Advanced - Paper - 2 (Q)

CRONOS(T-4)ADVANCED-P-2 (19.09.
2021)
PART – A (PHYSICS)
SINGLE OPTION (5 QUESTIONS)
1. A uniform electric field of 400 Vm -1 is directed at 450 above

y (cm)
the x – axis as shown in the figure. The potential difference
(0, 2) A
VA – VB is given by
(A) 0
(B) 4 V 450 B
(C) 6.4 V x(cm)
(3, 0)
(D) 2.8 V
2. A parallel plate capacitor C with plates of unit area and separation d is filled
d
with a liquid of dielectric constant K = 2. The level of liquid is initially. C
3
d R
Suppose the liquid level decreases at a constant speed V, the time constant d/3
as a function of time is
6  0R (15d  9Vt)0R
(A) (B)
5d  3Vt 2d3  3dVt  9V 2 t 2
6  0R (15d  9Vt)0R
(C) (D)
5d  3Vt 2d2  3dVt  9V 2 t 2
3. A parallel plate capacitor of capacitance C is connected to a battery and is charged to a potential difference V.
Another capacitor of capacitance 2C is similarly charged to potential difference 2V. The charging battery is
now discounted and the capacitors are connected in parallel to each other in such a way that the positive
terminal of one is connected to the negative terminal of the other. The final energy of configuration
3 25 9
(A) zero (B) CV 2 (C) CV 2 (D) CV 2
2 6 2
4. The figure shows two identical parallel plate capacitors connected S

to a battery with switch s closed. The switch is now opened and the
free space between the plates of the capacitors is filled with a B
A
V C C
dielectric of constant 3. The ratio of the total energy stored in both
capacitors before and after the introduced of the dielectric is
5 3 5 2
(A) (B) (C) (D)
3 5 2 5
5. A conductor ABCDEF, with each side of length L, is bent shown. z

It is carrying a current I in a uniform magnetic induction B, parallel B
L D
to the positive y direction. The force experienced by the wire is
(A) BIL in the positive y – direction C
(B) BIL in the positive z - direction
(C) BIL in the positive y – direction F
E
(D) ZERO y
O
B A
CHAMP SQUARE, Sunrise Forum, 2nd Floor (Debuka Nursing Home Lane), Circular Road, Ranchi – 834 001, Ph.: 73600 16500
CRONOS(T-4)ADVANCED-P-2 (19.09.2021)
PARAGRAPH (6 QUESTIONS)
Paragraph for Question 9 to 10
Read the paragraph carefully and answer the following questions:

A hollow cube of side L has two parallel sides conducting and remaining four sides are L
non-conducting. It is filled with a liquid of dielectric constant k. A small hole of area A at
the bottom of the cube is opened at t = 0 and liquid starts leaking through it. The two
conducting sides are connected by a battery of emf .
18
(Take: L = 9 m, A  m2 , k = 10,  = 81 V, g = 10 m/s2 )
20

9. The capacitance of the capacitor as a function of time is

0 2 0 2
(A) (t  54t  64) (B) (t  54t  810)
9 9
0 2 0 2
(C) (t  54t  810) (D) (t  54t  64)
9 9
10. The current through the connecting wire as a function of time is

0
(A) 0 (54  2t) (B) 9 0 (54  2t) (C) 9 0 (54  2t) (D) (54  2t)
9
Paragraph for Question 11 to 12

A charge particle of charge 1C and mass 10gm is moving with velocity  
B E A
10 î m/s in horizontal plane consisting of magnetic field –0.1 k̂ T of A
  
3
width m and electric field –0.1 ĵ N/C of width d. Particle enters the   
2

magnetic field at t = 0 perpendicularly and follows the path as shown in   
the figure and strikes the wall AB perpendicularly at A (neglect gravity)
y   
O x
  
B
3 d
m
2
11. The time t after which it strikes the wall
(A) 1.2 s (B) 0.97 s (C) 1.07 s (D) 1.98 s
12. Taking O as origin y-coordinate of A will be

