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PETROLEUM EXPLORATION AND DEVELOPMENT

Volume 37, Issue 6, December 2010


Online English edition of the Chinese language journal

Cite this article as: PETROL. EXPLOR. DEVELOP., 2010, 37(6): 641–653. RESEARCH PAPER

Geological characteristics and resource potential of shale


gas in China
Zou Caineng1,2,*, Dong Dazhong1,2, Wang Shejiao1,2, Li Jianzhong1,2, Li Xinjing1,2, Wang Yuman1,2,
Li Denghua1,2, Cheng Keming1,2
1. PetroChina Research Institute of Petroleum Exploration & Development, Beijing 100083, China;
2. State Key Laboratory of EOR, Beijing 100083, China

Abstract: With Sichuan Basin as focus, this paper introduces the depositional environment, geochemical and reservoir characteristics,
gas concentration and prospective resource potential of three different types of shale in China: marine shale, marine-terrigenous shale and
terrigenous shale. Marine shale features high organic abundance (TOC: 1.0%–5.5%), high-over maturity (Ro: 2%–5%), rich accumulation
of shale gas (gas concentration: 1.17–6.02 m3/t) and mainly continental shelf deposition, mainly distributed in the Paleozoic in the Yang-
tze area, Southern China, the Paleozoic in Northern China Platform and the Cambrian-Ordovician in Tarim Basin; Marine-terrigenous
coalbed carbonaceous shale has high organic abundance (TOC: 2.6%–5.4%) and medium maturity (Ro: 1.1%–2.5%); terrigenous shale in
the Mesozoic and Cenozoic has high organic abundance (TOC: 0.5%–22.0%) and mid-low maturity (Ro: 0.6–1.5%). The study on shale
reservoirs in the Lower Paleozoic in Sichuan Basin discoveried nanometer-sized pores for the first time, and Cambrian and Silurian ma-
rine shale developed lots of micro- and nanometer-sized pores (100–200 nm), which is quite similar to the conditions in North America.
Through comprehensive evaluation, it is thought that several shale gas intervals in Sichuan Basin are the practical targets for shale gas
exploration and development, and that the Weiyuan-Changning area in the Mid-South of Sichuan Basin, which is characterized by high
thermal evolution degree (Ro: 2.0%–4.0%), high porosity (3.0%–4.8%), high gas concentration (2.82–3.28 m3/t), high brittle mineral con-
tent (40%–80%) and proper burial depth (1500–4500 m), is the core area for shale gas exploration and development, the daily gas pro-
duction for Well Wei 201 is 1×104–2×104 m3.

Key words: unconventional hydrocarbon; shale gas; nanometer-sized pore throat; shale oil; tight oil; source rock hydrocarbon; core
area

1 Exploration and development status of shale targets and progress of E&P technologies, the unconventional
gas hydrocarbon (conventional hydrocarbon generally refers to
oil/gas accumulated in reservoirs with air permeability over
The 300-year development (1880-2180) of oil/gas industry
has mainly experienced three phases: structure reservoir, 1×103 ȝm2 or formation permeability over 0.1×103 ȝm2,
lithologic-stratigraphic reservoir and unconventional reservoir. while unconventional hydrocarbon refers to oil/gas in reser-
The reservoir distribution has three patterns: individual, ag- voirs with air permeability under 1×103 ȝm2 or formation
gregated and continuous. The transformation from structure permeability under 0.1×103 ȝm2), accounting for over 80% of
reservoir to lithologic-stratigraphic reservoir demonstrated the the total resources, such as shale gas, coal bed methane, tight
1st theoretical and technological breakthrough with focus on gas, tight oil and shale oil, has drawn great attention (Fig. 1)
finding oil/gas traps. The 2nd theoretical and technological and was effectively developed with proportional increase both
breakthrough or revolution was the transformation from in reserves and production year by year. It was thought tradi-
lithologic-stratigraphic trap reservoir to unconventional con- tionally that shale could generate oil and gas, but its oil/gas
tinuous reservoir, with focus on finding favorable hydrocar- storage capability was neglected, not to mention its industrial
bon accumulation bodies. the “retention reservoiring” mecha- accumulation capability of shale oil and gas. In recent years,
nism of shale gas has transcended the concepts of conven- the development of typical unconventional shale gas has wit-
tional reservoir property lower limit and finding oil in tradi- nessed rapid progress. The advancement of geological under-
tional traps[1]. With the increasing complexity of exploration standings, the concept of “core area discovery first” and app-

Received date: 10 Jun. 2010; Revised date: 27 Aug. 2010.


* Corresponding author. E-mail: zcn@petrochina.com.cn
Foundation item: Supported by National Large-scale Gas Field and Coal Bed Methane Development Project (2008ZX05001)
Copyright © 2010, Research Institute of Petroleum Exploration and Development, PetroChina. Published by Elsevier BV. All rights reserved.
Zou Caineng et al. / Petroleum Exploration and Development, 2010, 37(6): 641–653

