CHEMISTRY

Full Syllabus Test IIT-JEE

1. The Schrodinger wave equation for hydrogen atom is
3/2
1 Z
radial    (  1)(2  8  12) e /2
16 4  a0 
2Zr
where a0 & Z are constants in which the answer can be expressed &   . Minimum &
a0
maximum distance of radial node from nucleus are
a0 3a0 a 0 a0 a0 3a0 a0 4a0
(A) , (B) , (C) , (D) ,
Z Z 2Z Z 2Z Z 2Z Z

2. Identify the correct match:

H3C Br2
H3C
Br
(A) HO PCl3
HO
Etard reaction
O O
O OAg
Br
(B) Br2 HVZ reaction
heat
+ CO2 + AgBr

OH CHO
OH
KOH/H2O
(C) + CHCl3 + Reimer-Tiemann reaction
CHO
OH
H3C H3C
Na/Ether
(D) Fitting reaction
Br CH3

3. Identify the valid statements regarding Birch reduction.

R

(A) is the type of the product when R = electron donating group.

(B) is the type of the product when R = electron withdrawing group.

CH3 CH3
Sodium
(C) H2C H3C
liq. NH3
CH2 CH3
(D) All are correct
4. Statement-1: LDA is a very strong nucleophile but it is not a very good base.
Statement-2: Nucleophilicity is kinetic property but basicity is thermodynamic property.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for
statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation
for statement-1.
(C) Statement-1 is true, Statement-2 is false.
(D) Statement-1 is false, Statement-2 is true.

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CHEMISTRY Full Syllabus Test [2]

5. Which of the following options are not correct?

O
NaBH4/
(A) CO2H Lactone is formed as product
CO2H
(B) Tartaric acid CH(OH) has 2 optically active stereoisomers.
CH(OH)
H3C CH3
N NH2 NH2 NH2
CH3
(C) is more basic than (D) is more basic than

6. At 298K, the reduction potential of hydrogen electrode at pH = 10, will be

(A) 0.059 V (B) –0.59 V (C) 0.59 V (D) –0.285 V
7. A manganese (II) ion salt is oxidised by peroxodisulphate, then the oxidation number of Mn
in the product formed is
(A) +4 (B) +5 (C) +7 (D) +3
8. A non-reducing disaccharide is obtained by condensation of X & Y. Condensation takes
place between X & Y respectively at:
6 1
4 CH2OH O H O CH2OH
HO 5
5 2
HO 2 OH OH H
3 OH 1 HOH 2C OH
6 4 3

H OH
(X) (Y)
(A) C-1 & C-1 (B) C-1 & C-5 (C) C-5 & C-1 (D) C-1 & C-2
9. Cannizzaro's reaction can be exemplified by one of the following:
O OH O OH
OH COOK

(A) 2 KOH
+ (B) 2 KOH
+

O
COOK CH2OH O
O

(C) 2 KOH
+ (D) KOH O
2

10. Atoms 7 X A , 8 Y B , 9 Z17 are such that 8 Y is an isobar of 7 X & atom 9 Z17 is isotone of 8 Y .
Mass no. of 'X' & no. of neutrons in Y are respectively:
(A) 8, 8 (B) 17, 7 (C) 9, 8 (D) 16, 8

11. What is the decreasing order of rate of reaction with HBr for the following benzyl alcohol
and its derivative?
CH2OH CH2OH CH2OH CH2OH

OCH 3 Cl NO 2
(P) (Q) (R) (S)
(A) P > R > S > Q (B) P > Q > S > R (C) S > R > Q > P (D) P > Q > R > S

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CHEMISTRY Full Syllabus Test [3]

12. End centered Bravais Lattice is possible for:

(A) Cubic (B) Hexagonal (C) Monoclinic (D) Triclinic

13. Incorrect statement among the following is:

(A) PCl3 is prepared by action of thionyl chloride on white phosphorous.
(B) Partial hydrolysis of XeF6 is a redox reaction.
(C) Catalyst used in Deacon's process is CuCl2.
(D) FeCl2 is more ionic than FeCl3.

14. Least basic compound among the following:

H NH2 CH2 NH2
N
(A) (B) (C) (D)
N

O O C2H5ONa O
15. H3C + H3C H3C + H3C
O O OH
CH3 CH3
O
CH3
For the above reaction the applicable facts are:
(A) It is Claisen's condensation reaction.
(B) The base commonly employed is the sodium alkoxide corresponding to the OR of the
ester (R'COOR) function in order to avoid ester interchange which leads to
transesterification.
(C) It is an example for self-condensation.
(D) All are correct.