(A) 3.75 m (B) 0.50 m (C) 4.25 m (D) 3.25 m
Paragraph -3 (Q. 5 to Q.6)
A capacitor of capacitance C  0.1F is charged by a battery of e.m.f. E1 = 100 V 100V 1

and internal resistance r1 = 1  by putting switch S in position 1 as shown in r1
E1
figure. 0.1F 99 1
R
2
50V 1
E2 r2
13. Find out heat generated in R = 99 till steady state

(A) 500 J (B) 495 J (C) 1000 J (D) 485 J
14. Now switch is thrown to position 2. Find the work done on the battery till steady state
(A) 250 J (B) 300 J (C) 275 J (D) 325 J
MATCHING (2 QUESTIONS)
1. List – I contains the points charge Q at point P and List – II contains flux due to this charge Q through the
surface mentioned in List – I.
List - I List - II
A A point charge Q is kept at point (0, 0, a) z P 1 > 2
and 1 and 2 are the flux through Q P (0,0,a)
triangular surface OAC and OBC
respectively.
O B (0, a 0)
2 y
(a, 0, 0) 1
A
C (a,a,0)
x
B A point charge Q is kept at point (0,0, a) z Q Q

1 
and 1 and 2 are the flux through Q P (0,0,a) 480
triangular surface OAB and ABC
respectively.
O B (0, a 0)
1 y
(a, 0, 0)
A 2
C (a,a,0)
x
C A point charge Q is kept at point y R Q

1 
 a C  0, a ,0  240
 0,0, 2  and 1 and 2 are the flux  2 
   a 
through the triangular surface ABC and  ,0,0 
 1
A
2
ABD respectively.
2 B  a ,0,0  x
 
 2 
 a 
D  0,  ,0 
 2 
D A point charge Q is kept at point (0,0, a) z S Q

x 2 
and 1 and 2 are the flux through 120
Q P (0,0,a) D(-a,0,0)
square surface OABE and OECD C
respectively. 2 (-a, a ,0)
O
y E y
A 1
(a, 0, 0)
B (a,a,0)
x
2. Some current carrying wire are given in List – I and graph of variation of magnetic field versus position of point
P are given in List – II Match the graph in List – II for the current carrying wire in List – I.
List - I List - II
(A) A long straight current carrying wire, placed along y–axis. (P) B
Its magnetic field at point P(x, 0, 0) is observed along
x–axis.
x
I
(B) Two long parallel wires placed on xy plane O is origin. Its (Q) B
magnetic field is observed at point P(0, 0, z) along
positive z – axis
y
O x
I I
a a
(C) Two long parallel wires are placed along y–axis and (R) B
parallel to x–axis. Its magnetic field is observed at point
P(x, 0, 0) along positive x–axis parallel to wire – 2.
y
O
x
I

I wire - 2
wire - 1
(D) A current carrying ring is placed on y–z plane Origin is at (S) B

the centre of ring. Its magnetic field is observed at point
P(x, 0, 0) along positive x–axis.
O x
NUMERICAL (5 QUESTIONS)
1. The figure shows a RC circuit with a parallel plate capacitor. Before switching on –Q0
the circuit, plate A of the capacitor has a charge –Q0 while plate B has no net
A B
charge. Now, at t = 0, the circuit is switched on. How much time (in second) will
R
elapse before the net charge on plate A becomes zero. (Given C = 1F, S
2  106
Q0 = 1mC,  = 1000 V and R  ) 
ln3
2. A thin insulated wire forms a plane spiral of N = 100 tight turns carrying a current
I = 8 mA. The radii of inside and outside turns as shown in figure are equal to
a = 50 mm and b = 100 mm. Find the magnetic induction (in micro tesla) upto the
nearest integer at the centre of the spiral;
3. The potentiometer wire AB is 600 cm long. At what distance from A should E r

the jockey J touch the wire to get zero deflection in the galvanometer?
R=15r
A B
J
G
E/2 r
4. A miliammeter of range 10mA and resistance 9  is joined in a circuit as 9 ,10mA

shown. The meter gives full scale deflection for current I when A and B are
used as its terminals, i.e. current enters at A and leaves at B (C is left 0.1 0.9
isolated). The value of I is
A B C
5. The time constant of an RC circuit shown in the figure is