Chinese shale gas got through 3 stages, fracture hydrocarbon


exploration and accidental discovery (before 2005), base re-
search and technology prepare (2005-2009), and industry
breakthrough (2010). In 1966, Wei-5 well in the Weiyuan
structure in Sichuan Basin got daily gas production of
2.46×104 m3 at Cambrian Qiongzhusi Formation and became
the first shale gas well in China[4]. In 2008, PetroChina Re-
search Institute of Petroleum Exploration and Development
(RIPED) drilled the 1st shale gas geological coring well in
China—Changxin-1 well[5] in the Changning area, Sichuan
Basin. In 2009, PetroChina started the first batch of construc-
tion of shale gas industrial experiment areas in the regions of
Sichuan Weiyuan-Changning, Fushun-Yongchuan. In 2010,
PetroChina RIPED established the 1st Silurian shale gas digi-
Fig. 1 Oil/gas resources type and accumulation pattern
tal standard section for Chinese shale gas in the Changning
lication of various advanced technologies, including experi- area, Sichuan Basin in 2010, PetroChina gets industrial gas
mental analysis technology, logging evaluation technology, flow (daily gas production 1×104–2×104) from the Cambrian
resource potential evaluation technology, horizontal well and Silurian shale in Wei-201 well in the Sichuan Basin, real-
drilling and completion technology in shale reservoirs and izing the first industrial breakthrough of Chinese shale gas.
simultaneous multi-stage and repetitive fracturing and stimu- After years of study and development practices, important
lation technology, are key factors that facilitate the fast de- breakthroughs on shale gas forming mechanism and accumu-
velopment of shale gas. The scientific value of shale gas lation condition was made in Northern America[6-15], and
breakthrough lies in the following: (1) Breaking through into complete E&P associated techniques were formed. This paper
the resource forbidden zone, adding new resource type of analyzes the basic features, forming and accumulation condi-
shale gas, even adding the total reserves in the world; (2) tions, and current challenges of shale gas in China and pre-
breaking through the conventional reservoir concepts, that is, dicts the resource potential of shale gas resources in China,
the conventional reservoir property lower limit and conven- which may provide references for the future shale gas study
tional trapping theory. Proving nano-sized pores can also ac- and E&P in China.
cumulate industrial petroleum and gas, challenging the 2 Distribution of organic-rich shale rock in China
nano-sized reservoir limit, furthermore, revealing that density
oil and shale oil can also be a new exploration area; (3) break- Source rock hydrocarbon is one kind of new resource type,
ing through the unconventional exploration technology. It including shale oil, shale gas, coal bed gas etc. which are self
really realizes oil/gas technologies upgrading. Applying generation and self storage, mainly produced from reservoirs
horizontal multi-stage fracturing, micro-seismic and other inside source rocks.
technologies into unconventional and conventional reservoirs Shale is composed of fine debris, clay and organic matter
of tight hydrocarbon will be more economic and efficient and (the diameter is less than 0.0039 mm). It is laminated or la-
can dramatically improve oil/gas recovery ratio, promoting mellar bedding and brittle sedimentary rock, that is, the
unconventional resources of tight oil/gas and shale oil into fine-grained sedimentary rock with grain size less than 0.0039
conventional fields. mm in America.
The 1st shale gas well was drilled in the Devonian Dunkirk Shale gas (or gas shale) is natural gas produced from black
shale in the Appalachian Basin in 1821. The 1st shale gas field shale rich in organic matter, or self-generation and self-sto-
was the Big Sandy gas field discovered in 1914[2]. There are rage natural gas continuously accumulated in nano-scale mi-
four stages: the accidental discovery during 1821-1978, cropores in shale.
knowledge advancement and technology breakthrough during Organic-rich shale around China refers to marine facies,
1978-2003, extension and application of technologies such as marine-terrigenous alternated facies and lacustrine facies
horizontal well and hydro fracturing during 2003-2006, global shale and mainly focuses on good shale source rock in oil/gas
development during 2007-2010 (shale gas Chinese year, bearing basins. Fig. 2 is the distribution map of three types of
Europe year). George Mitchell, honored as “Father of Shale shale compiled from shale formation and distribution charac-
Gas”, intentionally carried out the large scale fracturing and teristics in China. In the Yangtze area, Southern China, marine
got success in the C. W. Slay No.1 well for Barnett shale in facies shale is mainly siliceous shale (e.g. Niutitang bottom
1981, which realized the real breakthrough of shale gas. By shale in the Yangtze area), black shale, calcareous shale and
the end of 2009, there were 30 shale gas basins discovered in sandy shale, which is laminated after weathering. Ma-
North America and over 50000 gas wells were completed with rine-terrigenous alternated facies shale is mainly carbona-
depth of 2500–4500 m. The annual production in 2009 was ceous shale and sandy shale. Lacustrine facies shale has
about 950×108 m3 [3], accounting for 12% of the total gas pro- well-developed lamination. The Cenozoic lacustrine facies
duction in North America (production in USA is 889×108 m3). shale in Bohai Gulf Basin and Qaidam Basin has high cal-
Zou Caineng et al. / Petroleum Exploration and Development, 2010, 37(6): 641–653

careous content, belonging to calcareous shale. The Mesozoic the minimum effective thickness of shale gas pay zone is 6 m
lacustrine shale facies in Ordos Basin has high quartz content. (Fayetteville) and the maximum thickness is 304 m (Marcel-
lus), but the effective thickness is over 30 m in the core area.
2.1 Features of shale with rich shale gas
Take the Longmaxi Formation (S1) and Qiongzhusi Forma-
Currently, the five enrichment and high production condi- tion (ȯ1) in Wei-201 well in the core area of Wei-
tions for commercial shale gas development area or core area yuan-Changning, Sichuan Basin, as an example, the TOC is
generally refer to effective shale which has TOC over 2%, is 2%–11%, brittle mineral 47–73%, clay mineral 24%–43%, Ro
within the gas window, and has a brittle mineral content over 2.4%–5.0%, porosity 1.2%–8.0%, permeability 12.7–955 nD,
40%. Commercial development of shale can be fulfilled when and the effective gas-layer thickness 33–49 m.
the thickness of effective shale is over 30-50 m (effective Based on shale gas E&P experiences, statistic analysis and
shale thickness should be over 30 m if continuously devel- key experimental results in North America, favorable shale gas
oped; if discontinuously developed or TOC value less than 2%, and core areas are thought to have four major characteristics
the total thickness should be over 50 m). In North America, and three major development characteristics, as shown in Table 1.

Fig. 2 Distribution of three major shale types in China

Table 1 Summary of shale gas features


Geological characteristics Development characteristics Accumulation and high production condition for core area
(1) TOC˚2% (non-residual organic carbon); (2) Brittle mineral
Same source rock and reservoir, con-
(e.g. quartz) content over 40% and clay mineral content less than
tinuous accumulation, saturated accumu- Low individual well production
30%; (3) Maturity of dark organic rich shale is over 1.1%; (4) Air
lation; No evident trap boundary, sealing and long production cycle
porosity over 2%, permeability over 0.000 1×103 ȝm2; (5) Effec-
or cap rock necessary
tive thickness of organic rich shale over 30–50 m
Tight reservoir, mainly nano-scale pores; Mainly non-Darcy flow, no
Natural gas was stored in adsorbed gas water production or very little
and free gas pattern; water production
Effective development requires horizontal well, multi-stage frac-
Not controlled by structure, continuous
turing, micro-seismic and other advanced technologies to improve
and large area distribution, same area as
“artificial” retiform permeability
effective gas-generation source rock Lower recovery ratio
Large resource potential, with local
“sweet spot” core areas
Zou Caineng et al. / Petroleum Exploration and Development, 2010, 37(6): 641–653

