Remedia: The Safest and Simplest Way To Destroy Dioxin

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remedia

R E M E D I A™ D / F C A T A L Y T I C F I L T E R S Y S T E M

The safest and simplest way to destroy dioxin.


The Safest and Simplest
Technology for Dioxin Control

W. L. Gore & Associates, the leader in filtration technology,

now brings you a revolutionary way to meet dioxin and

furan emission regulations. Now you can destroy gaseous

“ The REMEDIA D/F


dioxins and furans simply by installing new filters in your
catalytic filter system proved to

be the simplest solution to our


baghouse.This innovative system is effective and cost-
dioxin problem.The worldwide

team from Gore provided efficient—without requiring process changes or adding costly
superior service.


Operating Director,
new equipment. Safer for the environment, safer for
Crematorium

employees, simpler to use, our REMEDIA™ D/F catalytic filter

system is the safest and simplest way to destroy dioxin.

MEETING THE DIOXIN CHALLENGE for non-compliance, it’s more important


The threat of dioxins is drawing increasing than ever to avoid the risks associated with
attention around the world. Governments inadequate dioxin control.
are phasing in tougher dioxin restrictions, Now, a safe and simple solution is
and reports about dioxin levels in food available. Gore’s REMEDIA D/F catalytic filter
products have generated widespread system helps you efficiently meet dioxin
concern. Issues related to dioxin emissions emission requirements without the burden
and disposal are moving up the environmental of costly new equipment. It offers a broad
agenda. With heightened public awareness, range of benefits unmatched by any other
stricter regulations, and potential penalties dioxin control technology.
REMEDIA™ D/F CATALYTIC FILTER SYSTEM AN INNOVATIVE APPROACH
Combining the principles of surface filtration and catalysis. TO DIOXIN CONTROL
Here’s how the REMEDIA D/F catalytic filter
system works: the GORE-TEX® membrane
RAW GAS CLEAN GAS captures fine particulate on the surface of
Furan CO2 the filter. As the filter is cleaned, solids are
Dioxin CO2
O2 released from the surface and collected in
H2O
O2
Dioxin
Airflow the bottom of the baghouse hopper.The
HCl
O2 O2 CO2 gaseous dioxins and furans pass through the

Particulate H2O GORE-TEX® membrane into the catalytic felt.


Matter (dust) Furan
Dioxin The catalyst instantly reacts with the dioxin

GORE-TEX Membrane
®
Catalyst/ePTFE Felt and furan molecules to convert them into
Surface Filtration Catalytic Filtration
insignificant amounts of CO2, H2O and HCl.
Making the move to single-step
destruction of gaseous dioxins and removal
ELIMINATING DIOXIN IS A BREEZE laminated to a catalytic felt substrate. of particulates is easy. Simply replace your
WITH REMEDIA D/F FILTERS

A leading and proven filter technology, existing filter bags with REMEDIA D/F
Combining the principles of surface filtration GORE-TEX membrane is widely used to
®
catalytic filters. No process changes are
and catalysis, the REMEDIA D/F catalytic filter control and collect particulate matter in required—no additional equipment,
system is a unique dioxin control alternative industrial applications. procedures or worker training are needed.
that works in your existing baghouse to Using a patented process, catalysts, Since the REMEDIA D/F catalytic filter
destroy gaseous dioxins and furans to levels consistently proven to destroy gaseous system is a passive control technology that
far below regulatory limits—safely, dioxins, are combined with PTFE to form operates continuously, it offers reliable,
economically, and with minimal maintenance. a coherent catalytic fiber.The resulting consistent performance unequaled by any
The REMEDIA D/F catalytic filter system catalyst/ePTFE fiber is needlepunched into other alternative.The REMEDIA D/F catalytic
consists of GORE-TEX membrane, an
®
a RASTEX ePTFE scrim to create the
®
filter system also offers low maintenance and
expanded polytetrafluoroethylene (ePTFE), felt substrate. better filter cake management.

