Name:

Stoichiometry

UPGrade

Purple/Orange/ Blue

1. [1 mark]

Which compound has the greatest percentage by mass of nitrogen atoms?

A. N2H4

B. NH3

C. N2O4

D. NaNO3

Markscheme

2. [1 mark]

Which statements about mixtures are correct?

A. I and II only

B. I and III only

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C. II and III only

D. I, II and III

Markscheme

3. [1 mark]

5.0 cm3 of 2.00 mol dm–3 sodium carbonate solution, Na 2CO3(aq), was added to a volumetric flask and the
volume was made up to 500 cm 3 with water. What is the concentration, in mol dm–3, of the solution?

A. 0.0050

B. 0.0040

C. 0.020

D. 0.010

Markscheme

4. [1 mark]

What is the expression for the volume of hydrogen gas, in dm 3, produced at STP when 0.30 g of magnesium
reacts with excess hydrochloric acid solution?

Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)

Molar volume of an ideal gas at STP = 22.7 dm 3 mol−1

A.

B.

C.

D.

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Markscheme

5. [1 mark]

What is the sum of the coefficients when the equation is balanced with whole numbers?

—C8H18(g) + —O2(g) → —CO(g) + —H2O(l)

A. 26.5

B. 30

C. 53

D. 61

Markscheme

6. [1 mark]

How many moles of oxygen atoms are there in 0.500 mol of hydrated iron(II) ammonium sulfate,
(NH4)2Fe(SO4)2•6H2O(s)?

A. 4.00

B. 7.00

C. 8.00

D. 14.00

Markscheme

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7. [1 mark]

What is the maximum volume, in dm 3, of CO2(g) produced when 1.00 g of CaCO 3(s) reacts with 20.0 cm 3 of
2.00 mol dm–3 HCl(aq)?

CaCO3(s) + 2HCl(aq) → CaCl2(aq) + H2O(l) + CO2(g)

Molar volume of gas = 22.7 dm 3 mol–1; Mr(CaCO3) = 100.00

A.

B.

C.

D.

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8. [1 mark]

Which factors affect the molar volume of an ideal gas?

A. I and II only

B. I and III only

C. II and III only

D. I, II and III

Markscheme

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9. [1 mark]

Which equation represents sublimation?

A. 2Al(s)+3I2(g)→2AlI3(s)

B. HgCl2(s)→HgCl2(g)

C. I2(g)→I2(s)

D. CaCO3(s)+2HCl(aq)→CaCl2(aq)+CO2(g)+H2O(l)

Markscheme

10. [1 mark]

Which volume, in cm 3, of 0.20 mol dm -3 NaOH (aq) is needed to neutralize 0.050 mol of H 2S(g)?

H2S(g) + 2NaOH(aq) → Na2S(aq) + 2H2O(l)

A. 0.25
B. 0.50
C. 250
D. 500

Markscheme

11. [1 mark]

For which compound is the empirical formula the same as the molecular formula?

Ar(H)=1; Ar(C)=12; Ar(O)=16

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Markscheme

12. [1 mark]

In which mixture is NaOH the limiting reagent?

A. 0.20mol NaOH + 0.10mol H 2SO4

B. 0.10mol NaOH + 0.10mol H 2SO4

C. 0.20mol NaOH + 0.10mol HNO 3

D. 0.10mol NaOH + 0.10mol HNO 3

Markscheme

13. [1 mark]

The complete combustion of 15.0cm 3 of a gaseous hydrocarbon X produces 60.0 cm3 of carbon dioxide gas
and 75.0 cm3 of water vapour. What is the molecular formula of X? (All volumes are measured at the same
temperature and pressure.)

A. C4H6
B. C4H8
C. C4H10
D. C6H10

Markscheme

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14. [1 mark]

5.0mol of Fe 2O3(s) and 6.0mol of CO(g) react according to the equation below. What is the limiting reactant
and how many moles of the excess reactant remain unreacted?

Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)

Markscheme

15. [1 mark]

Why do gases deviate from the ideal gas law at high pressures?

A. Molecules have finite volume.

B. Cohesive forces increase the volume from the ideal.

C. Increasing pressure increases the temperature of the gas.

D. Collisions between molecules occur more frequently as pressure increases.

Markscheme

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16. [1 mark]

Combustion of ethanol takes place according to the following unbalanced equation.

___ ___ ___ ___

What is the mole ratio of ethanol to oxygen in the balanced equation?

A. 1:1

B. 2:1

C. 1:3

D. 2:7

Markscheme

17. [1 mark]

Which sample contains the largest amount, in mol, of oxygen atoms?

