Vidyamandir Classes

Solutions - Advanced Problem Package | Chemistry

Stoichiometry-I & II
1.(D) 2CrO5 +3H2SO4Cr2(SO4)3+ 3H2O + 7/2 O2.
 2Cr 6  6e    2Cr 3 
 0 
 7O 1   7 O  7e  
 1  
 O  e   O 2 
 
2.(B) Na 2C2O 4  KHC2O 4 .H 2C2O 4
mol (a) mol (b)

With NaOH : eq of Na 2C2O 4  eq of KHC2O 4 H 2C2O4  eq of KMnO 4

2a  4b  5  0.2  V …….(i)
With KMnO4 : gmeq of KHC 2 O4 .H 2 C 2 O4 (n  3 as acid)  gmeq of NaOH
3b  1 0.2  V .........(ii)
2a  4b a  2b 5 a 11
Divide (i)/(ii): 5    
3b 3b 2 b 2
3.(C)  4KAu(CN) 4  12KOH .
4Au  16KCN  6H 2O  3O 2 

 VOCl2  3H 2O  FeCl3 .
V(OH) 4 Cl  FeCl 2  2HCl 

4KMnO 4  4KOH 
 4K 2MnO 4  O 2  2H 2O.
2
In above reaction out of 4 mol of O present in KOH (R.A) , two are oxidised to O2 and other two moles remained as
such and went to H2O.
2MnO  5PbO 2  10HNO 3 
 2HMnO 4  5Pb(NO3 ) 2  4H 2O.

x
4.(C) XeFx  H 2  Xe  xHF
2
1000
m mol of Xe   22.4  1 ; m mol of HF (n = 1) = 6  x=6
22400
2
5.(B) Ist Part meq of I2(n= 2) = meq of S2O3 (n = 1) = 15 × 0.4 ×1 = 6, m mol of I2=3
IInd Part meq of I2 reacted = meq of NaOH initially – meq of H2SO4
with NaOH = 100 × 0.3 – 2 × 10 × 0.3 = 24
24
m mol of I2 (n = 2) reacted with NaOH =  12
2
15
Total m mol of I2 = 3 +12 = 15 ; [I2] =  0.1
150

APP | Stoichiometry-I & II 1 Solutions | Chemistry

 Vidyamandir Classes

6.(D) HCN  KOH 

 KCN  H 2 O
n 1 n 1
m mol of HCN  meq of HCN  meq of KOH  100

 Mn 2   NO3  CO2
HCN  KMnO4 
n 10 n 5
V ?

As HCN used in same for KMnO4 as is used for KOH.

m mol of HCN (n = 1) = 100.
meq of HCN (n = 10) = 100 × 10 = 1000
meq of HCN = meq of KMnO4  1000 = 5 × 5 × V :  V  40 mL
6
7.(A) Mn O24  on disproportination gives MnO
4 & MnO2

[MnO 24  
 MnO4  e  ]  2

MnO24   2H 2 O  2e  
 MnO 2  4OH 
On addition, we get :
2MnO4  MnO4  2H2 O 
 2MnO4  MnO2  4OH 
3MnO4  2H 2 O 
 2MnO 4  MnO 2  4OH 
2 1
1 MnO 4 
 MnO 4 ; 1 MnO 4 
 MnO 2
3 3
RH2  Ca 2 
 RCa  2H , pH  2, H   102 M
8.(A) [Ca 2 ]  5 103 , mass of Ca 2  40  5 103 g
40  5  10 3
Hardness in ppm of Ca 2   106  200
103
9.(D) Initial mmol of KOH = 500 × 0.1 = 50
2KOH  CO 2 
 K 2 CO3  H2 O

K 2CO3  BaCl2 
 BaCO3  2KCl

KOH  HCl   KCl  H 2 O

mmol of HCl = 30 × 0.1 = 3 ; mmol of KOH left unreacted in 50 mL solution = (50×0.1) –3 = 2
millimoles of KOH in 50 mL reacted with CO2 = 2 ; millimoles of KOH in 500 mL reacted with CO2 = 20
2 mol KOH = 1 mol CO2 ; 20 mmol KOH = 10 mmol CO2
Volume of CO2 = 10 × 10–3 × 22.4 L
10  103  22.4
ppm of CO2 = 106  1000 ppm
224
10.(C) mmol of BaCO3 = mmol of K2CO3 = mmol of CO2 = 1(considering in 50 mL)
m BaCO3 197
 1000  1, m BaCO3   0.197 g
197 1000
11.(A) Fe  Fe 2 (SO 4 )3 
 3FeSO 4
1 mol 3 mol