REMEDIA D/F
Catalytic Filter System
NO MAJOR MODIFICATIONS

NECESSARY The REMEDIA D/F Waste Heat


Boiler

Acid Gas
Catalytic Filter System works in your Dry Adsorption
existing baghouse, providing dioxin
Baghouse
destruction without process

modifications or changes to your


physical plant. Incinerator
The Total Dioxin Solution
for Industry and the Environment

The REMEDIA™ D/F catalytic filter system environment—both gas and solids—by more
offers substantial benefits over sorbent than 90 percent.
injection systems and other dioxin control
technologies. Lower disposal costs. With no dioxin-
contaminated sorbents to dispose of, the
Destroys dioxins. Unlike sorbent-based REMEDIA D/F catalytic filter system
systems such as powder activated carbon minimizes the cost of hazardous waste
(PAC), the REMEDIA D/F catalytic filter disposal. It addresses concerns about existing
system does not merely move dioxin and or future landfill restrictions on the amount
furan molecules from the gas stream to the and toxicity of sorbent levels in fly ash.

“ I am very pleased that


solid residue stream—it destroys them. Reducing hazardous waste disposal with the
we are eliminating almost all of Compared to sorbent-based systems, the REMEDIA D/F catalytic filter system also
REMEDIA D/F catalytic filter system demonstrates your company’s commitment
our dioxin/furan emissions using
decreases total release of dioxin to the to environmental protection.
the REMEDIA D/F catalytic

filter system, rather than simply

transferring the material from REMEDIA D/F CATALYTIC FILTER SYSTEM


The only dioxin abatement technology with all of the following benefits:
the flue gas to the solid residue

stream, such as with activated


BENEFIT Sorbent Catalytic Carbon REMEDIA D/F
Injection Reactor Bed Catalytic
carbon.


(e.g., carbon) (e.g., SCR) Filter System

Meets PCDD/F emissions regulations ▲ ▲ ▲ ▲


President and CEO, Medical
Waste Incinerator Destroys gaseous PCDD/F ▲ ▲

Provides dust control ▲

Reduces PCDD/F total emissions


▲ ▲
to the environment

Passive system—low maintenance ▲ ▲

No need to purchase

new equipment

Uses existing facility footprint ▲


AFFORDABLE TO OWN The REMEDIA D/F catalytic filter system provides an unmatched Reduces corrosion. The lower operating
combination of benefits and value. temperatures required with other dioxin
control systems can cause corrosion in your
baghouse. Since the REMEDIA D/F catalytic
Total Cost of Ownership of a Dioxin/Furan filter system works at higher temperatures,
Control Technology Over a 15-Year Period there is less chance of corrosion.
$
Long product life. Made of a
catalyst/ePTFE fiber, the REMEDIA D/F
catalytic filter system has high mechanical
strength and durability. In fact, system life can

Catalytic Sorbent REMEDIA D/F Catalytic


be expected to exceed five years—ensuring
Reactor Injection Filter System savings well into the future.

■ Purchase Price
■ PCDD/F Control Operating & Maintenance Cost
Efficient dust control. The GORE-TEX®
■ Dust Control Operating & Maintenance Cost membrane’s microporous structure filters

dust—even submicron particles. By capturing
fine particles it reduces total emissions of
toxins, such as trace heavy metals, to the

Easy to get started. No new capital Safer for employees. Carbon-based atmosphere.

equipment is required. REMEDIA D/F filters systems create a risk of baghouse fires.
work in your current baghouse so you can Hazardous carbon dust, especially when it is Flexible baghouse operation. The

optimize your existing assets. No change in contaminated with dioxin, also puts operators microporous structure and smooth surface

your current process is needed, and your at risk. With the REMEDIA D/F catalytic filter of the GORE-TEX® membrane make it easy

facility’s footprint remains the same. system, avoiding carbon eliminates the risk of to clean, providing better dust cake

fires and minimizes potential health risks. management.The resulting pressure drop can

Easy to operate. The REMEDIA D/F lead to increased production, more stable

catalytic filter system is a passive operation, Efficient dioxin removal. With sorbent- operation, and energy savings.

