AL/2021/02/T-I

[KOg;gjpg;GupikAilaJ/ All Rights Reserved]

mwpTWj;jy;fs; :
 MtHj;jd ml;ltiz toq;fg;gl;Ls;sJ.
 ,e;j tpdhj;jhs; 09 gf;fq;fisf; nfhz;Ls;sJ.
 vy;yh tpdhf;fSf;Fk; tpil vOJf.
 fzpg;ghidg; gad;gLj;j ,lkspf;fg;glkhl;lhJ.
 tpilj;jhspy; jug;gl;Ls;s ,lj;jpy; ckJ Rl;nlz;iz vOJf.
 tpilj;jhspd; kWgf;fj;jpy; jug;gl;Ls;s mwpTWj;jy;fisf; ftdkhf thrpj;Jg; gpd;gw;Wf.
 1 njhlf;fk; 50 tiuAs;s tpdhf;fs; xt;nthd;Wf;Fk; (1)>(2)>(3)>(4)>(5) vd ,yf;fkp;lg;gl;l
tpilfspy; rhpahd my;yJ kpfg;nghUj;jkhd tpiliaj; njhpe;njLj;J> mjidf; Fwpj;J epw;Fk;
,yf;fj;ijj; jug;gl;Ls;s mwpTWj;jy;fSf;F mika tpilj;jhspy; Gs;sb (X) ,Ltjd; %yk;
fhl;Lf.

mfpy thA khwpyp R = 8.314 J K-1 mol-1 gpshq;fpd; khwpyp h = 6.626 x 10-34 J s
mtfhjNuh khwpyp NA = 6.022 x 1023 mol-1 xspapd; Ntfk; c = 3 x 108 m s-1

1. gpd;tUk; $w;Wf;fs; I IAk; II IAk; fUJf.

I. %yf;$Wfspd; ikatZitr; #o;e;Js;s js;SifayFr; Nrhbfs; kpff;Fiwe;j
js;Sifia mDgtpf;ff;$ba tifapy; xOq;fikf;fg;gLk;.
II. cNyhfr; rhyfj;jpy; jsu;thf cs;s ,yj;jpud; KfpypDs; cNyhf Neuad;fs;
nghjpe;Js;sd.
Nkw;Fwpj;j vz;zf;fUf;fSld; njhlHGila tpQ;Qhdpfs; KiwNa
(1) fpy;Ngl; Y}ap]; , n`d;wpf; Nyhwd;]; (2) ePy;Nghu; , Yl;tpf; &l;
(3) nwhdhy;l; fpny];gp , kf;]; gpshq; (4) fpy;Ngl; Y}ap];; , Yl;tpf; &l;
(5) nwhdhy;l; fpny];gp , n`d;wpf; Nyhwd;];
2. %yf mZnthd;wpy; rf;jpr;nrhl;nlz;fs; MfTs;s ,yj;jpud;fspy;
ngWkjpiaf; nfhz;bUf;ff; $ba mjpfgl;r ,yj;jpud;fspd; vz;zpf;if.
(1) 2 (2) 3 (3) 4 (4) 5 (5) 8
3. ikatZtpidr;#o vz;Kfp ,yj;jpud;Nrhb Nfj;jpu fzpjj;ij nfhz;l %yf;$w;W
tbtq;fs; Mtd.
(1) rJuf;$k;gfk; , Neu;NfhL (2) Neu;NfhL , jsr;rJuk;
(3) jsKf;Nfhzk;, T-tbtk; (4) rP - Nrh tbtk; , Kf;Nfhz ,U $k;gfk;
(5) rJuf;$k;gfk; , jsr;rJuk;
4. jug;gl;Ls;s Nru;itapd; IUPAC ngau;.
(1) ethyl 2-formyl-5-oxo-3-pentynoate
O COOC2H5
(2) ethyl 2,4-diformylbut-3-ynoate
(3) ethyl-2-formyl-5-oxopent-3-ynoate H – C – C ≡ C – C – CHO
(4) ethyl 2,5-dioxo-3-pentynoate H
(5) ethyl-2,4-diformylbut-3-ynoate
5. NO43- , NO3- , NO2- , NO2 Mfpa iejurd; ,dq;fspy; O – N – O gpizg;Gf; Nfhzk; FiwAk;
rupahd tupir ahJ?
(1) NO2 , NO3- , NO2- , NO43- (2) NO3- , NO2- , NO2 , NO43- (3) NO3- , NO2 , NO2-, NO43-
(4) NO3- , NO43-, NO2- , NO2 (5) NO43- , NO3- , NO2- , NO2
[gf;. 2 Ig; ghu;f;f
AL/2021/02/T-I -2-
6. NH2OCOOH %yf;$wpd; vd;Gf;fl;likg;G mUNf O
jug;gl;Ls;sJ. ,k;%yf;$Wf;F tiuaf;$ba Y}ap Fw;W- H–N–O–C–O–H
Nfhl;L fl;likg;Gf;fspd; caH vz;zpf;if
(1) 3 (2) 4 (3) 5 H
(4) 6 (5) 7
7. 1mol dm-3 NaOH(aq) ,d; 1 cm3 Nru;f;Fk;NghJ mjp$ba pH khw;wj;ij fhl;lf;$ba fiury;.
(1) fha;r;rp tbj;j ePu; 100 cm3 (2) 0.01 moldm-3 HCl ,d; 10cm3
-3 3
(3) 0.1 moldm HCOOH fiurypd; 1dm (4) fha;r;rp tbj;j ePupd; 1dm3
(5) 0.1 moldm CH3COOH , 0.1moldm CH3COO Na ,d; 100 cm3
-3 -3 - +

8. P – Q vd;gJ xU gy;ypd <uZ %yf;$W MFk;. ,jd; tpisAs; ,UKidTjpUg;Gjpwd;

Cm. ,jd; gpizg;G ePsk; gpNfhkPww
; u;fspy;(pm) r MFk;. ,k;%yf;$wpy; gpizg;gpd; mad;
rjtPjj;ij rupahfj; jUtJ. ( xU ,yj;jpudpd; Vw;wk; e C )
μr
(3) μ x10 12 %
2μr
(1) x10 14 % (2) x10 14 %
e e re
(4)  x10 14 % (5) 12
%
re
9. ZnCl2 / nrwpe;j HCl cld; fyf;Fk; NghJ kpf tpiuthf fyq;fiyj; juhj Nru;it
gpd;tUtdtw;wpy; vJ?
CH3
(1) CH2 = CH – CH2OH (2) CH3 – C – CH2OH
CH3
CH3
(3) CH3 – C – OH (4) CH3 – CH – CH = CH2
CH3 OH

(5) CH2 = CH – CH – CH = CH2

OH
10. Fwpj;j nrwpTila NaCl fiurnyhd;W PbCl2 ,dhy; epuk;gy; milar; nra;ag;gl;Ls;sJ.
,f;fiurypy; PbCl2 ,d; fiujpwd; moldm-3 MFk;. fUjg;gLk; ntg;gepiyapy; PbCl2
,d; fiujpwd; ngUf;fk; vdpd; ,f;fiurypy; NaCl ,d; nrwpT moldm-3 ,y;

( ) ( )√ ( )√ ( )√ ( )√

11. miwntg;gepiyapy; ePu;, Ijhd HCl kw;Wk; Ijhd NaOH Mfpatw;wpy; gpd;tUk;
Nru;itfspd; fiujpwd; njhlu;ghd jfty;fis rupahfj; jUtJ?
Nru;itfs; ePu; HCl NaOH
(1) CH2OH fiuAk; fiuahJ fiuAk;

(2) CH2NH 2 fiuahJ fiuAk; fiuahJ

(3) CONH2 fiuahJ fiuAk; fiuAk;

(4) CH3 OH fiuahJ fiuahJ fiuahJ

(5) CH3 NH3+ Cl- fiuAk; fiuAk; fiuAk;

