY)
26. The structure of PCI5 in the solid state is:
(A) square planar [PCI4]+ and octahedral [PCI6]–
(B) trigonal biphyramidal
(C) tetrahedral [PCI4]+ and octahedral [PCI6]
(D) square pyramidal
27. In the sixty period, the orbitals that are filled are:
(A) 6s, 5f, 6d, 6p (B) 6s, 6p, 6d, 6f
(C) 6s, 4f, 5d, 6p (D) 6s, 5d, 5f, 6p
28. The increasing order of basicity of the following compounds is:
(A) (A) < (B) < (C) < (D) (B) (D) > (A) > (B) < (D)
(C) (B) < (A) < (C) < (D) (D) (B) < (A) < (D) < (C)
29. Identify the correct molecular picture showing what happens at the critical micellar
concentration (CMC) of an aqueous solution of a surfactant
(A) (B) (B) (A)

(C) (C) (D) (D)
30. Which of the following is not an essential amino acid?

(A) Valine (B) Tyrosine
(C) Leucine (D) Lysine
31. A flask contains a mixture of compounds A and B. Both compounds decompose by first
– order kinetics. The half lives for A and B are 300 s and 180 s, respectively. If the
concentrations of A and B are equal initially, the line required for the concentration of A
to be four times that of B (in s) is : (Use In 2 = 0.693)
(A) 120 (B) 300
(C) 900 (D) 180
32. The equation that represents the water – gas shift reactions is:
(A)
(B)
(C)
(D)
33. In the following reaction sequence the major products A and B are:
(A) (B)
(C) (D)
34. A diatomic molecule X2 has a body centered cubic (bcc). The density of the molecule is
6.17 g cm–3. The number of molecules present in 200 g of X2 is:
(Avogadro constant (NA) = 6 x 1023 mol–1)
(A) 2 NA (B) 8 NA
(C) 14 NA (D) 4 NA
35. If a person is suffering from the deficiency of nor – adrenaline, what kind of drug can be
suggested?
(A) Antidepressant (B) Antishistamine
(C) Analgesic (D) Anti – inflammatory
36. The potential energy curve for the H2 molecule as a function of internuclear distance is :
(A) (B)
(C) (D)
37. Consider the following reaction:
For each of the following cases (a, b) the direction in which the equilibrium shifts is:
(a) Temperature is decreased
(b) Pressure is increased by adding N2 at constant T
(A) (a) towards reactant, (b) towards product
(B) (a) towards reactant, (b) no change
(C) (a) towards product, (b) no change
(D) (a) towards reactant
38. The most appropriate reagent for conversion of C2H5CN into CH3CH2CH2NH2 is:
(A) CaH2 (B) Na(CN)BH3
(C) LiAIH4 (D) NaBH4
39. Which of the following derivates of alcohol is unstable is an aqueous base?
(A) (B) RO – CMe3
(C) (D)
40. The condition that indicates a polluted environment is:

(A) 0.03% of CO2 in the atmosphere (B) pH of rain water to be 5.6
(C) eutrophication (D) BOD value of 5 ppm
41. The values of the crystal field stabilization energies for a high spin d6 metal ion in
octahedral and tetrahedral fields, respectively, are:
(A) (B)
(C) (D)
42. The difference between the radii of 3rd and 4th orbits of Li2+ in R1.. The difference
between the radii of 3rd and 4th orbits of He+ is R2. Ratio R1 : R2 is:
(A) 8:3 (B) 2:3
(C) 3:8 (D) 3:2
43. The increasing order of the acidity of the -hydrogen of the following compounds is:
(A) (C) < (A) < (B) < (D) (B) (B) < (C) < (A) < (D)
(C) (D) < (C) < (A) < (B) (D) (A) < (C) < (D) < (B)
44. The correct electronic configuration and spin – only magnetic moment (BM) of Gd3+ (Z =
64), respectively, are:
(A)  Xe  4f 7 and 7.9 (B)  Xe  4f 7 and 8.9
(C)  Xe  5f 7 and 8.9 (D)  Xe  5f 7 and 7.9
45. An Ellingham diagram provides information about:

1. the condition of pH and potential under which a species is thermodynamically stable.
2. the standard Gibbs energies of formation of some metal oxides
3. the kinetics of the reduction process
4. standard electrode potentials of reduction reactions involved in the extraction of
metals
46. The total number of coordination sites in ethylenediaminetetraacetate (EDTA4-) is ____.
47. The minimum number of moles of O2 required for complete combustion of 1 mole of
propane and 2 moles of butane is ___
48. An oxidation – reduction in which 3 electrons are transferred has a G0 of 17.37 kJ mol–1
0
at 250 C. The value of Ecell (in V is ____  10–2)
(1 F = 96,500 C mol–1)
49. The number of chiral carbon(s) present in peptide, Iie-Arg-Pro, is ___
50. A soft drink was bottled with a partial pressure of CO2 of 3 bar over the liquid at room
temperature. The partial pressure of CO2 over the solution approaches a value of 30 bar
when 44 g of CO2 is dissolved in 1 kg of water at room temperature. The approximate
pH of the soft drink is ___ x 10–1/
7
(First dissociation constant of H2CO3  4.0  10 ;log 2  0.3; density of the soft drink =
1 g mL–1)
PART–C (MATHEMATICS)
51. 
If the four complex numbers, z,z,z  2Re z and z – 2Re(z) represent the vertices of a
square of side 4 units in the Argand plane, then z is equal to:

(A) 2 2 (B) 2
(C) 4 2 (D) 4
52. The negation of the Boolean expression x  y is equivalent to

(A)  x   y  v   x  y  (B)   x  y  v   x   y 
(C)  x  y     xv  y  (D)  x  y  v   x   y 
53. If 210  29.31  28.32  ...  2.39  310  S  211 , then S is equal to
311
(A)  210 (B) 311  212
2
(C) 2.311 (D) 311
54. Let  R. The system of linear equations.

2x 1 4x 2  x 3  1
x1  6x 2  x3  2
x1  10x 2  4x 3  3
Is inconsistent for:
(A) exactly one positive value of  (B) exactly one negative value of 
(C) every value of  (D) exactly two values of 
e x
 e x  e x
e x 
 e 
2x
55. If  2e x  e x  1 e dx  g  x  e +c where c is a constant of integration,
then g(0) is equal to:
(A) e (B) 2
(C) e2 (D) 1
56. If 32 sin 21 , 14 and 34 2 sin 2 are the first three terms of an AP for some , then the sixth
term of this AP is:
(A) 65 (B) 78
(C) 66 (D) 81
57. A survey shows that 73% of the persons working in an office like coffee, whereas 65%
like tea. If x denotes the percentage of them, who like both coffee and tea, then x cannot
be:
(A) 63 (B) 54
(C) 38 (D) 36
58. If the common tangent to the parabolas y 2  4x and x 2  4y also touches the circle,
x 2  y 2  c 2 , then c is equal to
1 1
(A) (B)
2 2 2
1 1
(C) (D)
2 4
59. The product of the roots of the equation 9x 2  18 x  5  0 , is:

5 25
(A) (B)
9 9
5 25
(C) (D)
27 81
 /2
1
60. The value of  dx is:
 /2
1  esin x
3 
(A) (B)
2 2

(C)  (D)
4
61. If S is the sum of the first 10 terms of the series

 1  1  1  1
tan1    tan1    tan1    tan1    ...., then tan(S) is equal to:
3 7  13   21 
5 10
(A) (B)
6 11
6 5
(C)  (D)
5 11
x 1 y 3 z
62. If (a, b, c) is the image of the point (1, 2, –3) in the line,   , then a + b+
2 2 1
c is equal to
(A) 3 (B) 1
(C) 2 (D) – 1
5  e x dy
63. If y = y (x) is the solution of the differential equation .  ex = 0 satisfying y(0) =
2  y dx
1, then a value of y  loge 13  is:
(A) 0 (B) 1
(C) – 1 (D) 2
1  cos p  x  
64. If  is the positive root of the equation, p  x   x 2  x  2  0,then lim
x  x4
is equal to:
1 1
(A) (B)
2 2
3 3
(C) (D)
2 2
65. If the co-ordinates of two points A and B are    

7,0 and  7,0 respectively and P is
ny point on the conic 9x   16y 2  144 , then PA + PB is equal to:
(A) 8 (B) 16
(C) 9 (D) 6
k  x   2 1 x  
 1
66. If the function f  x   is twice differentiable, then the ordered pair
 k cos x x
 2
k1,k 2  is equal to:
(A) (1, 0) (B) (1, 1)
1  1 
(C)  , 1 (D)  ,1
2  2 
 