E R
C
R
PART – B (CHEMISTRY)
1. Phenol reacts with chloroacetic acid followed by treatment with aq NaOH and then on acidification with HCl
gives A (C8H8O3) which on treatment with SOCl2 gives B (C8H7O2Cl). B on treatment with AlCl3 gives
C(C8H6O2). Which of the following options is correct?
O O
(A) A= (B) B=
O O
OH Cl
O
(C) C= (D) All are correct
H3O
2. Unbranched Ester A (C4H8O2) + CH3 MgBr   B  C4 H10O  .
(2 parts) (alcohol)
Alcohol B reacts fastest with Lucas reagent. Hence A and B are:

O CH3 O H3C
H3C , H3C H , OH
OH
(a) (b)
O O H3C
CH3
H5 C 2 H7 C 3
O OH O CH3
H3C , H3C H , H3C OH
(c) (d)
O CH3 O
CH3
H5 C 2 H7 C 3
3. Which of the following complex ions obeys Sidgwick’s effective atomic number (EAN) rule?
3 4 3 2
(a)  Fe  CN 6  (b)  Fe  CN 6  (c) Cr  NH3 6  (d)  Ni  en 3 
4. In closed packing of atoms

(a) The size of tetrahedral void is greater than the octahedral void.
(b) The size of the tetrahedral void is smaller than of the octahedral void.
(c) The size of tetrahedral void is equal of the octahedral void.
(d) The size of tetrahedral void may be larger or smaller or equal to that of the octahedral void depending
upon the size of atoms.
5. In two separate experiments equal quantities of an alkyl halide, C 4H9Cl were treated at the same temperature
with equal volume of 0.1 molar and 0.2 molar solutions of NaOH respectively. In the two experiments, the
times taken for the reaction of exactly 50% of the alkyl halide were the same. The most likely structure of
halide is:
(a) CH3CH2CH2CH2Cl (b) CH3CH(Cl) CH2 CH3
(c) (CH3)2 CHCH2Cl (d) (CH3)3 CCl
PASSAGE- 1 (Q. 1 TO 3)
Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when solute molecules
are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties
are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing
liquid in the radiator of automobiles.
A solution M is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixture is 0.9
Given: Freezing point depression constant of water ( K f water ) = 1.86K kg mol 1
Freezing point depression constant of ethanol ( K f ethanol )  2.0 K kg mol 1
Boiling point elevation constant of water ( Kb water )  0.52 K kg mol 1
Boiling point elevation constant of ethanol ( Kbethanol )  1.2 K kg mol 1

Standard freezing point of water = 273 K
Standard freezing point of ethanol = 155.7 K
Standard boiling point of water = 373 K
Standard boiling point of ethanol = 351.5 K
Vapour pressure of pure water = 32.8 mm Hg
Vapour pressure of pure ethanol = 40 mm Hg
Molecular weight of water = 18 g mol–1
Molecular weight of ethanol = 46 g mol–1
In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile
and non-dissociative.
6. The freezing point of the solution M is:

(a) 268.7 K (b) 268.5 K (c) 234.2 K (d) 150.9 K
7. The vapour pressure of the solution M is:

(a) 39.3 mm Hg (b) 36.0 mm Hg (c) 29.5 mm Hg (d) 28.8 mm Hg
8. Water is added to the solution M such that the mole fraction of water in the solution becomes 0.9. The boiling
point of this solution is:
(a) 380.4 K (b) 376.2 K (c) 375.5 K (d) 354.7 K
PASSAGE – 2 (Q. 4 TO Q. 6)
The acid catalyse rearrangement of vicinal diols to aldehydes or ketones with elimination of water molecule is known
as pinacol pinacolone rearrangement.
R2 R3 R2
O
R1 C C R4 R1 C C
OH OH R3 R4
(Pinacol) (Pinacolone)
Mechanism
R2 R3 R2 R3 R3
+ R1
H +
R1 C C R4 R1 C C R4 C C R4
-H2O
+ R2
: OH OH OH2 OH OH
..
+
R3
R3
O Migratory
R1 C C R1 C C R4
step.
R2 R4 R2 OH
The migratory aptitude depends on the stability of transition state. So order of migration will be
H > phenyl > alkyl.
This migratory aptitude comes only after the carbocation formation, so first preference should be given to carbocation
formation and then only migratory aptitude should be employed.
9. The product obtained in