12. HCN , H2C2O4 , HCOOH , C2N2 Mfpa fhgd; ,dq;fspy; fhgd; mZtpd; kpd;ndjpupay;G
mjpfupf;Fk; rupahd tupir.
(1) H2C2O4 < HCOOH < C2N2 < HCN (2) HCOOH < HCN < H2C2O4 < C2N2
(3) HCN < C2N2 < HCOOH < H2C2O4 (4) HCOOH < H2C2O4 < HCN < C2N2
(5) HCOOH < H2C2O4 < C2N2 < HCN
[gf;. 3 Ig; ghu;f;f
AL/2021/02/T-I -3-
13. MW mad;fspd; Vw;wq;fs; kw;Wk; Miufspd; ngWkjpfs; ml;ltizapy; jug;gl;Ls;sJ.
mad; J+ L+ M2+ X- Y- Z2-
Miu/nm 0.14 0.18 0.15 0.14 0.18 0.15
mad; jpz;kq;fs; JX , LY kw;Wk; MZ vd;gd xNu rhyf xOq;fikg;gpYs;sd. ,tw;wpd;
rhyfg; gpupifr; rf;jpapd; ,wq;Ftupiria rupahfj; jUtJ.
(1) JX > LY > MZ (2) JX > MZ > LY (3) LY > MZ > JX
(4) MZ > LY > JX (5) MZ > JX > LY
14. ePu; khjpup xd;wpy; fiue;Js;s xl;rprdpd; msitj; Jzptjw;fhf ,k;khjpupapd; 250 cm3
MdJ kpif MnSO4 , KI , NaOH Mfpatw;iwf; nfhz;l fiurYld; njhopw;gltplg;gl;lJ.
gpd;du; tpisTf;fiuriy mkpykhf;fpaNghJ ntspte;j I2 MdJ 0.02 moldm-3 nrwpTila
Na2S2O3 fiurypdhy; epakpf;fg;gl mf;fiurypd; 10 cm3 Njitg;gl;lJ. ,e;ePu; khjpupapy;
xl;rprdpd; mikg;G mg dm-3 ,y; ahJ? (O-16)
-
(1) 8 (2) 6.4 (3) 3.2 (4) 16 (5)
15. xNu epiyikfspd; fPo; S2(g)(,Ury;gu;), H2(g) , H2S(g) , SO2(g) , H2O(g) Mfpatw;Wf;fpilNa
fhzg;glf;$ba rkepiyfs; fPNo fhl;lg;gl;Ls;sd.
H2(g) + S2(g) H2S(g) ;
3H2(g) + SO2(g) H2S(g) + 2H2O(g) ;
- epak mKf;fq;fs; rhHghd mKf;fq;fspd; mbg;gilapyhd rkepiy khwpyp.
,e;epiyikfspd; fPo;r; rkepiy 4H2(g) + 2SO2(g) S2(g) + 4H2O(g) ,d; ahJ?
(1) 4.44 x 10-5 (2) 2.25 x 10-5 (3) 5.06 x 108 (4) 1.44 x 104 (5) 4.4 x 108
16. mdpyPd; njhlu;ghd gpd;tUk; $w;Wf;fspy; vJ jtwhdJ?
(1) CH3COCl cld; jhf;fk; Gupe;J xU top Vikl;il tpisthfj; jUfpwJ.
(2) NaOH(aq) cld; Nru;j;J ntg;gk; Vw;Wk;NghJ NH3(g) tpistpf;fg;glkhl;lhJ.
(3) ,J xU fUehbahfr; nraw;gLtJld;> ,yj;jpud; ehl;lg; gpujpaPl;Lj;jhf;fq;fSf;Fk;
cl;glf; $baJ.
(4) guhiej;jpNuh mdpyPDld; xg;gpLifapy; %y ,ay;G Fiwe;jJ.
(5) gpuPly; - fpuht; Cf;fpfSld; mdpyPd; %yf;$whdJ rpf;fiy cUthf;Ftjhy; ,jpy;
gpuPly; - fpuht; jhf;fq;fs; rhj;jpakpy;iy.
17. khwh mKf;fj;jpy; 1200 K ntg;gepiyapy; CaCO3 ,d; gpupif RakhdJ MFk;.
,e;epiyikfspd; fPo; ,j;jhf;fj;jpd; ∆H, ∆S , ∆G gw;wpa gpd;tUk; njhlu;Gfspy; rupahdJ.
(1) ∆H > , ∆S > 0 , ∆G < ( ) ∆H > , ∆S < , ∆G < (3) ∆H < , ∆S > 0 , ∆G >
(4) ∆H < , ∆S > , ∆G < (5) ∆H < , ∆S < 0 , ∆G >
18. 1.593 x 10-21 kJ rf;jpiaf; nfhz;l ,yj;jpud; xd;W cau; rf;jp epiyapy; ,Ue;J
rf;jpkl;lq;fSf;fpilapyhd mLj;jLj;j ,uz;L jhz;ly;fspd; %yk; jiuepiyia
milfpwJ. ,jd; KjyhtJ jhz;lypd; NghJ fhyy; nra;ag;gl;l fjpu;g;gpd; miyePsk;
200 nm vdpd; ,uz;lhtJ jhz;lypd; NghJ fhyy; nra;ag;gl;l fjpu;g;gpd; miyePsk; ahJ?
(1) 110 nm (2) 159 nm (3) 331 nm (4) 200 nm (5) 442 nm
19. %tYtsTs;s cNyhfk; M ,id kpd;tha;fshfg; gad;gLj;jp Na2SO4 fiurnyhd;iw
kpd;gFg;gpw;F cl;gLj;jpa NghJ mNdhl;by; cNyhfk; M fiujYld; fNjhl;by; H2 thA
ntspNaw;wKk; mtjhdpf;fg;gl;lJ. epak ntg;gmKf;f epge;jidapy; 5.6 dm3 , H2(g)
Nrfupf;fg;gl;l NghJ mNdhl;L kpd;thapd; jpzpT 4.5 g ,dhy; Fiwtile;jJ vdpd;
cNyhfk; M Mf mikaf;$baJ? (Al = 27,V=51,Cr = 52,Fe = 56,Co = 59) (thAtpd; 1 %y;
ep.nt.m. ,y; 22.4 yPww
; H fdtsitf; nfhz;bUf;Fnkdf; nfhs;f.)
(1) Al (2) Cr (3) Fe (4) V (5) Co
20. nkjapy; vjNdhNtw;Wf;Fk;(CH3COOCH3) kpif CH3MgCl ,w;Fk; ,ilapyhd jhf;fk;
njhlu;ghd gpd;tUk; $w;Wf;fspy; rupahdJ.
(1) ,q;F fhgidy; fhgd; mZtpid fUehb jhf;Fk;NghJ C–OCH3 gpizg;G ,yj;jpud;fs;
xl;rprd; mZit Nehf;fp efu;fpd;wd.
(2) jhf;fj;jpy; ,UNtW ehd;Kfp tbt ,ilepiyfs; ngwg;gl;L ,Wjp tpisT cUthFk;.
(3) ,j;jhf;fj;jpy; Kjypy; fUehl;lf;$l;lYk; gpd; fUehl;lg; gpujpaPLk; eilngWk;.
(4) nkjapy; vjNdhNtw;wpy; fUehl;lj; jhf;fj;jpw;F cl;gLk; fhgd; mZtpd; kpd;ndjpupay;G
jhf;fpAld; xg;gpLifapy; tpistpy; caHthf fhzg;gLk;.
(5) jhf;fj;jpd; ,Wjp tpisnghUs; xspapaw; njhopw;ghLilaJ.
[gf;. 4 Ig; ghu;f;f
AL/2021/02/T-I -4-
21. 250C ntg;gepiyapy; CH4(g) + 2O2(g) → CO2(g) + 2H2O(l) vDk; jhf;fj;jpd; CH4(g) , CO2(g) , H2O(l)
vd;gtw;wpd; Njhd;wYf;fhd epak fpg;rpd; rf;jpfs; kJ mol-1 ,y; KiwNa -50, -394 , -237
vdpd; ,j;jhf;fk; njhlu;ghd gpd;tUk; $w;Wf;fspy; vJ rupahdjd;W.
(1) ,j;jhf;fj;jpd; epak RahjPd rf;jp khw;wk; -818 kJ mol-1.
(2) jhf;f rhj;jpaj; jd;ikahdJ ntg;gepiy mjpfupg;Gld; FiwtilfpwJ.
(3) CO2(g) + 2H2O(l) ,d; epakntg;gTs;SiwahdJ CH4(g) + 2O2(g) If; fhl;bYk; FiwthdJ.
(4) jhf;fk; eilngWk;NghJ #oy; %yf;$Wfspd; ve;jpnuhgp Fiwfpd;wJ.
(5) ,j;jhf;fj;jpd; Kw;jhf;f Vtw;rf;jpia tpl gpw;jhf;f Vtw;rf;jp cau;thdJ.
22. gpd;tUtdtw;wpy; rupahd $w;iw ,dq;fhz;f.
(1) NH3 thAthdJ kpifahd Cl2 thATld; jhf;fk; GupAk; NghJ N2 , NH4Cl vd;gd
ngwg;gLfpd;wd.
(2) iej;jpu]; mkpykhdJ ,Utop tpfhuj;jpw;Fl;gl;L iej;jpupf; mkpyk; kw;Wk; epwkw;w
iej;jpu]; xl;irl;L vd;gd ngwg;gLk;.
(3) ePu;f;fiurypy; H2O2 ,d; gpupif mkpyq;fspd; %yk; J}z;lg;gLk;.
(4) xl;irl;L, Ngnuhl;irl; , Rg;gnuhl;irl; vd;gtw;wpd; xl;rprd; mZf;fspd; kpd;ndjpupay;G
,Nj Nghf;fpy; mjpfupf;Fk;.
(5) miwntg;gepiyapy; fe;jfj;jpd; cWjpahd gpwjpUg;g tbtk; xU rupTf; fe;jfkhFk;
23. 298 K ,y; td;fhu nkd;dkpy cg;G NaA(aq) ,d; nrwpT C moldm-3 ck; nkd;dkpyk; HA
apd; madhf;f khwpyp ck; MFk;. gpd;tUk; Nfhitfspy; vJ 298 K ,y; Fwpj;j
fiurypd; pH ,idj; jUtJ. (298 K ,y; ePupd; madhf;f khwpyp MFk;.)
(1) H – – C
(2) H – C
(3) H C
(4) H – – – ( C)
(5) H – – ( C)
24. Fwpj;j fdtsTila tpiwj;j FLit xd;wpy; A(g) , A2(g) Mfpa ,yl;rpathA %yf;$Wfs;
T1 K ntg;gepiyapYk; P1 Nm-2 mKf;fj;jpYk; cs;sd. ntg;gepiy T2 K ,w;F khw;wg;gl;l
NghJ gpd;tUk; rkd;ghl;Lf;fika A(g) KOtJk; A2(g) Mf khWfpd;wJ.
2A(g) → A2(g)
jw;nghOJ FLitapd; mKf;fk; P2 Nm-2 Mff; fhzg;gLfpwJ. Muk;gj;jpy; FLitapy; ,Ue;j
A(g) ,d; fdtsTg; gpd;dj;ij rupahfj; jUtJ.
 PT 
(1)  P2 T1 1 (2) 2 1  2 1  (3)  P1T1  P2 T2 
PT   PT   
 1 2   1 2   T2 T1 

(4)  P1T2  P2 T1  (5)  2P2 T1 1

   
 T2 T1   P1T2 

25. gpd;tUtdtw;Ws; vjid jhq;fy; gjhu;j;jkhff; fUj KbahJ?

(1) NaHC2O4 (2) NH2 – CHCOOH (3) KHSO4 (4) KH2PO4 (5) NaHCO3
CH3

26. Pt(s) | H2(g) | H+(aq) , Cl-(aq) | AgCl(s) | Ag(s) vd;w fyk; epakf;fykhfj; njhopw;gLfpwJ. ,f;fyj;jpd;
epak kpd;dpaf;ftpir 0.22V MFk;. ,f;fyk; njhlu;ghd gpd;tUk; vf;$w;W jtwhdJ.
(1) H+(aq) | H2(g) | Pt(s) kpd;thapd; epak kpd;thaOj;jk; G+r;rpakhff; nfhs;sg;gLfpwJ.
(2) AgCl(s) | Ag(s) ,d; epak jho;j;jy; kpd;thaOj;jk; +0.22V MFk;.
(3) Cl-(aq) | AgCl(s) | Ag(s) kpd;thapy; HCl ,d; nrwpitf; Fiwf;Fk; NghJ jho;j;jy; mOj;jk;
FiwfpwJ.
(4) H+(aq) | H2(g) | Pt(s) kpd;thapy; HCl ,d; nrwpitf; Fiwf;Fk;NghJ jho;j;jy; kpd;thaOj;jk;
kiwg;ngWkjpahf khWfpwJ.
(5) Nkw;gb fyj;jpy; HCl ,d; nrwpitf; Fiwf;Fk;NghJ fyj;jpd; kpd;dpaf;ftpir FiwAk;.

[gf;. 5 Ig; ghu;f;f

AL/2021/02/T-I -5-
27. SO2 thAthdJ KMnO4 ePH;f;fiurypD}lhf khwhtPjj;jpy; nrYj;jg;gl;lNghJ MnO4-
mad;fs; Mn2+ Mfj; jho;j;jg;gLtJld; SO2 MdJ SO42- MfTk; xl;rpNaw;wg;gLfpwJ.
,j;jhf;fj;jpy; Neuj;Jld; fiurypd; pH khWgLk; tpjj;ij vJ $basT rupahff;
fhl;LfpwJ.
pH pH pH pH pH

(1) Neuk; (2) Neuk; Neuk; Neuk; Neuk;

(3) (4) (5)
28. nkd;dkpyf; fiury;fspd; flj;Jjpwd; njhlHghd gpd;tUk; $w;Wf;fspy; vJ
cz;ikahdJ?
(1) fiurypd; ntg;gepiy mjpfupf;Fk; NghJ mad;fspd; xOq;fPdkw;w ,af;fk;
mjpfupg;gjhy; fiurypd; flj;Jjpwd; FiwtilfpwJ.
(2) ePH NrHj;J Ijhf;Fk; NghJ nkd;dkpyj;jpd; madhf;f msT mjpfupg;gjdhy;
fiurypd; flj;Jjpwd; mjpfupf;fpwJ.
(3) nkd;dkpyk; HA apw;F mjd; Nrhbak; cg;G NaA ,idr; NrHf;Fk; NghJ A- ,d;
nghJmad; tpistpd; fhuzkhf rkepiy gpd;Ndhf;fp efHj;jg;gLtjhy; fiurypd;
flj;Jjpwd; FiwtilfpwJ.
(4) xNu ntg;gepiyapy; rknrwpTila ntt;NtW nkd;dkpyf; fiury;fs; ahTk; xNu
flj;Jjpwd; cilait.
(5) nkd;dkpyf; fiurnyhd;wpd; flj;Jjpwd; mJ fiue;Js;s fiug;ghdpd;
KidTj;jd;ikapy; jq;fpAs;sJ.
29. 2A(g) → B(g) vDk; jhf;fk; Kjyhk; tupirf;F cupaJ. A apd; miutho;Tf;fhyk; 20 s vdpd;
80 s ,y; Aapd; Efu;TtPjkhdJ (Muk;gj;jhf;ftPjk; 100 R vd;f.)
(1) 25R (2) 6.25R (3) 12.5R (4) 3.125R (5) 2.5R
30. gpd;tUk; jhf;f xOq;iff; fUJf.
CH2 CHO
gPypq;fpd; 1)H+/H2O
P Q
Nrhjidg; 2)NaBH4
nghUs;
CHO
,q;F P , Q Mfpad KiwNa
CH2 CH2OH CH2 COOH CH2 COO- CH2 CH2OH
(1) (2)
,
,
CH2OH CHO COO- CH2OH
CH2 COO- CH2 CH2OH CH2 COO- CH2 COOH
(3) (4)
,
,
CH2OH CH2OH CHO CH2OH
CH2 COOH CH2 COOH

