VX193 - MSDS

Version: 3.
0
Last revised date: 15.11.2016
Supersedes Date: 31.10.2010
VX-193
SAFETY DATA SHEET

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name: VX-193
Additional identification
Chemical name: Organosilane ester
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Coating additive.
Uses advised against: Not known.
1.3 Details of the supplier of the safety data sheet
Manufacturer/Importer/Distr : Momentive Performance Materials GmbH

ibutor Information Chempark Leverkusen Gebaeude V7
DE - 51368 Leverkusen
Germany
Contact person : MomentiveEMEA.productsteward@momentive.com
Telephone : General information

00800.4321.1000 (Customer Service Centre)
1.4
Emergency telephone : Europe, Israel & All other: +44 (0) 1235239670; Middle East:+44
number (0) 1235239671
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
The product has been classified according to the legislation in force.
Classification according to Regulation (EC) No 1272/2008 as amended.
Physical Hazards
Flammable liquids Category 3 H226: Flammable liquid and vapor.
Health Hazards
Acute toxicity (Inhalation - vapor) Category 4 H332: Harmful if inhaled.
2.2 Label Elements

Contains: Vinyltrimethoxysilane
Methanol
Signal Words: Warning
SDS_GB 1/14
Version: 3.0
VX-193
Hazard Statement(s): H226: Flammable liquid and vapor.

H332: Harmful if inhaled.
Precautionary Statements
Prevention: P210: Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
Response: P303+P361+P353: IF ON SKIN (or hair): Take off immediately all

contaminated clothing. Rinse skin with water/shower.
P304+P312: IF INHALED: Call a POISON CENTER or
doctor/physician if you feel unwell.
P340: Remove person to fresh air and keep comfortable for breathing.
P370+P378: In case of fire: Use to extinguish.
Disposal: P501: Dispose of contents/container to an appropriate treatment and

disposal facility in accordance with applicable laws and regulations, and
product characteristics at time of disposal.
Unknown toxicity - Health
Acute toxicity, inhalation, vapor 0%

Acute toxicity, inhalation, dust 0%
or mist
Additional Information: No data available.
2.3 Other hazards No data available.
SECTION 3: Composition/information on ingredients
Chemical nature: Organofunctional Silane Ester
3.2 Mixtures
General information: No data available.
Chemical name Concentration CAS-No. EC No. REACH M-Factor: Notes

Registration
No.
Vinyltrimethox 50 - <100% 2768-02-7 220-449-8 01- No data
ysilane 2119513215- available.
52-0001
1-Dodecanol 1 - <2,5% 112-53-8 203-982-0 No data No data

available. available.
Methanol 0,1 - <1% 67-56-1 200-659-6 01- No data #

2119433307- available.
44-0093
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by
volume.
# # This substance has workplace exposure limit(s).
SDS_GB 2/14
Version: 3.0
VX-193
PBT: persistent, bioaccumulative and toxic substance.
vPvB: very persistent and very bioaccumulative substance.
Classification
Chemical name Classification Notes
Vinyltrimethoxysilane Flam. Liq.: 3: H226 Acute Tox.: 4: H332 No data
available.
1-Dodecanol Eye Dam.: 2: H319Aquatic Chronic: 2: H411Aquatic Acute: 1:
H400
Methanol Flam. Liq.: 2: H225 Acute Tox.: 3: H331Acute Tox.: 3: No data
H311Acute Tox.: 3: H301STOT SE: 1: H370 available.
CLP: Regulation No. 1272/2008.
SECTION 4: First aid measures
4.1 Description of first aid measures

Inhalation: Move the exposed person to fresh air at once.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least
15 minutes. Get medical attention.
Skin Contact: Wash off promptly and flush contaminated skin with water. Promptly
remove clothing if soaked through and flush skin with water. Wash
contaminated clothing before reuse. Get medical attention.
Ingestion: If conscious, drink plenty of water.
4.2 Most important symptoms Product may hydrolyse upon contact with body fluids in the gastrointestinal
and effects, both acute and tract to produce additional methanol; therefore, consider the
delayed: signs/symptoms of methanol poisoning and also observe the known latency
period of several days!
4.3 Indication of any immediate medical attention and special treatment needed
Hazards: No data available.
Treatment: No data available.
SECTION 5: Firefighting measures
General Fire Hazards: Do not use water jet as an extinguisher, as this will spread the fire.
5.1 Extinguishing media

