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    Champ-L8 - Practice Sess. - Question Ans. (Cordination Compound)

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    Champ-L8 - Practice Sess. - Question Ans. (Cordination Compound)

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    Champ-L8_Practice Sess._question Ans.(Cordination Compound)

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    Champ-L8 - Practice Sess. - Question Ans. (Cordination Compound)

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    ManohaR Gaherwar

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    @elviecintselsie) | CHAMP-2022 CHEMISTRY Question Practice Session TARGET : JEE (Main) 2022 NO. 08 Syllabus: Coordination Compound 1. A complex whose IUPAC name is not correctly written is Complex Name @) | FeC.H), Bis (cyclopentadienyl) iron (0) (8) | CriCeHe)2 Bis (benzene) chromium (0) (©) _| [CoCh(H;0),JCL2H20 | Tetraaquadichlorocobaiti|li)chioride-2-water (| nnes)* Tetrathiocynato-N-zincate(I|) ion 2. Match List-! with Listll and select the correct answer using the codes given below List-I(lon involved) List-il (Agent) [irene (A) [173 8M (i) | Tie), FP (B) | 5.93 BM Gi) TenNH,),F © [osm (iv) | INiH,0), 7° (D) | 2.83 BM () | (Fe(cn),I" (©) |388BM @) > BA (> Ci M> 0, W>E (B) (> B; (i) A; (i) > E ; (iv) D; (> (C) (> B; i> C; (ii) > D; (WW) > E; WA (D) (i) D; (il) > E; (i) >A (iv) > B; (VC 3. In which of the following complexes of Co, the magnitude of CFSE (Ac) is maximum ? (A) [Co(NHs)e]” (B) [CoCl|* (C) [Co(C20.)3]* (D) [Co(CN).}* 4. The correct order of matching of complex compound in column | with the properties in column II: Column! Column Il (A) | (CriNHs)6)” (P)_ | Tetrahedral and paramagnetic (B) | [Co(CN)s} (Q) | Octahedral and diamagnetic (C) | [IN(CN). (R) | Octahedral and paramagnetic (D) | INCI). (S)_| Square planar and diamagnetic (A) A>R, BQ, CoP, DoS (B) AQ, BoR, CoP, DoS (C) AR, BQ, CS, D>P_ (D) A>Q, BR, CS, DP 5. [Co(NHs)s (NO2)2] Cl exhibits (A) linkage isomerism, geometrical isomerism and optical isomerism. (B) linkage isomerism, ionisation isomerism and optical isomerism. (C) linkage isomerism, ionisation isomerism and geometrical isomerism. (D) ionisation isomerism, geometrical isomerism and optical isomerism. 10. 1". 12. 13. Column-| and Column-lI contains four entries each. Entries of Column-I are to be matched with some entries of Column-ll. One or more than one entries of Column-I may have the matching with the same entries of Column-IL Column Columnll (Molar conductance at infinite dilution) (Complex compound) @) [229 ®)_ | PUNF,)sCICE ® |e @) | (PUNHS).Ch] (C) | 404 (R) | [Pt(NHs)4ChJCl, (0) | 523 (S)_| [PtNHs)6]Cla (A) AR; BQ; CS; DoP (8) AQ; BOR; CS; DP (C) AR; BQ; CP; DoS (0) A398; BoP; C>R; D3 The type of isomerism exhibited by pentaamminenitrito-N-chromium(Ill) chloride is (A) Polymerization — (B) Geometrical (C) Optical (D) Linkage The spin only magnetic moment value (in Bohr's magneton units) of [Cr(CO)el is: How many of the following complexes. Ka[Fe(CN)e] (K) [Co(NHs)s] Cls. oo wo Nag[Co(ox)s] (mM) INi(H20)¢]Cle. (N) Ke[Pt(CN)4] (0) and [Zn(H20)s] (NOs)2 ) Number of diamagnetic complexes are An excess solution of silver nitrate is added to 100 mL of 