(5)
,
CHO CH2OH

[gf;. 6 Ig; ghu;f;f

AL/2021/02/T-I -6-

 31 njhlf;fk; 40 tiuAs;s tpdhf;fs; xt;nthd;Wf;Fk; (a), (b), (c), (d) vd;Dk; ehd;F
njupTfs; jug;gl;Ls;sd. mtw;Ws; xd;W jpUj;jkhdJ my;yJ xd;Wf;F Nkw;gl;lit
jpUj;jkhdit. jpUj;jkhd njupit / njupTfisj; Nju;e;njLf;f.
(a), (b) Mfpad khj;jpuk; jpUj;jkhditnadpy; (1) ,d; kPJk;
(b), (c) Mfpad khj;jpuk; jpUj;jkhditnadpy; (2) ,d; kPJk;
(c), (d) Mfpad khj;jpuk; jpUj;jkhditnadpy; (3) ,d; kPJk;
(a), (d) Mfpad khj;jpuk; jpUj;jkhditnadpy; (4) ,d; kPJk;
NtW njupTfspd; vz;Nzh Nru;khdq;fNsh jpUj;jkhditnadpy; (5) ,d; kPJk;
ckJ tpilj;jhspy; nfhLf;fg;gl;l mwpTWj;jy;;fSf;fika tpiliaf; Fwpg;gpLf.
Nkw;$wpa mwpTWj;jw; RUf;fk;.
(1) (2) (3) (4) (5)
(a), (b) Mfpad (b), (c) Mfpad (c), (d) Mfpad (a) , (d) Mfpad NtW njupTfspd;
khj;jpuk; khj;jpuk; khj;jpuk; khj;jpuk; vz;Nzh NrHkhdq;fNsh
jpUj;jkhdit jpUj;jkhdit jpUj;jkhdit jpUj;jkhdit jpUj;jkhdit

31. 3d njhFg;G %yfq;fspd; ,ay;Gfs; njhlu;ghd gpd;tUk; $w;Wf;fspy; vJ / vit

rupahdJ /rupahdit?
(a) jhz;ly; %yfq;fs; ahTk; khWgl;l tYtsTfisAk;, epwKila Nru;itfisAk;
cUthf;Fk;.
(b) Mtu;j;jdj;jpd; topNa fUNtw;w mjpfupg;Gf; fhuzkhf kpd;ndjpupay;G mjpfupf;fpd;w
NghjpYk; Mn , Zn Mfpad cWjp ,yj;jpud; epiyaikg;Gf; fhuzkhf ,g;Nghf;fpy;
,Ue;J tpyFfpd;wd.
(c) 60Co rkjhdpahdJ Gw;WNeha;r; rpfpr;irapy; fjpHj;njhopw;ghl;L Kjyhf gad;gLj;jg;
gLfpwJ
(d) ,tw;wpd; cNyhfg;gpizg;G typikahdJ madhiu, mZf;fshy; gpizg;gpw;F
toq;fg;gLk; ,yj;jpud;fspd; vz;zpf;if vd;gtw;wpy; khj;jpuk; jq;fpAs;sJ.
32. gpd;tUk; %yf;$iw fUJf.
P

Q CH CH C C H
R S T U

,q;F P , Q , R , S , T , U vd;gd fhgd; mZf;fis milahskpLtjw;F gad;gLj;jg;

gl;Ls;sd. ,r;NrHit njhlu;ghd rupahd $w;W/$w;Wf;fs; vJ/vit?
(a) Q , R , S , T , U fhgd; mZf;fs; xNu Neu;Nfhl;by; fhzg;gLfpd;wd.
(b) Q , R , S , T , U fhgd; mZf;fs; xNu jsj;jpy; fhzg;gLfpd;wd.
(c) R , S , T , U fhgd; mZf;fisf; fUJifapy; mtw;wpd; kpd;ndjpupay;G S , R , T , U vDk;
xOq;fpy; mjpfupf;fpd;wJ.
(d) P , Q , R , S fhgd; mZf;fs; xNu jsj;jpy; fhzg;gLfpd;wd.
33. T K ntg;gepiyapy; B , C thAf;$Wfs; jhf;fkile;J tpistpf;Fk; gpd;tUk; Kjd;ikj;
jhf;fr; rkepiyj; njhFjpiaf; fUJf.
2B(g) + C(g) D(g)
,r;rkepiyj; njhFjpapy; ,Ue;J T K ,y; Fwpj;jsT D mfw;wg;gl;L kPz;Lk; rkepiy
ngwg;gl;lJ. ,j;njhFjp njhlHghd gpd;tUk; $w;Wf;fspy; vJ/vit rupahdJ /rupahdit?
(a) D I mfw;WjYld; Kw;jhf;ftPjk; mjpfupg;gjdhy; rkepiyg;Gs;sp Kd;Ndhf;fp efu;fpwJ
(b) D I mfw;Wjy; gpw;jhf;f tPjj;jpy; ghjpg;ig Vw;gLj;jhJ.
(c) D mfw;wg;gLk;NghJ gpw;jhf;ftPjk; cldbahff; Fiwfpd;wJ>
(d) Muk;gr; rkepiyr; nrwpTld; xg;gpLk;NghJ Gjpa rkepiyapy; B , C , D Mfpatw;wpd;
nrwpTfs; Fiwthff; fhzg;gLk;.
34. xU mw;fNfhiy cz;lhf;Ftjw;F Nru;it S ,w;Fk; Ijhd H2SO4 ,w;FkpilNa cs;s
jhf;fk; gw;wpa gpd;tUk; $w;Wf;fspy; vJ/ vit gpioahdJ/ gpioahdit?
(a) gpujhd tpisthf 1–phenylpropan–2–ol ngwg;gLk;.
(b) fhgpNdhy; fhgd; mZtpy; xU Ijurd; mZitf; nfhz;l> CH CH — CH3
xU Ijpupf; mw;fNfhiy tpistpf;fpd;wJ. Nru;it S
(c) H+ mad; ,yj;jpud;ehbahf njhopw;gLk; ,yj;jpudhl;l
$l;ly; jhf;fk; eilngWfpwJ.
(d) ,j;jhf;fj;jpy; cUthFk; ,ilepiyAld; OH- fUehbahfj; jhf;fp tpisit
cUthf;FfpwJ.
[gf;. 7 Ig; ghu;f;f
AL/2021/02/T-I -7-
35. rkepiyj; jhf;fq;fs; njhlu;ghd gpd;tUk; $w;Wfspy; vJ/vit rupahdJ /rupahdit.
(a) ve;jpNuhg;gp mjpfupg;Gld; eilngWk; rkepiyj; jhf;fq;fs; mfntg;gj;jpw;Fupait.
(b) ve;jpNuhg;gp mjpfupg;Gld; eilngWk; rkepiyj; jhf;fq;fs; Gwntg;gj;jpw;Fupait.
(c) ve;jpNuhg;gp FiwTld; eilngWk; rkepiyj; jhf;fq;fs; mfntg;gj;jpw;Fupait.
(d) ve;jpNuhg;gp FiwTld; eilngWk; rkepiy jhf;fq;fs; Gwntg;gj;jpw;Fupait.
36. xsp ,urhad Gfhu; njhlu;ghd gpd;tUk; $w;Wf;fspy; vJ/vit rupahdJ /rupahdit.
(a) #upa xsp cs;s NghJ thfd neupry; cs;s re;ju;g;gj;jpy; Vw;gLfpwJ.
(b) ntw;Wf;fz;Zf;F GydhFk; xNunahU tspkhriljy; ,JthFk;.
(c) thfdf; fhyy;fspypUe;J ntspNaWk; IjNuhf;fhgd;fs; jho; tspkz;lyj;jpy; XNrhd;
cUthjYf;Ff; fhuzkhf mikfpd;wd.
(d) ,q;F cUthf;fg;gLk; XNrhd; er;Rj;jd;ikaw;w xU thAthFk;.
37. fe;jfKk; mjd; Nru;itfs; njhlu;ghd gpd;tUk; $w;Wf;fspy; vJ/vit rupahdJ/
rupahdit?
(a) fe;jfk; vl;L mZf;fisf; nfhz;l tisnespf; fl;likg;Gila fpuPl tbt
%yf;$Wfshf; fhzg;gLfpd;wJ.
(b) ry;G+uR mkpykhdJ (H2SO3) epue;ju ntspw;wiy Vw;gLj;Jfpd;wJ.
(c) H2O cld; xg;gpLifapy; gpizg;Gr;Nrhb ,yj;jpud;fSf;fpilapyhd js;Stpir
Fiwthf miktjdhy; H2S ,y; gpizg;Gf;Nfhzk; FiwthdJ.
(d) fe;jfkhdJ #lhd nrwpe;j HNO3 ,dhy; SO2 thf xl;rpNaw;wg;gLfpd;wJ
38. xU Kidtw;w fiuak; X MdJ Fwpj;j ntg;gepiyapy; A,B vDk; Kw;whff; fyf;Fk;
jftw;w jputg;gilfspilNa guk;gpr; rkepiyapy; fhzg;gLfpwJ. ,U fiug;ghd;
gilfspw;fpilNaahd X ,d; nrwpT tpfpjk; F MdJ gpd;tUkhW jug;gLkplj;J
[X]A
F
[X]B
F ,d; ngWkjp jq;fpapUg;gJ.
(a) njhFjpapy; cs;s fiuaj;jpd; jpzptpy;
(b) fiug;ghd; gilfspd; fdtsTfspy;
(c) njhFjpapd; ntg;gepiyapy;
(d) fiug;ghd; gilfspd; Kidthf;f msTfspy;
39. gpd;tUk; gygbj; jhf;fj;ijf; fUJf.
A(g) + B(g) → tpisTfs;
Fwpj;j epge;jidfspd; fPo; Nkw;nfhs;sg;gl;l gupNrhjidapd;gb jhf;ftPjk; = k[B(g)] vd
mwpag;gl;lhy; ,e;epge;jidfspy; ,j;jhf;fk; njhlu;ghd $w;Wf;fspy; vJ/vit rupahdJ/
rupahdit.
(a) A ahdJ Vtw;rf;jp Fiwe;j xUgbapy; rk;ge;jg;gl;bUf;fyhk;.
(b) jug;gl;l epge;jidapy; A apd; nrwpT B I tpl kpfTau;thf ,Uf;fyhk;.
(c) jhf;fk; eilngWk; nghOJ A apd; nrwpT Neuj;Jld; khw;wkilahJ.
(d) B apd; nrwpT miuthrpahFk; fhyk; gupNrhjidapy; gad;gLj;jg;gLk; B ,d; Muk;gr;
nrwptpy; jq;fpapUf;Fk;.
40. rpy ifj;njhopw; nrad;Kiwfs; njhlu;ghd gpd;tUk; $w;Wf;fspy; vJ/vit rupahdJ /
rupahdit?
(a) rtHf;fhu cw;gj;jpapy; ePu;tyaj;jpy; rtHf;fhuj;jpd; fiujpwid mjpfupg;gjw;fhf gpiud;
fiury; (NaCl) Nru;f;fg;gLfpd;wJ.
(b) iej;jpupf;fkpy cw;gj;jpapy; NH3 ck; tspAk; Vwj;jho 1 : 9 vDk; fdtsT tpfpjj;jpy;
fyf;fg;gLfpd;wd.
(c) ry;G+upf;fkpy cw;gj;jpapy; jputf; fe;jfj;jpy; cs;s mkpyg; gjhHj;jq;fis
mfw;Wtjw;F CaO gad;gLj;jg;gLfpwJ.
(d) TiO2 J}a;ikg;gLj;jypy; fhupak; xU %yg;nghUshfg; gad;gLj;jg;gLfpwJ.

