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Niels Bohr
Niels Bohr
Bohr developed the Bohr model of the atom, in which he proposed that
energy levels of electrons are discrete and that the electrons revolve in
stable orbits around the atomic nucleus but can jump from one energy
level (or orbit) to another. Although the Bohr model has been
supplanted by other models, its underlying principles remain valid. He
conceived the principle of complementarity: that items could be
separately analysed in terms of contradictory properties, like behaving
as a wave or a stream of particles. The notion of complementarity
dominated Bohr's thinking in both science and philosophy.
During the 1930s, Bohr helped refugees from Nazism. After Denmark
was occupied by the Germans, he had a famous meeting with
Heisenberg, who had become the head of the German nuclear weapon
project. In September 1943 word reached Bohr that he was about to be
arrested by the Germans, and he fled to Sweden. From there, he was
flown to Britain, where he joined the British Tube Alloys nuclear
weapons project, and was part of the British mission to the Manhattan
Project. After the war, Bohr called for international cooperation on
nuclear energy. He was involved with the establishment of CERN and
the Research Establishment Risø of the Danish Atomic Energy
Commission and became the first chairman of the Nordic Institute for
Theoretical Physics in 1957.
Early years
Harald became the first of the two Bohr brothers to earn a master's
degree, which he earned for mathematics in April 1909. Niels took
another nine months to earn his on the electron theory of metals, a
topic assigned by his supervisor, Christiansen. Bohr subsequently
elaborated his master's thesis into his much-larger Doctor of
Philosophy (dr. phil.) thesis. He surveyed the literature on the subject,
settling on a model postulated by Paul Drude and elaborated by
Hendrik Lorentz, in which the electrons in a metal are considered to
behave like a gas. Bohr extended Lorentz's model, but was still unable
to account for phenomena like the Hall effect, and concluded that
electron theory could not fully explain the magnetic properties of
metals. The thesis was accepted in April 1911,[11] and Bohr conducted
his formal defence on 13 May. Harald had received his doctorate the
previous year.[12] Bohr's thesis was groundbreaking, but attracted little
interest outside Scandinavia because it was written in Danish, a
Copenhagen University requirement at the time. In 1921, the Dutch
physicist Hendrika Johanna van Leeuwen would independently derive a
theorem in Bohr's thesis that is today known as the Bohr–Van Leeuwen
theorem.[13]
A young man in a suit and tie and a young woman in a light coloured
dress sit on a stoop, holding hands
Physics
Bohr model
Bohr returned to Denmark in July 1912 for his wedding, and travelled
around England and Scotland on his honeymoon. On his return, he
became a privatdocent at the University of Copenhagen, giving lectures
on thermodynamics. Martin Knudsen put Bohr's name forward for a
docent, which was approved in July 1913, and Bohr then began
teaching medical students.[27] His three papers, which later became
famous as "the trilogy",[25] were published in Philosophical Magazine
in July, September and November of that year.[28][29][30][31] He
adapted Rutherford's nuclear structure to Max Planck's quantum
theory and so created his Bohr model of the atom.[29]
Planetary models of atoms were not new, but Bohr's treatment was.
[32] Taking the 1912 paper by Darwin on the role of electrons in the
interaction of alpha particles with a nucleus as his starting point,[33]
[34] he advanced the theory of electrons travelling in orbits of
quantized “stationary states” around the atom's nucleus in order to
stabilize the atom, but it wasn’t until his 1921 paper that he showed
that the chemical properties of each element were largely determined
by the number of electrons in the outer orbits of its atoms.[35][36][37]
[38] He introduced the idea that an electron could drop from a higher-
energy orbit to a lower one, in the process emitting a quantum of
discrete energy. This became a basis for what is now known as the old
quantum theory.[39]
In 1885, Johann Balmer had come up with his Balmer series to describe
the visible spectral lines of a hydrogen atom:
The model's first hurdle was the Pickering series, lines which did not fit
Balmer's formula. When challenged on this by Alfred Fowler, Bohr
replied that they were caused by ionised helium, helium atoms with
only one electron. The Bohr model was found to work for such ions.[41]
Many older physicists, like Thomson, Rayleigh and Hendrik Lorentz, did
not like the trilogy, but the younger generation, including Rutherford,
David Hilbert, Albert Einstein, Enrico Fermi, Max Born and Arnold
Sommerfeld saw it as a breakthrough.[42][43] The trilogy's acceptance
was entirely due to its ability to explain phenomena which stymied
other models, and to predict results that were subsequently verified by
experiments.[44][45] Today, the Bohr model of the atom has been
superseded, but is still the best known model of the atom, as it often
appears in high school physics and chemistry texts.[46]
Institute of Physics
The Bohr model worked well for hydrogen and ionized single electron
Helium which impressed Einstein,[52][53] but could not explain more
complex elements. By 1919, Bohr was moving away from the idea that
electrons orbited the nucleus and developed heuristics to describe
them. The rare-earth elements posed a particular classification problem
for chemists, because they were so chemically similar. An important
development came in 1924 with Wolfgang Pauli's discovery of the Pauli
exclusion principle, which put Bohr's models on a firm theoretical
footing. Bohr was then able to declare that the as-yet-undiscovered
element 72 was not a rare-earth element, but an element with chemical
properties similar to those of zirconium. (Elements had been predicted
and discovered since 1871 by chemical properties [54]) and Bohr was
immediately challenged by the French chemist Georges Urbain, who
claimed to have discovered a rare-earth element 72, which he called
"celtium". At the Institute in Copenhagen, Dirk Coster and George de
Hevesy took up the challenge of proving Bohr right and Urbain wrong.
Starting with a clear idea of the chemical properties of the unknown
element greatly simplified the search process. They went through
samples from Copenhagen's Museum of Mineralogy looking for a
zirconium-like element and soon found it. The element, which they
named hafnium (Hafnia being the Latin name for Copenhagen) turned
out to be more common than gold.[55][56]
In 1922 Bohr was awarded the Nobel Prize in Physics "for his services in
the investigation of the structure of atoms and of the radiation
emanating from them".[57] The award thus recognised both the Trilogy
and his early leading work in the emerging field of quantum mechanics.
For his Nobel lecture, Bohr gave his audience a comprehensive survey
of what was then known about the structure of the atom, including the
correspondence principle, which he had formulated. This states that
the behaviour of systems described by quantum theory reproduces
classical physics in the limit of large quantum numbers.[58]
Quantum mechanics
Bohr became convinced that light behaved like both waves and
particles and, in 1927, experiments confirmed the de Broglie hypothesis
that matter (like electrons) also behaved like waves.[69] He conceived
the philosophical principle of complementarity: that items could have
apparently mutually exclusive properties, such as being a wave or a
stream of particles, depending on the experimental framework.[70] He
felt that it was not fully understood by professional philosophers.[71]