1 mol Fe 2 (SO 4 )3 .(NH 4 ) 2 SO 4 . 24H 2O  1 mole Fe2 (SO 4 )3

2.41 2.41 3  2.41
mol Fe2 (SO4 )3 .(NH 4 )2 SO4 . 24H 2 O  mole Fe 2 (SO4 )3  mol FeSO4
964 964 964
moles of FeSO4  0.0075

APP | Stoichiometry-I & II 2 Solutions | Chemistry

 Vidyamandir Classes

12.(B) Cu  Fe 2 (SO 4 )3 
 2FeSO 4  CuSO 4
1 mol 2 mol

[Note :  only FeSO 4 reacts with K 2Cr2 O7 and not CuSO 4 as Cu is in its highest O.S ].
2.41 2.41 2  2.41
mol Fe2 (SO4 )3 .(NH 4 )2 SO4 . 24H 2O  mole Fe 2 (SO4 )3  mol FeSO4
964 964 964
moles of FeSO4  0.005
13.(C) meq of FeSO4 = meq of K2Cr2O7
 3  2.41  3 1
1    10  6   V ( n-factor of FeSO 4  1 and K 2 Cr 2 O7   6 )
 964  60
 V  75 mL
14.(AC) Cu2+ does not react with MnO 4 . Only C2 O42 will react

meq of MnO 4  meq of C 2 O 42 

1
20   5  meq of C2 O 42  25
4
m eq 25
m mol of C2 O 42     12.5
nf 2
2Cu 2  4I  
 Cu 2 I 2  I2
n f 1 n f 1/2

I 2  2S2 O32   2I   S4 O62


nf  2 n f 1

1
meq of Cu2+ = meq of KI = meq of I2 = meq of S2O32 = 25   1 = 2.5
10
2.5
m mol of Cu 2 (n  1)   2.5  Difference in mmol of C2 O42 and Cu2+ = 12.5–2.5 = 10
1
 7 
Ca  Mn O4   Mn 2 
15.(ABCD)  2
n  10
1
meq of Ca(MnO4)2 = nMV = 10 ×  100  100 meq
10
100
meq of FeSO4  n  1  1  1  100  100 meq ; meq of FeC 2 O 4 (n  3)  3  1   100 meq
3
meq of K 2Cr2 O7 (n  6)  6  1 16.6  100 meq ; meq of C2O 42 (n  2)  2  1  50  100 meq

 2Na  HPO4

16.(ABC) Na 2 HPO4 
 2

 H 2 PO4  H  

HPO24   H   H3 PO4
Base acid (n 1)
n 1

 H3 PO 4
HPO 24   2H   ;  H   PO 34
HPO 24  
(n  2) Acid
base (n 1)

meq of H 2 O 2  meq of KMnO 4

17.(BCD) w 1
 1000  1 100   w  0.34 g
34 / 2 5

APP | Stoichiometry-I & II 3 Solutions | Chemistry

 Vidyamandir Classes

In basic medium : MnO  MnO 42  (n  1)

4 

H 2 O2 
 O2 (n  2)

18.(AB) 2HCl  Ba(OH) 2 

 BaCl2  2H 2 O
120 mmol 100 mmol

L.R is HCl (Also 20 mL of water is also added)

mmol Ba(OH)2 left = (100–60) = 40
–
mmol of OH in excess = 40 × 2 = 80
80
[OH  ]   0.8 ; mmol of BaCl2 = 60 ;
mmol of Cl– = 120
100
120
[Cl–] =  1.2M ; mmol of Ba(OH)2 left + mmol of BaCl2 = 40 + 60 = 100
100
100
[Ba 2 ]  1
100
19.(ABD)
H 2O + SO3 
 H 2SO 4
18 80 98
12 80 98
12 12
18 18
= 53.3 g = 65.33 g
(100 – 53.3) = 46.7 g of H2SO4 is initially present and 65.33 g of H2SO4 is newly formed on add of 12 g of water.
H2SO4 total = 65.33 + 46.7 = 112 g
12 9 1
But on addition of 9 g of water, moles of free SO 3   
18 18 6
98
Addition of 9 g of water will produce  9  49 g of newly formed H2SO4.
18
Total H2SO4 = 49 + 46.7 = 95.7

20.(BD) 2 mol of HCO3 will make one mole each of CaCO3, CaCl2 and MgCl2 to have equal hardness
ppm of HCO3  61 2  122g in 106 mL of H2 O
1 mol of CaCO3  100 ppm ; 1 mol of CaCl2  111 ppm ; 1 mol of MgCl2  95 ppm

21.(AB) H2O is L.R.