[gf;. 8 Ig; ghu;f;f

AL/2021/02/T-I -8-
 41 njhlf;fk; 50 tiuAs;s tpdhf;fs; xt;nthd;wpYk; ,uz;L $w;Wf;fs; jug;gl;Ls;sd.
ml;ltizapy; cs;s (1), (2), (3), (4), (5) Mfpa njupTfspypUe;J xt;nthU tpdhTf;Fk; jug;gl;Ls;s
$w;Wf;fSf;F kpfTk; rpwg;ghfg; nghUe;Jk; njupitj; njupe;J nghUj;jkhf tpilj;jhspw; Fwpg;gpLf.

njupT Kjyhk; $w;W ,uz;lhk; $w;W

(1) cz;ik cz;ikahf ,Ue;J Kjyhk; $w;Wf;F jpUj;jkhd tpsf;fj;ijj; jUtJ
(2) cz;ik cz;ikahf ,Ue;J Kjyhk; $w;Wf;F jpUj;jkhd tpsf;fj;ijj; juhjJ
(3) cz;ik ngha;
(4) ngha; cz;ik
(5) ngha; ngha;

Kjyhk; $w;W ,uz;lhk; $w;W

41. NCl3 MdJ ePiu njhw;W ePf;fg; NCl3 ,d; ePu;g;gFg;ghy; cgFNshuR
gad;gLj;jg;gLfpd;wJ. mkpyKk; > mNkhdpahTk; tpisTfshfg;
ngwg;gLfpd;wd.
42. khwhntg;gepiyapy; rknrwpTila> rk xU td;dkpyf;fiuriy ePu; Nru;j;J
fdtsTila HCl , CH3COOH Mfpa Ijhf;Fk;NghJ mjd; nrwpT tPo;r;rp
fiury;fis jdpj;jdpNa xNu klq;fpdhy; milfpwJ. vdpDk; Xu; nkd;dkpyf;
Ijhf;Fk;NghJ HCl fiurypy; Vw;gLk; pH fiuriy ePu;Nru;j;J Ijhf;Fk;NghJ mjd;
mjpfupg;ig tpl, CH3COOH fiurypy; nrwpT tPo;r;rp miltJld; madhf;f msT
mjpfupf;fpwJ.
Vw;gLk; pH mjpfupg;G cau;thdJ.
43. Vgu;Kiw mNkhdpah jahupg;gpy; Vgu;Kiw mNkhdpah jahupg;gpy; tpisit
N2(g) + 3H2(g) 2NH3(g) vDk; jhf;fj;jpy; mfw;Wtjd; %yk; Kw;jhf;ftPjk;
MdJ I tplr;rpwpjhf mikAkhW mjpfupf;fg;gLtJld; gpw;jhf;ftPjk; Fiwf;
Ngzg;gLfpwJ. fg;gLfpwJ.
44. HNO3 , ePHf; fyitapd; nfhjpepiyahdJ ePHf;fiurypy; HNO3 ,d; madhf;fj;jpdhy;
HNO3 , ePH Mfpa ,U J}a $WfspdJk; Njhw;Wtpf;fg;gLk; mad; $Wfs; ePUld;
nfhjpepiyfis tpl caHthf typikahd ,ilf; ftHr;rpia
mikayhk;. Vw;gLj;Jfpd;wd.
45. butan-1-ol ,d; nfhjpepiyahdJbutan-1-ol ,d; xl;rprd; mZtpd;
2-methylpropan-2-ol ,d; nfhjpepiyia kpd;ndjpupay;ghdJ
tpl cau;thdJ. 2-methylpropan-2-ol xl;rprd; mZtpd;
kpd;ndjpupay;ig tpl cau;thdJ.
46. CH3 − CH CH − Cl + NaOH(aq)→ vDk; CH3 − CH = CH − Cl vDk; %yf;$wpy;
jhf;fk; rhjhuz epge;jidfspy; FNshupd; mZtpd; jdpr;Nrhb ,yj;jpud;fs;
eilngWtjpy;iy. fhgd; mZf;fSf;F ,ilapyhd
,yj;jpud;fSld; Xuplg;ghlw;W miktjhy;
fhgd; , FNshuPd; mZf;fSf;F ,ilapyhd
gpizg;G ePsk; FiwtJld; , gpizg;G
typik mjpfupf;fpwJ.
47. Nrhy;Nt Kiw %yk; NaHCO3 ,urhadj; jhf;fq;fspd; tPjk; nghJthf
cw;gj;jpapy; muz;fspd; ntg;gepiy ntg;gepiy mjpfupf;Fk; NghJ mjpfupf;Fk;.
cau;thf Ngzg;gLfpwJ.
+
48. CH2 = CH − CH2Cl I fhl;bYk; CH2 CH − CH2 If; fhl;bYk;
CH3 CH3 MdJ cWjpahd
CH3 - C - Cl MdJ AgNO3(aq) cld; CH3 – C+ fhNghfw;wad; MFk;.
tpiuthf fyq;fiyj; jUk;.
CH3 CH3
49. Fwpj;j fdtsT, Fwpj;j jpzpT thA xU thAj;njhFjpapy; ntg;gepiy
xd;wpd; mKf;fkhdJ ntg;gepiyAld; mjpfupg;Gld; %yf;$WfSf;fpilapyhd
Neu;tpfpj rkdhd khw;wj;ijf; fhl;Lk;. ftu;r;rp kPwg;gLtjdhy; mjd; RahjPdk;
mjpfupf;fpd;wJ.
50. jw;fhyj;jpy; CFCs ,w;F khw;wl
P hf HFCs , HFCs kw;Wk; HFOs vd;gd vt;tpj Rw;whly;
HFOs vd;gd gad;gLj;jg;gLfpd;wd. gpur;rpidfisAk; Vw;gLj;jhJ.
AL/2021/02/T-I -9-
AL/2021/02-T-II(A)
[KOg;gjpg;GupikAilaJ/ All Rights Reserved]

 MtHj;jd ml;ltiz 16 ,y; toq;fg;gl;Ls;sJ. Rl;nlz; :……..………………………

 fzpg;ghid gad;gLj;j ,lkspf;fg;glkhl;lhJ.
 mfpy thA khwpyp R = 8.314 J K −1 mol−1
 mtfhjNuh khwpyp NA = 6.022 × 1023 mol−1
 ,t;tpdhj;jhSf;F tpil vOJk; NghJ mw;ifw; $l;lq;fisr; RUf;fkhd tpjj;jpy; fhl;lyhk;.
H H
cjhuzk; : H – C – C – $l;lj;ij CH3CH2 − vdf; fhl;lyhk;.

H H
 gFjp A - mikg;Gf; fl;Liu ( gf;fq;fs; 2 – 8 )
 vy;yh tpdhf;fSf;Fk; tpilfis ,t;tpdhj;jhspNyNa vOJf.
 xt;nthU tpdhTf;Fk; fPNo tplg;gl;Ls;s ,lj;jpy; ckJ tpilfis vOJf. nfhLf;fg;gl;Ls;s ,lk;
ckJ tpilfSf;Fg; NghJkhdJ vd;gijAk; tpupthd tpilfs; vjpHghHf;fg;gltpy;iy vd;gijAk;
ftdpf;f.
 gFjp B ck; gFjp C ck; - fl;Liu ( gf;fq;fs; 9 - 16 )
 xt;nthU gFjpapypUe;Jk; ,uz;L tpdhf;fisj; njupTnra;J vy;yhkhf ehd;F tpdhf;fSf;F tpil
vOJf. ckf;F toq;fg;gLk; vOJk; jhs;fis ,jw;F gad;gLj;Jf.
 ,t;tpdhj;jhSf;nfd toq;fg;gl;l Neu Kbtpy; gFjp A NkNy ,Uf;Fk; gbahf A, B, C Mfpa %d;W
gFjpiaAk; xd;whfr; Nru;j;Jf; fl;ba gpd;du; guPl;ir Nkw;ghu;itahsuplk; ifaspf;f.
 tpdhj;jhspd; B, C Mfpa gFjpfis khj;jpuk; guPl;ir kz;lgj;jpypUe;J ntspNa vLj;Jr; nry;y
mDkjpf;fg;gLk;.

guPl;rfupd; cgNahfj;jpw;Fkhj;jpuk;
gFjp tpdh ,y. Gs;spfs;
1
,Wjpg; Gs;spfs;
2
A ,yf;fj;jpy;
3
4 vOj;jpy;

5
B 6 FwpaPl;nlz;fs;
7 tpilj;jhs; guPl;rfu; 1
8 tpilj;jhs; guPl;rfu; 2
C 9 Gs;spfisg; guPl;rpj;jtu;
Nkw;ghu;it nra;jtu;
10
nkhj;jk;
rjtPjk;

[gf;. 2 Ig; ghu;f;f

AL/2021/02-T-II(A) -2-
,e;epuypy;
gFjp A – mikg;Gf; fl;Liu vjidAk;
vOJjy;
ehd;F tpdhf;fSf;Fk; tpilfis ,j;jhspNyNa vOJf. MfhJ.
(xt;nthU tpdhtpw;Fk; 100 Gs;spfs; toq;fg;gLk;)

01. (a) gpd;tUk; tpdhf;fs; Mtu;j;jd ml;ltizapd; Kjy; 20 %yfq;fSld;

njhlu;ghdit. (i) njhlf;fk; (vi) tiuAs;s tpdhf;fSf;F jug;gl;Ls;s
Gs;spf;Nfhl;bd; kPJ tpil vOJf.
(i) rlj;Jt <uZ %yf;$whf fhzg;gLk; %yfk; ……………
(ii) thA epiyapy; ,U gFjpakhf fhzg;gLk; FNshiul;il
cUthf;Fk; %yfk; ……………
(iii) cau; mkpyr; rpwg;gpay;G cila xl;irl;il cUthf;Fk; %yfk; ……………
(iv) kpff; Fiwe;j ,uz;lhk; madhf;fw; rf;jpia nfhz;l %yfk; ……………
(v) cau; nfhjpepiyAila gq;fPl;L Ijiul;il cUthf;Fk; %yfk; ……………
(vi) Kf;Nfhzf; $k;gf tbthd <uyF xl;rp vjpuaid Njhw;Wtpf;Fk;
%yfk; ……………
(24 Gs;spfs;)
(b) (i) %yf;$W C3N2H2O ,w;F kpfTk; Vw;Wf;nfhs;sj;jf;f Y}ap Fw;W - Nfhl;Lf;
fl;likg;ig tiuf. mjd; mbg;gilf; fl;likg;G fPNo jug;gl;Ls;sJ.
O
H–N– C–C–C–N
H
(ii) %yf;$W H3N3CO ,dJ kpfTk; cWjpahd Y}ap Fw;W - Nfhl;Lf; fl;likg;G
jug;gl;Ls;sJ. ,jw;F NkYk; ,uz;L Y}ap Fw;W - Nfhl;Lf; fl;likg;Gf;fis
(gupTf; fl;likg;Gf;fis) tiuf.
H
:
:

H−N–C−N=N−H
:

:O:

(iii) fPNo jug;gl;Ls;s Y}ap Fw;W - Nfhl;Lf; fl;likg;igAk; mjd; ngauplg;gl;l

mbg;gilf; fl;likg;igAk; mbg;gilahf nfhz;L jug;gl;Ls;s ml;ltizia
G+uzg;gLj;Jf.
:O : :O: O O
:

: :

H – C − N = C = S − Cl : H – C1 – N2 – C3 – S4 − Cl
:Cl : Cl
:

C1 N2 C3 S4
mZit Rw;wpAs;s VSEPR
Nrhbfs;
mZit Rw;wpAs;s
,yj;jpud; Nrhbf; Nfj;jpu
fzpjk;
mZit Rw;wpAs;s tbtk;

mZtpd; fyg;ghf;fk;

(iv) njhlf;fk; (v) tiuahd gFjpfs; NkNy (iii) ,y; jug;gl;l Y}ap Fw;W -
Nfhl;L fl;likg;ig mbg;gilahff; nfhz;lit. mZf;fis ngaupLjy; (iii)
,y; cs;sthwhFk;.

[gf;. 3 Ig; ghu;f;f

AL/2021/02-T-II(A) -3-
,e;epuypy;
(iv) fPNo jug;gl;Ls;s ,U mZf;fSf;FkpilNa σ - gpizg;Gfis cUthf;Ftjpy; vjidAk;
gq;Fgw;Wk; mZ / fyg;gpd xgpw;wy;fis ,dq;fhz;f. vOJjy;
MfhJ.
I. H - C1 H : ……………………… C1 : ………………………
II. C1 - O C1 : ……………………… O : ……………………….
III. C1 - N2 C1 : ……………………… N2 : ………………………
IV. N2 - C3 N2 : ……………………… C3 : ………………………
V. C3 - S4 C3 : ……………………… S4 : ………………………
VI. S4 - Cl S4 : ……………………… Cl : ………………………
(v) gpd;tUk; ,U mZf;fspw;fpilNa π gpizg;Gfis cz;lhf;Ftjpy; gq;Fgw;Wk;
mZ xgpw;wy;fis ,dq;fhz;f.

