Sarlink Blow Molding

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Guidelines for the

Blow Molding of Sarlink

Contents
Introduction

The principles of blow molding 3


Introduction 3
Continuous extrusion blow molding 3
Multi-layer/sequentional
co-extrusion blow molding 3
Injection blow molding 4
3D Blow molding 4
Suction blow molding 5
Press injection blow molding 5

Characteristics of the typical


blow molding equipment for Sarlink 6
Screw design 6
Head and die design for
continuous extrusion blow molding 6
Mold design 7
Shrinkage 7

Processing conditions for optimal


blow molding of Sarlink 8
Drying and storage of Sarlink 8
Use of regrind 8
Coloring of Sarlink 8
Temperature settings 8
Blowing parameters 9
Maintenance of the equipment 9
Ancillary equipment 9

Appendix 1 10
Troubleshooting table for the
extrusion blow molding of Sarlink

1 | Guidelines for the Blow Molding of Sarlink www.sarlink.com


Introduction
Sarlink® thermoplastic vulcanizates (TPV) In addition to standard types, a wide range of
are based on dynamically vulcanized EPDM specialty grades are available, including high
rubber particles dispersed in a polypropylene flow and UV stabilized grades.
matrix.
Because of its combination of excellent
Because of this morphology, Sarlink finished part properties and easy processing,
thermoplastic vulcanizates combine the Sarlink thermoplastic vulcanizates have
performance characteristics of widely used found many applications in a wide range of
thermoset rubbers, such as EPDM and markets, including: automotive, building and
polychloroprene, with the ease of plastic construction, electrical, mechanical rubber
processing. goods, medical and leisure.

Sarlink offers a wide range of properties Sarlink thermoplastic vulcanizates are widely
valuable to the end user. For instance: used in many blow molded parts such as rack
• resistance to high temperature & pinion steering gear boots, shock absorbers,
• resistance to low temperature strut covers, steering column cover, (3D
• excellent flexural fatigue endurance sequential) automotive air ducts, cable ducts
• high impact strength and many other applications in all market
• excellent resistance to chemicals and segments.
solvents This brochure is a guideline for the blow
• excellent resistance to weathering molding of Sarlink and shows an overview
• good electrical properties of the different blow molding techniques.
• high tear resistance A checklist for troubleshooting is available
• low tension and compression set on the last pages.
• good resistance to oils (particularly harder
grades).

In addition to their superior performance


characteristics, Sarlink thermoplastic
vulcanizates, which are fully compounded,
ready-to-use pellets, offer the following
processing advantages compared to thermoset
rubber:
• no compounding
• no vulcanization
• low capital investment.
• easy processing on standard thermoplastic
equipment for extrusion, injection
molding and blow molding
• fast processing (short cycle times)
• thermal stability/wide processing
window
• low energy consumption
• recycling of scrap generated during
processing
• recycling of parts after service life
• excellent control of product quality and
dimensional tolerances
• in-line colorability
• easy weldability (profiles, sheeting...)
• material combinations by co-extrusion,
co-injection or co-blow molding to
produce hard/soft articles, solid/sponge
profiles...

2 | Guidelines for the Blow Molding of Sarlink www.sarlink.com


The Principles of Continuous extrusion
blow molding
Blow Molding
The principle of the extrusion blow molding
process is that a parison, which is formed by
Introduction continuous extrusion of material and rotating
of the screw in the barrel, is clamped between
Blow molding is the established technique Extrusion blow molding is the most widely two halves of a mold, cut-off and inflated with
for the production of hollow articles such as used technique. Sarlink is very suitable for air to fill the mold. The mold is cooled so that
bellows and airducts. There are three major blow molding because it has excellent melt the product is frozen into the mold shape,
techniques for this process: strength and a high blow ratio. Sarlink gives while still under air pressure. The mold is then
• extrusion blow molding a significant weight reduction compared opened and the part removed. Due to the
• press injection blow molding to thermoset rubber and Sarlink is fully high melt stability and large blow-ratio (up to
• injection blow molding. recyclable. Table 1 shows an overview of 4.5 for the high hardness grades) of Sarlink,
application and material combinations. large blow molded articles can be made. The
processing steps are shown in figure 2.