the Lower Permian Shanxi Formation–Taiyuan Formation in


2.2 Regional geological background of shale in China
Ordos Basin, the Carboniferous–Permian in Junggar Basin,
During the Paleozoic period, wide marine facies and ma- the Carboniferous–Permian in Tarim Basin, the Carbonife-
rine-terrigenous alternated facies deposition formed in South- rous–Permian in Northern China, and the Permian Longtan
ern China, Northern China and Tarim area, where several sets Formation in Southern China. It can also be major source rock
of marine organic-rich shale and marine-terrigenous alternated for large-scale oil/gas fields. For example, the Upper
coal seam carbonaceous shale developed[6]. However, most Paleozoic carbonaceous shale in Ordos Basin is the major gas
Paleozoic marine shale experienced compressive deformation source rock for Sulige and other large gas fields. The Trias-
or uplift during the later reformation process. For example, sic–Jurassic and Tertiary developed several sets of carbona-
the southern Yangtze area is mainly later uplifting reformation. ceous shale, which were associated with coal beds. It was also
In some tectonically stable area, such as Sichuan Basin, good gas source rock. Most oil/gas fields discovered in Tuha
Northern China and Tarim Basin, the formation preservation Basin originated from carbonaceous shale rock of the Jurassic
condition was good. coal bed.
Since the Mesozoic and Cenozoic, unique terrestrial lake China has well developed lacustrine shale in hydrocarbon
basin deposition was formed in China[6]. These terrestrial bearing basins, such as the Paleogene in Bohai Gulf Basin, the
deposition basins were not big, but deposited widely-distri- Cretaceous in Songliao Basin, the Triassic in Ordos Basin, the
buted lacustrine source rock during the stable subsidence
Triassic in Sichuan Basin, the Triassic–Jurassic in Tarim Ba-
stage, which has great hydrocarbon generation potential[6]. For
sin and the Jurassic in Junggar Basin. During the extensional
example, the Lower Cretaceous Qingshankou Formation in
stage of the lake basin, thick lacustrine facies shale, which
Songliao Basin and the Upper Triassic Yanchang Formation
contained very rich organic matters and fossils like mus-
lacustrine shale in Ordos Basin are both important source
sel-shrimp, sporopollen, bacteria and other higher plants, was
rocks in these basins.
formed. It was about 200–2 500 m thick and the organic
2.3 Depositional features of shale carbon content is 2%–3% and the maximum value is 7%–14%.
Different stages of basin evolution directly control the de- In the Mesozoic and Cenozoic formations, several different-
velopment and distribution of organic-rich shale[16]. Accord- sized oil/gas accumulation belts were discovered[18], such as
ing to the depositional environment, organic-rich shale rock Daqing Oilfield, Shengli Oilfield, Liaohe Oilfield and Ordos
can be divided into marine shale, marine-terrigenous coal bed Mesozoic oil/gas accumulation belt.
carbonaceous shale and lacustrine shale (Table 2). 2.4 Distribution features of shale
Paleozoic marine shale in Southern China, Northern China
platform and Tarim platform mainly formed in deep Marine facies shale developed well in China with extensive
continental shelf facies, where water depth was over 200 m, distribution and large thickness[19]. It includes Sinian Dou-
fossila organism was abundant and the depositional environ- shantuo Formation (Z2), Qiongzhusi Formation (ȯ1),
ment was strong reducing environment. For example, the Dachengshi Formation (O1), Wufeng–Longmaxi Formation
Cambrian Qiongzhusi Formation and Silurian Longmaxi (O3–S1), Luofu Formation (D2), Dewu Formation–Datang
Formation black shale developed in Sichuan Basin are deep Formation (C1) and Longtan Formation (P2) (Table 3). The
water continental shelf deposition controlled by continental best shale is mainly distributed at the Lower Cambrian, Upper
margin depressions[17] (Fig. 3). The area of organic rich black Ordovician top and Lower Silurian bottom, with the Yangtze
shale is 13.5×104–18.0×104 km2 and the thickness is 200–400 cratonic area as a typical example.
m. It contains graptolite and other marine planktonic organism Lower Cambrian marine shale developed well in the
and authigenic pyrite. The organic carbon content is 1.85%– mid-upper Yangtze area. Its organic type belongs to sapropel
4.36% and the highest value can reach 11.0%–22.3%. A large type–mixed type. From its depositional environment, three
amount of shale gas was discovered within both two sets of deep water continental shelf areas, including Eastern Si-
black shale. chuan–Western Hubei, Southern Sichuan and the Hu-
Coal bed shale was formed in marine-terrigenous transi- nan-Guizhou area, have the best-developed marine shale[20].
tional facies, such as the Carboniferous Benxi Formation and The average thickness reaches 100 m and the TOC average

Table 2 Shale classification and distribution in China


Depositional type Distribution area
Marine shale Paleozoic in Yangtze area, Paleozoic-Proterozoic in Northern China, Cambrian-Ordovician in Tarim Basin
Marine-terrigenous transi- Carboniferous Benxi Formation and Lower Permian Shanxi-Taiyuan Formation in Ordos Basin,
tional coal bed carbonaceous Carboniferous-Permian in Junggar Basin, Carboniferous-Permian in Tarim Basin, Carboniferous-
shale Permian in Northern China area, Permian Longtan Formation in Southern China
Cretaceous in Songliao Basin, Paleogene in Bohai Gulf Basin, Triassic in Ordos Basin, Triassic-Jurassic in
Lacustrine shale
Sichuan Basin, Jurassic in Junggar-Tuha Basin, Triassic-Jurassic in Tarim Basin, Tertiary in Qaidam Basin
Zou Caineng et al. / Petroleum Exploration and Development, 2010, 37(6): 641–653