I. C1 - O C1 : ……………………… O : ………………………
II. N2 - C3 N2 : ……………………… C3 : ………………………
(48 Gs;spfs;)
(c) Ijurd; mZtpy; Xu; Fwpj;;j cau; rf;jpg; gbapy; ,Ue;J jho; rf;jpg; gbf;F
,yj;jpud; jhz;ly; milAk; NghJ ntsptplg;gLk; fjpu;g;gpd; miyePsk;
1 1 1
MdJ = RH { } ,dhy; jug;gLfpwJ.

,q;F>
- fjpu;g;gpd; miy ePsk;
RH - wpl;Ngf;fpd; khwpyp
n1 - jho; rf;jp kl;lk;
n2 - cau; rf;jp kl;lk;
(i) Ijurdpd; ,iykd; njhlupd; kpff;Fiwe;j > kpff;$ba rf;jpAila NfhLfis
cUthf;Fk; ,yj;jpud; jhz;ly;fisf; fUJifapy; n1 , n2 ,w;Fg; nghUj;jkhd
ngWkjpfs; ahjhf mikayhk;?
kpff;Fiwe;j rf;jp n1 : ……………… n2 : ……………….
kpff;$ba rf;jp n1 : ……………… n2 : ……………….

(ii) Ijurd; mZtpy; madhf;fj;ij Vw;gLj;Jtjw;Fj; Njitahd fjpHg;gpd;

kpff;$ba miyePsk; ahJ? (RH = 1.097 x 107 m-1 )
.…………………………………………………………………….……………………..
.…………………………………………………………………….……………………..
.…………………………………………………………………….……………………..
.…………………………………………………………………….……………………..
.…………………………………………………………………….……………………..
(iii) Ijurdpd; madhf;fw; rf;jpia kJ mol-1 ,y; fhz;f.
= 6.62 × 10−34 = 3 × 10 −1
= 6.022 × 1023 −1

.…………………………………………………………………….……………………...
.…………………………………………………………………….……………………..
.…………………………………………………………………….……………………..
.…………………………………………………………………….……………………..
.…………………………………………………………………….……………………..
100
(28 Gs;spfs;)
[gf;. 4 Ig; ghu;f;f
 AL/2021/02-T-II(A) -4-
,e;epuypy;
02. (a) A , B , C , D vd;gd ,uz;lhk; my;yJ %d;whk; MtHj;jdj;ijr; NrHe;j %yfq;fs; vjidAk;
MFk;. mtw;wpd; Ijiul;Lf;fs; KiwNa E , F , G , H MFk;. A mlq;Fk; vOJjy;
$l;lj;ijr; NrHe;j %yfq;fs; ahTk; mad; Ijiul;Lf;fis cUthf;Fk; MfhJ.
mNjNtis B mlq;Fk; $l;lj;jpy; B khj;jpuk; mad; Ijiul;il
cUthf;Ftjpy;iy. A Ak; G Ak; jhf;fkile;J ngwg;gLk; tpisT>
er;Rj;jd;ikaw;w jputepiy Ijiul;lhfpa H cld; jhf;fkilAk; NghJ kPz;Lk;
G ngwg;gLfpwJ. A apd; cg;Gf;fs; Rthiyapy; nre;epwj;ij nfhLf;fpd;wd.
(i) A njhlf;fk; H tiuahd $Wfis ,dq;fhz;f.
A……………………… E…………………………
B……………………… F…………………………
C……………………… G…………………………
D……………………… H…………………………
(ii) A , G ,ilapyhd jhf;fk; kw;Wk; E , H ,ilapyhd jhf;fk; vd;gtw;wpw;fhd
rkg;gLj;jpa rkd;ghLfis vOJf.
.…………………………………………………………………….……………………...
.…………………………………………………………………….……………………...
(iii) G apid ,dq;fhz;gjw;fhd gupNrhjidiaAk; mtjhdj;ijAk; Fwpg;gpLf.
.…………………………………………………………………….……………………..
.…………………………………………………………………….……………………..
(iv) Ijiul;Lf;fs; G,H Mfpatw;wpd; gpd;tUtdtw;wpw;fhd rhHgUkd;fis xg;gpLf.

I. mkpy typik >

II. gpizg;Gf; Nfhzk; >
III. nfhjpepiy >
IV. ,UKidTj; jpUg;Gjpwd; >
(v) A,B vd;gd jkJ $l;l %yfq;fspypUe;J NtWgLk; ,ay;Gfs; xt;nthd;W
Fwpg;gpLf.
A.…………………………………………………………………….……………………
.…………………………………………………………………….……………………...
B.…………………………………………………………………….……………………
.…………………………………………………………………….……………………..
(60 Gs;spfs;)
(b) Pb(NO3)2 , Al2(SO4)3 , KNO2 , MgCl2 , Na2S2O3 , (NH4)2Cr2O7 Mfpatw;wpd;
ePHf;fiury;fs; P,Q,R,S,T,U (,Nj xOq;fpyd;wp) vdg; ngauplg;gl;l Nghj;jy;fspy;
cs;sd. mtw;iw ,dq;fhz;gjw;F mit ahTk; Ijhd NaOH , Ijhd HCl
fiury;fSld; jdpj;jdpNa fyf;Fk; NghJ fpilf;Fk; rpy gad;kpf;f
mtjhdpg;Gf;fs; fPNo jug;gl;Ls;sd.

fiury;fs; NaOH fiurYld; mtjhdpg;G HCl fiurYld; mtjhdpg;G

thA ntspNaw;wj;Jld; fyq;fy;
P njspthd fiury; fiury; ngwg;gl;lJ. (1)
ntz; tPo;gbT (2)
Q ntz; tPo;gbT
kpif NaOH ,y; fiue;jJ

R ntz; tPo;gbT (3) njspthd fiury;

[gf;. 5 Ig; ghu;f;f

AL/2021/02-T-II(A) -5-
,e;epuypy;
ntz; tPo;gbT (4) vjidAk;
S njspthd fiury;
kpif NaOH ,y; fiue;jJ vOJjy;
MfhJ.
thA ntspNaw;wj;Jld;
T kQ;rs; epwf; fiury; njspthd fiury;
ngwg;gl;lJ. (5)
thA ntspNaw;wj;Jld; njspthd
U njspthd fiury; fiury; (6)

(i) P njhlf;fk; U tiuahd fiury;fis ,dq;fhz;f.

P:……………………… Q:……………………… R:………………………
S:……………………… T:……………………… U:………………………
(ii) NkNy (1) - (6) tiuAs;s jhf;fq;fs; xt;nthd;Wf;Fk; rkg;gLj;jpa ,urhadr;
rkd;ghLfisj; jUf.(thA ntspNaw;wj;ij ↑ MYk; tPo;gbit ↓ MYk; fhl;Lf)
.…………………………………………………………………….……………………
.…………………………………………………………………….……………………
.…………………………………………………………………….……………………
.…………………………………………………………………….……………………
.…………………………………………………………………….……………………
.…………………………………………………………………….…………………… 100
(40 Gs;spfs;)
03. (a) 0.1 mol Q thA> kpifasT jpz;kk; P vd;gd 1.0 dm3 fdtsTila %ba
tpiwg;ghd FLitapy; ,lg;gl;L 270C ntg;gepiyapy; jhf;fkilar; nra;Ak;NghJ
gpd;tUk; rkepiy va;jg;gLfpwJ.
P(s) + Q(g) R(g) + S(g)
rkepiyj; njhFjpapd; nkhj;j mKf;fk; 4 x 105 Pa vd mwpag;gl;lJ.
(270C ntg;gepiyapy; RT = 2500 J mol-1 )
(i) rkepiyapy; R(g) , Q(g) vd;gtw;wpd; gFjpaKf;fq;fisf; fzpf;Ff?
.…………………………………………………………………….……………………...
…………………………………………………………………….………………………
…………………………………………………………………….………………………
.…………………………………………………………………….……………………...
……………………………………………………………………….……………………
.…………………………………………………………………….……………………..
…………………………………………………………………….………………………
…………………………………………………………………….………………………
…………………………………………………………………….………………………
……………………………………………………………………………………………
(ii) Fwpj;j rkepiyj; jhf;fj;jpd; ,w;Fupa Nfhitia vOJf?
…………………………………………………………………….……………………..
…………………………………………………………………….……………………..
(iii) 270C ntg;gepiyapy; Fwpj;j jhf;fj;jpd; If; fzpf;f
…………………………………………………………………….………………………
…………………………………………………………………….………………………
…………………………………………………………………….………………………
[gf;. 6 Ig; ghu;f;f
AL/2021/02-T-II(A) -6-
,e;epuypy;
(iv) , vd;gtw;Wf;fpilapyhd njhlu;gpidj; jUtjd; %yk; 270C vjidAk;
ntg;gepiyapy; ,id mol dm-3 ,y; fzpf;f. vOJjy;
MfhJ.
…………………………………………………………………….………………………
……………………………………………………………………….……………………
.…………………………………………………………………….……………………...
(v) ,Nj ntg;gepiyapYs;s , ,Nj fdtstpidf; nfhz;l NtnwhU
FLitnahd;wpy; Fwpj;j fzj;jpy; kpifasT P(s) cld; Q(g) , R(g) , S(g) vd;gtw;wpd;
%y; msTfs; KiwNa 0.2mol, 3 mol , 2mol Mff; fhzg;gbd;, Fwpj;j fzj;jpy;
Qc ,idf; fzpj;J jhf;fk; efUk; jpiria vjpu;T $Wf.
…………………………………………………………………….……………………..
…………………………………………………………………….……………………..
…………………………………………………………………….……………………..
…………………………………………………………………….……………………..
(vi) nghJthf xU rkepiyj; jhf;fj;jpd; fpg;rpd; RahjPd rf;jpkhw;wk; ∆Gr MdJ
xU Fwpj;j ntg;gepiyapy;
∆Gr = ∆Gr𝜃 + RT ln K
vDk; rkd;ghl;bd; %yk; jug;glyhk;. (,q;F K MdJ mol dm-3 ,yhd ,d;
gUkd; MFk;.) Nkw;Fwpj;j jhf;fj;jpd; epak fpg;rpd; RahjPd rf;jpkhw;wk; ∆Gr𝜃
,idf; fzpf;f. ( ln 9 = 2.2 , ln 0.01= 4.6)
…………………………………………………………………….………………………
…………………………………………………………………….………………………
…………………………………………………………………….………………………
…………………………………………………………………….………………………
(65 Gs;spfs;)
(b) fPo;tUk; ml;ltizapy; 250C ,y; ,urhadf; $Wfspd; epak Njhd;wy;
ntg;gTs;Siw khw;wg;ngWkhdq;fs; jug;gl;Ls;sd.
P(s) Q(g) R(g) S(g)
∆H𝜃f (kJ mol-1) 0 -263 -107.2 -120
(kJ mol-1)
(i) Nkw;Fwpj;j jhf;fj;jpd; epak ntg;gTs;Siw khw;wj;jpidf; fzpf;Ff.
…………………………………………………………………….………………………
…………………………………………………………………….………………………
…………………………………………………………………….………………………
(ii) gFjp (a)(vi) ,y; jug;gl;l rkd;ghl;Lld; NkNy (b)(i) ,y; fzpf;fg;gl;l
ntg;gTs;Siw khw;wj;jpd; FwpahdJ xj;jpirfpwJ vdf;fhl;Lf.
…………………………………………………………………….………………………
…………………………………………………………………….………………………
…………………………………………………………………….………………………
…………………………………………………………………….………………………
…………………………………………………………………….………………………
(iii) gFjp (a) (vi) ,y; ePu; fzpg;gpl;l ∆G𝜃r ,d; ngWkhdj;ijg; gad;gLj;jp Fwpj;j
jhf;fj;jpd; epak ve;jpug;gp khw;wj;jpidf; fzpg;gpLf.
…………………………………………………………………….………………………
…………………………………………………………………….………………………
…………………………………………………………………….………………………