67. If the minimum and the maximum values of the function f :  ,   R , defined by
2 2
 sin2  1  sin2  1
f      cos2  1  cos2  1 are m and M respectively, then the ordered pair (m,
12 10 2
M) is equal to:
(A) (0, 4) 
(B) 0,2 2 
(C) (–4, 4) (D) (–4, 0)
68. The mean and variance of 7 observations are 8 and 16, respectively. If five observations
are 2, 4, 10, 12, 14, then the absolute difference of the remaining two observations is:
(A) 2 (B) 4
(C) 1 (D) 3
69. If the point P on the curve, 4x 2  5y 2  20 is farthest from the point Q(0, –4) then PQ2
is equal to:
(A) 21 (B) 48
(C) 36 (D) 29
70. If the volume of a parallelepiped, whose coterminus edges are given by the vectors
  
a  î  ˆj  nk,
ˆ b  2iˆ  4ˆj  nkˆ and c  î  njˆ  3kˆ n  0  , is 158 cu.units. then:

(A) a.c  14 (B) n=7

(C) b.c  10 (D) n=9
71. The natural number m, for which the coefficient of x in the binomial expansion of
22
 m 1
x  2  is 1540, is ____
 x 
x
72. Let f  x   x.   , for – 10 < x < 10, where [t] denotes the greatest integer function.
2
Then the number of points of discontinuity of f is equal to ___
1 2
73. If the line, 2x  y  3  0 is at a distance and from the lines 4x  2y    0
5 5
and 6x  3y    0, respectively, then the sum of all possible values of  and  is ____.
74. Four fair dice are thrown independently 27 times. Then the expected number of times, at
least two dice show up a three or a five, a ___.
75. The number of words, with or without meaning, that can be formed by taking 4 letters at
a time from the letters of the word ‘SYLLABUS’ such that two letters are distinct and two
letters are alike, is ___.
FIITJEE
Solutions to JEE (Main)-2020
PART –A (PHYSICS)
1. D
Sol. As it just floats B = mg
 4R3   4 R3 4 r 3 
 (
   ) (g)     (s ) (g)
 3   3 3 
 27 
R3 = (R3  r 3 )  
 8 
On solving we get,
8
r  R (approx)
9
2. D
Sol. h1
1 h2
d
h1  h2 1 h1

3.464d 3
45° 30°
3.464d A B C
d  h2  d 2.464 d
3
h2 = 2d – d = d
3. D
4. No option.
5. A
Sol. As Torquenet = 0
Hence, L = constant
I = (3I + I)

 
4
1 2 1 2
Loss in K.E. = I  (I  3I)
2 2 16
1 2  1
= I 1  
2  4
1 23
I
Fractional loss = 2 4 3
1 2 4
I
2
6. B
Sol. V(n)
f (as closed from end)
 17 
4 1  
 100 
(n  2) (v)
f
 24.5 
4 1  
 100 
nV(100) (n  2) (v) (100)


4(83) (4) (75.5)
75.5 n = 83 (n – 2)
75.5 n = 83 (M – 2)
7.5 n = 166
n = 22 (approx)
(330) (22) (100)
f = 2200 Hz
4(83)
7. D
E0
Sol. C
B0
E0
B0 
C
Force, Fmax = QVB
8. D
Sol. Photodiode operate in reverse bias. The photocurrent increases initially and saturates
finally.
9. C
1
Sol. m(210)2  m(0.03)  (4.2)  1000  T ; Q = mSt
4
(210) (210)
T = = 87.5°C
(4) (4.2) (0.03) (1000)
10. C
2
 R 
Sol. g  g   above
R  h
2
2 R
g  g   h
3 2
 d
g  g  1   above
 R
d 4 d 5
I  
R 9 R 9
11. B
Sol. V is always less than u.
1 1 1
 