Suitable extinguishing Alochol-resistant foam Carbon dioxide
media:
Unsuitable extinguishing No data available.

media:
5.2 Special hazards arising Vapors may travel considerable distance to a source of ignition and flash
from the substance or back.
mixture:
5.3 Advice for firefighters

Special fire fighting No data available.
procedures:
SDS_GB 3/14
Version: 3.0
VX-193
Special protective Wear self-contained breathing apparatus and protective clothing.

equipment for fire-fighters:
SECTION 6: Accidental release measures
6.1 Personal precautions, Extinguish and do not turn on any ignition source until the area is
protective equipment and determined to be free from fire or explosion hazards. Avoid contact with
emergency procedures: eyes, skin, and clothing. Avoid contact with liquid and vapors. Use personal
protective equipment.
6.2 Environmental Precautions: Do not allow runoff to sewer, waterway or ground.
6.3 Methods and material for Absorb spillage with suitable absorbent material.
containment and cleaning
up:
6.4 Reference to other No data available.

sections:
SECTION 7: Handling and storage:
7.1 Precautions for safe Do not breathe vapor/spray. Avoid contact with eyes, skin, and clothing.
handling: Wash hands after handling. Material can accumulate static charges which
may cause an electrical spark (ignition source). Use proper bonding and/or
grounding procedures.
7.2 Conditions for safe storage, Store in tightly closed original container in a dry and cool place.
including any
incompatibilities:
7.3 Specific end use(s): No data available.
SECTION 8: Exposure controls/personal protection
8.1 Control Parameters

Occupational Exposure Limits
Chemical name type Exposure Limit Values Source
Methanol TWA 200 ppm 266 mg/m3 UK. EH40 Workplace Exposure Limits (WELs)
(12 2011)
STEL 250 ppm 333 mg/m3 UK. EH40 Workplace Exposure Limits (WELs)
(12 2011)
TWA 200 ppm 260 mg/m3 EU. Indicative Exposure Limit Values in
Directives 91/322/EEC, 2000/39/EC,
2006/15/EC, 2009/161/EU (12 2009)
Ethanol TWA 1.000 ppm 1.920 mg/m3 UK. EH40 Workplace Exposure Limits (WELs)
(12 2011)
Biological Limit Values

None.
8.2 Exposure controls

Appropriate Engineering Provide eyewash station and safety shower. General (mechanical) room
Controls: ventilation is expected to be satisfactory if handled at low temperatures or
in covered equipment.
Individual protection measures, such as personal protective equipment
General information: No data available.

SDS_GB 4/14
Version: 3.0
VX-193
Eye/face protection: Safety glasses with side-shields conforming to EN166
Skin protection
Hand Protection: Advice: This recommendation is valid only for our Product as delivered. If
this product will be mixed with other substances you need to contact a
supplier of CE approved protective gloves (e.g. KCL GmbH, D-36124
Eichenzell, Tel. 0049 (0) 6659 87300, Fax. 0049 (0) 6659 87155, email:
vertrieb@kcl.de).
Material: 730 Camatril
Minimum break through time: 480 min
Glove thickness: 0,4 mm
Guideline: EN 374
Other: Safety shoes Wear suitable protective clothing.
Respiratory Protection: Respirator with a vapour filter (EN 141)
Hygiene measures: No data available.
Environmental exposure No data available.