[gf;. 7 Ig; ghu;f;f

AL/2021/02-T-II(A) -7-
,e;epuypy;
(iv) NkYs;s rkepiyj; jhf;fj;jpd; ntg;gepiy mjpfupf;fg;gLk; NghJ jhf;fr; vjidAk;
rhj;jpaj; jd;ik, tpisTfspd; nrwpT vd;gtw;Wf;F ahJ epfOk; vd;gij vOJjy;
ntg;g ,urhad fzpaq;fspd; mbg;gilapy;; vjpHT$Wf. MfhJ.
…………………………………………………………………….………………………
…………………………………………………………………….………………………
…………………………………………………………………….………………………
(v) 27 0C , 427 0C Mfpa ntg;gepiyfspy; Nkw;Fwpj;j jhf;fj;jpd; epak fpg;rpd;
RahjPdrf;jp khw;wj;jpw;Fk; jhf;fmsTf;Fk; ,ilapyhd khwiy xNu tiugpy;
gUk;gbahf tiuf.
G𝜃 G𝜃
-1
(kJ mol ) (kJ mol-1)

jhf;fp tpisT 100

jhf;f msT (35 Gs;spfs;)
04. (a) C5H13N vd;Dk; %yf;$w;Wr; #j;jpuj;ijf; nfhz;l A,B,C,D Mfpad NaNO2/dil HCl
cld; jhf;fkile;J N2 %yf;$iw cUthf;Fk;. ,it xd;Wf;nfhd;W
fl;likg;Gr; rkgFjpaq;fshFk;. ,tw;wpy; A , B , C Mfpad khj;jpuk; xspapaw;
njhopw;ghl;ilf; fhl;Lk;. A,B,C,D Mfpad NaNO2/dil HCl cld; jhf;fkile;J
cUthFk; tpisTfs; KiwNa E, F, G, H MFk;. ,jpy; E, H Mfpadtw;iw
cyu; ZnCl2/con HCl cld; Nru;f;Fk; NghJ H MdJ kpftpiuthf fyq;fy;
jd;ikiaf; nfhLf;Fk; mNjNtis E MdJ miwntg;gepiyapy; fyq;fiyj;
jutpy;iy. F,G vd;gtw;iw con H2SO4 cld; Nru;j;J ntg;gNkw;wp ePufw;wpa NghJ
cUthfpa tpisTfs; KiwNa X, Y MFk;. ,jpy; X kl;Lk; <u;ntspika
rkgFjpakhff; fhzg;gLk;.
(i) A,B,C,D,E,H,X,Y Mfpatw;wpd; fl;likg;Gf;fis ngl;bfspy; tiuf.

A B C

D E H

X Y
(ii) X ,d; <u;ntspika rkgFjpaq;fspd; fl;likg;Gfis tiuf.

[gf;. 8 Ig; ghu;f;f

AL/2021/02-T-II(A) -8-
,e;epuypy;
(iii) E,G,H Mfpatw;wpd; nrwpe;j H2SO4 cldhd ePufw;wy; ,yFj;jd;ik mjpfupf;Fk; vjidAk;
tupirapy; mtw;iw xOq;FgLj;jp mjw;fhd fhuzj;ijAk; jUf. vOJjy;
MfhJ.
…………………………………………………………………….………………………
…………………………………………………………………….………………………
…………………………………………………………………….………………………
…………………………………………………………………….……………………...
(b) (55 Gs;spfs;)

(i) L,M,N,O Mfpa NrHitfspd; fl;likg;Gf;fis tiutjd; %yKk; P,Q Mfpa

Nrhjidg; nghUl;fs; / Cf;fpfis jUtjd; %yKk; gpd;tUk;
jhf;fj;njhlupfisg; G+uzg;gLj;Jf.

1. CH=CH2 C≡C−H
Br2/CCl4 P HgSO4/
L M
jhf;fk; 1 jhf;fk; 2 Dil.H2SO4

2. L P M
OH Al2O3/∆ Q OH OH PCl5
N O
CH3 – CH − CH3 CH3 – CH – CH2 jhf;fk; 3

N Q O
(ii) jhf;fk; 2 > jhf;fk; 3 Mfpatw;wpd; jhf;fg;nghwpKiw tiffis gpd;tUk;
gl;baypypUe;J njupT nra;J vOJf.
fUehl;lg;gpujpaPL> ,yj;jpud;ehl;lf;$l;ly;> fUehl;lf;;$l;ly;> ePf;fy;

jhf;fk; 2 :………………………………………………………………………

jhf;fk; 3 :………………………………………………………………………

(iii) jhf;fk; 1 ,w;fhd nghwpKiwia G+uzkhf vOJf.

(45 Gs;spfs;)
100

[gf;. 9 Ig; ghu;f;f

AL/2021/02-T-II(B,C) -9-
[KOg;gjpg;GupikAilaJ/ All Rights Reserved]

mfpy thA khwpyp

mtfhjNuh khwpyp
gFjp B − fl;Liu
,uz;L tpdhf;fSf;F khj;jpuk; tpil vOJf.(xt;nthU tpdhtpd; tpilf;Fk; 150 Gs;spfs; tPjk;toq;fg;gLk;)

5. (a) 27 C ntg;gepiyapy; P , Q vd;gd Jtpj ,yl;rpaf; fiuriy cUthf;ff; $ba ,uz;L

jputq;fs; MFk;. P(l),Q(l) Mfpad KiwNa n mol , 0.8 mol fyf;fg;gl;L %ba ghj;jpuk;
xd;wpy; 27 C ,y; rkepiy milatplg;gl;lJ. NkYk; ,Nj ntg;gepiyapy; Mtp
epiyapy; P,Q Mfpad xd;Wlndhd;W jhf;fp gpd;tUk; rkepiyia cUthf;Ffpd;wd.

,q;F R MdJ Mtpmtj;ijapy; khj;jpuk; fhzg;gLfpwJ. rkepiyapy; nkhj;j mKf;fk;

2.7 x 105 Pa MfTk; R(g) ,d; gFjpaKf;fk; 9 x 104 Pa MfTk; fhzg;gl;lJ. Mtp
mtj;ijapd; fdtsT 8.314 dm3 ck; 27 C ntg;gepiyapy; J}a P(l) , J}a Q(l) ,d;
epuk;gy; Mtp mKf;fq;fs; KiwNa 8 x 104 Pa , 4.8 x 105 Pa MFk;.(P(g),Q(g),R(g) Mfpad
,yl;rpa elj;ijiaf; fhl;Lfpd;wd.)
(i) Mtp mtj;ijapy; cs;s nkhj;j %y; vz;zpf;ifiaf; fzpf;f.
(ii) Mtp mtj;ijapy; R(g) ,d; %y; vz;zpf;ifiaf; fzpf;f.
(iii) Mtp mtj;ijapypUf;Fk; P,Q vd;gtw;wpd; gFjpaKf;fq;fSf;fhd Nfhitia jput
mtj;ijapypUf;Fk; mtw;wpd; %w;gpd;dq;fs; rhHghf vOJf.
(iv) jput mtj;ijapy; P(l) ,d; %y; gpd;dj;ijf; fzpf;f.
(v) Mtp mtj;ijapy; P(g) , Q(g) Mfpatw;wpd; gFjpaKf;fq;fisf; fzpf;f.
(vi) 27 C apy; Nkw;Fwpj;j rkepiyj; jhf;fj;jpd; apid fzpf;f.
(vii)Mtp mtj;ijapy; P , Q ,d; %y; msTfis fzpj;J mjpypUe;J Muk;gj;jpy;
Nru;f;fg;gl;l P(l) ,d; %y; msT n If; fzpf;f.