!PPLICATION -ATERIAL Multi-layer/sequentional


co-extrusion blow molding
2ACKPINIONSTEERINGGEARBOOTS 3ARLINK" $" "
$" $" Several polymers can be extruded in a
3HOCKABSORBER STRUTCOVER 3ARLINK" " " multi-layer parison. The equipment is based
on continuous extrusion or equipment with
3TEERINGCOLUMMCOVER 3ARLINK" " a melt accumulator. The thickness of each
individual layer can be varied. Sarlink can be
!UTOMOTIVEAIRDUCTSDIMENSIONAL 3ARLINK" " " " used in this kind of process to create e.g. a soft
!UTOMOTIVEAIRDUCTSDIMENSIONAL FLEXIBLEPART 00STIFFPART touch or rubber-like layer on polypropylene.
The principles of the multi-layer extrusion
#ABLEDUCT 3ARLINK" "
blow molding system are shown in figure 1.

4ABLE%XAMPLESFORPOSSIBLE3ARLINKAPPLICATIONCOMBINATIONS

0HASE 0HASE 0HASE 0HASE 0HASE 0HASE

0ARISON -OULD "LOWING )NFLATING -OULD 4RIMMING


FORMATION CLOSING STAGE COOLING OPENING STAGE
STAGE STAGE STAGE STAGE

&IG /VERVIEWOFTHEEXTRUSIONBLOWMOULDINGPROCESS

3 | Guidelines for the Blow Molding of Sarlink www.sarlink.com


&IG 4WOLAYER
CO EXTRUSIONBLOW
MOULDING

-AINEXTRUDER
3ECONDEXTRUDER

The different materials can also be extruded Injection blow molding ends which have better control of dimensional
sequentially. This is accomplished by reducing tolerances. These machines are typically
layer thickness to zero for one layer at a time in The injection blow molding process is based arranged in 3 or 4 stations that perform
an alternating pattern. This technique is used on an injection molded preform instead of individual process steps. In the first station the
to create hard-soft combinations. Automotive a directly extruded parison in the extrusion preform is injection molded. The machine is
air ducts with flexible ends and rigid pipe blow molding process. This process has the then indexed to the second position where the
sections are produced with this process. advantage of producing injection molded preform is inflated into a blow molding cavity.
In the third station the parts are ejected off the
core rod. In the fourth station the core rods
are tempered. This process is typically used to
produce high production volume parts such as
rack & pinion boots.

3D blow molding

This process is typically used for automotive


air intake ducts. An advantage of three
dimensional blow molding is that it is possible
to make complex parts without generating
flash along the edges. There are different
techniques to make 3D articles. Figure 4a
shows the process with a movable mold;
figure 4b shows the movable head system on
a fixed mold. The parison can also be put into
the mold by manipulating the parison with a
robot.

&IG )NJECTIONBLOWMOULDING

4 | Guidelines for the Blow Molding of Sarlink www.sarlink.com


"LOW PIN
8
9 :

