Chemical Bonding 1

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polemoment anod ds appleatos

diatommc moleade;
-

pole momenl fe paty


polar dwatomu'e
The dipole moment f a

molecale odmct o Charqe v ecCh erd Yl.

estane betiton le Conbu f eY


molecade and
b ed lcng
For a
polay datmic molecde AB,
Qton me elechvnegat e aN A
SSo 93uí Choge ov A,
meYlale.enCe dipele
Charqe v B.of
AB g t n by
mment U moleade
ov lle ends df mel'cale
ue mole'ule

At dpelom omentL TLe


L Charqe
and a
Duall drf
A°), murot
be
ef
dev vde f 8n ( 1 Debye.
TVue Calle
l 1o"°esm.cm

dipols moment
S 1 Debye
a
=

Velto anth
C . ha Tpreoente)
has ball
n
irchm
- e end f'Li mlo L
aqnitud

Printing fom t e end


A 9 Poluatomc moloawes
lyatonicmele Cl
2D polemment of mrre 2 atoms), eve
t bmded atos
C Containi nq
bond mment Te Calle
kanc
havC eddipelsmoment hu
LT Polyatmic mele de
e t diþelamment f
olffectat bend momens
Tioultant o Comicel Constthtian)
( Dypulomoment &
Applecahov D:polo mmert
fmolotndes
Jn Cmbaring telatve Polart'eo ofh
D.M HEH, HBY &H9 a e 2L 1-03, o.78 80 38
Shis Wat U pelar Checace abore kydroge, hal'
T
deccaneo fm HE to H9
bend
2) n Celud atn q iondc Charace af a þolar Crales
EX HC: Athual DM t Hcl 1.03 D by cxpt)
94 bond bet H ar C HC lco/, dondt
Le
en each end moloade ll ac9jure fll oe
Carq ( 4.8xlo esu Te brnd distano n HCI=:27A0,
kn) hare ber
So c HC r e 100, emu's, de pelomoment
P=4Sxj°uX (1:275 x jo8
=
6 |lXloezu
= 6.11 Dabye »
ionic Chcvacter fHcl bnd= ; t D,M 1d
TKerctiCal
DM

Ca HCI
A-6316D16.9
16.9. ori S3.17reu
ind us dmic Characler H-F bmd
(D.Mo HE= 198 D , B lop HF =092
Trerecticel D.M 9d h 8 xioex 092xio442D
7. ton'c Chersck4 H b .98D
44-8.

Dipalbnament an Stochure_f Le moledes


ay Di atomic moledy! 9rrespe ctir of Y D.M, ana
di alom c moln aleD @re

Tr etomc maleCade Moleal e CO, &Cs, ame


ILay are unear
han Ze depelamret
o==o?

Cmieale, bo| Cadon-ygen bends


ara
pelar B4ars
L apale mnment C=o bmd w
mdscade n e a r
de i mleade j CsACell)
ndecd e g t p n e t o l :polemment 3mle s ur Can l
So2S02 mde shapa&dt hao depela mment
40 meleade e V
For ho N=-84Db & f S02, lo=| 63D
The Kde msleale V-phapD a phoa kacr.

t O-4 bmdo au þolar & ley


loly.s0,
eata
ae acline at a angte
ta 0-H bord momen Kao acanlttn DM 890
Siae.
Smad E hes e Tumltan D.M
S-0 bmd mamens S0
mule olar
letre ctomic noletude L4. u47
a) D.M t BEZeso a Kt
rte B bmdo
BXa a pynmer caltmCurt TTe krce brds he
126 brd s Can
to 0me anolk
dretated at an; goq oof ene N anolb g
tone Plane a
net depolemoment e a l t
Re bond mom e O
Ca
NmolecJekeo Pyram'dalAmocture
9n meleade Unes s
re AN
a teDultant D.M
N-4 bond mmenb fr
mlecade pilar H/ H
hCh
pala -84D
Similarb PFa& Pcls are also
deftntD.y
a tey kase
d)Penta atom molocede T D.M CH4CClySClS e
e e moleGdes hare Aymmetr cal jZncHoc
Tt because ihck es
L dif bmd mmenb Canlel a t each ohe,
anod
Teputaat D.M Za
Ht

0
also tetrahedrad Abnctsta
CCA moleale h
be cause Aom ctur
but its drpalomament o not as
bmdg a e
ymmeriCal D.M C-H&C-CA
ot eqhLal.