(b) 27 C ntg;gepiyapy; fiuak; X MdJ Kw;whff; fyf;Fk;jftw;w ,Ujputg;gilfshfpa

fiug;ghd; A, ePH vd;gtw;wpy; fiuaf;$baJ. Fwpj;j jpzpTila fiuak; X MdJ
55 cm3 ePupy; fiuf;fg;gl;lJ. gpd;dH 220 cm3 fiug;ghd; A iar; NrHj;J ed;whff;
FYf;fp 27 C apy; rkepiyailatplg;gl;l NghJ ePu;, fiug;ghd; A Mfpa ,U fiug;ghd;
gilfspYk; rkjpzpT fiuak; X fiue;jpUf;ff; fhzg;gl;lJ.
(i) ePu;, fiug;ghd; A vd;gtw;Wf;fpilNa fiuak; X ,d; gq;fPl;L Fzfk; ( ) ,w;fhd
Nfhitia vOjp 27 C apy; ,idf; fzpf;f.
3
(ii) 55 cm ePupy; fiue;Js;s fiuak; X ,d; jpzpitg; Nghd;W ,Uklq;fsT X MdJ
rkepiyapy; fiug;ghd; A apy; fiue;jpUf;Fk; tiu A NrHf;fg;gLkhapd;
NrHf;fg;glNtz;ba A apd; Nkyjpf fdtsT ahJ ?
(iii) ,y; ePupy; X ,d; fiujpwd; 28 mg dm-3 Mapd; mNj ntg;gepiyapy; fiug;ghd;
A apy; X ,d; fiujpwd; mg dm-3 ,y; ahJ?
(iv) NtnwhU gupNrhjidapy; 27 C apy; 100 cm3 ePu; , 100 cm3 A Mfpa ,U
fiug;ghd;fisAk; nfhz;l njhFjpnahd;wpy; fiuak; X ,d; 0.025 mol
rkepiyailatplg;gl;lJ. ,j; njhFjpapypUe;J 25 cm3 ePHf;fiury; MdJ ntspNa
vLf;fg;gl;L 25 cm3 J}a ePupdhy; gpujpaplg;gLfpwJ. ntspNa vLf;fg;gl;l 25 cm3
gFjpapDs; Fwpj;j jpzpTila Y(s) vDk; fiuak; Nru;f;fg;gLk; NghJ X(aq) , Y(aq)
vd;gd jhf;fkile;J Z (aq) ,id cUthf;FfpwJ. X(aq) + Y(aq) → Z (aq)
[gf;. 10 Ig; ghu;f;f
AL/2021/02-T-II(B,C) - 10 -
NkYs;s jhf;fj;jpd; Muk;g jhf;ftPjk; fz;lwpag;gLfpwJ. ,t;thW NkYk; ,U
jlitfs; 25 cm3 ePHg;gFjpahdJ gpujpaplg;gLtJld; mNj jpzpTila Y(s) cld;
jhf;fq;fs; epfo;j;jg;gl;L Muk;g jhf;ftPjq;fs; msf;fg;gl;ld. ,g;gupNrhjidapy;
ngwg;gl;l juTfs; fPNo ml;ltizapy; jug;gl;Ls;sd.(Y(s) NrHf;fg;gLtjhy; fiurypd;
fdtstpy; khw;wk; Vw;gltpy;iy vdf; fUJf.)
X ,d; nrwpT Y ,d; nrwpT Muk;g jhf;ftPjk;
k;
1 nrad;Kiw L 0.2 mol dm-3 4 x 10-5 mol dm-3 s-1
2k; nrad;Kiw M 0.2 mol dm-3 3.2 x 10-5 mol dm-3 s-1
3k nrad;Kiw N 0.2 mol dm-3 J
1. L,M,N ,d; ngWkhdq;fisf; fzpf;f.
2. NkYs;s jhf;fj;jpw;fhd tPjtpjpf; Nfhitia vOJf.
3. X rhu;ghd jhf;f tupiriaf; fhz;gJld; J ,d; ngWkhdj;ijf; fzpf;f.
4. NtnwhU gupNrhjidapy; X,Y Mfpatw;wpd; Muk;g nrwpTfs; 0.4 mol dm-3 Mfg;
Ngzg;gl;l NghJ Muk;gj; jhf;ftPjk; 3.2 x 10-4 mol dm-3 s-1 Mff; fhzg;gl;lJ
vdpd; Y rhu;ghd jhf;f tupiriaf; fhz;f.
5. NkYs;s jhf;fj;jpw;fhd jhf;ftPj khwpypapd; ngWkhdj;ijf; fzpf;f.
6. NkNy (b)(iv) ,y; $wg;gl;l nrad;Kiw NkYk; njhlu;r;rpahf nra;ag;gLk; NghJ
nrad;Kiw ,yf;fj;jpw;F vjpuhf Muk;g jhf;ftPjj;jpd; khwiy tiuGgLj;Jf.
6.
(a) 3-ry;Ngh Gug;gpNahdpf; mkpyk;(HSO3CH2CH2COOH) MdJ xU td;dkpyg; gFjpiaAk;
(-SO3H) xU nkd;dkpyg; gFjpiaAk;(-COOH) nfhz;l ,U%y mkpykhFk;. 250C
ntg;gepiyapy; ,jd; 0.8 moldm-3 nrwpTila fiurypd; 20cm3 MdJ epakpg;Gf;
FLitapy; vLf;fg;gl;L 0.8 moldm-3 nrwpTila NaOH ,dhy; tYg;ghu;f;fg;gl;lJ.
250C ntg;gepiyapy; ,t;tkpyj;jpYs;s nkd;dkpyg;gFjpapd; madhf;fkhwpyp
ck; ePupd; madhf;f khwpyp ck;
MFk;. vdf; fUJf.)
(i) nghUj;jkhd vLNfhisf; Fwpg;gpl;L epakpg;Gf; FLitapYs;s Muk;gf; fiurypd; pH
,idf; fzpf;f.
(ii) Nkw;Fwpj;j mkpyf;fiuryhdJ In(1) fhl;b (pH tPr;rk; 1 – 2) Kd;dpiyapy; NaOH
,dhy; epakpf;fg;gLk; NghJ KbTg;Gs;spia milaj;Njitahd NaOH ,d;
fdtsitf; fhz;f.
(iii) NkNy (ii) ,y; epakpg;gpd; KbTg;Gs;spapy; fiurypd; pH ,idf;fhz;f.
(iv) NkNy (ii) ,y; epakpg;gpw;Fj; Njitg;gl;l NaOH ,d; fdtstpd; gq;F fdtsT
NaOH MdJ (ii) ,y; ngwg;gl;l tpisTf; fiurYf;F Nru;f;fg;gl;lJ.
1. tpisTf;fiurypd; pH ,idf; fhz;f.
2. tpisTf;fiurypd; jhq;fw; njhopw;ghl;il RUf;fkhf Muha;f.
(v) Nkw;Fwpj;j mkpyf;fiuryhdJ In(2) fhl;b (pH tPr;rk; 8 – 10) Kd;dpiyapy; NaOH
,dhy; epakpf;fg;gLk; NghJ KbTg;Gs;spia milaj;Njitahd NaOH ,d;
fdtsit nghUj;jkhd fhuzq;fisj; je;J ca;j;jwpf.
(vi) gFjp (v) ,d; epakpg;gpd; KbTg;Gs;spapy; fiurypd; pH ,idf; fzpf;f.
(b) (i) 25 C apy;; AB2(s) ,d; ePHf;fiujpwd; 0.001 mol dm-3 vdpd;; ,t;ntg;gepiyapy; AB2(s)
,d; fiujpwd;ngUf;fk; ,idf; fzpf;f. (AB2(s) MdJ A2+,B- Mfpa mad;fis
ePHf;fiurypy; Njhw;Wtpf;Fk;.)
(ii) 25 C apy; 0.2 moldm-3 nrwpTila nkd;dkpyk; HB fiurypd; pH = 2.7 Mff;
fhzg;gbd; ,t;ntg;gepiyapy; HB ,d; madhf;fkhwpyp ,idf; fzpf;f.(100.3 = 2)
(iii) NkNy fzpf;fg;gl;l rkepiykhwpypfspypUe;J
AB2(s) + 2 H3O+ (aq) A2+(aq) + 2HB(aq) + 2H2O(l)
vDk; rkepiyj; jhf;fj;jpd; rkepiykhwpyp ,id 25 C apy; fzpf;f.
(iv) Gjpa ghj;jpuk; xd;wpYs;s mkpyf;fiurypDs; AB2(s) Nru;f;fg;gl;lJ. ,jd; NghJ
tpdh (iii) ,y; jug;gl;l rkepiy cUthfpaJ. ( )
1. NkYs;s fiurypy; rkepiyapy; fiurypd; pH = 2.6 Mapd; Fwpj;j fiurypy; AB2(s)
,d; fiujpwd; ahJ?
2. Fwpj;j fiurypy; B-(aq) mad; nrwpitf; fzpf;f.
[gf;. 11 Ig; ghu;f;f
AL/2021/02-T-II(B,C) - 11 -
7. (a) mg;gNyh tpz;ntspr; nraw;wpl;lj;jpw;fhf vjpH kpd;tha; NeH kpd;tha;
cUthf;fg;gl;l fyj;jpd; jpl;l tiuglk; cUtpy; A B
fhl;lg;gl;Ls;sJ. vjpH kpd;thia(A) Nehf;fp H2(g)
O2(g,1 atm)
ck; Neu;kpd;thia(B) Nehf;fp O2(g) ck; H2(g,1atm)
njhlu;r;rpahf nrYj;jg;gLfpd;wNghJ kpd;dpaf;ftpir KOH
Njhw;Wtpf;fg;gLtJld; ePUk; tpistpf;fg;gLfpd;wJ.
,q;F kpd;gFnghUshf KOH(aq) gad;gLj;jg;gLfpd;w
mNjNtis rlj;Jtkpd;tha;fshf Ez;JisAs;s H2O(l)
epf;fy; gad;gLj;jg;gLfpd;wJ. ,f;fyk; 298 K ,y;
njhopw;gLfpd;wJ.
(i) Nkw;gb fyj;jpy; mNdhl;L > fNjhl;L
vd;gtw;iw ,dq;fhz;gJld;(A/B) mtw;wpy; Ez;JisAila epf;fy; kpd;tha;
eilngWk; miuj;jhf;fq;fisAk; vOJf.
(ii) epfu fyj;jhf;fj;ij vOJf.
(iii) ,f;fyj;jhf;fj;jpd; epak ntg;gTs;Siwkhw;wj;ijf; fzpf;f.∆Hᶿf (H2O(l)) = -286 kJmol-1
(iv) ,f; fyj;jhf;fj;jpd; epak ve;jpug;gp khw;wj;ijf; fzpf;f.
Sᶿ(H2(g)) = +143 J mol-1 K-1 > Sᶿ(O2(g)) = +219 J mol-1 K-1 > Sᶿ(H2O(l)) = +70 J mol-1 K-1
(v) fyj;jhf;fj;jpd; ∆Gᶿ ,idf; fzpj;J 298 K ,y; fyj;jpd; epak kpd;dpaf;ftpir Eᶿcell
,idf; fzpf;f. [∆Gᶿ = -nF Eᶿcell , F = 96500 C mol-1 , ,q;F n – epfu fyj;jhf;fj;jpd;
NghJ gupkhw;wg;gLk; ,yj;jpud;fspd; vz;zpf;if]
(vi) ,f; fyk; 298 K ,y; njhopw;gLk; NghJ fyj;jpy; ,Ue;J ngwg;gLk; khwhkpd;Ndhl;lk;
19.3 A Mf ,Ug;gpd;
1) 20 epkplq;fSf;F fyj;jpy; ,Ue;J kpd;Ndhl;lk; ngwg;gLk; NghJ
cUthFk; ePupd; jpzpitf; fzpf;f. (H – 1, O - 16)
2) ,f; fyj;jpy; H2(g) ,d; Efu;T tPjj;ij mol s-1 ,y; fzpf;f
(b) cg;G A MdJ ePupy; fiuf;fg;gLifapy; epwf; fiury; xd;W ngwg;gl;lJ.
,f;fiuryhdJ gpd;tUk; jhf;fq;fSf;F cl;gLfpd;wJ.
Ijhd HCl (gr;irepwf; fiury; , thA ntspNaw;wk; vJTkpy;iy)
B

Al J}s;
A NaOH(aq) C (epwkw;w fhu thA)

NaOH(aq) Y / NaOH
Jspahf D E
(ePyg; gr;ir tPo;gbT) (kQ;rs; epwf; fiury;)
Y MdJ Mtu;j;jd ml;ltizapy; Kjy; ,U Mtu;j;jdj;jpy; cs;s %yfq;fspidf;
nfhz;Ls;sJ.
B MdJ vz;Nfhzf; Nfj;jpu fzpjKilaJk; > XuyF NeNuw;wKilaJk;> ,U
tifahd ,izapfisf; nfhz;lJkhd ,izg;Gr;NrHit MFk;.
(i) cg;G A apYs;s fw;waidAk; > md;daidAk; ,dq;fhz;f.
(ii) fiury; B ,y;> epwj;jpw;Ff; fhuzkhd ,dj;jpYs;s cNyhf madpd; ,yj;jpud;
epiyaikg;igj; jUf.
(iii) B, C, D, E, Y Mfpatw;wpd; ,urhadr; #j;jpuq;fis vOJf.
(iv) B apid ePH NrHj;J Ijhf;Fk;NghJ cUthFk; ,izg;Gr;NrHitapd; IUPAC ngaiuj;
jUf.
(v) cg;G A apYs;s fw;waDld; ,U ,izg;ig Vw;gLj;jf;$ba ,izapfs; vjpyPd;
,Umikd; (NH2CH2CH2NH2 or en) > xl;rNyw;Nwh(C2O42- or ox) kw;Wk; fpisrpNdw;Nwh
(NH2CH2COO- or gly) Mfpad cUthf;Fk; rpf;fy;fspd; fl;likg;Gr; #j;jpuq;fis
,izapfspd; RUf;ff; FwpaPLfis gad;gLj;jp jdpj;jdpahf vOJf.(xt;nthU
rpf;fYk; xUtif ,izapia kl;Lk; nfhz;lJ.)
(vi) D ,ypUe;J E cUthjYld; njhlu;Gila jhf;fj;jpd; rkg;gLj;jpa mad;
rkd;ghl;ilj; jUf.
(vii) thA C cUthjYld; njhlu;Gila jhf;fj;jpd; rkg;gLj;jpa rkd;ghl;ilj; jUf.
(viii) fiury; E apw;F I,II Mfpa nrad;Kiwfs; Nkw;nfhs;sg;gLfpd;wd. mtw;wpy; ePH
vjpHghHf;Fk; mtjhdpg;Gf;fisAk; mtw;wpw;fhd rkg;gLj;jpa rkd;ghLfisAk; jUf.
I. fiuriy mkpyg;gLj;Jjy;.
II. NkNy I ,y; ngw;w tpisTf;fiurYf;F SO2 thAitr; nrYj;Jjy;.
[gf;. 12 Ig; ghu;f;f
AL/2021/02-T-II(B,C) - 12 -
gFjp C − fl;Liu
,uz;L tpdhf;fSf;F khj;jpuk; tpil vOJf.(xt;nthU tpdhtpd; tpilf;Fk; 150 Gs;spfs; tPjk;toq;fg;gLk;.)
8. (a) xNu Nrjd njhlf;f Nru;itahf CH3CH=CH2 ,id khj;jpuk; gad;gLj;jp Nru;it
I ,d; njhFg;Gf;fhd xU jhf;f xOq;F Kiw fPNo jug;gl;Ls;sJ. A, B, C, D, E, F, G
Mfpa Nru;itfspd; fl;likg;Gf;fis tiutjd; %yKk; gbfs; 1 - 8 ,w;F
nghUj;jkhd Nrhjidg; nghUl;fisg; gl;baypy; jug;gl;Ls;stw;wpypUe;J khj;jpuk;
njupe;njLj;J vOJtjd; %yKk; ,j;jhf;f xOq;F Kiwiag; G+uzg;gLj;Jf.

gb 1 gb 2
CH3CH = CH2 A B

gb 4 gb 3 H O
gb 7

=
CH3 - C - C – O - CH2CH2CH3
C
CH3
gb 5 gb 6
D E F kpif C

I H OH
CH3 - C - C - CH2CH2CH3 G
gb 8
CH3 CH2CH2CH3

Nrhjidg; nghUl;fspd; gl;bay;

Mg , H2O2 , cyH CH3-O-CH3 , C2H5OH/KCN , HBr , Ijhd H2SO4 , nrwpe;j H2SO4 , HCHO , NaOH(aq)

(b) (i) gpd;tUk; khw;wy; vq;qdk; Ie;Jf;F Nkw;glhj gbfspy; epiwNtw;wg;glyhk; vdf;
fhl;Lf.
CH2CH3

(ii) P Q
CH3CH2CH2OH B C
HgSO4/
dil H2SO4
R
E D

E apd; %yf;$w;Wr; #j;jpuk; C5H12O

B, C, D, E Mfpa Nru;itfspd; fl;likg;Gf;fis tiuf.