9
8

6ACU»M

&IGA %XAMPLE &IGB %XAMPLE &IG 3UCTION


OF$BLOW OF$BLOW BLOWMOULDING
MOULDINGWITH MOULDINGWITH
MOVABLEMOULD MOVABLEHEAD

Suction blow molding of the mold and the addition of a vacuum injection mold which produces the end fitting
pump. One disadvantage of this system is of the part. This mold is then lifted vertically
In this blow molding process the parison is the impossibility to produce complex 3D while extruding a parison against the force of
sucked in the (closed) mold by a vacuum geometries. Another disadvantage is that gravity. The wall thickness is adjusted during
pump. This pump is connected to the bottom the part diameter is limited. Figure 5 shows a the extrusion process by varying the die gap.
of the mold. The filling process of the mold simplified representation of the suction blow The mold closes around the injection mold
takes place very rapidly (typically within a molding system. and the parison, and the parison is blown into
second). When the mold is filled, the parison the mold cavity. The mold opens and the part
is inflated via an injected blow needle. This is removed for trimming. The principle of this
blow needle is injected on the top side of the Press injection blow molding press injection blow-molding system is shown
parison. in figure 6.
Sarlink is an excellent material to use in a press
The advantage of this blow molding injection blow molding system. This process ®Registered trade name of Ossberger-
technology is that it is possible to produce is also known as the Ossberger process® , Turbinenfabrik GmbH & Co.
3D blow molded parts on standard extrusion named after the equipment manufacturer. In
blow molding machines after a (small) change this process the extruder initially fills a small

0HASE 0HASE 0HASE 0HASE

)NJECTIONMOULD $RAWINGOFPARISONWITH "LOWING 4RIMMING


MEETSEXTRUSIONDIE CLOSEDLOOPSPEED STAGE STAGE
)NJECTIONMOULDINGOFHEAD DIECAPCONTROL

&IG 0RESSINJECTIONBLOWMOULDINGSYSTEMOF/SSBERGER

5 | Guidelines for the Blow Molding of Sarlink www.sarlink.com


Characteristics of Mixing pins or shear segments are often used
with general purpose screws to improve melt
the Typical Blow homogeneity and dispersion of colorants and
additives.
Molding Equipment
Barrier screws (YDRAULICPLUNJER
for Sarlink The use of a low shear barrier screw will -ATERIALMELT
provide the higher throughput and improved
Sarlink can be processed on existing melt quality. A generous barrier clearance
blow-molding equipment without further is used (typically 1.5 to 2.0 mm). The barrier
modification. However, in order to obtain section should be followed with a Maddock
the best blow molding performance, or if mixing section to further homogenize ! !
dedicated equipment for processing Sarlink the melt. Consult DSM for further design
has to be purchased, it is recommended to take recommendations regarding barrier screws.
the following items into consideration.
&IG
!CCUMULATOR
Head and die design for continuous
HEADDESIGN
Screw design extrusion blow molding

General purpose screws Head design. Polyolefin head designs are also
For the processing of Sarlink a single stage, recommended for Sarlink. Important factors in
three zone polyolefin type metering screw head design are:
is adequate. The optimum general purpose • streamlined design
screw design is as follows: • uniform temperature control the part weight plus the flash. The maximum
• feed zone: this zone should be relatively • programmable die parison wall thickness accumulator capacity should not be greater
short, about 25 % of the total screw length control. than 3 times the part weight plus flash. The
• transition section: recommended is a accumulator head design is shown in figure 7.
transition section with a length of about 25 In cases where large parisons are necessary
% of the total an accumulator head is preferred. The Die design
• metering section: about 50 % of the total principle of this head design is that the molten The die can be converging or diverging,
screw length is recommended, in order to material will be stored in the head, prior to depending on head design and on required
provide adequate shear mixing the formation of the parison. The parison parison diameter. Smaller parts are typically
• L/D ratio of 24:1 to 32:1 is recommended. will be formed by pressing the material run with diverging head tooling. Figure 8a and
Shorter screws should be avoided out of the head (melt ram). The minimum 8b shows the difference between a diverging
• compression ratio of 3:1 is recommended. accumulator capacity should be greater than and converging die.