OCH3 CH3
Ph CH3
and Ph CH3 on
Ph C C Ph OH OH
OH OH
treatment with hot and dil H2SO4 are
CH3 CH3
(a) Ph O
and Ph C C CH3
CH3
Ph C C Ph
O
OCH 3 CH3
(b) CH3 O
and Ph C C Ph
CH3
Ph C C Ph
O
OCH 3
(c) Ph
O
and Ph C C
CH3
CH3
Ph C C Ph
H3C
OCH 3
(d) CH3 O
and Ph C C Ph
CH3
Ph C C Ph
H3C
10.
+
H
P, P is
-H2O
OH OH
O
(a) (b)
O
(c) (d) b & c both
O
11. The product of the rearrangement of the following compound

Ph
C CH3 is
OH OH
O O
H
(a) C CH3 (b)
C CH3
Ph
O
Ph
Ph
Ph CH3
(c) (d)
CH CH3
O
12. Match the column as directed
Column – I Column – II
A. NaCl type structure P. FCC lattice of cation
B. ZnS type structure Q. FCC lattice anion
C. CsCl type structure R. Coordination number of cation is 4
1 M
D. Na2O type structure S. density of crystal 
a 3  No
13. Match the following complexes with the number of geometrical isomers they can form.
Column – I Column – II
(A) [Pt(NH3)2 Cl NO2] (P) 0
(B) [Pt (NH3)(NH2OH)(NO2)(py)]NO2 (Q) 5
(C) [Pt (NH3)3Cl]+ (R) 2
(D) [Pt (py)2(NH3)2Cl2]2+ (S) 3

Ans. A - R; B – S; C – P; D - Q
14. EAN of Fe in Fe in Fe(CO)5 is ………..
15. NH4Cl crystallizes in a body centred cubic lattice, with a unit cell distance of 387 pm. Calculate the distance
between the oppositely charged ions in the lattice in terms of nearest integer in pm.
16. River water is found to contain 11.7% NaCl, 9.5% MgCl2, and 8.4% NaHCO3 (Kb for water = 0.52). Find boiling
point of solution in terms of nearest integer in °C.
17. How many of the following reactions are correct?

H3C H3C CH3
3 O 
dry HCl
 CHCOCH
i)
H3C H3C CH3
Phorone
CH3
ii) 3CH 3COCH 3 

conc. H 2SO 4

H3C CH3
mesitylene
iii) CH 3COCl  H 2 

Pd / BaSO 4
quinolene
 CH 3CHO  HCl
H3C
iv) CO 
NH 2 NH 2
C2 H5ONa
 CH 3CH 2CH 3
H3C
Cl O O
Cl O
O CH3
t  BuOK
  CH 
t  BuOH
O
O O
Cl C 2H5
H5C 2 H5 C 2
-
v) Cl
O
O C 2H5
CH  CH + CH3MgBr  CH  C – MgBr
CO2/H3O+
– COOH is (EWG) CH  C  COOH

HgSO4/H2SO4
vi)
OHC – CH2 – COOH
Ag2O
HOOC – CH2 – COOH
18. Which one of the following compounds most readily undergoes substitution by S N2 mechanism?
CH3
Cl CH3
H3C H3C H3C
(1) (2) (3) H3C (4)
Cl Cl
C 3H7 H3C
Cl
Br
Br OH Br
(5) (6) (7) (8)

H3C CH3 H3C CH3
PART – C (MATHEMATICS)
1. Which of the following function is surjective but not injective

(A) f : R  R f(x)  x 4  2x 3  x 2  1 (B) f : R  R f(x)  x 3  x  1
(C) f : R  R f(x)  1  x2 (D) f : R  R f(x)  x 3  2x 2  x  1
2. If f(x)  2x 3  7x  5 then f 1 (4) is
(A) equal to 1 (B) equal to 2 (C) equal to 1/3 (D) non existent
3. Which one of the following statement is true?