continuously destroying gaseous dioxins and based systems, cooling of the flue gas is
furans while in operation. With no additional often required to maximize dioxin removal
equipment to operate, ongoing maintenance efficiency.The REMEDIA D/F catalytic filter
demands are kept to a minimum. system operates at temperatures up to
260oC. Because no cooling is necessary, no
additional equipment or system modification
is required to cool the flue gases.
A TESTED AND PROVEN the REMEDIA D/F catalytic filter system were
TECHNOLOGY significantly lower than those achievable using
Since 1995, Gore has performed more than a PAC system.The results are impressive.
200 polychlorinated dibenzo-dioxin/furan Total dioxin and furan emissions to the
(PCDD/F) measurements in combustion environment—including release of both gas
facilities around the world. In addition, more and solids from the baghouse—were reduced
than 700 REMEDIA™ D/F catalytic filter more than 90% compared to PAC systems.
samples have been tested in more than 70 These results are consistent with

“ The best thing about facilities, including municipal waste incinerators, numerous tests performed in both full-scale
as well as crematoria, pyrometallurgical plants, systems and pilot test programs.Tests were
REMEDIA D/F catalytic filters is
and cement kilns burning hazardous waste. conducted at temperatures ranging from
that the system destroys dioxin Specifically, tests of the REMEDIA D/F 180 o to 250 oC and at filtration velocities
catalytic filter system at a full-scale municipal varying from 0.8 m/minute to 1.4 m/minute.
instead of simply capturing it.
waste combustor burning 200 tons of waste Within these ranges, the REMEDIA D/F
There were no changes to our per day yielded dioxin emissions well below catalytic filter system is designed to perform
the required level of 0.1 ng (TEQ)/Nm over 3
with the same efficiency and reduce
process or equipment. In addition,
a three-year period. Raw gas concentrations emissions of dioxins/furans to below
no operator is needed after these of dioxins and furans were measured to be 0.1 ng (TEQ)/Nm3.
between 2.9 and 5.9 ng (TEQ)/Nm3, with At facilities operating under good
filters are installed.


Plant Manager, Municipal
subsequent emission concentrations as low
as 0.002-0.04 ng (TEQ)/Nm —substantially3

below the required 0.1 ng (TEQ)/Nm3 level.


combustion practices—a typical inlet dioxin
concentration below 10 ng (TEQ)/Nm3—
the REMEDIA D/F catalytic filter system is
Waste Incinerator
Furthermore, analysis revealed that the designed to meet and exceed dioxin
concentrations of dioxin in the fly ash using regulations.

PROVEN RESULTS Field tests over a long period of time confirm that the REMEDIA D/F Catalytic Filter System
efficiently controls dioxins and furans below regulatory requirements.

Full Scale Municipal Waste Incinerator


REMEDIA D/F filters installed REMEDIA D/F filters installed in
in first of 3 compartments

remaining 17 compartments

6 0.5
▲ ▲
5.9 5.9 ▲ Raw Gas (Gas Phase PCDD/F)
5 0.4
[ng (TEQ)/Nm @ 11% O2]

[ng (TEQ)/Nm @ 11% O2]

■ Clean Gas (Gas & Solid Phase PCDD/F)



PCDD/F Concentration

PCDD/F Concentration

4.7
4 ▲
Clean Gas

4.1 0.3
Raw Gas
3

3

3

2.9 0.2
2 Compartment Data Stack Data
0.1
1 .004 .002 .011 .037 .002 .025 .006 .023 .02 .02

0 0
3 8 13 16 18 21 25 28 32 35
Months in Use
“Compartment Data” represent 3-hour measurements directly before the baghouse (raw gas) and after the baghouse compartment (clean gas).
“Stack Data” represent measurements in the stack (clean gas).
All measurements were conducted according to the Euro Norm EN 1948. After destruction efficiency was quantified, raw gas readings were discontinued.
PROVEN RESULTS Emissions data from a variety of full scale applications confirm that the
REMEDIATM D/F catalytic filter system controls dioxins and furans below regulatory requirements.

Full Scale Systems


Stack Emissions
0.1

“ There will likely be


Dioxin Concentration

0.08
0.072 increasingly stringent regulations
[ng (TEQ)/Nm3 ]

0.06
0.054 governing the release of dioxin
0.042
0.04 to the environment and
0.021
0.02 REMEDIA D/F catalytic filters
0.012
0 will help facility operators meet
Municipal Municipal Medical Crematory 1 Crematory 2
Waste Waste Waste Germany Germany these requirements while
Incinerator Incinerator Incinerator
Belgium Japan USA
utilizing their existing baghouse.