Fig. 3 Composite stratigraphy column of black shale in Sichuan Basin

Table 3 Marine facies shale distribution in China


Thickness (m)
Strata Area/104 km2 Distribution area
Range Average
Dewu Formation–
Carboniferous 50–150 100 6 Yunnan, Guizhou and Guangxi
Datang Formation (C1)
Yunnan, Guizhou and Guangxi,
Devonian Luofu Formation (D2) 100–600 200 13
west and south Hunan
Wufeng-Longmaxi
Silurian 20–700 120 42 Yangtze area
Formation (O3–S1)
Ordovician Dachengsi Formation (O1) 20–100 40 3 Upper Yangtze area
Qiongzhusi Formation (ȯ1) 50–700 100 30–50 Yangtze area
Cambrian
ȯ1+2 50–110 80 7 Tarim Basin
Eastern part of Upper Yangtze–
Sinian Doushantuo Formation (Z2) 10–100 47 15
Western part of Mid-Yangtze
Zou Caineng et al. / Petroleum Exploration and Development, 2010, 37(6): 641–653

value is about 8%. The Lower Cambrian marine shale devel- except those thick layers in the Upper Yangtze area and the
oped around the whole Sichuan Basin and the lithology Yunnan-Guizhou-Guangxi area, is mostly thin-layered in
mainly includes siliceous shale, carbonaceous shale, silty most areas and is often interbedded with coal bed and tight
shale and black shale. The average thickness is 139 m and the sand, or even limestone. The average thickness of individual
average TOC is 1.0%–5.5%. The burial depth in the southern layer is less than 15 m. It will be very challenging to develop
part of the basin is less than 4 000 m. this thin coal bed shale gas alone, and multi-target joint de-
Upper Ordovician–Lower Silurian marine shale has wide velopment of shale gas, tight gas and coalbed methane could
distribution in Southeast and Northeast Sichuan, Western be new ways for effective development.
Hubei–Eastern Chongqing and the mid-lower Yangtze area[5]. Lacustrine facies shale, distributed mainly in terrestrial hy-
The lithology is mainly black shale, carbonaceous shale, black drocarbon-bearing basins, has the widest distribution (Table
graptolite shale and calcareous shale with the average thick- 5). Statistic data indicates that over 80% of the current oil/gas
ness of 120 m and the average TOC of about 4%. Kerogen in China is from lacustrine source rock. Songliao Basin, Or-
type is sapropel type. The Upper Ordovician–Lower Silurian dos Basin and other Mesozoic-Cenozoic depressions and
marine shale in Sichuan Basin developed well in southern and Bohai Gulf Cenozoic rifting basins[21] all deposited thick
eastern Sichuan area. According to the statistics of the digital lacustrine organic-rich shale, limestone, sandstone and mud-
type section of Upper Ordovician Wufeng Formation–Lower stone[22]. For example, in Songliao Basin, Nenjiang Formation
Silurian Longmaxi Formation marine shale in Shuanghe, and Qingshankou Formation, shale developed very well. Nen-
Changning established by integrated application of Gamma jiang Formation is distributed around the whole basin very
spectrometry, element capture, ground penetrating radar and stably and its thickness at the central depression area exceeds
continental laser 3D perfect information scanning technolo- 250 m. The 1st member of Qingshankou Formation is almost
gies (Fig. 4), the thickness of Upper Ordovician Wufeng all black shale at the central depression area with thickness of
Formation–Lower Permian Longmaxi Formation black shale 60–80 m. Its kerogen type is I–II and Ro value is 0.9%–1.8%.
in southern Sichuan is over 308 m and its kerogen type is The Chang 7 Member of Yanchang Formation in Ordos Basin
sapropel type with the average TOC value of 2.94% and is mainly deep lacustrine facies deposition. The average thick-
maximum value of 8.75%. ness of organic-rich shale is 20–40 m and the distribution area
The marine-terrigenous alternated facies and lacustrine fa- exceeds 4×104 km2 with average TOC content of 14%. Its
cies coal bed carbonaceous shale is distributed widely at kerogen type is I–II and Ro value is 0.6%–1.2%. Recently, a
Northern China, Southern China and Tarim Basin (Table 4). lot of tight oil was discovered in this set of lacustrine shale.
In Northern China, it mainly developed at the Tianshan-Xing- The oil layers are tight silty stone interbeds, which are 1020
meng trough. The thickness of the Shanxi Formation–Taiyuan m thick with porosity of 10.2% and permeability of 0.21×103
Formation–Benxi Formation marine-terrigenous alternated ȝm2, the sandstone with pore throat radius between 40-100
facies shale in Ordos Basin is 40–120 m. Single layer thick- nm occupies 96%. There are almost 200 industrial oil wells
ness is not large but it mainly alternated with coal beds, tight now, with the average daily production of 8.6 t/d, oil API 55 o
sandstone and even thin layer limestone. The maximum –70o. In the Jurassic of the Sichuan Basin, Dingdaanzhai
thickness of the Carboniferous Dishuiquan Formation carbo- Formation developed continuous testaceous tight shale oil,
naceous shale in Junggar Basin reaches 249 m and the total Lianggaoshan Formation and Saximiao Formation developed
thickness of Permian Lucaogou Formation (P2) black shale tight sandstone oil; the favorable distribution area is over
exceeds 200 m. The Permian Longtan Formation shale carbo- 1.5×104 m2, porosity 1-5%, permeability 0.03-1.00 mD, crude
naceous shale in Southern China is 20–200 m thick, with oil API 70–100o, the discovered tight oil reserves in place are
maximum thickness of 670 m and distribution area of 8118×104 t. These characteristics are very close to those of
30×104–50×104 km2. The Upper Permian Longtan Formation tight oil discovered in Bakken Shale in Willistone Basin,
shale in the Yunnan-Guizhou-Guangxi area is 20–60 m. The North America[23]. Bakken Shale is a set of organic rich shale
Upper Permian shale in Sichuan Basin is 10–125 m thick, in developed at the top of Upper Devonian, can be divided into 9
which Central Southwestern Sichuan is 80–110 m thick while intervals from up to bottom, the lowest interval has the shale
the Northwest, Northern and Northeast margins of Sichuan with thickness of 12–15 m, TOC value of 14%–18% and Ro
Basin are thin, mostly less than 20 m. The Mesozoic-Ceno- value of 1.1%–1.3%, which is a shale layer rich in organic
zoic lacustrine facies coal bed carbonaceous shale mainly matter. The overlying second interval tight silty sandstone oil
developed in depressions and rifting basins. For example, the layer has the porosity of 10%–13%, permeability 0.01×103
Jurassic in Ordos Basin and Junggar Basin, the Upper Triassic –1×103 ȝm2, thickness is 5–15 m and the total area is 75 563
(150–1 000 m) in Sichuan Basin and the Jurassic in Tuha Ba- km2. In 1999, USGS experts estimated that the tight oil re-
sin (50–400 m thick and the maximum thickness can reach source potential in the shale was 578×108 t, generally
1 200 m). 241×108– 518×108 t. Nano-scale pores are the main pores for
Generally, marine-terrigenous alternated facies and Meso- tight hydrocarbon. While tight oil is another great discovery
zoic-Cenozoic lacustrine facies carbonaceous shale in China, after shale gas breakthrough, being the new highlight.
Zou Caineng et al. / Petroleum Exploration and Development, 2010, 37(6): 641–653