(A) If Lim f(x)  g(x) and L im f(x) exist, then L im g(x) exists.
x c x c x c
(B) If Lim f(x)  g(x) exists, then L im f(x) and L im g(x) exist.
(C) If Lim(f(x)  g(x)) and L im f(x) exist, then L im g(x) exist.

(D) If Lim(f(x)  g(x)) exists, then L im f(x) and L im g(x) exist.

12 n  22 (n  1)  32 (n  2)  .....  n2 .1
4. Lim is equal to :
n 13  23  33  .....  n3
1 2 1 1
(A) (B) (C) (D)
3 3 2 6
x  e x  cos 2x
5. If f(x)  ,x  0 is continuous at x = 0, then
x2
5
(A) f(0)  (B) [f(0)] = – 2 (C) {f(0)} = –0.5 (D) [f(0)] . {f(0)} = –1.5
2
where [x] and {x} denotes greatest integer and fractional part function
Paragraph – I (Q. 1 TO Q. 3)
Let f : R  R, y = f(x), f(0) = 0, f(x) > 0 and f(x) > 0. Three points A(, f()), B(, f()), C(, f()) on y = f(x) such
that 0 <  <  < .
6. Which of the following is false

(A)  f() >  f() (B)  f() <  f() (C)  f() <  f() (D)  f() <  f()
7. Which of the following is true

f( )  f()  f( )  f() 
(A)  f  (B)  f 
2  2  2  2 
f( )  f()  2f( )  f()  2   

(C)  f  (D)  f 
2  2  3  3 
8. Which of the following is true?

(A) f() = f’(C) for some C  (0, ) (B) f() ≠ f’(C) for some C  (0, )
(C) f() ≠ f’(C) for some C  (, ) (D) f() ≠ f’(C) for some C  (, )
Paragraph – II (Q. 4 – Q. 6)
x2  1
Let f(x)  ,x  R  {0,2}
x2  2x
9. Which of the following is FALSE?

(A) lim f(x)  1 (B) lim f(x)  1
x  x 
(C) equation f(x) = 1 has exactly one real root (D) f(x) = 4 has exactly one real root
10. Which of the following TRUE?

(A) f(x) has one local maxima and one local minima
(B) f(x) has one local maxima and two local minima
(C) f(x) has no local extremum
(D) f(x) has atleast one local extremum
11. Range of f(x) is

(A) R (B) R – {1/2, 0} (C) R – (0, 1] (D) none
1. Match the following

Column - I Column - II
(x  1)2 (x  4)3 (x  7)
(A) The number of integral solution of the inequality  0 is/ are (P) 1
(x  2)(x  6)
(B) The integral value that the function f(x)  x  2  2 6  x can take is/are (Q) 2
 x 49 
Let f : D  R and f(x)= lnlnln .... ln  x 2    cos 4 x  then the value/s of n
(C) n times  2 16  (R) 3
for which f is onto is/are
If f(x) is continuous and differentiable  x  R function and f(c) = 0 for exactly 2
(D) (S) 4
real values of c then the number of real value of d for which f(d) = 0 can be
2. Observe the following column:
Column - I Column - II
 x d(tan
2 1
(A) If x)  x  f(x)  c , then f(1) is equal to (P) 0
x x  
(B) If 1  2 tan x(tan x  sec x) dx  aln cos  sin  c then a is equal to 0  x  2  (Q) -2
2 2  

x e
2 2x
(C) If dx  e2x f(x)  c, then the minimum value of f(x) is equal to (R)
4
x4  1 b
(D) If
 x(x2  1)2 dx  aln | x |  x2  1  c then a – b is (S) 1
1
(T)
8
(x  y  z)(xy  xz  yz)
1. Let f be the function defined by f(x,y,z)  for all positive real numbers x, y and z. The
xyz
smallest possible value of f, is
n
 1 
2. The value of lim   1  2n  is
n0  2 
n 
3. f(x)  | x  2 | 3 is not differentiable at number of points = ?
2
x 
x
4. Evaluate : e
0
2
sin    dx
2 4
1 1 x x 1
5. Let f1(x)  x,f2 (x)  1  x;f3 (x)  ,f4 (x)  ;f5 (x)  ;f 6(x) 
x 1 x x 1 x
Suppose that f6 (fm (x))  f4 (x) and fn (f4 (x))  f3 (x) then n is ________