v u F
1 1 1
 
v u F
uF u
V= 
uF u 
  1
 F 
12. B
Sol. dwef = Eqdx
kQ
 du et 
x2
dxq
R y
 1
= kQq   
 2 R
kQq(y)
Wef 
(R) (R  y)
Wall = k
d
1
Wmg + Wef = mv 2
2
2  kQqy 
V2    mg y 
m  (R) (R  y) 
 kQq  1
V 2  2y   g ; k 
 m(R) (R  y)  4 0
13. A
Sol. V = IG (G + R1)
1 = IG (G + R1) …(1)
G
R1
2 = IG (G + R1 + R2)
2 = 1 + IGR2
IGR2 = 1
R2 = G + R1
14. D
Sol. Use the equation to find ‘N’:
2 N 1
P  ( )( mu 2 )
3 V 2
15. D
Sol.  I
B1  o
2( ) b
  
  r F
2a
 = 2aF
 I B on the also equal to B1 as

 = 2(a) (I) (2a)  o 
 2b   0I
i B
 02
2 oI2a2 i 2 b 2 
 4
b
b >>> a
a
16. C
 kg   s   m3 
Sol. disp   2   (s)  
 ms   m   kg 
 1   1 
disp= (1) (16)     (1)
 300   1000 
1000
disp in mm =  0.03333
300  100
3

100
17. C
Sol. V2 = 2gh
2gh V= 2gh
gt 2
h =  2gh 
h 2
gt2 – 2 2gh t  2h  0
2 2gh  8gh  8gh

t
2g
2 2gh  4 gh
t as cannot be negative.
2g
h h
 t  (2  2)  3.4
g g
18. B
Sol. ln R  ln R0  t
1
and T1/2 

where ‘N’ is slope
10 5 5
T1/2 (A) : T1/2 (B) : T1/2 (C)  : :
6 6 2
=2:1:3
19. A
Sol. Power delivered = 1000 W
Voltage = 220 V
1000
Transmission ‘I’ =
220
Power loss = I2R

1000  100
Efficiency =
1000  I2R
20. A
Sol. 4CV  q CV  q –CV +CV
 (as same point)
2 c
q
4cV – q = –2cV + 2q
–4CV
+4CV
q = 2cV
(2cv)2 (cV)2 3cV 2

Energy =  
4c 2c 2
21. 195.00

Sol. F  (iˆ  2ˆj  3k)N
ˆ


r  (4  1)iˆ  (3  2)ˆj  ( 1  1)kˆ 
  
  r F
  
= 3iˆ  ˆj  2kˆ  î  2ˆj  3kˆ 
î ˆj kˆ
3 1–2  î(3  4)  ˆj(11)  (6  1)kˆ
1 2 3 7iˆ  11jˆ  5kˆ

  121  25  49

  195 ; x = 195
22. 51.00
Sol. Mo = 200 MeV/C2, m = 1 Gev/C2
Initial velocity of particle is ‘Vo’.
Final velocity of hydrogen atom is ‘V’
MoVo = mV
MV
V o o …(1)
m
1 1 3
Also, M0 V02  mV 2   13.6
2 2 4
Put (1) and get answer
1 51
M0 V02  eV
2 4
Hence, N = 51.
23. 5.00
  I (200)
Sol. B o R2 = 20 cm ; R1 = 1 cm
2R2
d dB
e  (R1 )2 (500)
dt dt
 I 
= (R12 ) (500)  o  (200) (10t  2)
 2R2 
 1  (500)(200) (o ) (8) (5)
=  
 10000  (2)
= 162 × 10 × 5 × 10–7
= 8002 × 10–7
e = 0.7887 mv
4
 0.8 ; x = 5.
x
24. 50.47
h
Sol. We know, P  2 Em and   …(1)
2 Em
For 1st maxima, 2nd sin  = 
Put (1) and get the answer
E = 50.47 eV.
25. 50.00
Sol. Image by objective must be at focus of eye piece.
1 1 1
 
v u fo
1 1 1 5
  ; u   cm
5 u 1 4
Hence, N = 50.
PART –B (CHEMISTRY)
26. A
Sol. In solid state PCl5 exists as an ionic solid with constituent ions PCl4 (Tetrahedral) and
PCI6 (Octahedral)
27. C
Sol. According to Aufbau’s principal, the increasing energy of atomic orbitals for sixth period
element follows the order
6s < 4f < 5d < 6p
28. C
Sol. B is least basic as lone pair of electron is present in resonance so as to make the
system aromatic in nature
D is most basic as it results in formation of equivalent resonating structures upon attack
of H+
Among A and C, the former is less basic as sp2 hybridistion of nitrogen decrease its
basic strength.
Hence option 3 follows
Sol. H H
N N N
 H 