&IGB &IGA $IVERGING


#ONVERGING DIEDESIGN
DIEDESIGN

6 | Guidelines for the Blow Molding of Sarlink www.sarlink.com


The use of equipment with programmable Mold design
parison wall thickness control is preferred.
This will allow for compensation of parison Blow mold cavity material
sagging due to the forces of gravity: if a long, Aluminum materials are typically used for
or heavy parison is extruded with constant Sarlink. Machined molds are often more
thickness, it will be thicker at the bottom expensive to produce but are more durable.
end, and thinner at the top. Consequently Pre-hardened steel material can be used for
the bend of the finished part will be thinner high volume production to reduce wear.
and constitute a weak point. To correct this,
it is possible to vary the wall thickness of the Venting of the mold
parison during the extrusion by moving either Venting of the mold is necessary in order to
the internal or external part of the die. allow for escape of air and optimally following
the shape of the mold. For Sarlink parting line
Die dimensions vents are recommended, with a depth of 0.05
The outer diameter of the extrusion die (ddie) to 0.08 mm. Vents to the outside can be much
is equal to the outer diameter of the requested deeper from 0.25 mm to 0.40 mm. Incavity
parison (d extrudate) divided by 1 plus the die vent plugs are used for convoluted molds or
swell divided by 100. for larger parts which require more air flow
to vent.

D EXTRUDATE Cooling of the mold


D DIE  For large molds, it is advisable to have several
 DIESWELL
cooling zones. Most intensive cooling should

be located in the pinch relief section, where
the material is the thickest. Small molds should
The minimum parison outer diameter is the have a single cooling circuit. Recommended
ratio of the finished part outer diameter mold temperatures are 10 to 40 °C.
divided by the blow-ratio of the used Sarlink
grade.
Shrinkage
The parison diameter should be chosen so that
the parison enters easily into the mold and The approximate shrinkage of Sarlink in a
minimizes the required blow ratio. blow molding process for a wall thickness of
a part, up to 2 mm, will be 1.5 % for the soft
Die swell grades, below 75 Shore A and 2 % for the high
Die swell for Sarlink products ranges from 0 hardness grades.
to 15 %. The die swell is low for low hardness
grades. Die swell is also influenced by the
shear rate through the die. As the flow rate
increases the die swell will increase. Lower
melt temperatures will increase the die swell.

7 | Guidelines for the Blow Molding of Sarlink www.sarlink.com


Processing Coloring of Sarlink

Conditions for Natural Sarlink can be colored by addition of If possible the feed throat of the barrel should
a suitable masterbatch. Polypropylene based be cooled with water to avoid agglomeration
Optimal Blow masterbatches offer the best compatibility of the pellets and to facilitate the feeding. If
with Sarlink, but may slightly increase cooling is not available, it is recommended
Molding of Sarlink the hardness. Low density polyethylene to keep the first zone of the barrel below 190
based masterbatches are also suitable. °C. Fine-tuning of the temperature settings is
Recommended level of color Masterbatch in dependent on the blow-ratio, parison length
Drying and storage of Sarlink Sarlink: 1 to 5 % by weight, to minimize the and grade used.
impact on Sarlink properties.
In exposure to air Sarlink granules may pick Screw temperature control
up moisture to a slight degree. The presence During blow molding, dispersion of the color Internal heating or cooling of the screw is not
of moisture in the granules produces porosity Masterbatch can be improved if needed, by recommended.
in the parison, leading to parison failure utilizing a mixing screw.
during the blowing stage. It is therefore Mold temperature
recommended to store Sarlink carefully and Blow molds are typically cooled with water.
to dry both virgin pellets and regrind before Temperature settings Recommended mold temperatures range from
blow molding. 10 °C to 40 °C. Higher mold temperatures will
Material melt temperature improve surface quality but will increase the
Recommended storage conditions A melt temperature in the range of 185 °C to cooling time.
Suggested storage conditions for Sarlink are: 220 °C is optimal for blow molding of Sarlink.
• store Sarlink bags closed and undamaged If the temperature is too low a rough surface Internal part cooling
in a non-humid environment will appear, parison stability will be improved For large parts with a lengthy cooling cycle the
• open bags just before use 3 close the bags but blow-ratio will be reduced. A high melt part can be cooled by circulating air through
securely when the whole content has not temperature will result in a lower stability of the part. This is accomplished by means of two
been used completely the parison due to lower melt strength, which blow pins, one for air supply and the other to
• bring cold granules to ambient will result in less control of wall thickness of vent.
temperature in the processing room while the blow molded part.
keeping the bags closed.
Barrel temperatures
Recommended drying conditions For blow molding of Sarlink the material
• dry minimal 3-4 hours at 80 °C using a should be processed in the range of 185 °C to
desiccant dryer with a dew point of -40°C 220 °C. For soft grades low temperatures are
recommended. Wide variations in cylinder
temperatures should be avoided. Typical
Use of regrind barrel temperatures for Sarlink are shown in
table 2.
Sarlink 3000 and 4000 thermoplastic
vulcanizates have excellent melt stability, and
all scrap generated during processing can be 0ROCESSINGTEMPERATURESę#
recycled provided it is kept clean. High levels (ARDNESS ! $
of regrind can be used.
"ARRELZONE  
"ARRELZONE  
The viscosity of Sarlink decreases slightly
after reprocessing. For this reason, it is
"ARRELZONE  
recommended during production to blend a (EAD  
constant level of less than 20% regrind within $IE  
the virgin material in order to keep processing -OULD  
conditions constant. Addition of regrind has
no negative influence on surface quality, as 4ABLE2ECOMMENDEDTEMPERATURE
mentioned in the ’drying’ paragraph. SETTINGSFORBLOWMOULDING3ARLINK