Fig. 4 Composite stratigraphy column of Upper Ordovician Wufeng Formation–Lower Silurian Longmaxi Formation marine facies
shale in the Shuanghe area, Changning, Sichuan Basin
Zou Caineng et al. / Petroleum Exploration and Development, 2010, 37(6): 641–653

Table 4 Marine-terrigenous alternated facies and coal bed carbonaceous shale distribution in China
Stratigraphy Shale interval Thickness/m Area/104 km2 Distribution
Cretaceous Shehezi Formation (J3sh) 100–350 4.0–5.0 Songliao Basin
Shuixigou Group (J1—2sh) 50–600 0.3–0.5 Tuha Basin
Jurassic Xishanyao Formation (J2x) 350–400 2.0–3.0 Junggar Basin
Kezhilenuer Formation (J2k) and Yangxia Formation (J1y) 300–800 7.0–9.0 Tarim Basin
Upper Triassic Xujiahe Formation (T3x) 150–1 000 3.0–4.0 Sichuan Basin
Longtan Formation (P2l) 20–200 30.0–50.0 Yangtze area
Carboniferous- Shanxi Formation (P1s), Taiyuan Formation (P1t)
50–180 20.0–30.0 Northern China area
Permian and Benxi Formation (C2b)
Lucaogou Formation (P2l) and Dishuiquan Formation (C1d) 200–450 2.0–3.0 Junggar Basin

Table 5 Lacustrine shale distribution in China accumulations. Its organic matter is mainly III type, belonging
Epoch 4
Thickness/m Area/10 km 2
Distribution to humic type kerogen, which mainly generates gas during the
T—J 1 200–1 500 2.0–3.0 Junggar Basin whole maturity evolution phase. When its Ro value reaches
T 20–160 4.0–5.0 Ordos Basin 1.0%, the natural gas conversion rate can be over 40%; when
Mesozoic
K 200–400 4.0–5.0 Songliao Basin Ro value reaches 2.5%, the natural gas conversion rate can
J 300–500 0.3–0.5 Tuha Basin reach 95%. The Ro range of 0.8%–2.5% is the main gas gen-
E 800–2 300 0.8–1.0 Liaohe Depression eration stage of coal bed organic matter[28]. The blocks with
E 2 000–2 500 1.0–1.5 Huanghua Depression higher hydrogen rich matter content are favorable for shale
Cenozoic
E 220–1 300 1.2–1.5 Jiyang Depression gas accumulation. Therefore, all three types of shale in China
E-N 800 0.3–0.5 Qaidam Basin have fulfilled the requirements of forming shale gas resources.
However, some geochemical characteristics of shale gas
3 Geochemical features of shale gas in China prospective areas in China are different from those of North
Shale gas is natural gas (mainly methane) accumulated in America shale gas producing areas. For example, Paleozoic
organic-rich source rock formations. As an important type of source rock in most of the Yangtze Platform area including
“organic mineral grain”, organic matter can not only provide Sichuan Basin is the regional main source rock. Although it
abundant material basis for conventional oil/gas reservoirs, belongs to I type kerogen, but the maturity is generally high or
itself can also store and produce oil/gas. Lots of researches over mature with low remaining hydrocarbon generation po-
indicated that the preliminary selection of geothermal origin tential. Most mid-large coal type gas fields in China, for ex-
shale gas zone required that shale should meet some geo- ample, the Upper Paleozoic Carboniferous–Permian carbona-
chemical index, for example, organic matter abundance (TOC) ceous shale in Ordos, Tarim and the Northern China area of-
should be over 2%, maturity (Ro) should be higher than 1.1%. ten have high organic matter content and Ro value of
Shale gas E&P risks can be significantly reduced in areas 1.1%–2.5%. The organic matter is mostly II–III type. In Or-
where all these standards are mainly fulfilled. dos Basin, the Mesozoic Triassic Chang 7 member black shale
is good source rock and has high GR value, high resistivity,
3.1 General geochemical features of shale
low density and high interval transit time. The organic matter
Marine shale, marine-terrigenous alternated shale and is I type and has very good hydrocarbon generation potential.
lacustrine shale are distributed widely in China[2427]. Different However, its maturity is only 0.90%–1.16%, belonging to oil
depositional environments may form different types of or- generation peak stage.
ganic matter. The oil-prone or gas-prone property may also be Shale oil developed extensively within the terrestrial for-
different. Several basins or blocks have fulfilled the basic mations in China. Shale oil is the petroleum accumulated
geochemical standards of shale gas accumulation (Table 6). within the internal pores and fractures of source rock. For
The Lower Paleozoic Cambrian Qiongzhusi Formation and example, it has been discovered that oil shale accumulated in
Silurian Longmaxi Formation marine facies black shale in Lower Cretaceous Qingshankou Formation and Nenjiang
Sichuan Basin, the Cretaceous lacustrine shale in Songliao Formation in the Gulong Sag, Songliao Basin. The shale is
Basin, the Triassic lacustrine shale in Ordos Basin all belong organic rich, the total thickness is 300–620 m, with abnormal
to I–II1 type kerogen and have good oil-prone property. When high pressure, the kerogen is I–II type and the Ro value is
Ro value over 1.2%, in the high- and over-mature shale forma- 0.9%–1.8%. At first, the Qingshankou Formation shale in
tion, oil is first generated, then cracked to form gas, thus form Da-4 well in the Da’an structure got daily production of 2.66 t,
the “continuous” gas generation and gathering for marine and over 50 other wells had oil/gas shows, in which 4 of them
shale. As important gas source rock, the Paleozoic Carbonif- produce little oil/gas (wells Gu-501, Ying-15, Ying-3 and
erous–Permian and Mesozoic Jurassic coal bed carbonaceous Da-111) and 5 of them got industrial oil/gas flows (wells
shale in Northern China has formed large-scale natural gas Ying-12, Ying-18, Ying-16, Gu-1 and Da-4). In the southern
Zou Caineng et al. / Petroleum Exploration and Development, 2010, 37(6): 641–653