16. Which of the following is an amphoteric oxide?

(A) ZnO (B) CrO3 (C) NO (D) Mn2O7

17. 0.1 mole of 'XO' loses 1.806  1023 electrons then the oxidation state of 'X' in the product
will be
(A) +4 (B) +5 (C) +6 (D) –5

18. Which of the following is correct?

(A) Silicones are good electric conductors (B) on methylation of diborane, we get
B2(CH3)6
(C) Borax is having all planar units (D) Graphite is thermodynamically more stable
than diamond

19. When the complex K6[(CN)5Co–O–O–Co(CN)5] is oxidised by bromine into K5[(CN)5Co–O–

O–Co(CN)5]. Then which of the following statements will be true about this change:
(A) Co(II) is oxidised to Co(III) (B) The O–O bond length will increase
(C) The O–O bond length will decrease (D) (A) & (B) both are correct
20. Assume that the decomposition of HNO3 is 4HNO3 (g) 4NO2 (g)  2H2O(g)  O2 (g) and the
reaction approaches equilibrium at 400K & 30 atm pressure. At equilibrium the partial
pressure of HNO3 is 2 atm. Find KC at 400 K (R = 0.08 -atm/K-mol)
(A) 4 (B) 8 (C) 16 (D) 32
21. In which species number of lone pair on iodine and number of d-orbitals used in
hybridisation by iodine are same
(A) ICl 2 (B) ICl 2 (C) IF7 (D) ICl 4
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CHEMISTRY Full Syllabus Test [4]

22. Which of the following acid remains unaffected on heating?

(A) Adipic acid (B) Maleic acid (C) Fumaric acid (D) Succinic acid

23. If one mole of a monoatomic gas ( = 5/3) is mixed with 1 mole of a diatomic gas ( = 7/5).
The value of  for the mixture:
(A) 1.4 (B) 1.5 (C) 1.53 (D) 3.07

24. The molecule (SiH3)3N is

(A) Pyramidal and more basic than (CH3)3N (B) Planar and less basic than (CH3)3N
(C) Pyramidal and less basic than (CH3)3N (D) Planar and more basic than (CH3)3N

25. Tyndall effect will be observed for:

(A) Colloidal solutions in which the diameter of dispersed particles is very much smaller
than the wavelength of incident light.
(B) Colloidal solutions in which the diameter of dispersed particles is not much smaller than
the wavelength of incident light.
(C) The refractive indices of dispersed phase & the dispersion medium must differs
(D) Both (2) and (3)

26. A student decides to demonstrate NaCl and CsCl structure in his annual practical
examination. He decides to make a two-in-one structure. He takes some wire and creates a
3-D cubical mesh like structure and tries to locate only the lattice points and void position by
small bulbs of different colour.
Na = Green colour; Cl = Red colour; Cs = Blue colour
He finally decides to show a 3-D structure which contains only 4 NaCl or 8 CsCl molecule.
Once it look like NaCl then after 1 min again CsCl and on so on. Number of extra red colour
bulbs that start glowing after 1 min are
(A) 12 (B) 11 (C) 13 (D) 14

27. Which of the following is incorrect?

(A) Ellingham diagram can be used to find the faster reducing agent.
(B) Ellingham diagram is based on thermodynamic concepts.
(C) In Ellingham diagram, it is presumed that the reactions and products are in equilibrium.
(D) In Ellingham diagram, G increases with an increase in temperature for the formation of
metal oxides.

28. The correct electronic configuration for a metal ion of d 4 configuration in weak octahedral
field is:
4
(A) t 2g e0g (B) t 32g e1g (C) eg4 t 02g (D) t 22g e2g

29. At 298 K, for the following reaction, 2A  B C , H & S are 82.424 kJ mol–1 & 0.2 mol–1
K–1 respectively then equilibrium constant for the above equilibrium will be (approximate
value)
(A) 10–10 (B) 10–2 (C) 10–4 (D) 10–6

30. Which of the following is incorrect?

(A) Rhombic sulphur is insoluble in water but dissolves to some extent in benzene.
(B) Below 369 K, -sulphur transforms into -sulphur.
(C) Both Rhombic and monoclinic sulphur have S8 molecules.
(D) -sulphur insoluble in CS2.