6H 2 O 
 4Fe(OH)3
4
2 mole  2  1.33
6
22.(AB) Volume strength = 5.6 × N
NfVf = N1V1 + N2V2 + N3V3
0.5 L of each solution and 1.5 L of water makes final solution 3L
10 15 20
N final  3   0.5   0.5   0.5
5.6 5.6 5.6
N f  1.34
Volume strength of final solution = 1.34 ×5.6 = 7.5

APP | Stoichiometry-I & II 4 Solutions | Chemistry

 Vidyamandir Classes

23.(AD) 8 MnO 4  5S2 O32  

 8 Mn 2  10SO 42 (Acidic medium)
5
 1 mole MnO4 oxidisesmole S2 O32
8
Also, oxidation number of S changes from  2 to  6
In basic medium,
8 MnO4  S2 O32 
 8 MnO42   2SO 42
Change in medium from acidic to basic will change the nature of product & stoichiometry of reaction.
24.(AB) In Al2 O3  Al is in highest oxidation state of  3
CrO3  Cr is in highest oxidation state of  6

 2AO3
25.(ABC) Oxidation reaction is A 2 O n 
1.34 (10  2n)  32.2  0.05  5
n2
 Molecular formula  A 2O 2
Empirical formula  AO
Since oxidation state of A changes from  2 to  5,
 It cannot be a Group-II metal
26.(AC) Number of equivalents of acid = Number of equivalents of base
1.25
 1000  25  0.25  2  E acid  100 g
E acid
If n-factor  2, M0  200g
n-factor  1, M0  100 g
27.(AC) The hydrolysis reaction is
SO 2 Cl 2  2 H 2O 
 H 2SO4  2 HCl
5 mmol 5 mmol 10 mmol
5 mmol
M H 2SO 4   0.05 M
100 mL
10 mmol
M HCl   0.10 M
100 mL
10 mL stock solution has
10  0.05  2 10  0.10
   2 meq of acid
H 2 SO 4 HCl
2
 Volume of NaOH req.   mL
0.2
28.(C) Let 100 mL mix (A) has R and S millimoles of NaOH and Na2CO3
At Phenolpthalein end pt: a = R + S
At Methyl orange end pt: b = R + 2S
Therefore b–a=S
2a–b = R
Let 100 mL of (B) has L & M millimoles of NaHCO3 & Na2CO3
At Pthenolphtalein end point: x=M
At Methyl orange end point : y = 2M + L
Therefore L= y – 2x

APP | Stoichiometry-I & II 5 Solutions | Chemistry

 Vidyamandir Classes

29.(B) (P) – 3 eq of Fe2(C2O4)3 + eq of FeC2O4 = eq of KMnO4

2.5 × 6 + 2.5 × 3 = 5 × x
x = 4.5
(Q)–4 eq of Fe2(C2O4)3 + eq of FeC2O4 = eq of K2Cr2O7
2.5 × 6 + 2.5 × 3 = 6 × x
x = 3.75
(R)–2 eq of CuS + eq of Cu2S = eq of KMnO4
2.5 × 6 + 8 × 2.5 =5×x
x=7
(S)–1 eq of KMnO4 + eq of K2Cr2O7 = eq of H2O2
2×5 + 2×6 =x×2
x = 11
30.(C) Reciprocal of n-factor is the molar ratio.
(P)–2 FeC2 O 4  Cr2O72 
 (Q) –4 H 2 O2  Cr(OH)3 

n 3 n 6 n 2 n 3
Molar Ratio of RA to OA is 2:1 Molar Ratio of RA to OA is 2:3
(R) –3 N 2 H 4  Cu(OH) 2 
 (S) –1 C2O42  MnO4 
 MnO2  CO2
n 6 n 2 n 2 n 3
Molar Ratio of RA to OA is 1:3 Molar Ratio of RA to OA is 3:2
31.(D) (P) –3 N 2  3H 2 
 2NH 3
5 mol 9 mol 6 mol

x
L.R is H2, % yield is 80. Therefore, moles of NH3 produced,  100  80, x  4.8
6
(Q) –1 2C  H 2   C2 H 2
12 mol 5 mol 5 mol
x
L.R is H2, % yield is 70. Therefore, moles of NH3 produced,  100  70, x  3.5
5
(R)–2 P4  5O 2  2P2 O5
5 mol 20 mol 8 mol
x
L.R is O2, % yield is 50. Therefore, moles of P2O5 produced,  100  50, x  4
8
(S)–4 2SO 2  O 2 
 2SO3
4 mol 3 mol 4 mol

L.R is SO2, % yield is 75.

x
Therefore, moles of SO3 produced,  100  75, x  3
4
7 1 0
32.(5) 2 K M nO4  16H Cl 
 2KCl  2MnCl2  5Cl 2  8H 2 O
2 mole of KMnO4 gained 10e–.
Therefore 10 mol of HCl has lost 10e– .For this to happen 10 mole of HCl is acting as reducing agent. So for per mole
of KMnO4 5 mole of HCl as RA is required.