Advanced - Paper - 2 (Q)

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Advanced - Paper - 2 (Q)

Uploaded by

Copyright:

Available Formats

CRONOS(T-4)ADVANCED-P-2 (19.09.

SINGLE OPTION (5 QUESTIONS)

1. A uniform electric field of 400 Vm -1 is directed at 450 above

4. The figure shows two identical parallel plate capacitors connected S

5. A conductor ABCDEF, with each side of length L, is bent shown. z

Paragraph for Question 9 to 10

Read the paragraph carefully and answer the following questions:

9. The capacitance of the capacitor as a function of time is

10. The current through the connecting wire as a function of time is

Paragraph for Question 11 to 12

12. Taking O as origin y-coordinate of A will be

Paragraph -3 (Q. 5 to Q.6)

A capacitor of capacitance C  0.1F is charged by a battery of e.m.f. E1 = 100 V 100V 1

13. Find out heat generated in R = 99 till steady state

B A point charge Q is kept at point (0,0, a) z Q Q

C A point charge Q is kept at point y R Q

D A point charge Q is kept at point (0,0, a) z S Q

(D) A current carrying ring is placed on y–z plane Origin is at (S) B

3. The potentiometer wire AB is 600 cm long. At what distance from A should E r

4. A miliammeter of range 10mA and resistance 9  is joined in a circuit as 9 ,10mA

5. The time constant of an RC circuit shown in the figure is

SINGLE OPTION (5 QUESTIONS)

(C) C= (D) All are correct

Alcohol B reacts fastest with Lucas reagent. Hence A and B are:

4. In closed packing of atoms

Given: Freezing point depression constant of water ( K f water ) = 1.86K kg mol 1

Freezing point depression constant of ethanol ( K f ethanol )  2.0 K kg mol 1

Boiling point elevation constant of water ( Kb water )  0.52 K kg mol 1

Boiling point elevation constant of ethanol ( Kbethanol )  1.2 K kg mol 1

6. The freezing point of the solution M is:

7. The vapour pressure of the solution M is:

9. The product obtained in

treatment with hot and dil H2SO4 are

11. The product of the rearrangement of the following compound

12. Match the column as directed

A. NaCl type structure P. FCC lattice of cation

B. ZnS type structure Q. FCC lattice anion

C. CsCl type structure R. Coordination number of cation is 4

(A) [Pt(NH3)2 Cl NO2] (P) 0

(B) [Pt (NH3)(NH2OH)(NO2)(py)]NO2 (Q) 5

(C) [Pt (NH3)3Cl]+ (R) 2

(D) [Pt (py)2(NH3)2Cl2]2+ (S) 3

14. EAN of Fe in Fe in Fe(CO)5 is ………..

17. How many of the following reactions are correct?

ii) 3CH 3COCH 3 

iii) CH 3COCl  H 2 

– COOH is (EWG) CH  C  COOH

HOOC – CH2 – COOH

(5) (6) (7) (8)

SINGLE OPTION (5 QUESTIONS)

1. Which of the following function is surjective but not injective

(C) f : R  R f(x)  1  x2 (D) f : R  R f(x)  x 3  2x 2  x  1

2. If f(x)  2x 3  7x  5 then f 1 (4) is

3. Which one of the following statement is true?

(C) If Lim(f(x)  g(x)) and L im f(x) exist, then L im g(x) exist.

(D) If Lim(f(x)  g(x)) exists, then L im f(x) and L im g(x) exist.

6. Which of the following is false

7. Which of the following is true

f( )  f()  2f( )  f()  2   

8. Which of the following is true?

9. Which of the following is FALSE?

10. Which of the following TRUE?