It is recommended to dry recycled material


before reuse to avoid porosity in the parison.

8 | Guidelines for the Blow Molding of Sarlink www.sarlink.com


Blowing parameters Maintenance of the equipment Ancillary equipment

Pre-blowing Purging of equipment Equipment typically used for PE or PP, such as


Pre-blowing may be necessary to prevent before processing Sarlink toothed circular saws, may not be suitable for
collapsing of the parison during closing of the To avoid contamination, the blow soft Sarlink grades, because of its rubber-like
mold or by gravity. molding equipment should be cleaned nature. Sarlink parts are best trimmed with
before processing Sarlink. Polyethylene razor blades. For the lower durometer grades,
Blowing pressure/time or polypropylene of low melt index are hot knives are recommended in order to get
Rapid blowing into the mold is preferred. recommended. Purge at a temperature of an optimal surface. These soft parts should be
Actual blow speed should be defined 200 °C. This cleaning operation is particularly supported during cutting to avoid distortion.
experimentally. The optimal blow speed is important if the equipment has been used Rotating knife systems are typically used to
influenced by parison, part design, wall- previously for PVC or POM/acetals. trim ends of cylindrical parts.
thickness, temperature settings and blow-
ratio. Blowing pressure of 0.3 to 0.7 MPa is Equipment shut down and cleaning
recommended for maximum part definition At the end of the production, run the hopper
and adequate heat transfer. The volume and and screw empty of Sarlink. Purge the
pressure of the air should be maintained extruder thoroughly with polyethylene or
throughout the cooling cycle prior to mold polypropylene if change over to another
opening. material is anticipated. The use of high
viscosity polyolefins will speed up the purging
Blow-ratio process.
From the hollow parison the product is
formed by expansion of air. The blow-ratio Perform a general clean up of the hopper and
(maximum part finished outer diameter any pneumatic conveying lines to remove
divided by die outer diameter) of the parison residual fines. Clean the mold and protect the
is dependent on: mold for corrosion.
• the parison temperature
• the parison thickness
• the hardness of the Sarlink grade used.

An overview of the blow-ratio of Sarlink is


shown in table 3.

