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Non-woodfibers-Apotential - PolymPlastTechnolEng06
Non-woodfibers-Apotential - PolymPlastTechnolEng06
Non-woodfibers-Apotential - PolymPlastTechnolEng06
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1133
1134 A. ASHORI
NONWOOD FIBERS AS A PULP AND PAPERMAKING countries to take a renewed look at nonwoods. Nonwoods
RAW MATERIAL are abundantly available in many countries and are the
The term nonwood fiber encompasses a range of plants major source of fiber for papermaking in some developing
with widely differing characteristics. Nonwood fibers, also countries, particularly China and India. Approximately 2.5
referred to as ‘‘alternate fibers’’, are nonwoody cellulosic billion tonnes of nonwood raw materials are available each
plant materials from which papermaking fibers can be year worldwide, however, most of this raw material is cur-
extracted. The most widely used nonwoods for papermak- rently untapped for pulp and papermaking[9].
ing are straws, sugar cane bagasse, bamboo, kenaf, hemp,
jute, sisal, abaca, cotton linters, and reeds. Most nonwood
plants are annual plants that develop full fiber potential in WORLDWIDE PULPING CAPACITY OF NONWOOD
one growing season. FIBERS
There is a wide variety of nonwood plant fibers that can In 1970, the total worldwide capacity for production of
be used for papermaking[11]. Nonwoods such as bagasse, nonwood fibers papermaking pulp was only 7 million met-
wheat and rice straws, bamboo, and kenaf are being used ric tons compared with the total papermaking pulp
in the manufacture of pulp and paper all over the world[12]. capacity of 113 million metric tons. This amount repre-
Kenaf (Hibiscus cannabinus), for example, is being explored sented only 6.7% of the total. However, since that time
as a useful raw material for papermaking in developing and there has been a dramatic increase in nonwood fibers pulp-
developed countries. Total kenaf production in 1999–2000 ing capacity. By 1993, total papermaking pulp capacity
was 0.51 million tons, among which production from based on utilizing nonwood fibers amounted to almost 21
China accounts for 44%, India for 39%, Thailand for million metric tons out of a total papermaking pulping
12%, and the remainder coming from Indonesia, Vietnam capacity of 197 million tonnes, equivalent to 10.6%. From
and elsewhere[13]. 1970 to 1996, nonwood fiber pulping capacity on a global
Table 1 lists the physical and chemical properties of basis increased 2-3 faster than the capacity for production
some nonwoods in comparison to those of wood. The papermaking wood pulp. For example, during the period
dimensions of nonwood fibers are between those of hard- from 1988–93, nonwood papermaking pulp capacity
woods and softwoods. The cellulose content of most of increased on average 6% annually, or three times faster
nonwoods listed in Table 1 is comparable to that of woods than papermaking wood pulp capacity[12]. There is scope
commonly used for papermaking, while the lignin content for 10–15% of wood pulp being replaced by nonwood pulp
is much lower than for woods. Hence, the delignification without significantly affecting strength, optical, and sur-
of nonwoods is relatively easy and consumes less chemicals. face properties of most paper grades[21].
Nonwoods are a critical fiber resource in regions with There is scope for 10–15% of wood pulp being replaced
inadequate forest resources, and will continue to play an by nonwood pulp without affecting much of the strength,
increasingly important role in these regions. Environmental optical, and surface properties of paper[22]. The percentage
pressures, restrictions on forest uses and significant annual increase in the nonwood plant fiber pulp capacity is
increases in wood and recycled fiber costs are also forcing more than double the average annual increase in the wood
many paper companies in the traditionally forest-rich pulp capacity, i.e., 4.7% vs. 2.0%[19].
TABLE 1
Comparison of physical and chemical properties of nonwood fibers with those of wood raw materials
Properties Kenaf[11,12] Straw[13,14] Bagasse[15,14] Bamboo[14] Eucalyptus[16] Birch[16] Spruce[17,18]
Physical:
Fiber length, mm 1.3a 1.3 1.7 2.3 1.0 1.9 3.6
Fiber width, mm 27a 12.9 20 14.4 18 25 35
Felting factorb 49a 102 85 161 51 58 101
Chemical:c
Holocellulose, % 76.5 78.1 77.8 76.6d 74d 81d 71d
Hemicellulose, % 32.6 24.1 27.9 19.5d 18d 40d 27d
Lignin, % 16.2 18.4 20.8 23.4d 26d 19d 29d
a
Dimensions for whole stem kenaf from bast and core in the ratio of 35% and 65%, respectively.
b
The ratio of fiber length to fiber width.
c
Expressed on dry matter.
d
Extractive free basis.
NONWOOD FIBERS IN PAPERMAKING 1135
ADVANTAGES AND DRAWBACKS OF USING d) High silica content is a problem with nonwood fibres
NONWOOD FIBER FOR PAPERMAKING generally. Most nonwood pulp mills are small and do
Some nonwood fibers used as raw materials for paper- not have adequate chemical recovery facilities to deal
making have high annual yields per hectare. As can be seen with the large volumes of silica that must be removed.
in Table 2, the average annual yield per hectare of kenaf is e) A disadvantage of using certain nonwood fibers (e.g.
about twice that of fast-growing softwoods. Nonwoods kenaf) can be the high inputs required for growth and
have lower lignin content than do woods and generally it harvesting of these annual crops.
is easier to delignify nonwoods, as they have lower acti-
vation energies. Another advantage of non-woods includes
CONCLUSIONS
lower raw material cost (for bagasse and wheat straw).
World demand for paper has increased at an average
It may be surprising that nonwood plant fibers have not
annual rate of 4.7% over the past 40 years. With the rapid
been embraced by the pulp and paper industry, given the
growth of economies in the Asia-Pacific region and Eastern
positive attributes described previously and the speculation
Europe, it is likely that similar growth in demand will con-
that worldwide fiber supply will tighten significantly in the
tinue in these regions for the forseeable future. The existing
next years. The industry does understand some apprehen-
wood resources in these regions may be inadequate to meet
sions over using nonwood fibers for papermaking. In
this growing demand for paper. In addition, logging is
particular:
coming under increasing pressure from environmentalists
a) The use of annual plants represents a real culture concerned about habitat destruction and other longer-term
change for the industry, with significant implication impacts of forest harvesting. It is, therefore, necessary to
for capital costs, operating costs, products uniformity, consider alternative fiber sources to meet the possible
quality, and reliability. shortfall of wood fiber for papermaking.
b) The availability of a constant, year-round supply of
fiber is a primary concern for paper mills. Given that REFERENCES
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1136 A. ASHORI
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