Table 6 Organic geochemical parameters of three types of shale in China


TOC/% Ro/% Kerogen type
Shale type Location Strata and lithology
Range Average
Cambrian black shale 1.00–5.50 2.30–5.20 I–II1
Sichuan Basin Silurian Longmaxi Fm. black
2.00–4.00 1.60–3.60 I–II 1
graptolite shale
Cambrian deep gray muddy lime-
Marine 0.18–5.52 2.28 1.90–2.04
Tarim Basin stone, black shale I–II1
Lower Ordovician black shale 0.17–2.13 1.15 1.74
Southeast Margin of Wufeng Formation–Longmaxi
1.73–3.12 2.46 1.83–2.54 I
Upper Yangtze Formation bottom
Carboniferous dark shale 0.19–37.98 4.20 0.60–1.90 II–III
Hexi Corridor
Marine-terrigenous Carbonaceous shale 0.27–50.52 5.44
transition Black and deep gray
Ordos Basin 2.68–2.93 1.10–2.50 III
carbonaceous shale
Triassic Yanchang Formation
Ordos Basin 6.00–22.00 14.00 0.90–1.16 I–II 1
Chang 7 Member black shale
Lacustrine
Cretaceous Qingshankou
Songliao Basin 0.50–4.50 0.60–1.20 I–II1
Formation black shale

part of the basin, Xinbei Oilfield has produced from the shale marine shale in Southern China has good storage conditions
fracture type reservoir for over 10 years and the cumulative and thus has good E&P potential in formations and areas that
oil production exceeded 3×104 t. Source rock in other basins has high organic matter abundance.
like Ordos and Bohai Gulf Basin also developed shale oil. In Australian Beetaloo Basin, shale gas was discovered in
Shale oil is another area of “source rock oil” after shale gas, the oldest formation on earth (about 14×108 a)—Proterozoic.
which should be paid much attention to. The TOC value is 4%, Ro value is 3.49%, and estimated shale
gas resources are 5600×108 m3.
3.2 Key geochemical parameters and its correlation with
shale storage capacity 4 Forming mechanism of shale gas and reservoir
characteristics
For self-generation and self-storage shale gas reservoirs,
their organic geochemical parameters, such as organic matter 4.1 Forming mechanism of shale gas
abundance and maturity, are closely related to the gas bearing The forming mechanism of shale gas is on site “retention
property of shale reservoirs and the development of storage reservoiring”, distributed in continuous pattern. Methane infill
space. In North America, the shale gas volume has a positive sequentially in the shale micro-pores (pore radius less than 2
correlation with TOC value and the I and II type kerogens nm), and is adsorbed to capillary to gather in multi-layer me-
often have high adsorption capability[29]. The experiment test dium pores (pore radius 2–50 nm), and it occurs in a com-
data of high-over mature marine shale from Sichuan Basin pressed or dissolute state in large pores (pore radius large than
also proved that those with higher TOC value would have 50 nm). During the biochemical gas generation phase, natural
more abundant gas and would be more favorable shale reser- gas or oil cracking gas initially adsorbed on the organic matter
voirs. or rock grain surface or accumulated within the organic pore
When maturity increases, the cracking of kerogen and oil space and stayed there until saturated. Then, the over-satura-
will generate a large amount of hydrocarbon. Besides gener- ted natural gas experienced primary migration in free phase or
ating oil and gas and providing rich material source for con- dissolved phase to the pore space of the overlying inorganic
ventional oil/gas reservoirs, the organic matter itself can gen- shale interval. Part of it will be stored within the intergranular
erate nano-scale pore space of about 5–200 nm[30]. During the and intragranular pores or fractures in free phase. After
study on Cambrian-Silurian high- and over-mature marine re-saturation, part of the natural gas will be migrated to con-
shale reservoirs in Sichuan Basin, the authors, for the first ventional reservoir rock through secondary migration and
time, found that the bottom of these two formations has high form conventional gas reservoir (Fig. 6)[31,32].
organic matter abundance and large gas volume. Moreover, a
4.2 Rock mineral composition
lot of micro-pores or nano-scale pores formed within the dis-
persive and laminated “organic matter grains” (Fig. 5). Some Fragile mineral content is an important factor that affects
large pores are about 3–4 ȝm and some small ones are even the shale matrix pore space and micro-fracture development,
several nanometers. Most of them are over 100–200 nm, gas-bearing property and fracturing stimulation pattern. The
which means that they can provide enough storage space for lower the clay content, the higher the brittle mineral content
shale gas accumulation. This strongly indicates that the tight (e.g. quartz, feldspar, calcite etc.) and the higher brittleness
Zou Caineng et al. / Petroleum Exploration and Development, 2010, 37(6): 641–653

a—Near circular micro-pores within organic matter in Longmaxi Formation black shale, Xin-1 well, Sichuan Basin;
b—Nano-scale pores within the organic matter dispersed between illite and pyrite in Longmaxi Formation black shale, Xin-1 well, Sichuan Basin;
c, d—Nano-scale pores within dispersive and laminated organic matter in Longmaxi Formation black shale, Wei-201 well, Sichuan Basin;
e, f—Nano-scale pores within organic matter dispersed between pyrite crystalline in Jiulaodong Formation sandy shale, Wei-201 well;
g, h—Intergranular organic matter micro- and nano-scale pores in Jiulaodong Formation sandy shale, Wei-201 Well
Fig. 5 Organic matter micro-and nano-scale pore distribution features of Lower Paleozoic shale in Sichuan Basin
Zou Caineng et al. / Petroleum Exploration and Development, 2010, 37(6): 641–653

ment of shale gas. For shale that has commercial development


potential, its fragile mineral content is over 40% and clay
content should be less than 30%.

