@elviecintselsie) | CHAMP-2022 CHEMISTRY Question Practice Session TARGET : JEE (Main) 2022 NO. 09 Syllabus: General Organic Chemistry 1. Inwhich of the following molecules all the effects namely inductive, mesomerie and hyperconjugation operate? i og ya @ s-3 oC pte of one CH 2. Ci C2 bond is shortest in 2 4 CHECH, o ° CY CH-cH, 3. The decreasing order of stability of following cation is CH i (R) 8) ()P>Q>R>S — Q)P>R>Q>S — B)Q>P>S>R_— (4) Q>P>R>S 4. The decreasing order stability of following anions is He z Gite No, cN CH ) (2) (R) (8) ()S>R>Q>P — )P>Q>R>S —G)Q>P>R>S (4) P>Q>S>R Write the order of basie strength 9 O26 H (P) (a) (R) ()Q>R>S>P (2)P>R=Q>S G)R>P>=S>Q (4)P=Q>R>S10, Which of the following is correct order of stability of alkene ? (1) CH CH= CHe\_/ XN (2) CH—CH=CH:<\_/<\= < =< @)\S/< CCH = CH KN Tautomerism is not exhibited by fo} Which among the given acids has lowest pKa value := (1) Chloroacetic acid (2) Bromoacetic acid (3) Nitroacetic acid (4) Cyanoacetic acid Rearrangement not possible in ()) CH CH, CH, (2) CHe-CH-CH-CH, OCH; Cis CH3 cl 6) O ® On Which of the following, cation will not show resonance ? Ch, oO (2) CH=CH-CH=CH-CH, @ @) @ Correct order of stability of the following species is 8 An A Add nA~0 0 a «il vy ()UeIveI=mM QM HIV I= N> MeV ay te tvemt12, Identify benzene ring which has maximum electron density ? ° © (2) (3) “CO 06K) oO “OO u u 13, Comectonderof Acie strenath ooH GooH goon oO ¢ooH 102 oO” O.. %. @ a) qu) (Iv) ()1> M+ >IV Q)1>0>I>IV G)0>IV>1>0 @IVe1> > 14, Which of the following compound has two different C-C bond lengths 8 of af} oZ\ (4) cH, -cH-CH, 15. CI-CH,-CH,OH is stronger acid than CH;-CH;-OH because of : (1) = Leffect of CI increases negative charge on O atom of alcohol (2) effect of Cl disperses negative charge on O atom to produce more stable cation (3) effect of Cl disperses negative charge on O atom to produce more stable anion (4) None of these “ANSWER KEY 1 @B) @ . Q) 4 @ 3. Q) 6. Q) 7 Q . 8 2 © &@ On OR WM Bw & @ 15. @B)