substance: cadmium sulfide (CdS) 26s10d60

property: thermodynamic properties, vapor pressure, phase diagram

enthalpy of melting
∆Hm 38.5 kJ mol–1 estimated 90K
50.6 kJ mol–1 estimated 96S
volume change
∆Vm 2.3 % 90K
characteristic data of formation
∆Hf0(298.15) – 149.4 kJ mol–1 optimized 74M
– 159.0 kJ mol–1 optimized 74M
– 153.3(28) kJ mol–1 calorimetry 92N
∆Gf0(298.15) – 149.8(20) kJ mol–1 emf 92N
reaction: Cd(l) + S(l) → α-CdS(s)
∆Gf0 – 164295 + 31.37 T J mol–1 T = 640...690 K, emf 92N
– 162760 + 40.1786 T J mol–1 T = 600...1400 K, optimized 96S
–(G0T–H00)/T 39.31(33) J mol–1K–1 83B
entropy and enthalpy
S0298.15 69.04 J mol–1 K–1 74M
72.18(16) J mol–1 K–1 83B
72.0 J mol–1 K–1 92N
H0298.15_H00 9.802(19) kJ mol–1 83B
thermodynamic functions
adiabatic calorimetry, polycrystalline sample 83B
T Cp ∆ST0 –(G0−HT)/RT H298.150 − H00
[K] [J mol–1 K–1] [J mol–1 K–1] [J mol–1]
5 0.043 0.030 0.002 0.000
10 0.889 0.237 0.051 0.002
15 3.137 0.986 0.221 0.011
20 5.799 2.255 0.563 0.034
25 8.321 3.824 1.054 0.069
30 10.560 5.544 1.658 0.117
35 12.504 7.321 2.340 0.174
40 14.207 9.104 3.074 0.241
45 15.748 10.868 3.842 0.316
50 17.197 12.603 4.632 0.399
60 19.971 15.985 6.244 0.584
70 22.644 19.265 7.871 0.798
80 25.204 22.458 9.495 1.037
90 27.613 25.567 11.109 1.301
100 29.845 28.593 12.707 1.589
110 31.887 31.535 14.286 1.897
120 33.735 34.390 15.843 2.226
130 35.393 37.157 17.376 2.572
140 36.872 39.835 18.885 2.933
150 38.185 42.425 20.369 3.308
160 39.348 44.927 21.826 3.696
170 40.379 47.344 23.256 4.095
180 41.295 49.679 24.660 4.503
190 42.112 51.934 26.036 4.920
200 42.845 54.113 27.386 5.345
210 43.506 56.219 28.709 5.777
220 44.106 58.257 30.006 6.215
230 44.653 60.230 31.278 6.659
240 45.153 62.141 32.527 7.108
250 45.609 63.994 33.746 7.562
260 46.024 65.791 34.944 8.020
270 46.401 67.535 36.119 8.482
280 46.743 69.229 37.271 8.948
290 47.055 70.875 38.402 9.417
298.15 47.293 72.182 39.307 9.802
300 47.345 72.475 39.511 9.889
400 49.475 86.461 49.572 14.755
500 50.688 97.638 58.105 19.766
600 51.672 106.968 65.492 24.886
700 52.546 115.000 72.004 30.097
800 53.363 122.071 77.829 35.393
900 54.146 128.401 83.103 40.796
1000 54.909 134.146 87.924 46.222
1100 55.657 139.414 92.369 51.750
vapor pressure
log p 7.376 – 11601 T –1 T in K, p in bar 74M
see Figs. 1 and 2.
phase diagrams: Figs. 3...5.
References:
63W Woodbury, H. H.: J. Phys. Chem. Solids 24 (1963) 881.
74M Mills, K. C.: Thermodynamic Data of Inorganic Sulphides, Selenides and Tellurides, Butterworth,
London, (1974).
83B Beyer, R. P., Ferrante, M. J., Mrazek, R. V.: J. Chem. Thermodyn. 15 (1983) 827.
90K Kulakov, M. P.: Inorg. Mater. 26 (1990) 1947.
92N Nasar, A., Shamsuddin, M.: Thermochim. Acta 197 (1992) 373.
96S Sharma, R. C., Chang. Y. A.: J. Phase Equilibria 17 (1996) 425
Fig. 1.
CdS. Calculated partial pressure of Cd along the Cd-S liquidus [96S].
Fig. 2.
CdS. Calculated partial pressure of S2 along the Cd-S liquidus [96S].
Fig. 3.
CdS. Phase diagram for the system Cd−S [63W].
Fig. 4.
CdS. Assessed phase diagram, symbols are experimental points [96S].
Fig. 5.
CdS. p- T diagram, symbols are experimental points [96S].