P, Q, R Mfpa Nrhjidg; nghUl;fisj; jUf.

[gf;. 13 Ig; ghu;f;f

AL/2021/02-T-II(B,C) - 13 -
(iii) O OH

=
(1) P
CH3 - C - CH3 CH3 - C - CH3
(2) Q
CH3
,j; jhf;fj;ij epiwNtw;Wtjw;Fj; Njitg;gLk; P, Q Mfpa ,urhadg; nghUl;fis
,dq;fhz;f. ,j;jhf;fj;jpd; nghwpKiwia vOJf.
(c) (i) fUehb vd;gjdhy; ahJ tpsq;Ffpd;wPH?
(ii) R-O- , C6H5O- , NH3 , H2O Mfpad fUehbahf njhopw;gLk; Mw;wy; mjpfupf;Fk;
tupirapy; xOq;FgLj;Jf.
(iii) “CH3CH2NH2 fUehbahfj; njhopw;glf;$baJ vdpDk; CH3CONH2 fUehbahf
njhopw;gLtjpy;iy”. tpsf;Ff.

9. (a) (i) gpd;tUk; gha;r;rw; Nfhl;Lg;glj;jpy; A - M ,y; jug;gl;Ls;s gjhu;j;jq;fspd; ,urhadr;

#j;jpuq;fis vOJf.
(Fwpg;G : gjhu;j;jq;fs; A - M I ,dq;fhz;gjw;F ,urhadr; rkd;ghLfSk;
fhuzq;fSk; vjpu;ghu;f;fg;gltpy;iy.)
jpz;kq;fs; > tPo;gbTfs; > fiury;fs; > thAf;fs; Mfpatw;iwf; Fwpg;gjw;Fg;
ngl;bapy; ( Kwpe;j NfhLfs; ) cs;s FwpaPLfs; gad;gLj;jg;gLfpd;wd.

Ijhd mkpyk; 5
A,B C,D + E

,U cNyhfq;fs; epwKilait epwkw;wJ> jpz;kk;

kzkw;wJ tPo;gbT
kpif NH3(aq)

fiury; thA
H G F
fgpyr; rptg;G kQ;rl; fgpyk;
ntz;zpwk;
kpif nrwp HCl

rhil : I tspf;Fj; jpwe;Jtpl kpif nrwp

cNyhfq;fs; HCl
ePyk;
A,B apypUe;J
J M
KiwNa C,D
cUthfpd;wd. H2O kQ;rs;
fUq;fgpyk;

C Ijhd HCl
nkd; rptg;G
NaOH K
Jspj;Jspahf
ntspw;Wk;
L ,ay;GilaJ

nkd; rptg;G
(ii) A , B ,d; G+uz ,yj;jpud; epiyaikg;Gf;fis vOJf.
(iii) G apypUe;J H cUthFtjw;Fupa nrad;Kiwiaf; Fwpg;gpl;L mq;F eilngWk;
mad;jhf;fj;ijj; jUf.
(iv) K ,d; NtnwhU njhopw;ghl;il vOJf.

[gf;. 14 Ig; ghu;f;f

AL/2021/02-T-II(B,C) - 14 -
(b) Nghf;Ftuj;Jg; nghyprhupdhy; rhujpfs; kJ mUe;jpAs;shu;fsh vdf; fz;lwpa ntspr;
Rthr tspapYs;s C2H5OH ,d; msT fz;lwpag;gLfpwJ. ,jw;fhf gpd;tUk; ,U
eilKiwfs; Nkw;nfhs;sg;gLfpd;wd.
( K - 39 , Cr - 52 , O - 16 , Fe - 56 , C - 12 , H - 1 )
eilKiw : 01
8.28 g ntspr;Rthr khjpupahdJ jpzpTg;gb 1.47% I cila kpif mkpy K2Cr2O7
fiurypd; 64cm3 ,Ds; nrYj;jg;gl;lJ.
(K2Cr2O7 fiurypd; mlu;j;jp 1 g cm-3 , ntspr;Rthr tspapd; mlu;j;jp = 1.8 kg m-3 vd;f)
eilKiw : 02

eilKiw : 01 ,ypUe;J ngwg;gl;l tpisTf; fiury; 0.2 mol dm-3 FeSO4 fiurYld;
diphenylamine fhl;b Kd;dpiyapy; epakpf;fg;gl;l NghJ Njitg;gl;l mstp thrpg;G
24.00 cm3 Mf ,Ue;jJ.
(i) Nkw;Fwpj;j eilKiwfspy; eilngWk; jhf;fq;fSf;Fupa rkg;gLj;jpa mad;
rkd;ghLfis vOJf.
(ii) K2Cr2O7 fiurypd; %yu; nrwpT ahJ?
(iii) ntspr; Rthr khjpupapYs;s C2H5OH ,d; msit
1. ppm ,y;,
2. mgdm-3 ,y; fzpf;f.
(iv) nghJthf kJ mUe;jpa xUtupd; FUjpapd; 1 cm3 fdtstpy; cs;s C2H5OH
mstpw;Fk; 1 cm3 ntspr;Rthr tspapYs;s C2H5OH ,,w;Fk; ,ilapYs;s tpfpjk;
2000:1 MFk;. rhujp xUtu; FUjpapYs;s C2H5OH ,d; mikg;G 15 mg/ml ,Yk;
mjpfupg;gpd; mJ Xu; Fw;wkhf fUjg;gLk;.
1. rhujp xUtu; kJ mUe;jp Fw;wk; ,iof;fhJ ,Ug;gjw;F mtupd; ntspr;Rthr
tspapy; fhzg;glf;$ba C2H5OH ,d; Mff; $ba msit mg dm-3 ,y; fhz;f.
2. Nkw;Fwpg;gpl;l egu; Fw;wk; Gupe;jtuh vdj; jPHkhdpf;f.

10. (a) ,Uk;G gpupj;njLf;fg;gLk; CJiy Kiwia mbg;gilahff; nfhz;l gpd;tUk;

tpdhf;fSf;F tpil jUf.
(i) ,Uk;G gpupj;njLg;gpy; gad;gLj;jg;gLk; ,Uk;Gj;jhJ xd;wpidAk; Vida
%yg;nghUl;fisAk; jUf.
(ii) ,Uk;Gj;jhJ jtpu;e;j Vida%yg;nghUl;fspd; njhopw;ghLfis nghUj;jkhd
rkg;gLj;jpa rkd;ghLfSld; Fwpg;gpLf.
(iii) ,k;Kiwapy; jpz;k%yg;nghUl;fisAk; neUf;fg;gl;l tspiaAk; KuNzhl;l
nghwpKiw %yk; nrYj;Jtjd; Kf;fpaj;Jtk; ahJ?
(iv) ,q;F eilngWk; gpujhd jhf;fq;fspy; xd;W CO2(g) + C(s) 2CO(g) MFk;.
1. ,j;jhf;fj;jpd; epak ve;jpnuhg;gp khw;wj;jpd; Fwpapid ca;j;jwpf.
2. jho;>cau; ntg;gepiyfspy; CO(g), CO2(g) ,d; cWjpg;ghl;bid ntg;gtpaf;ftpaypd;
mbg;gilapy; xg;gpl;L tpsf;Ff
3. ,q;F CO(g) MdJ Fe2O3(s) ,id njhlu;r;rpahd gbKiwj;jhf;fq;fspDlhf
jho;j;Jfpd;wJ. mg;gbKiwj;jhf;fq;fis vOJf
4. jhf;fk; eilngWk; NghJ jpzpTg;gha;r;ry; tPjj;ij tpl thAg;gha;r;ry; tPjj;ij
mjpfupj;jhy; Vw;gLk; gpujp$yk; ahJ?
(v) fPOs;s juTfisg;gad;gLj;jp CJiy %yk; ,Uk;G gpupj;njLj;jy; rhj;jpakhdJ
vd fzpg;Gf;fs; %yk; tpsf;Ff
2 CO(g) + O2(g) → 2 CO2(g) ∆G𝛳 = -514.4 kJ mol-1
2 Fe2O3(s) → 4 Fe(l) + 3 O2(g)
∆G𝛳 = + 1487 kJ mol-1
(v) CJiy Kiwahy; Vw;gLk; Kf;fpa Rw;whly; gpur;rpid ahJ?

[gf;. 15 Ig; ghu;f;f

AL/2021/02-T-II(B,C) - 15 -
(b) jw;NghJ Gtp vjpu; Nehf;fpAs;s ghupa gpur;rpidfspy; xd;W XNrhd; gil twpjhjyhFk;.

(i) XNrhd; gil twpjhjy; vd;gjhy; fUjg;gLtJ ahJ?

(ii) XNrhd; gil twpjhjyhy; Vw;glf;$ba ghjfkhd tpisTfs; %d;W jUf.
(iii) XNrhd; gilia Nja;Twr; nra;Ak; gpujhd NrHitf; $l;lj;ijf; Fwpg;gpLtJld;
mjDila vspa fl;likg;Gf;fs; %d;iwAk; jUf.
(iv) NkNy (iii) ,y; $wpa gpujhd NrHitf; $l;lk; UV fjpu;tPry; Kd;dpiyapy; XNrhd;
gilia twpjhf;Ftjw;Fupa jhf;fq;fisj; njspthf tpgupf;Ff.
(v) XNrhd; gil twpjhjiyj; jtpu;g;gjw;fhf (iii) ,y; $wg;gl;l gpujhd NrHitf;
$l;lj;jpw;Fg; gjpyhf khw;wPlhf mwpKfk; nra;ag;gl;l gjhu;j;jk; ahJ? ,J Vd;
XNrhd; gil twpjhjypy; gq;fspg;Gr; nra;atpy;iy vd tpsf;Ff.
(vi) NkNy (v) ,y; Fwpg;gpl;l gjhu;j;jk; XNrhd; gil twpjhjiy Kw;whf epWj;jpa
NghJk; mJ NtnwhU #ow; gpur;rpidf;F top Nfhyhf mike;Js;sJ. mg;
gpur;rpid ahJ?
(vii) NkNy (vi) ,w; Fwpg;gpl;l #ow; gpur;rpidiaj; jtpu;f;Fk; Kfkhf (v) ,w; Fwpg;gpl;l
gjhu;j;jj;jpw;F khw;wPlhf jw;NghJ gad;gLj;jg;gLk; khw;wPl;Lg; gjhu;j;jq;fspd;
fl;likg;Gf;fisj; jUf.
(c)
(i) capH vjNdhy;(bio ethanol) cw;gj;jpf;fhd %yg;nghUl;fs; ,uz;ilf; Fwpg;gpLf.
(ii) capH vjNdhy; cw;gj;jpAld; rk;ge;jg;gLk; jhf;fq;fSf;fhd rkg;gLj;jpa
jhf;fq;fisf; Fwpg;gpLf.
(iii) rhw;Wj;ijyq;fspd; gpupj;njLg;gpy; gad;gLj;jg;gLfpd;w gpujhd Kiwfs; %d;iwf;
Fwpg;gpLf.
(iv) rhw;Wj;ijyq;fspd; gpupj;njLg;gpy; gad;gLj;jg;gLfpd;w jhtuq;fs; ,uz;bidf;
Fwpg;gpl;L mtw;wpypUe;J gpupj;njLg;G nra;ag;gLk; ,urhadg; gjhHj;jq;fs;
xt;nthd;iwf; Fwpg;gpLf.
(v) rhw;Wj;ijyq;fspd; gpupj;njLg;gpy; nfhjpePuhtp tbg;igg; gad;gLj;Jtjw;fhd
fhuzq;fs; ,uz;ilf; Fwpg;gpLf.
AL/2021/02-T-II(B,C) - 16 -