controls:
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance
Physical state: liquid
Form: liquid
Color: Pale yellow
Odor: ester like
Odor Threshold: No data available.
pH: No data available.
Freezing point: < 0 °C estimated
Boiling Point: 122 °C (1.013 hPa) estimated
Flash Point: ca. 27 °C (Closed Cup)
Evaporation Rate: No data available.
Flammability (solid, gas): No data available.
Flammability Limit - Upper (%): No data available.
Flammability Limit - Lower (%): No data available.
Vapor pressure: No data available.
Vapor density (air=1): No data available.
Density: ca. 0,994 g/cm3 (25 °C)
Relative density: No data available.
Solubility(ies)
Solubility in Water: Reactive.
Solubility (other): No data available.
Partition coefficient (n-octanol/water) Log No data available.
Pow:
Autoignition Temperature: No data available.
Decomposition Temperature: No decomposition if stored and applied as directed.
SADT: No data available.
SDS_GB 5/14
Version: 3.0
VX-193
Viscosity, dynamic: No data available.
Viscosity, kinematic: No data available.
Explosive properties: No data available.
Oxidizing properties: No data available.
SECTION 10: Stability and reactivity
10.1 Reactivity: No data available.
10.2 Chemical Stability: Material is stable under normal conditions.
10.3 Possibility of hazardous Under normal conditions of storage and use, hazardous polymerization will
reactions: not occur.
10.4 Conditions to avoid: No data available.
10.5 Incompatible Materials: Water Acids. Peroxides. Moisture.
10.6 Hazardous Decomposition Carbon oxides Oxides of silicon.

Products:
SECTION 11: Toxicological information
Information on likely routes of exposure

Inhalation: No data available.
Ingestion: No data available.
Skin Contact: No data available.
Eye contact: No data available.
11.1 Information on toxicological effects
Acute toxicity
Oral
Product: LD 50 (Rat): 7.300 mg/kg Slightly toxic
Specified substance(s)
Vinyltrimethoxysilane No data available.
1-Dodecanol No data available.
Methanol LD 50 (Rat): 5.628 mg/kg
Dermal
Product: LD 50 (Rabbit): 3.400 mg/kg Slightly toxic
Vinyltrimethoxysilane LD 50 (Rabbit): > 3.400 mg/kg
LD 50 (Rabbit): 3.460 - 4.000 mg/kg

Methanol LD 50 (Rabbit): 15.800 mg/kg
Inhalation
Product: LC50 (Rat, 4 h): 16,79 mg/l Toxic by inhalation.
ATEmix18,76 mg/l Vapour
SDS_GB 6/14
Version: 3.0
VX-193
Methanol LC 50 (Rat, 4 h): 6,4 mg/l
Repeated dose toxicity

Product: No data available.
Methanol No data available.
Skin Corrosion/Irritation: No skin irritation

Product: (Rabbit): Slightly irritating.
Methanol (Rabbit): Corrosive
Serious Eye Damage/Eye No eye irritation

Irritation:
Product: (Rabbit): Slightly irritating.
Vinyltrimethoxysilane OECD-Guideline 405 (Acute Eye Irritation/Corrosion) (Rabbit): No eye
irritation
Respiratory or Skin
Sensitization:
Product: (Guinea Pig)did not elicit a delayed contact hypersensitivity response
Vinyltrimethoxysilane , OECD-Guideline 406 (Skin Sensitisation) (Guinea Pig)Did not cause
sensitization on laboratory animals.
Methanol (Guinea Pig)negative
Germ Cell Mutagenicity
In vitro
Vinyltrimethoxysilane Chinese Hamster Ovary (CHO) (OECD 476): negative (not mutagenic)
Ames-Test (OECD-Guideline 471 (Genetic Toxicology: Salmonella
typhimurium, Reverse Mutation Assay)): negative (not mutagenic)
Chromosomal aberration (OECD 473): positive
In vivo
Vinyltrimethoxysilane Chromosomal aberration Intraperitoneal (Mouse): negative
SDS_GB 7/14
Version: 3.0
VX-193
Carcinogenicity
Reproductive toxicity
Specific Target Organ Toxicity - Single Exposure

Specific Target Organ Toxicity - Repeated Exposure

Aspiration Hazard
Other effects: No data available.
SECTION 12: Ecological information
12.1 Toxicity
Acute toxicity
Fish
Methanol LC50 (Pimephales promelas, 96 h): 28.100 mg/l
SDS_GB 8/14
Version: 3.0
VX-193
Aquatic Invertebrates
Vinyltrimethoxysilane EC50 (Daphnia magna, 48 h): > 100 mg/l (OECD Test Guideline 202)
EC50 (Daphnia magna, 24 h): 297,2 mg/l
EC50 (Daphnia magna, 48 h): 168,7 mg/l
NOEC (Daphnia magna, 21 d): 28 mg/l
Chronic Toxicity
Fish
Aquatic Invertebrates
Toxicity to Aquatic Plants