N N N
H H H
29. D
Sol. At CMC, the particles cluster together through lyophobic end to form associated colloid
called micelle. Further all lyophilic ends(polar head) get projected towards water.
30. B
Sol. Tyrosine is a non essential amino acid.
31. C
Sol. For A
0.693 2.303 A
 log 0
300 t At
For B
0.693 2.303 B
 log 0
180 t Bt
Given A0 = B0 & At = 4Bt
Substituting & solving we get t = 900 s
32. A
Sol. In water gas shift reaction carbon monoxide is oxidized into carbon dioxide by treating it
with steam in presence of catalyst.
33. B
Sol.
34. D
M
Sol. 
V
2 MX2
6.17   3
NA 
300  10 10 
Solving MX2 = 50 g
No. of molecules in 200 g
200
  NA  4NA
50
35. A
Sol. Among its different uses noradrenaline is used as an anti-depressant.
36. D
Sol. With decrease in inter-nuclear distance, the potential energy of the system decreases,
reaches a minimum value and then sharply increases due to rise in inter-electronic as
well as inter-nuclear repulsions
37. B
Sol. In endothermic reaction formation of reactants is favoured upon decrease in
temperature. Addition of inert gas at constant volume and temperature has no effect on
equilibrium.
38. C
Sol. LiAlH4 is a versatile reducing agent which can be used for reduction of cyanide into 1o
amine.
39. C
Sol. Esters are susceptible to reaction in basic medium.
40. C
Sol. Excess of nitrogen and phosphorus is primarily responsible for eutrophication and hence
an indicator of polluted environment.
41. C
Sol. Octahedral high spin
d6
CFSE = 4(-0.40) + 2(0.60) = -0.440

Tetrahedral
d6
CFSE = 3(-0.6t) + 3(0.4t) = -0.60
42. B
a0
Sol. R1  16  9 
3
a
R2  0 16  9 
2
R1 2
 
R 2 3
43. C
Sol. B is the most acidic as it is active methylene group. D is least acidic due to cross-
conjugation in conjugate base.
 Option 3 follows
44. A
Sol. Gd : [Xe]4f 75d16s2
 Gd3+ is [Xe]4f7
  n  n  2  B.M
Also
 7  9 B.M  7.9 B.M
45. B
Sol. Ellingham diagram provides information on Gibb’s free energy for formation of oxides as
a function of temperature.
46. 6
Sol. EDTA as shown is hexadentate
47. 18
Sol. C3H8  5 O2 
 3 CO 2  4H2O
13
C4H10  O 2   4 CO2  5H2O
2
 2 mol C4H10 is given
 13 mol O2 is required for combustion of Butane
 Total mol of O2 = 5 + 13 = 18
48. -6
Sol. G0 = -nFEo
 17.37  103 = -3  96500  Eo
 Eo = -6  10–2 V
49. 4
Sol. The structure of the given compound is as show below
50. 37
Sol. Mass of CO2 dissolve at 3 bar pressure in 1 kg water(which is same as 1 litre since
density is 1 gm/mL) = 4.4 gm = 0.1 mol.
For weak electrolytes of Ostwald’s dilution law we have pH = ½(pKa – log C)
 pH = ½ [6.4 + 1] = 37 = 37  10–1
PART–C (MATHEMATICS)
51. A
Sol.  length of side = 4
then z  z  4
2iy  4
y 2

also z  z  2Re  z   4 
2x  4  x  2
z  x2  y2  2 2
52. D
Sol. Negation of x ~ y
~  x  ~ y 
 x ~  ~  y  
xy
  x  y   ~ x ~ y 
53. D
Sol. S'  210  29 .3  28.32  ........  2.3 9  310
3
G.P.  a  210 ,r  , n  11
2
 3 11 
    1
 2   11
S'  210.    211  3  1
 11 
3 2 
1
2
 311  211
54. B
2 4 
Sol. Here D  1 6 1     3  3  2 
 10 4
2
D0    3, 
3
1 4 
D1  2 6 1  2 3   
3 10 4
2
For    , D1  0
3
55. B
 e e dx
x x
Sol. 
I   e2x  2e x  e x  1 e 
 ex  e x  dx  x
 e x
I   e 2x
 ex  1 e  e
x

 e x ee dx
ex e  x e
 e x
I   e x
 1  e x e dx  e x
e x  e x  x  du
ex  e x  1 dx  du 
x x x
e x x
e  x
I  ee e
 ee  ee e x