4.3 Porosity and permeability characteristics and micro-


fractures
4.3.1 Porosity and permeability characteristics
Rock pore space is important space for oil/gas storage and a
key parameter to determine the free gas volume. Statistic data
indicates that about 50% of the shale gas is stored in matrix
pore space within shale rock. Shale reservoir belongs to ul-
tra-low porosity and permeability reservoir and is character-
Fig. 6 Shale gas forming mechanism of on site “retention reser- ized by different types of micro-pores or even nano-scale pore
voiring” space, including intergranular micro-pores, inter-layer mi-
would be. And, under external forces, it will be even easier to cro-pores, grain dissolved pores, dissolved matrix inner pores,
form natural fractures and induced fractures and form intragranular dissolved pore space and organic matter pore
tree–network shaped fractures, which are favorable for shale space etc. Pore size is mostly less than 2 ȝm, organic matter
gas development. On the contrary, shale with high clay con- pore throats are mostly 100-200 nm, has high surface to vol-
tent often has high ductility and can absorb energy to form ume ratios and complicated textures. The large inner surface
tabular fractures, which are not favorable for shale stimulation area can store a large amount of gas in adsorption pattern[33].
operation. In America, the quartz content of gas producing The matrix porosity of shale rock is about 0.5%–6.0% and the
shale is 28%–52%, carbonate content is 4%–16%, and total median value is mostly 2%–4%. The measurement of Huay-
fragile mineral content is 46%–60%. The authors studied the ingshan Hongyan Coal Mine Longmaxi Formation and
mineral composition of three different types of shale in China Qiongzhusi Formation in the Weiyuan area in Sichuan Basin
and concluded that, no matter marine shale, ma- indicates that the Longmaxi Formation shale porosity is
rine-terrigenous alternated carbonaceous shale or lacustrine 2.43%–15.72% with the average value of 4.83%. The
shale, the fragile mineral content is generally high, mostly Qiongzhusi Formation shale porosity is 0.34%–8.10% with
over 40%. For example, the quartz content of Paleozoic ma- the average value of 3.02%. The measured porosity of Meso-
rine shale in the Upper Yangtze area is 24.3%–52.0%, feldspar zoic lacustrine shale from Ordos Basin is 0.4%–1.5% and
content is 4.3%–32.3%, calcite content is 8.5%–16.9% and permeability is 0.012×103–0.653×103 ȝm2.
total fragile mineral content is 40%–80% (Table 7, Fig. 7). Marine facies organic rich shale in China has well-devel-
The clay content of Xujiahe Formation in Sichuan Basin is oped nano-scale pore space (Fig. 5). It contains both inter-
15%–78% and the average value is about 50% while the frag- granular pores and intragranular pores and organic matter
ile mineral content (quartz, feldspar etc.) is 22%–85% and the pores. The nano-scale micro-pores formed after the organic
average value is about 50%. In Ordos Basin, the quartz con- matter was mature can be major pore space for shale gas
tent of Upper Paleozoic coal-bearing carbonaceous shale is storage.
32%–54% with average value of 48%, and the total fragile
4.3.2 Micro-fractures
mineral content is 40%–58%. The quartz content of Mesozoic
lacustrine shale in Ordos Basin is 27%–47% with average value The development of fractures can provide enough storage
of 40%, and the total fragile mineral content is 58%–70%. space for shale gas, and can also provide migration pathway
Rock mineral composition is crucial for the later develop- and effectively enhance shale gas production[2]. Shale perme-

Table 7 Geological property comparison between shale from North America and Sichuan Basin
Effective Quartz Porosity Gas content Resource abun-
Shale Epoch Depth/m TOC/% Ro/%
thickness/m content/% /% /(m3·t1) dance/(104 m3·km2)
Barnett Miss. 1 981–2 926 30.00–183.00 2.00–7.00 1.10–2.00 35–50 4.00–5.00 8.50–9.91 7.15
Fayetteville Miss. 305–2 287 6.10–76.20 2.00–9.80 1.20–>4.00 2.00–8.00 1.70–6.23 6.30
Haynesville J3 3 048–4 115 616.00–91.44 0.50–4.00 2.20–3.20 8.00–9.00 2.83–9.34 8.71
Woodford D3 1 829–3 353 36.58–67.10 1.00–14.00 1.10–3.00 60–80 3.00–9.00 5.66–8.50 2.29
Antrim D3 183–732 21.00–37.00 1.00–20.00 0.40–0.60 20–41 9.00 1.13–2.83 0.69
Lewis K2 914–1 829 61.00–91.00 0.45–2.50 1.60–1.90 3.00–55.00 0.40–1.30 1.74
Marcellus D2 475–2 591 15.20–304.00 3.00–12.00 1.50–3.00 50–70 10.00 1.70–2.83 1.73
Montney T 400–4 400 30.00 1.20–1.60 1.75–3.75 50–70 5.00–9.50 0.44
Qiongzhusi ȯ1q 2 600–4 600 20.00–80.00 2.30–4.20 1.50–5.70 28–56 1.46–2.61 1.17–6.02 0.90–2.30
Longmaxi S1l 1 600–4 200 20.00–100.00 1.60–3.60 1.88–4.36 24–44 1.00–5.00 1.73–3.28 1.00–2.50
Zou Caineng et al. / Petroleum Exploration and Development, 2010, 37(6): 641–653

Fig. 7 Lower Paleozoic mineral composition in Sichuan Basin


ability will be very low without fracture development. Quartz Qiongzhusi Formation in Sichuan Basin is 1.17–6.02 m3/t, the
content is an important factor of influencing fracture devel- average value is 2.82 m3/t. The gas concentration of Long-
opment. Quartz-rich black shale has good brittleness, thus, the maxi Formation black shale is 1.73–3.28 m3/t, which is com-
fracture development is better than calcite-rich shale[34]. Nel- parable with the North American gas producing shale and
son stated that feldspar and dolomite are also fragile composi- reaches the lower limit of commercial shale gas development
tions besides quartz[35]. Shale often has high clay mineral (Table 7). Since shale gas development in China hasn’t en-
content, but dark organic-rich shale generally has low clay tered into development stage, there are very few shale gas
mineral content. In shale gas exploration, we should look for wells. Thus, we cannot acquire enough shale gas concentra-
shale that can be fractured, which means that the shale clay tion data. However, according to the old well review result,
content should be low enough (<50%) and fragile mineral the previous wells had a lot of gas shows in the black shale
content should be high to make it easy to fracture. intervals and experienced well kick and blowout, indicating
Marine shale, marine-terrigenous alternated carbonaceous good gas concentration at the shale intervals. For example,
shale and lacustrine shale in China all have good brittleness. among 107 wells that penetrated Qiongzhusi Formation in the
The field geologic profile and downhole core observation Weiyuan area, Sichuan Basin, 32 of them had 52 gas shows of
found well-developed fracture systems. For example, Cam- different levels. Well Wei-5 even had well blowout when
brian Qiongzhusi Formation and Silurian Longmaxi Forma- drilled through the Qiongzhusi Formation shale interval at
tion black shale in the Upper Yangtze area is brittle and hard, 2795–2798 m. DST test got 2.46×104 m3 of natural gas. As for
with well-developed joints and fractures distributed in net- the 15 wells penetrated the Lower Silurian Longmaxi Forma-
work shape in 3D space. The rock thin section shows that the tion shale interval in the Southern Sichuan area, there are
micro-fractures are as slender as hair and are partially filled good gas shows in 32 intervals. Well Yang-63 penetrated the
by calcite, bitumen and other secondary minerals. Mi- Longmaxi Formation shale at the interval of 3 505–3 518 m
cro-fracture network can also be observed in the Upper Pa- and got daily gas production of 3500 m3 during the test.
leozoic Shanxi Formation core section in Ordos Basin. The
5 Resources potential and peculiarity
Mesozoic Chang 7 Member black shale in Ordos Basin has
well-developed lamellation and will be in thin lamination after Several scholars and organizations have made prediction on
weathering. China shale gas resource potential and the general evaluation
result is optimistic[3638].
4.4 Gas-bearing property
Shale gas and conventional gas have obvious differences,
Shale gas area can be divided into core area and outer zone not only including geologic uncertainty, but also development
by its gas concentration. Shale gas concentration, including risk, especially; the determination of recovery ratio mainly
free gas, adsorbed gas and dissolved gas, is an important in- relies on well control data. Therefore, objective and accurate
dex to determine whether it has economic benefits and to per- prediction of shale gas resource potential is full of challenge.
form resource potential evaluation. Halliburton Corp. pro- China shale gas E&P is still at starting phase there are very
posed that the minimum shale gas concentration for commer- limited data available for the prediction of shale gas resource
cial development is 2.8 m3/t. Currently, the minimum shale potential. Although the development scale and shale quality of
gas concentration under development in North America is organic rich shale in different areas have great similarity, the
about 1.1 m3/t and the highest concentration can reach 9.91 generation and accumulation of shale gas in different areas
m3/t. The measured gas concentration of Lower Cambrian still have lots of differences due to the complicated tectonic
Zou Caineng et al. / Petroleum Exploration and Development, 2010, 37(6): 641–653