A. 0.20 mol

B. 0.30 mol

C. 0.40 mol

D. 0.80 mol

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18. [1 mark]

Which compound has the highest percentage of carbon by mass?

A.

B.

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C.

D.

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19. [1 mark]

Which solution contains the biggest amount, in mol, of chloride ions?

A. of

B. of

C. of

D. of

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20. [1 mark]

What is the total number of protons and electrons in one mole of hydrogen gas?

A. 2

B. 4

C.

D.

Markscheme

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21. [1 mark]

A hydrocarbon contains 85.7 % carbon by mass. What is the empirical formula of the hydrocarbon?

A.

B.

C.

D.

Markscheme

22. [1 mark]

What is the sum of all coefficients for the combustion of one mole of propane?

___ ___ ___ ___

A. 8

B. 12

C. 13

D. 15

Markscheme

23. [1 mark]

A gas with a molar mass ( ) of occupies a volume of at a pressure of

and a temperature of 25 °C. Which expression is correct for the calculation of the mass of

the gas, in g?

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A.

B.

C.

D.

Markscheme

24. [1 mark]

4.0 g of solid sodium hydroxide is added to of aqueous sulfuric acid.

Which statement is correct?

A. Neither reactant is in excess.

B. 0.10 mol is formed.

C. Excess remains in solution.

D. Excess NaOH remains in solution.

Markscheme

25. [1 mark]

Which expression gives the sum of all the coefficients for the general equation for the complete

combustion of hydrocarbons?

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___ ___ ___ ___

A.

B.

C.

D.

Markscheme

26. [1 mark]

0.040 mol of is dissolved in water to give of aqueous solution. What

is the concentration, in , of ammonium ions?

A. 0.00040

B. 0.0080

C. 0.20

D. 0.40

Markscheme

27. [1 mark]

When sodium bromate(V), , is heated, it reacts according to the equation below.

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What amount, in mol, of produces of oxygen gas, measured at room temperature and

pressure? (Molar volume of gas at room temperature and pressure.)

A. 0.017

B. 0.067

C. 0.10

D. 0.15

Markscheme

28. [1 mark]

Aluminium carbide reacts with water according to the equation below. What is the sum of all the coefficients
when the equation is balanced?

___ ___ ___ ___

A. 13

B. 14

C. 19

D. 20

Markscheme

29. [1 mark]

At which temperature, in K, assuming constant pressure, is the volume of a fixed mass of gas at 127 °C
doubled?

A. 200 K

B. 254 K

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C. 400 K

D. 800 K

Markscheme

30. [1 mark]

The structural formula of a dioxin is shown below.

What is its empirical formula?

A.

B.

C.

D.

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31. [1 mark]

of a solution of is added to of a solution

of . A precipitate of is formed according to the equation below.

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What is the amount, in mol, of produced?

A. 0.0050

B. 0.010

C. 0.050

D. 0.10

Markscheme

32. [1 mark]

Which volumes of gases at standard temperature and pressure have the same mass as of ?

I. of

II. of

III. of

A. I and II only

B. I and III only

C. II and III only

D. I, II and III

Markscheme

33. [1 mark]

What is the mass, in g, of one mole of hydrated copper(II) sulfate, , given the following
relative atomic mass values?

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A. 160

B. 178

C. 186

D. 250

Markscheme

34. [1 mark]

For which compounds is the empirical formula the same as the molecular formula?

I. Methane

II. Ethene

III. Ethanol

A. I and II only

B. I and III only

C. II and III only

D. I, II and III

Markscheme

35. [1 mark]

Some sodium chloride is dissolved in water. Which term describes the role of sodium chloride in this process?

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A. Solute

B. Solvent

C. Solution

D. Saturated

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36. [1 mark]

At which temperature, in K, assuming constant pressure, is the volume of a fixed mass of gas at 127 °C
doubled?

A. 200 K

B. 254 K

C. 400 K

D. 800 K

Markscheme

37. [1 mark]

Under which conditions does have the same number of molecules as of at 27 °C and

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Markscheme

38. [1 mark]

Which represents an empirical formula?

A.

B.

C.

D.

Markscheme

39. [1 mark]

What are the coefficients of and when the following equation is balanced using
the smallest possible whole numbers?

___ ___ ___ ___

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Markscheme

40. [1 mark]

What is the pressure, in Pa, if 3 mol of gas occupies at 25 °C?

Given:

A.

B.

C.

D.

Markscheme

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41. [1 mark]

7.102 g of is dissolved in water to prepare of solution.

What is the concentration of in ?

A.

B.

C.

D.