Vinyltrimethoxysilane EC50 (Desmodesmus subspicatus (green algae), 72 h): > 100 mg/l (OECD
Test Guideline 201)
EC50 (Selenastrum capricornutum, 7 d): 210 mg/l Fresh water
EC10 (Selenastrum capricornutum, 7 d): 32 mg/l Fresh water
NOEC (Selenastrum capricornutum, 7 d): Approximate 25 mg/l Fresh water
12.2 Persistence and Degradability
Biodegradation
Product: (28 d, OECD-Guideline 301 F (Manometric Respirometry Test)): The product
is not readily biodegradable.
Vinyltrimethoxysilane (28 d, OECD-Guideline 301 F (Manometric Respirometry Test)): The product
is not readily biodegradable.
BOD/COD Ratio
Product No data available.
SDS_GB 9/14
Version: 3.0
VX-193
12.3 Bioaccumulative potential

Vinyltrimethoxysilane hydrolyses The product is not bioaccumulating.
12.4 Mobility in soil: No data available.

Known or predicted distribution to environmental compartments
12.5 Results of PBT and vPvB No data available.

assessment:
12.6 Other adverse effects: No data available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
General information: See Section 8 for information on appropriate personal protective

equipment. The generation of waste should be avoided or minimized
wherever possible. Do not discharge into drains, water courses or onto the
ground. Dispose of waste and residues in accordance with local authority
requirements.
Disposal methods: Can be incinerated when in compliance with local regulations.
SECTION 14: Transport information
ADR
14.1 UN Number: UN 1993
14.2 UN Proper Shipping Name: FLAMMABLE LIQUID, N.O.S.(VINYLTRIMETHOXYSILANE)
14.3 Transport Hazard Class(es)
Class: 3
Label(s): 3
Hazard No. (ADR): 30
Tunnel restriction code: (D/E)
14.4 Packing Group: III
Limited quantity 5,00L
Excepted quantity E1
14.5 Environmental Hazards: Not regulated.

Marine Pollutant No
ADN
SDS_GB 10/14
Version: 3.0
VX-193
Class: 3
Label(s): 3
Hazard No. (ADR): –

Marine Pollutant No
RID
14.2 UN Proper Shipping Name FLAMMABLE LIQUID, N.O.S.(VINYLTRIMETHOXYSILANE)
Class: 3
Label(s): 3

Marine Pollutant No
IMDG
Class: 3
Label(s): 3
EmS No.: F-E, S-E

Marine Pollutant: No
IATA
14.2 Proper Shipping Name: Flammable liquid, n.o.s.(VINYLTRIMETHOXYSILANE)
14.3 Transport Hazard Class(es):
Class: 3
Label(s): 3
Cargo aircraft only Packing 366
Instructions:
Passenger and cargo aircraft 366
Packing Instructions:
Limited quantity: 10,00L
Packing Instructions: Y344

Marine Pollutant: No
SDS_GB 11/14
Version: 3.0
VX-193
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code:
not applicable
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
EU Regulations
Regulation (EC) No. 2037/2000 Substances that deplete the ozone layer: none
Regulation (EC) No. 850/2004 on persistent organic pollutants: none
Regulation (EC) No. 689/2008 Import and export of dangerous chemicals: none
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended:
none
Regulation (EC) No. 1907/2006 Annex XVII Substances subject to restriction on marketing and use:
Chemical name CAS-No. Concentration

Methanol 67-56-1 0,1 - 1,0%
Ethanol 64-17-5 0,1 - 1,0%
Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens
and mutagens at work.: none
Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently
given birth or are breast feeding.: none
Directive 96/82/EC (Seveso III): on the control of major accident hazards involving dangerous
substances: none
EU. Regulation No. 166/2006 PRTR (Pollutant Release and Transfer Registry), Annex II: Pollutants:
none
Directive 98/24/EC on the protection of workers from the risks related to chemical agents at work:
Chemical name CAS-No. Concentration