0.01 M pentaaquachlorochromium (III) chloride solution. The mass of silver chloride acquired in grams is [Atomic mass of silver is 108] (A) 287 x 10° (B) 143.5 x 10° (C) 143.5 x 107 (D) 287 x 107 Arrange the following order in increasing order of spin magnetic moment (A) [Mn(CN)eJ < [Fe(CN)el™ < [Fe(CN)eI~ (B) [Fe(CN)e]* < [Fe(CN)e]* < [Mn(CN) 6] (©) [Fe(CN)e)* < [Fe(CN)e)™ < [Mn(CN)s (O) [Fe(CN)eJ* < [Mn(CN)s]* < [Fe(CN)e]* The colour of the coordination compounds depends on the crystal field splitting. What will be the correct order of absorption of wavelength of light in the visible region, for the complexes, [Co(NH:)6]*" , [CO(CN)e]*, [Co(H:0)s }* (A) [Co(CN)e]* > {(Co(NHs)<}** > [Co(H:0)3)* (B) [Co(NHs)el” > [Co(HsO)e]” > [Co(CN). (©) [CocHsO)x}* > [Co(NHs)sP" > [Co(CN).™ (D) [Co(CN)e]* > [Co(NHs)e]** > [Co(H-0).]** The stabilisation of coordination compounds due to chelation is called the chelate effect. Which of the following is the most stable complex species? ( Fe(CO)s) (8) [Fe(CN)e> (C) [Fe(C.0)s* (0) [Fe(H20).]* 14, 15. 16. 17. 18. 19. 20. 2. 22. 23. IUPAC name of [Pt (NHs)2 Cl(NOz)] is (A) Platinum diaminechioronitrite (B) Chloronitrito-N-ammineplatinum(|!) (C) Diamminechloridonitrito-N-platinum(II)_ (D) Diamminechloronitrito-N-platinate(|I) Which of the following options are correct for [Fe(CN).]* complex? (A) d?sp® hybridisation (8) sp°d? hybridisation (C) p= 2.83B.M (D) diamagnetic ‘An aqueous pink solution of cobalt(II) chloride changes to deep blue on addition of excess of HCI. This is because_ (A) [Co(H20)¢J** is transformed into [CoCl.]* (B) [Co(H20)<)** is transformed into [CoCl.]* (C) tetrahedral complexes have larger crystal field splitting than octahedral complex. (D) None of these Identify the optically active compounds from the following (A) [Co(en).}*" (8) trans-{Co(en),Cha]" (C) cis— [Co(NHs).Cl]” (D) [Cr (NHs)s Cl] The correct order of energies of d-orbitals of metal ion in a [Ni(CN),] is : (A) 4, =d, =d, 2d. =, (8) 4, .=d. >, =, =d,, (©) ds .>d.>4,=4, =, (0) dz 2>d, >d.>d, =, The number of geometric isomers that can exist for square planar [Pt (Cl) (py) (NH,) (NH,OH)}" is @ (A)2 (8)3 (C)4 (D)6 The oxidation states of Cr in [Cr(H,O),ICl,, [Cr(CgH,),], and K,{Cr(CN),(0),(0,)(NH,)] yridine ) respectively are (A) +3,0and+6 — (B) +3, Oand+4—(C) +3, +4 and+6 (0) +3, +2 and +4 Consider the following reaction and statements: [Co(NH,),Br,]* + B77 —> [Co(NH,),Br,] + NH, (I) Two isomers are produced if the reactant complex ion is a cis-isomer. (ll) Two isomers are produced if the reactant complex ion is a trans-isomer. (lll) Only one isomer is produced if the reactant complex ion is a trans-isomer. (IV) Only one isomer is produced if the reactant complex ion is a cis-isomer. The correct statements are: (A) (lll) and (iv) (B) (ll) and (IV) (C) () and (I) (0) (1) and (ily The oxidation state of Mo in its oxido-complex species [Mo,0,(C;H,)(H,0)3)* is (A) +2. (8) +3 (©) +4 (0) +5 Co-ordination number of platinum in [Pt(NH,),Cl,]** ion is: (a4 (B)2 (cs (6 24. The crystal field-splitting for Cr’ ion in octahedral field increases for ligands I, H,O, NH, , CN’ and the order is (A) F< H,O < NH, < CN- (8) CN < F< H,0 < NH, (C) CN < NH,

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