 3n  4   2n  4 
33.(4) CH 3 (CH 2 ) n COOH    O 2 
(n  2)CO 2    H 2O
 2   2 
1 mole of acid = (n + 2) mol of CO2.
0.58 n2
mol of acid   0.58 mol of CO 2
60  14n (60  14n)

APP | Stoichiometry-I & II 6 Solutions | Chemistry

 Vidyamandir Classes

This CO2 is passed through excess of NaOH where CO2 is converted to Na2CO3 and some NaOH is left.
With Phenolpthalin Na 2 CO3  HCl 
 NaCl  NaHCO3
meq  a

NaOH  HCl 
 NaCl  H 2 O
meq  b

a
 b  50  1 ........ (i)
2
With methyl orange Na 2 CO3  2HCl 
 2NaCl  H 2 O  CO 2
meq  a

NaOH  HCl 
 NaCl  H2 O
meq  b

a + b = 80 ........... (ii)
From (i) to (ii)
a(Mg of Na2CO3) = 60, b(meq of NaOH left) =20
meq of Na2CO3 = meq of CO2
(n  2)0.58
60 =  2  103  n  4
60  14n

34.(9) 2IO  
3  10I  12H 
 6I2  6H 2O
2mol IO3 
 6 mol I 2 ; 1 mol IO3 
 3 mol I 2
0.27
% yield   100  9
3
0 5 2 1
35.(1) 4 M g  10H N O3 
 4 M g(NO3 )2  N 2 O  5H 2 O
4 mole of Mg required = 2 mole of HNO3 as RA
2 mole of Mg required = 1 mole of HNO3
36.(0.82) Reaction Change in ON
Sn 2 
 Sn 4  2e  2 units

Fe2  
 Fe3  e 1 unit

Cr2 O72   6e 

 2Cr 3 6 units
Thus, 0.04 M Sn 2   0.08 NSn 2 
x M Fe 2  x N Fe 2 
0.125 M Cr2O72  0.125  6  0.750 N Cr2 O 72 
Equivalent of Fe2   Equivalent of Sn 2   Equivalent of Cr2 O72 
15  0.08 15x 18  0.750
 
1000 1000 1000
1.2  15x  13.5  15x  12.3  x  0.82 M
2
37.(1.75) Fe is 1.0 ppm
Thus, 106 g solution has Fe2   1g
250
250 mL ( 250g) solution has Fe2   g (Note d  1g / mL)
106
56 g of Fe2  is in  392 g salt

APP | Stoichiometry-I & II 7 Solutions | Chemistry

 Vidyamandir Classes

250 392 250

 g of Fe2  is in   g  1.75 103 g
6 56 106
10

38.(200) RH 2  Ca 2  RCa  2H 
1 mol 2 mol
? 0.01mol L1

When [H  ] is 2 mol then, [Ca 2  ] is  1mol

0.01
When [H  ] is 0.01 mol then [Ca  ] is  mol L1
2
 [Ca 2  ]  0.005 M  0.005  40 g L1  0.2 g L1

1000 mL of water has [Ca 2  ]  0.2 g

0.2  106
106 mL (parts per million) has [Ca 2  ]   200
103
39.(3.12) Given reaction is not balanced
Based on stoichiometry
1 mol Na 2CO3 is from 2 mol NaHCO3
2 mol NaHCO3 is from 2 mol NH 4 HCO3
2 mol NH 4 HCO3 is from 2 mol NH3
Thus, 1 mol Na 2CO3 is form  2 mol NH3
106 g Na 2CO3 is from  2  17 g NH3
34 g NH3 gives  106 g Na 2CO3
106 1000
Thus, 1000g NH3 gives  g Na 2 CO3  3118g Na 2CO3  3.118 kg Na 2 CO3
34
40.(44.25) 2 moles Na 2CO3 give  4 moles NaNO 2
0.3375 mole Na 2CO3 gives
 2  0.3375  0.6750 mol NaNO 2
 0.6750  69 g NaNO2
 46.575g NaNO2 with 100% yield
 46.575  0.95g NaNO 2 with 95% yield  44.2462 g
41.(1.104)
Na 2SO 4  2Na 
  SO42 
1 mole 2 moles 1 mole
Na 2SO 4  6.0 micromoles  6.0 106 mole
 Na  ions  2  6.0 10 6 mole  2  6.0 10 6  23g
In 250 mL solution (250g H 2 O being dilute solution)

250 g H 2O has Na  ions  2  6.0 10 6  23g

2  6.0 10 6  23  10 6
106 g (per million) H 2O has Na  ions   1.104 g  1.104 ppm
250

APP | Stoichiometry-I & II 8 Solutions | Chemistry