It’s also beneficial that—in

addition to controlling dioxin—


Gore: A Trusted Name
REMEDIA D/F catalytic filters
W. L. Gore & Associates is a worldwide industrial smokestacks, customers rely on the
effectively collect particulate
leader in providing high technology solutions consistent performance of Gore filtration
for demanding electronic, industrial, medical and separation products. matter.
and fabric applications. Gore is a global
manufacturer with worldwide sales and service.
In order to keep up with environmental
regulations and evolving customers’ needs,
” Technology Manager,
Our innovation and technical Gore has pushed the frontiers of traditional Pollution Control Equipment
accomplishment in the application and use filtration and separation technology. Catalytic Manufacturer
of fluoropolymers, particularly PTFE, has processes yield higher purity output with
resulted in the development of thousands less by-products and reduced environmental
of diverse products. hazards.The microporosity, cleanability, and
As the pioneer in the use of expanded non-particulating properties of PTFE,
PTFE membrane technology for filtration, combined with the chemically reactive
Gore benefits from more than 25 years of properties of catalysts, provide particular
experience in particulate control. Expanded value in applications like fuel cells and
PTFE’s inherent strength, chemical inertness, industrial filtration.
thermal stability and microporosity make it a Now the REMEDIA D/F catalytic filter
versatile, highly efficient filter media. From system, the first in a series of catalytic
vents and adsorbent modules to cartridges filtration products, is transforming the future
and filter bags, whether capturing of filtration and toxic emissions control.
contaminants in computer disk drives or
Learn More About REMEDIA™ D/F
Catalytic Filter System
www.gore.com/remedia
To find out if the REMEDIA™ D/F catalytic filter system is right for your facility, contact your
local sales representative.

France: Korea: Taiwan:


W. L. Gore & Associés Sarl W. L. Gore & Associates W. L. Gore & Associates
Z. I. De Saint-Guénault (Korea) Ltd. (Far East) Ltd. (Taiwan Branch)
4, rue Jean Mermoz 12F, Chong Kun Dang Building 4F, No. 136
91031 Evry Cedex 368 Chungjungro–3 Ka Sec. 3, Nanking East Road
FRANCE Sudaemoon-Ku Taipei,Taiwan
Tel: +33 (0) 1 60 79 60 79 Seoul 102-103 REPUBLIC OF CHINA
KOREA Tel: +886 2 8771 7799
Germany: Tel: +82 2 393 3411
W. L. Gore & Associates GmbH UK (Scotland):
Wernher-von-Braun-Str. 18 Benelux: W. L. Gore & Associates (UK) Ltd.
Plant 1 W. L. Gore & Associates B.V. Heather Park
D-85640 Putzbrunn Pettelaarpark 64A Kirkton South Road
GERMANY 5216 PP ’s-Hertogenbosch Kirkton Campus
Tel: +49 (0) 89 4612 0 THE NETHERLANDS Livingston
Tel: +31 (0) 73 687 2444 West Lothian, EH54 7BT
Japan: SCOTLAND
JAPAN GORE-TEX INC. Sweden: Tel: +44 (0) 1506 460123
Business Operations Center W. L. Gore & Associates
1-42-5 Akazutsumi Scandinavia AB USA:
Setagaya-Ku Box 268 W. L. Gore & Associates, Inc.
Tokyo 156-8505 S-431 23 Moelndal 101 Lewisville Road
JAPAN SWEDEN P.O. Box 1100
Tel: +81 (0) 3-3327-0011 Tel: +46 (0) 31 706 7800 Elkton, MD 21922-1100
USA
Tel: +1 410 392 3300

REMEDIA™ D/F CATALYTIC FILTER SYSTEM*

Fiber content Staple – GORE-TEX®


Expanded PTFE/catalyst
Scrim – RASTEX®
Expanded PTFE fiber

Felt construction Supported needlefelt

Membrane surface GORE-TEX® ePTFE

Continuous operating temperature 500°F / 260°C (maximum)

Surge temperature 525°F / 274°C (maximum)

Acid resistance Excellent

Alkali resistance Excellent


* All specifications are subject to change without notice.

©2000 W. L. Gore & Associates, Inc.


GORE, GORE-TEX, REMEDIA, RASTEX and designs are trademarks of W. L. Gore & Associates, Inc.
Printed in Germany

4-323-016E 10/00

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