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CHEMISTRY Full Syllabus Test [5]

31. Find Ecell for Ag(s) | AgBr(s) | KBr(aq., 10 1M) || KCl(aq., 10 6 M), AgCl(aq., 106 M) | Ag(s)
Given: Ksp (AgCl) = 10–10 M2, Ksp (AgBr) = 10–15 M2
(A) +0.5910 V (B) +0.2955 V (C) –0.5910 V (D) +0.4728 V

32. Which of the following antibiotics contains As=As linkage?

(A) Azodye (B) Prontosil (C) Salvarsan (D) Ofloxacin

33. A compound (A) on reaction with potassium hydroxide produces a green coloured
compound (B) in the presence of air. (B) disproportionates into a purple coloured compound
(C) and (A) on addition of aqueous acid. (C) on heating can produce (A) along with some
other components. Identify (A).
(A) K2MnO4 (B) FeCr2O4 (C) MnO2 (D) Cr2O3
34. Find the mean free path of a molecule of a vander waal gas at 360 K (the Boyle's
temperature for the given gas) & 1 atm. Given the excluded volume for the gas is 9.6  10–3
dm3 mol–1.
3
[use  = 3, NA = 6  1023, 2 = , Boltzmann constant k = 1  10–23 J/K, 1 atm = 105 Pa]
2
(A) 2  10–7 m (B) 3  10–7 m (C) 4  10–7 m (D) 5  10–7 m

35. In manufacturing of Cl2 gas, according to the reaction: HCl O2 
CuCl
 ? 2


{ Cl is one isotope of chlorine}
The probable products for this reaction are
 
(i) Cl2 + H2O (ii) Cl2 + H2O (iii) Cl Cl + H2O
Which of the above three set of products can actually be obtained?
(A) only (i) (B) (i) & (ii) (C) only (iii) (D) (i), (ii) & (iii)
36. A colourless oily liquid P(C2HCl3O) when treated with chlorobenzene in the presence of a
catalytic amount of sulfuric acid form a colorless, crystalline compound Q (C14H9Cl5) which is
used as insectiside. Hydrate of P is stable.
Choose incorrect option.
(A) Q is dichlorodiphenyltrichloroethane (B) P is chloral
(C) P disproportionate on treatment with NaOH (D) Q is Non-biodegradable pollutant
37. Which of the following is INCORRECT?
(A) BeCO3 is kept in the atmosphere of CO2 since, it is thermally unstable.
(B) Magnesium can be burnt in the atmosphere of CO2 and SO2.
(C) The function of Ca(H2PO4)2 in baking powder is to react with NaHCO3 because of its
acidic nature.
(D) Gypsum when added to cement makes the setting of the cement faster.
38. Which of the following is CORRECT?
(A) C6H13COOK has a lower CMC than C11H23NH4Cl.
(B) Blood can be purified by coagulation.
(C) A fat soluble dye cannot give consistent colouration to the entire volume when added to milk.
(D) A protective colloid that has higher gold number, is a better protective colloid.
39. SO32  Zn  H  gas(A)  Zn2  H2 
Which of the following is correct for gas A?
(A) Zn(NO3)2 solution gives white ppt. with gas A.
(B) Violet colouration is NOT obtained when the gas A is passed through a solution of
sodium nitroprusside.
(C) gas A is of oxidising nature.
(D) gas A is colourless and odourless.
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CHEMISTRY Full Syllabus Test [6]

40. For a process involving gases which behave ideally which of the following can be a criteria
for spontaneity (Here, U = Internal energy, S = Entropy, T = Temperature in Kelvin, H =
Enthalpy)
(A) (dU)S,V > 0 (B) (dG)T,P > 0 (C) (dS)U,V < 0 (D) (dH)S,P < 0

O
Electrolysis of
41. C CH3 A + Salt of acid ; A is:
Brine

(A) CH4 (B) CHI3 (C) CHCl3 (D) CH3–COONa

42. Which of the following can produce fair amount of H2 gas at anode on the electrolysis of the
fused mass?
(A) NaCl (B) KHF2 (C) BeH2 (D) CaH2

43. (Q) in following sequence is:

Benzyl amine  CHCl
KOH
(P) 
LiAlH
3
(Q) 4

NHCH 3 CH2 NH CH3 CN OH

(A) (B) (C) (D)

44. For the dissociation of SO3 into SO2 and O2, at a given Pressure (atm)
temperature, the equilibrium constant Kp = x atm2, then find x.
8
The variation of the partial pressure of the three gases with time SO2
is as shown:
(A) 729
3 O2
(B) 27 SO3
(C) 5.19
(D) 9 O
Time

45. Consider the following sequence of reactions:

CH3
Br2 1. CH3I(Excess)
CH3 CH2 CHCONH2 (A) (B)
KOH, Heat 2. AgOH, Heat

The major product (B) is:

(A) CH3 CH CH CH3 (B) CH3 CH2 CH CON(CH 3)2
CH3
(C) CH3 CH2 CH CH2 (D) CH3 CH2 CH N(CH 3)2
CH3

46. Dissociation constant for HNO2 and HF are 4.5  10–4 M and 6.75  10–4 M respectively.
What will be the ratio of the concentration of F to NO 2 in the solution that is 0.5 M in HF
and 0.5 M in HNO2?
(A) 3 (B) 2.0 (C) 1.5 (D) 4

47. Which of the following is not the product of acidic dehydration of ?

OH

(A) (B) (C) (D)

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CHEMISTRY Full Syllabus Test [7]

48. Exchange of ligands in complex results in colour change. In the view of the above
statement which of the following is incorrect?
(A) Co(H2O)62  CoCl42 (B) Ni(NH3 )62  Ni(H2O)62
Pink Blue Green Blue

(C) Cr(H2O)63  Cr(H2O)62 (D) FeCl2 .4H2O  FeCl2 .6H2O

Violet Blue Pale green Green

49. According to Bravais, how many of the 7 crystal systems have only two possible lattice?
(A) 1 (B) 2 (C) 3 (D) 4

50. Which of the following is a correct set of the formula & the type of the silicate?
(A) Na2Mg3Al2Si8O22 : Sheet Silicate (B) CaSiO3 : Pyrosilicate
(C) LiAlSi2O6 : Single Chain Silicate (D) Be3Al2Si6O18 : Double Chain Silicate

51. In the carbyl amine reaction, the number of moles of KOH & CHCl 3 used permole of
isocynide produced are:
(A) One mole of KOH & one mole of CHCl3 (B) Three moles of KOH & two moles of
CHCl3
(C) Four moles of KOH & one mole of CHCl3 (D) Three moles of KOH & one mole of
CHCl3

52. For two different reactions having the activation energy E a1 & Ea2, the rate constants at
temperature T1K and k1 & k2 respectively. If k1 < k2, then which of the following can never
be true for the rate constant k1' and k '2 at some higher temperature T2, for the two reactions
respectively:
(A) k1' > k '2 , if Ea1 > Ea2 (B) k1' < k '2 , if Ea1 > Ea2
(C) k1' > k '2 , if Ea1 < Ea2 (D) k1' < k '2 , if Ea1 < Ea2

53. Which of the following is correct regarding extraction of Zn?

(A) Reduction of ZnO by CO is favourable at low temperature.
(B) Zn is obtained as molten layer with slag.
(C) Reduction of ZnO by C is reversible and high temperature is required.
(D) In reduction process CO2 is the only gaseous product.

54. Compound which can show stereoisomerism:

(A) Penta-2,3-diene (B) Penta-1,4-diene
(C) 1,4-dichloro butane (D) 1,4,4-trimethyl cyclohexene

55. A certain substance A tetramerises in water to the extent of 80%. A solution of 5 gm of A in

100 gm of water lowers the freezing point by 0.6C. Then molar mass of A is:
[Kf = 1.86 K mol Kg–1]
(A) 93 (B) 61 (C) 62 (D) 63
56. Which of the following is incorrect order for the indicated property?
(A) Cr < Mn < Fe : Ionisation energy (B) I < Br < F < Cl : Electron affinity
(C) 2nd ionisation energy : C < N < F < O (D) N  > P  > O  > S  : Ionisation energy
57. Which of the following contains thioether (R–S–R) group?
(A) Cystine (B) Cytosine (C) Cysteine (D) Methionine

58. On Heating (NH4)2C2O4 decomposes as, (NH4 )2 C2O4   x  y  z  H2O
Given that, x has a distinct smell & y is used in solvay ammonia process to produce baking
soda. Then x, y, z are respectively:
(A) CO2, NH3, N2 (B) NH3, CO2, N2 (C) CO2, NH3, CO (D) NH3, CO2, CO

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CHEMISTRY Full Syllabus Test [8]

59. Which of the following is a condensation homopolymer?

(A) Nylon 6 (B) Nylon 6, 6 (C) Dacron (D) Acrilane

60. Which of the following statements is INCORRECT?

(A) BeSO4 < MgSO4 < CaSO4 < SrSO4 is the thermal stability order for group II sulphates.
(B) (SiH3)2O & H2O have the same hybridisation of O-atom.
(C) OF2 < H2O < Cl2O < ClO2 is the bond angle order.
(D) The dipole moments of chlorobenzene & m-dichlorobenzene are equal.



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