evolution, depositional environment and geothermal evolution So, during the E&P practice, they should be treated based on
process in China. The Paleozoic marine organic-rich shale has their own conditions. Paleozoic shale is mainly marine depo-
wide distribution, large continuous thickness and high organic sition and has stable regional distribution. The thickness is
matter abundance. However, it also has high evolution degree large and the organic matter is abundant and the evolution
and experienced several tectonic events with many changes. degree is high. A lot of gas shows were discovered. It can be
The Mesozoic lacustrine organic-rich shale has large lateral practical areas for shale gas exploration and development.
variation and its lithology is mainly thick shale or sandstone The carbonaceous shale and coal beds developed in the
and shale interbeds. The organic matter abundance is medium Carboniferous-Permian and Triassic-Jurassic coal series have
and thermal maturity is low. Therefore, we estimated the shale high TOC content and are associated with sandstone. Shale
gas resource potential in China based on geologic correlation. gas and tight gas are distributed continuously. Mesozoic
The favorable distribution area of Paleozoic marine organic lacustrine shale is mainly thick-layered shale with low matur-
shale in China is 63×104–90×104 km2. The favorable area of ity and continuously-distributed oil shale and tight oil.
Mesozoic lacustrine organic rich shale is 23×104–33×104 km2, Source rock hydrocarbon is a new area, including shale oil,
effective shale thickness is 20300 m, TOC content is shale gas, coal bed gas etc. with the forming mechanism of on
0.50%–25.71%, Ro value is 0.8%–4.5%, and the predicted site “retention reservoiring”. Shale gas can be developed si-
shale gas resources are 30×1012–100×1012 m8. These predic- multaneously with the underlying and overlying tight sand gas
tion data are all preliminary results. The development tech- and coal bed methane to improve its production and efficiency.
nologies and economically recoverable shale gas reserves in The drilling data and outcrop data indicate that Sichuan
China are still under study. Basin developed several sets of shale gas intervals, including
Currently, China has initiated several promising shale gas marine facies, marine-terrigenous alternated facies and lacus-
pilot production projects in Southern Sichuan Basin. The un- trine facies. It can be the most practical area for shale gas ex-
dergoing preliminary evaluation on the mid-lower Yangtze ploration and development. The Paleozoic shale interval has
area, Ordos Basin, Tarim Basin and Songliao Basin will select abundant 100–200 nm nanometer scale pore space and thus
favorable shale gas replacement areas. Shale gas has impor- high shale gas saturation. The Weiyuan-Changning area, in the
tant significance in mitigating the short-supply status of mid-southern part of the basin, is favorable area for shale gas
China’s natural gas market, changing energy structure and accumulation and can be one of the most important core areas
guaranteeing national energy security. It will also have im- for future exploration and development. It also needs to
portant scientific value on theoretical innovation of petroleum strengthen the optimization of core area and economic evalua-
geology and E&P technology improvement.
tion of other basins in China.
Compared with the North American shale gas, China’s
shale gas has three distinctive features: (1) Marine shale has
Acknowledgements
high thermal evolution degree (Ro value is 2.5%–5.0%) and
tectonic movements were frequent. We need to find areas that
We acknowledge the significant contribution to shale gas
have favorable preservation conditions and avoid outcrop
study made by Hu Suyun, Zhu Rukai, Liang Digang, Li Jin-
zones and fault damage zones; (2) Lacustrine shale has low
chao, Zhang Shiben, Gao Xiaohui, Tao Shizhen, Huang Ling,
thermal evolution degree and high heterogeneity, thus, it re-
Huang Jinliang, Yuan Xuanjun, Hou Lianhua, Jia Jinhua, Lü
quires pertinent technologies for effective development; (3)
Weining and Tanghui. We thank Dai Jinxing (Academician)
The surface condition is mainly mountainous area and the
for the helpful review comments, and thank Qiu Zhongjian,
burial depth is large (5 0007 000 m), thus, proper technolo-
Jia Chengzao, Zhao Zhengzhang, Wang Daofu, Zhao Wenzhi,
gies for cost reduction is required. Therefore, shale gas E&P
Ma Xinhua and other academicians and experts for their sup-
in China should pay attention to some special geologic condi-
port. Thanks also go to Chen Gengsheng, Wang Shiqian,
tions, such as complicated surface, burial depth and later
Wang Lansheng, Lü Zonggang and other experts from
preservation. For example, the deep burial depth of marine
Southwest Oil Gas Company.
shale in Tarim Basin, the preservation problem of Southern
China shale after exposure, and the challenging mountainous
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