 1 then g  x   e x  1
g 0   2
56. C
Sol. a, b, c are in AP then
2b  a  c
28  32 sin 21  3 2 sin 2
Put 32sin 2   x
x 81
28    x 2  84x  243  0
3 x
 x  3  x  81  0
32sin 2   3 or 34
2 sin2  1 or 4
1
sin 2 
2
terms are 1, 14, 27,…………….then T6  1  5 13 
57. D
Sol. n  C   73, n  T   65, n C  T   x
n  C  T   100
 n  C   n  T   n  C  T   100
 x  38
n  C  T   min  n  C ,n  T    x  65
 38  x  65
58. B
Sol. y 2  4x and x 2  4y
1
any tangent of y 2  4x is y  mx 
m
it also tangent for x 2  4y
1
  m2  m  1
m
 common tangent is y   x  1, it also touches x 2  y 2  c 2
1
 1  c 2 . 1  1  c 2 
2
59. D
2
Sol. x 2  x  t let
9t 2  18t  5  0
 3t  1 3t  5   0
1 5
x  ,
3 3
1  1  5  5  25
Product of roots     
3  3 
 3  3  81
60. B
 /2  /2
1 1
Sol. I  sin x
dx.I   sin x
dx
 /2 1  e /2 1  e
 /2
esin x  Re place
I  dx 
x  a  b  x 
sin x
 /2 e
b b
  f  x   dx   f  a  b  x  dx
a c
/2 /2
1
2I   1dx  I   dx
/2
2  /2
1  /2 
I  x /2  I 
2 2
61. A
1 1 1
Sol. S  tan1  tan1  tan1  ..... upto 10 term
3 7 13
 2 1   32   43   11  10 
S  tan1    tan1    tan1    .....  tan1  
 1  1.2   1  2.3   1  3.4   1  11.10 
    
S  tan1 2  tan1 1  tan 1 3  tan1 2  ......  tan1 11  tan 110 
S  tan1 11  tan1 1

S  tan1 11 
4
5
tan  S  
6
62. C
Sol. R  1  2r, 3  2r,  r 
dr's of PR are  2  2r,  1  2r,  3  r 
Then 2  2  2r   2 1  2r   1 3  r   0
9  9r  0  r=1
R (1, 1, –1)
then a 1 2 b2 2 c  3  2
a 1 b0 c 1
 abc  2
63. C
dy e x dx
Sol. Given 
2  y 5  ex

n  2  y   n 5  e x  nC
C
y 2
5  ex
y 0  1  C = 18
18
y 2
5  ex
 y   loge 13   1
64. C
Sol. P x  0
x2  x  2  0
 x  2  x  1  0
x  2,  1  2
 x2  x  2 
2 sin2  
Now lim

1  cos x 2  x  2   lim
 2 
x 2 x2 x 2 x2
 x2  x  2 
sin  
 2  x2  x  2
 lim  for x  2 ,  0
x 2 x2 2
2 sin
 2

x  x  2 x2  x  2
lim 2 . 2  lim
1
.
 x  2  x  1  3
x 2 2
 x x 2  x  2 x 2 2  x  2 2
 
 2 
65. A
x2 y2 9 7
Sol. For ellipse   1, a  4, b  3, e  1  
16 9 16 4
A and B are foci then PA  PB  2a  2  4   8
66. D
Sol. f(x) is differentiable then will also continuous then f     1, f 1  k 2  
k2  1
2k1  x    x  
Now f '  x   
 k 2 sin x x  
   
then f '   f '   0
 2k1 x
f "x   then 2k1  k 2
k 2 cos x x  
1
k1 
2
67. D
Sol. C3  C2  C1
 sin2  1 1
 
 
f      cos2  1 1  4 cos2   sin2   4  cos 2  ,    , 
4 2
12 2 2
f   max  M  0
f   min  m  4
68. A
2  4  10  12  14  x  y
Sol. x 8
7
 42  x  y  56  x  y  14
2
2  xi2   xi 
   
n  n 
 
4  16  100  144  196  x 2  y 2 2
16   8 
7
460  x 2  y 2
 16  64 
7
 560  460  x  y 2
2
 x 2  y 2  100 ………(2)
 xy  48
2 2
x  y   x  y   4xy  4
xy 2
69. C
x2 y2
Sol. Equation
5

