@ehviecittselsie) | CHAMP-2022 CHEMISTRY Question Practice Session TARGET : JEE (Main) 2022 NO. 07 Syllabus: lonic Equilibrium 1. 10. A saturated solution of CaF? is found to contain 2 « 10-4 M of F- ions. Key of CaF is: (A) 8 x10"? (84x10 (2107 (0) 10°? Calculate the degree of ionisation of 0.04 M HOCI solution having ionisation constant 1.25% 10+ 2 (A) 0.025 (0s (C) 0.25 (0) 0.055 What will be solubility of A2Xs is its solubility product (Kep) is equal to 1.08 x 107° ? (A) 10% moi, (8) 3.7 « 10 mov. (C) 1.2 « 10 mol (0) 7.5 x 10% mol. What is the pH of a neutral solution at 37°C, where K,, equals 2.5 x 10-"* ? (log 2 = 0.3) (A) 7.0 (8) 136 (68 (266 Three solutions of strong electrolytes, 25 ml of 0.1 M — HX, 25 ml of 0.1 M— HY and 50 ml of 0.1 N-Z (OH): are mixed. pOH of the resulting solution is (ay 1.6 (70 (©) 12.4 (0) 116 PH of 0.01 M — (NHs)zSO, and 0.02 M— NH,OH buffer (pK, of NH." = 9.26) is (A) 9.26+log2 — (B) 9.26 -log 2 (©) 4.74 + log 2 (0) 9.26 Separate solutions of NaW, NaX, NaY and NaZ, each of concentrations 0.1 M, has pH 7.0, 9.0, 10.0 and 11.0, respectively, at 25°C. The strongest acid among these is (A) HW. (B) HX (C) HY (D) HZ The correct order of increasing [OH/] in the following aqueous solution is (A) 0.01 M—NaHCOs< 0.01 M—NaCN < 0.01 M— KCI (B) 0.01 M—KCI < 0.01 M—NaCN < 0.01 M—NaHCOs (C) 0.01 M—KCI- 0.01 M— NaHCO; < 0.01 M—NaCN (D) 0.01 M— NaCN < 0.01 M—KCI < 0.01 M—NaHCOs Solubility product constant (K.y) of salts of types MX, MX: and MsX at temperature, T are 4.0 x 10°, 3.2 10" and 2.7 x 10", respectively. Solu! are in the order (A) MX > MXe > MaX. (8) MX > MX2 > MX (C) MX. > MsX > MX (0) MX > MX > MX The addition of solid ammonium chloride to acetic acid solution will cause (in M) of the salts at temperature, T, (A) increases in its pH values (B) decrease in its pH values (C) no change in pH value (0) change in pH which cannot be predicted" 12. 13. 14, 15. 16. 17. 18. 19. The base imidazole has a Ke of 1.0 x 10-7 at 25°C. In what volumes should 0.02 M -HCI and 0.02 M imidazole be mixed to make 120 ml of a buffer at pH = 77 (A) 60 mi, 60 mi (8) 40 mi, 80 mi (C) 30 mi, 90 ml (A) 20 ml, 100 mi How much water in ml must be added to 300 ml of 0.2 M solution of CHsCOOH (Ke for the degree of ionisation (a) of the acid to double 8x 105) Which of the following is not correct — (A) [H'] = [OH] ik, for a neutral solution at all temperature (B) [H'] = [OH"] = 10” for a neutral solution at all temperature (©)[H']> YK, and [OH] < JK, for an acidic solution (0) H* < JK, and [OH] > K,, for an alkaline solution The pH of neutral water at 25°C is 7.0. As the temperature increases, ionisation of water increases, however, the concentration of H* ions and OH" ions are equal. What will be the pH of pure water at 60°C? (A) Equal to 7.0 (8) Greater than 7.0 (C) Less than 7.0 (0) Equal to zero The ionisation constant of an acid, Ka, is the measure of strength of an acid. The Ka values of acetic acid, hypochlorous acid and formic acid are 1.74 x 10%, 3.0 x 10% and 1.8 = 104 respectively. Which of the following orders of pH of 0.1 mol dm’ solutions of these acids is correct? (A) acetic acid > hypochlorous acid > formic acid (8) hypochlorous acid > acetic acid > formic acid (©) formic acid > hypochlorous acid > acetic acid (0) formic acid > acetic acid > hypochlorous acid In which of the following solvents is silver chloride most soluble? (A) 0.1 mol dm? AgNOs solution —_(B) 0.1 mol dm? HCI solution (©) H:0 (0) Aqueous ammonia Calculate the pH of a solution formed by mixing equal volumes of two solutions A and B of a strong acid having pH = 6 and pH = 4 respectively. (A) 5 (8) 10 (C)5.5 (D) 4.3 Which of the following aqueous solutions acts as buffer? (A) 100 ml each of 0.1 M CHsCOOH and 0.2 M NaOH (B) 100 ml each of 0.1 M HCI and 0.2 M CHsCOONa (©) NHC! solution (D) None of these The total number of diprotic acids among the following is HyPOs HaSO« HoPOs H2COs HaS207 HsPO2 HeCrO«, -HaSOs HsBOs20, For the following Assertion and Reason, the correct option is, Assertion (A) : When Cu (|) and sulphide ions are mixed, they react together extremely quickly to give a solid. Reason (R) : The equilibrium constant of Cu*(aq) + S*(aq) ™ CuS(s) is high because the solubility product is low. (A) (A) is false and (R) is true. ) (B) Both (A) and (R) are true but (R) is not the explanation for (A). (C) Both (A) and ( (O) Both (A) and ( R) are true and (R) is the explanation for (A). R) are false. 24. The solubility product of X(OH), at 298 K is 6.0 « 10. The concentration of hydroxide ions in a saturated solution of Cr(OH), will be (A) (2.22 x 10%)" (B) (18 x 10)" (C) (18 x 10)" (D) (4.86 x 10)" ANSWER KEY 1 ® 2 © 3 @® 4 © & © 6&6 O 7% & (€) 9 (©) 12 @ 1. @ 12 {900} 13 [) 14 © 15. (0) 16 (0) 17 (© 1% @ 1% @ 2 () 2. ©