X
epiztng
TFe orces f ctreCtian *
IntermdleCulay orces: 2ub3tante gases, u g u s
molecdes a cr
Cchesive foreS
Omong
among arcea
olled
termalecla o l e ra
ole Cteng
r a (renf.

orSolucds) are
IEve
Eves m
ma yþes
ain
n t
ce'gi nate fom
)Dpole- induted dpclepele
These
hese Jerces Dpele- indutec
dpole
n t e r a Ctan induted dipele
dipcle
)Bipcle- induted d pcle-
t e raCtan
and () (n)
interacRon
) Dipole-d ple interacH n inle ra Cton
2ipcle-d:psle
etr

moleCdes &ke NH, So,, HE fiC ferce


Jer
n Case f pola P c l e s , d e r mole
Ls orter Cula
moleCila
OkCh haNe
nawe peTmanent
enteracton
h
betiten
betrten
electiCal
are manly due to
Ond
Onct ue
negtive ale Le
negctive Pale
mcleCude
one
Postve pele ef iteraCtoo
ano di pole
OLes molecle
inter octon. TThe dpcle-
a b e r . el14 maqnitube
maqntude
d pele- d'pole arr
abevt.
hobn u n d p c l emenevls
molecdes depends momAris
pcle
amn 9 HC dthis upon
f
interocton
t dipol menl
momenl
dipole me
i s pe oecte t
CanceTnedThe
To: Uas
molecules intera Ct'on Aie
Cl t dpele- d:pole
u qreater oND at
caaly kqafice
pe irteroctton U 9e) 1
inte raCtÉon eneray
The ave req
dpede
mements Mre
Cut Permanent
tu molecides

ven by
e expression
Trtera Ct'on enera d
2/M ) GT
betceen teo meleales
eve ' di stance ui
pemitivrl
e is
Boltzmaon's Cmstant,
k
facto T med um. b n ding i a Special k f
Hydvgen
Hydavgn
d intera C t .
dpole- pole

1 H
(2
Acccu
cecuYg i n molecdes Cerlaininq ehydwgen alt
unce by a Covelenl bond toa hiqhly elechtneqatr
atam Ko EO ano N. Because f ie arge electenegatv
betwee
dffeverCe toH-atom gr e higkl, elechnegatvr atm
T Cha rge developcav H-atom on Carg
elechomegate a m , T Po24ire eno
developed Cn e

atlrocs lo ne9at ve er f CILe mcleGlej


One nole Cde meatroned
Becaustf qrecte
greate Polare ly Le abare
iv eDe Cases La iter roleaJar foces
molecule3
od'ract'o B s o n q er. a n Li troercry d bele-dpole
t t v s aCtton .

d. pole inle raction


t pole- induced
The PoStive end f
PolaY mol e Cul e may
ollract u elecsav foYce f nduced dpele
Pernanenl atire Cttcn\
a nan -polGv
Cloud
Ckc lies pale) a t rcCtton beTueen
mole cl For Ces t
venl and Pevman end d bole and indu Ced de pole
al
induce Polanty i ten interacts i
mole cde. t in duted dbele
frst mole aJe and erbu tur odec-Jes
torards Te maqnefuude 1S
attre ct e)
Ue maqn tude cy
interacton depends upon
aay moleGale and d polenzebil
di pelemom enT
tt Nc-Polav mdecA energy er l
average nteraCtrn

tKD m ale Caue A 2-


X) =
2M
Jatevackm ener 6
T
Loteve l e Pevmcneal dpele mvemenl
moleGle 1 and l llo pelavzebrkt e m
I Secend moleciJe ane lt i

dslance betueen tL tad molecedes


Induced depale-Jnduced dipole interactons
Londen Jorces CY d'spekve foce)
R noW &C Knou Knt vancey Waal's forces exisi
2vev nn-palar diatomic molecdes Like Oz adN2, end
also iv nn-Polas d manoctomik molecde CEe H,NAret
Tho
To altraCon eederd from U Condensatom ef tese
bressure en
ga9es into liquids
at ffcienty
Lo temperatur ppo sed

key 'are tesmo Lende


by F. Lndon i 1930 for otch
Accarding to Londdn edectrs ef a nm-polor
farces
molecde Keap n QClateng k resfectto nucle f Ke afans.
As a Yesult of kes, at agiven enstont postve CCKg
may be Con centated Vin One regon and neqdt v

Cha
ChaTge i an oeY e qi'on ftBame molecde.
a nn-Þolay molecle nay become momertarely
Selk-Polanised Tis pelansed mole ade may ndnce a

dple ènom eht iN a netgkbaurung mdecle

Avengeherg / Lndu ce depole.


deshi buton v a
non-polar moleCde .
nduced dpele
teraCkw
T ele ctro8tact foces q cthactn betucon indute
d-poles and Onginel dipole C due to electoon icrlatin)
are Len den dorces TKese oces are also alled

disberive orces
o Pafadjaent moleades
ondon forCes ma vary nversely as u AixIK Þower
distance Betwee n m 9e
Fd
le apozènate nte racton enev i Caoe
3EE2
2CE+E)/
E ono E ave tonZctiom energiea flz tav'moleCuJes
Form No.- S.10 SECRE
2nd&SUBSEQUENT PAGES Page No-

(QUESTIONPAPER)
3RDCOPY
(TO BE USED AS SECOND PAGE AND SUBSEQUENT PAGES)

Unit Question Please write within the space provided


Mark
Chapter SI.No. allotte

EIRylene
H
P
.State) IS as
n h yb r i l s e

2P
3phybmdi sat'en

H
)Cvela Seetap

Katlene:
2S

t nhybrid:'sed

a T

berzent 6 -ekchn
clou

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