4
 1 then P  5 cos ,2sin  
2 2
PQ   5 cos2   4  sin   2   cos2   16 sin   20
  sin2   16 sin   21
2
 85   sin   8 
2
 PQ max  85  49  36,
2
  sin   8    49, 81
70. C
  
Sol. Volume of parallelepiped v   a b c
 
1 1 n
v  2 4 n  158
1 n 3
 
1 12  n2  1 6  n   n  2n  4   158
3n2  5n  152  0 or 3n2  5n  164  0
D  0 (no real roots)
19
n  8,   n=8
3
 
then b.c  2  4n  3n  10
 
a.c  1  n  3n  33
71. 13.00
22r
Sol. Tr 1  22Cr xm   x 2r
Tr 1  22Cr x  
m 22r 2r
22m  mr  2r  1
22m  1  r  m  2 
22m  1
r
m2
22m  44  45
r
m2
3.3.5
r  22 
m2
So possible value of m = 1, 3, 7, 13, 43
but 20 Cr  1540
only possible condition is m = 13
72. 08.00
x
Sol. 5  5
2
x
l  2   5,  4,  3,  2,  1,0,1,2,3,4
 
Hence, function is discontinues at = –4, –3, –2, –1, 1, 2, 3, 4
Number of values is 8.
73. 30.00
Sol. 2x  y  3  0 ……….(i)

4x  2y    0  2x  y  0 ………….(ii)
2

6x  3y    2x  y   0 …………(iii)
3

3
2 1
d1    6  2    6  2,  2    8, 4
2 2 5
2 1

3
3 2
d2   9  6    9  6,  6    15,3
2 2 5
2 1
Sum of all value of  and   30 .
74. 11.00
2 2 3 4
 2  4 4  2  4 4 2
4
Sol. P (at least 2 show 3 or 5)  C2 .      C3      C4  
6 6 6 6 6
384  128  16 11
 
64 27
n = 27
 expectation of number of times = np
11
 27.  11
27
75. 240.00
Sol. SYLLABUS
S – 2, L – 2, A, B, Y, U
4! 24
Required  2C1 . 5C2 .  2.10.  240
2! 2

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FIITJEE

PHYSICS, CHEMISTRY & MATHEMATICS

Time Allotted: 3 Hours Maximum Marks: 300

2. A balloon is moving up in air vertically above a

4. Three different processes that can occur in an ideal

8. With increasing biasing voltage of a photodiode, the photocurrent magnitude:

12. A solid sphere of radius R carries a charge Q + q

13. A galvanometer of resistance G is converted into a voltmeter of range 0 – IV by

14. Number of molecules in a volume of 4 cm3 of a perfect monoatomic gas at some

18. Activities of three radioactive substances A, B and C are

instant t = 1 s is 4 . The value of x is __________.

28. The increasing order of basicity of the following compounds is:

(A) (B) (B) (A)

30. Which of the following is not an essential amino acid?

37. Consider the following reaction:

(A) (B) RO – CMe3

40. The condition that indicates a polluted environment is:

45. An Ellingham diagram provides information about:

46. The total number of coordination sites in ethylenediaminetetraacetate (EDTA4-) is ____.

49. The number of chiral carbon(s) present in peptide, Iie-Arg-Pro, is ___

square of side 4 units in the Argand plane, then z is equal to:

52. The negation of the Boolean expression x  y is equivalent to

54. Let  R. The system of linear equations.

59. The product of the roots of the equation 9x 2  18 x  5  0 , is:

61. If S is the sum of the first 10 terms of the series

65. If the co-ordinates of two points A and B are    

nV(100) (n  2) (v) (100)

 I B on the also equal to B1 as

2 2gh  8gh  8gh

Power loss = I2R

(2cv)2 (cV)2 3cV 2

CFSE = 4(-0.40) + 2(0.60) = -0.440

CFSE = 3(-0.6t) + 3(0.4t) = -0.60

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