Markscheme

42. [1 mark]

Which statements are correct about Avogadro’s constant?

I. It is the number of ions in 12 g of sodium hydride, NaH.

II. It is the number of molecules in of hydrogen gas at 0 °C and 1 atm.

III. It is the number of atoms in 12 g of .

A. I and II only

B. I and III only

C. II and III only

D. I, II and III

Markscheme

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43. [1 mark]

What is the molar mass, in , of a substance if 0.30 mol of the substance has a mass of 18 g?

A. 5.4

B. 6.0

C. 30

D. 60

Markscheme

44. [1 mark]

What is the whole number ratio of the coefficients of ammonia to oxygen when the following equation is
balanced correctly?

___ ___ ___ ___

A. 1 : 2

B. 2 : 1

C. 4 : 5

D. 5 : 4

Markscheme

45. [1 mark]

When of a hydrocarbon, , was burned in excess oxygen, of carbon dioxide and

of steam were produced (all volumes were measured under the same conditions). What is the
molecular formula of the hydrocarbon?

A.

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B.

C.

D.

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46. [1 mark]

What is the pressure, in Pa, in a container containing 1.8 g of steam at a temperature of 727 °C? (

A.

B.

C.

D.

Markscheme

47. [1 mark]

Which contains the largest number of ions?

A. 1 mol of

B. 1 mol of

C. 2 mol of

D. 3 mol of

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Markscheme

48. [1 mark]

Which is the best description of relative atomic mass, Ar?

A. The number of neutrons and protons present in the nucleus of an atom

B. The average number of neutrons and protons in all isotopes of an element

C. The weighted mean mass of naturally occurring isotopes of an element compared to the mass of an atom of
carbon-12

D. The weighted mean mass of naturally occurring isotopes of an element compared to 1/12 th of the mass of
an atom of carbon-12

Markscheme

49. [1 mark]

What mass of carbon dioxide, CO 2(g), in g, is produced when 5.0 g of calcium carbonate, CaCO 3(s),reacts
completely with hydrochloric acid, HCl(aq)?

A. 0.050

B. 2.2

C. 4.4

D. 5.0

Markscheme

B
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50. [1 mark]

What volume of carbon dioxide, CO 2(g), in dm3, is produced when 1 dm 3 of octane, C 8H18(g), undergoes
complete combustion?

A. 1

B. 4

C. 8

D. 9

Markscheme

51. [1 mark]

What are the coefficients of and when the following equation is balanced using
the smallest possible whole numbers?

___ ___ ___ ___

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Markscheme

52. [1 mark]

7.102 g of Na2SO4 (M = 142.04 g mol –1) is dissolved in water to prepare of solution. What is

the concentration of in ?

A.

B.

C.

D.

Markscheme

53. [1 mark]

Which graph represents the relationship between volume and pressure for a fixed mass of gas at constant
temperature?

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Markscheme

54. [1 mark]

What is the number of ions in 0.20 mol of ?

A.

B.

C.

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D.

Markscheme

55. [1 mark]

What is the molar mass, in , of washing soda crystals, ?

A. 105.99

B. 124.00

C. 263.15

D. 286.19

Markscheme

56. [1 mark]

The equation for the reduction of iron(III) oxide is:

What mass of carbon dioxide, in g, is produced by the complete reduction of 80 g of iron(III) oxide?

A. 44

B. 66

C. 88

D. 132

Markscheme

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B

57. [1 mark]

of ethyne, , is mixed with of hydrogen and ignited. The equation for the reaction
that occurs is shown below.

Assuming the reaction goes to completion and all gas volumes are measured at the same temperature and

pressure, what volume of ethane, , in , is formed?

A. 1.5

B. 2.0

C. 3.0

D. 6.0

Markscheme

58. [1 mark]

What is the total number of atoms in 0.100 mol of ?

A. 11

B.

C.

D.

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D

59. [1 mark]

Nitroglycerine, , can be used in the manufacture of explosives. What is the coefficient of

when the equation for its decomposition reaction is balanced using the lowest whole
numbers?

___ ___ ___ ___ ___

A. 2

B. 4

C. 20

D. 33

Markscheme

60. [1 mark]

The volume occupied by one mole of an ideal gas at 273 K and is . What volume,

in , is occupied by 3.20 g at 273 K and ?

A. 2.24

B. 4.48

C. 22.4

D. 71.7

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61c. [2 marks]

The percentage composition of HA is 70.56% carbon, 23.50% oxygen and 5.94% hydrogen. Determine its
empirical formula.

Markscheme

and and

Award [2] for correct final answer.

Accept answers using integer values of molar mass.

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