Methanol 67-56-1 0,1 - 1,0%
Ethanol 64-17-5 0,1 - 1,0%
15.2 Chemical safety No Chemical Safety Assessment has been carried out.
assessment:
Inventory Status
Australia AICS: n (Negative listing) Remarks: None.
EU EINECS List: y (positive listing) Remarks: None.
Japan (ENCS) List: n (Negative listing) Remarks: None.
China Inventory of Existing y (positive listing) Remarks: None.
Chemical Substances:
Korea Existing Chemicals Inv. n (Negative listing) Remarks: None.
(KECI):
Canada DSL Inventory List: y (positive listing) Remarks: None.
Canada NDSL Inventory: n (Negative listing) Remarks: None.
New Zealand Inventory of n (Negative listing) Remarks: None.
Chemicals:
SDS_GB 12/14
Version: 3.0
VX-193
Philippines PICCS: n (Negative listing) Remarks: None.
US TSCA Inventory: y (positive listing) Remarks: None.
Taiwan. Taiwan inventory n (Negative listing) Remarks: None.
(CSNN):
SECTION 16: Other information
Revision Information: Not relevant.
Key literature references and No data available.

sources for data:
Wording of the H-statements in section 2 and 3

H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H370 Causes damage to organs.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
Training information: No data available.
Classification according to Regulation (EC) No 1272/2008 as amended.

Flam. Liq. 3, H226
Acute Tox. 4, H332
Issue Date: 15.11.2016
SDS_GB 13/14
Version: 3.0
VX-193
Disclaimer:
Notice to reader
Unless otherwise specified in section 1.2, Momentive Products are intended

for industrial application only.
They are not intended for specific medical applications, neither for long-
lasting (> 30 days) implantation into the human body, injected or directly
ingested, nor for the manufacture of multiple usable contraceptives.
Further Information
The information provided in this Safety Data Sheet is correct to the best of
our knowledge, information and belief at the date of its publication. The
information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be
considered a warranty or quality specification. The information relates only to
the specific material designated and may not be valid for such material used
in combination with any other materials or in any process, unless specified in
the text.
®,*, and TM indicate trademarks owned by or licensed to Momentive.
SDS_GB 14/14

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Version: 3.

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.3 Details of the supplier of the safety data sheet

Manufacturer/Importer/Distr : Momentive Performance Materials GmbH

Contact person : MomentiveEMEA.productsteward@momentive.com

Telephone : General information

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

The product has been classified according to the legislation in force.

Classification according to Regulation (EC) No 1272/2008 as amended.

2.2 Label Elements

Signal Words: Warning

Hazard Statement(s): H226: Flammable liquid and vapor.

Response: P303+P361+P353: IF ON SKIN (or hair): Take off immediately all

Disposal: P501: Dispose of contents/container to an appropriate treatment and

Unknown toxicity - Health

Acute toxicity, inhalation, vapor 0%

Additional Information: No data available.

2.3 Other hazards No data available.

SECTION 3: Composition/information on ingredients

Chemical nature: Organofunctional Silane Ester

General information: No data available.

Chemical name Concentration CAS-No. EC No. REACH M-Factor: Notes

1-Dodecanol 1 - <2,5% 112-53-8 203-982-0 No data No data

Methanol 0,1 - <1% 67-56-1 200-659-6 01- No data #

CLP: Regulation No. 1272/2008.

SECTION 4: First aid measures

4.1 Description of first aid measures

Ingestion: If conscious, drink plenty of water.

Treatment: No data available.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Unsuitable extinguishing No data available.

5.3 Advice for firefighters

Special protective Wear self-contained breathing apparatus and protective clothing.

SECTION 6: Accidental release measures

6.2 Environmental Precautions: Do not allow runoff to sewer, waterway or ground.

6.4 Reference to other No data available.

SECTION 7: Handling and storage:

7.3 Specific end use(s): No data available.

SECTION 8: Exposure controls/personal protection

8.1 Control Parameters

Biological Limit Values

8.2 Exposure controls

Individual protection measures, such as personal protective equipment

General information: No data available.

Eye/face protection: Safety glasses with side-shields conforming to EN166

Other: Safety shoes Wear suitable protective clothing.

Respiratory Protection: Respirator with a vapour filter (EN 141)

Hygiene measures: No data available.

Environmental exposure No data available.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

SECTION 10: Stability and reactivity

10.1 Reactivity: No data available.

10.2 Chemical Stability: Material is stable under normal conditions.

10.4 Conditions to avoid: No data available.

10.5 Incompatible Materials: Water Acids. Peroxides. Moisture.