 4ABLE-AXIMUM
-AXIMUMBLOW RATIO

BLOW RATIOOF3ARLINK
ASFUNCTIONOFTHE
 PARISONWALLTHICKNESS


! ! ! ! ! ! $ $
MM
MM0ARISONWALLTHICKNESS
MM (ARDNESS3HORE

9 | Guidelines for the Blow Molding of Sarlink www.sarlink.com


Appendix 1
Troubleshooting Table for the
Extrusion Blow Molding of Sarlink

0ROBLEM #AUSE 3OLUTIONCORRECTIVEACTION

5NSTABLEPARISON -ELTTEMPERATURETOOHIGH $ECREASECYLINDERTEMPERATURES


$ECREASEHEADDIETEMPERATURES

$IENOTCENTRAL #ENTREDIEANDPIN

$IEHEADDIRTY #LEANDIE

0ARISONISRUNNINGTO 0RESSUREDIFFERENCESOFTHE #ENTREDIEANDPIN


ONESIDE PARISONASITLEAVESTHEDIE #HECKHEADANDDIEHEATERBANDS
ORCIRCUMFERENCE
TEMPERATUREDIFFERENCESIN
THEMELTWHENTHEPARISONIS
FORMEDANDLEAVESTHEDIE

2OUGH -ATERIALTOOCOLD 2AISECYLINDERTEMPERATURESCHECKHEATER BANDS


MOULDINGSSURFACE 2AISEHEADDIETEMPERATURESCHECKHEATER BANDS
$ECREASEEXTRUSIONSPEEDLONGERHEATINGPERIOD

-OULDTOOCOLD )NCREASEMOULDTEMPERATURE

(EADDIEDIRTY $ISMANTLEPINANDDIEANDCLEANPOLISHIFNECCESSARY

$ISPERSIONPROBLEM 5SESCREWWITHMORECOMPRESSION
$ECREASEHOPPER SIDETEMPERATURE

"LOWNPARTSCONTAIN )NHOMOGENEOUS )NCREASECYLINDERTEMPERATURES


UNMOLTENPARTICLES TEMPERATUREDISTRIBUTIONIN )NCREASEDIEHEADTEMPERATURESFORMELTING
THEMELTORMATERIALISIN $ECREASEEXTRUSIONSPEED
GENERALTOOCOLD )NCREASEBACKPRESSUREIFPOSSIBLE
-IXINGELEMENTS

$ISPERSIONPROBLEM 5SESCREWWITHMORECOMPRESSION
!DDMIXINGELEMENTTOSCREW

"LOWPROBLEMS )MPOSSIBLETOBLOWPARISON $RYGRANULATES


$RYREGRIND
)NCREASEORDECREASEBLOWPRESSURE

"LOWRATIOTOOLOW #HANGETOHIGHERHARDNESS
)NCREASEPARISONWALLTHICKNESS
$ECREASEORINCREASEMATERIALMELTTEMPERATURE
#HANGEDIETOOLINGTOINCREASETHEPARISONDIAMETER

10 | Guidelines for the Blow Molding of Sarlink www.sarlink.com


0ROBLEM #AUSE 3OLUTIONCORRECTIVEACTION

7ELDLINES 7ELDLINESVISIBLEORCRACKS )NCREASEMELTTEMPERATURE


ONPARTANDPARISONFORMED )NCREASEDIETEMPERATURE
INSPIDER 0URGINGORCLEANINGOFHEADSPIDERDIE

&LASHING &LASHOFMATERIALONPART $ECREASEBLOWPRESSURE


)NCREASECLAMPFORCE
$ECREASEMELTTEMPERATURE

#ONTAMINATIONIN $IRTINEQUIPMENT 0URGETOREMOVEDEGRADEDMATERIAL


PARISONPART
$IRTINREGRIND $ECREASEBARRELHEADTEMPERATURE

"URNEDDEGRADEDMATERIAL 2EDUCEOVERALLCYCLETIME

3ILVERSTREAKSORVOIDS 7ATERVAPOURENCLOSURE 5SEDRYMATERIALPRE DRYMATERIAL


INPARISON MATERIALCONTAINSMOISTURE $RYREGRINDIFUSED

11 | Guidelines for the Blow Molding of Sarlink www.sarlink.com

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