Set~1 Series 1HKPQ6/C Roll No. coteno. 56/1/41 Candidates must write the Code on the title page of the answer-book. Please check that this question paper contains 10 printed pages. Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate. Please check that this question paper contains 33 questions. Please write down the serial number of the question in the answer-book before attempting it. 15 minute time has been allotted to read this question paper. The question paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the students will read the question paper only and will not write any answer on the answer-book during this period. CHEMISTRY (Theory) Time allowed : 3 hours Maximum Marks : 70 General Instructions : Read the following instructions very carefully and strictly follow them @ Wi Gi) (iv) @ wi) (wii) (viii) ig] This question paper comprises four Sections — A, B, C and D. There are 33 questions in the question paper. All questions are compulsory. Section A — Questions no. 1 to 16 are very short answer type questions, with each question [part carrying 1 mark. Answer these questions in one word or one sentence. Section B - Questions no. 17 to 25 are short answer type questions, carrying 2 marks each. Section C - Questions no. 26 to 30 are long answer type-I questions, carrying 3 marks each. Section D — Questions no. 31 to 83 are long answer type-I questions, carrying 5 marks each. There is no overall choice in the question paper. However, an internal choice has been provided in 7 questions! parts of one mark, 3 questions of two marks, 2 questions of three marks and all the 3 questions of five marks. You have to attempt only one of the choices in such questions. In addition to this, separate instructions are given with each section and question, wherever necessary, Use of calculators and log tables is not permitted. Page 1 of 20 P.T.O.ag SECTION A 1. _ Read the passage given below and answer the following questions : 4x14 Amines can be considered as derivatives of ammonia and are usually formed from nitriles, nitro, halides, amides, ete. They show hydrogen bonding which influences their physical properties. In aromatic amines, electron releasing and withdrawing groups respectively increase and decrease their basic character. Hinsberg test is used for the identification and distinction between primary, secondary and tertiary amines. The following questions are multiple choice questions : () Ethyl amine can be prepared by the action of LiAIH 4 on (A) CH,NO, (B) © (D) CH, - CH, - CONH, Gi) Which of the following reagents is used for the Hinsberg test of amines ? (A) C,H,Cocl (B) CH, Coc! (©) C,H,-S0,H ) — C,H;-S0,Cl (iii) Out of the following, the strongest base in aqueous solution is (A) (CH,),NH (B) © © (iv) The reaction of ammonia with a large excess of CH, “ ®) (CH,),NH Cl will give mainly : (©) (CH,),N*cr () CH,-NH, OR Among the following amines, which one is expected to have the lowest boiling point ? (A) C,H,-NH, (B) (C,H,),N © — (C,H,),NH ©) CH,-NI Page 2 of 20Read the passage given below and answer the following questions : a. Colloidal solutions are intermediate between true solutions and suspensions based on particle size. A colloidal system consists of two phases — the dispersed phase and the dispersion medium. Based on the nature of interaction between the dispersed phase and dispersion medium, colloids are of two types — Lyophobic and Lyophilic colloids. The colloidal particles always carry an electric charge. The colloidal solutions are purified by dialysis. In the following questions (Q. No. 2 (i) - (iv), a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices. (a) By (©) (D) Assertion and Reason both are correct statements and Reason is the correct explanation of the Assertion. Assertion and Reason both are correct statements, but Reason is not the correct explanation of the Assertion. Assertion is a correct statement, but Reason is a wrong statement. Assertion is a wrong statement, but Reason is a correct statement. () Assertion: True solution shows scattering of light. Reason : In true solution, size of solute particles is much smaller than the wavelength of light used. Gi) Assertion: Lyophilic sols are more stable than Lyophobic sols. Reason Lyophilie sols are highly solvated in the solution, Gii) Assertion; Colloidal solutions are purified by dialysis. Reason Colloidal particles pass through a suitable membrane in dialysis, (iv) Assertion: _A positively charged sol is obtained when KI is added to AgNO. Reason This is due to preferential adsorption of Ag* ions OR Assertion: Colloidal solution shows Brownian Movement. Reason Colloid is not a substance but a state of substance. The following questions (Q. No. 3 to 11) are multiple choice questions : 3. ‘The helix structure of proteins is stabilized by (A) peptide bond (B) hydrogen bond (C) disulphide bond () van der Waals forces OR Nucleic acids are polymers of (A) nucleosides (8) Drribose (©) amino acids (D) nucleotides Page 3 of 20 P.T.O.5. 1 8. Which of the following is a strong oxidising agent ? (At. No. Mn = 25, Zn = 30, Cr =24, Se = 21) (A) Mn3+ (BR) Zn (cr ©) si A compound formed by elements P and Q crystallizes in a cubie structure where P atoms are at the corners of a cube and Q atoms are at the face centres. The formula of the compound is : (A) P2Q, ®) PQ, © PQ ©) PQ Nitrogen is unable to form pentahalides because of (A) the presence of s and p orbitals. (B) the absence of both p and d orbitals. (©) the absence of d orbitals. (D) _allof the above OR Which of the following hydrogen halides is most volatile ? (A) H-F () H-I (Cc) H-Br @) H-cl ‘The oxidation number of Co in [Co(en)3],(80,), is a +2 ® 8 (C) +4 ©) +6 Which of the following ligands form a ‘chelate’ complex with metal ion ? (A) HO (B) cN™ © 0 o or OR ‘The coordination number of Cr in [CrCl,(ox),]*~ is : @ 6 ®) 5 (Cc) 4 ©) 3 Page 4 of 20 a83 ‘The formula of the coordination compound tetraamminechloridonitrito-N-cobalt(IIDchloride is (A) [Co(NH,),CKONO)ICL, ®) — (CotNH,),C1,(NO,)}C1 (©) (CotNH,),ClONO,)IC1 @) — [Co(NH,),(NO,ICI, 10. The reaction given below cl CH cr +2Na + CHCl —> +2NaCl is called (A) Wurtz reaction (B) Wurtz - Fittig reaction (©) Fittig reaction (D) None of the above oR Which of the following reactions will be the fastest under identical conditions ? (A) ©,H,OH + HI —> C,H,I +H,0 (B) C,H,OH + HCl —> C,H,Cl+H,0 (© C,H,OH + HBr —> C,H,Br + H,0 (D) C,H,OH + HF —> C,H,F + H,0 11. Cubic close packing of equal sized spheres is described by (A) ACB ACB ACB... (B) ABABAB (©) ABC ABC ABC. (D) ABACACAB In the following questions (Q. No. 12 - 16) a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices. (A) Assertion and Reason both are correct statements and Reason is the correct explanation of the Assertion. (B) Assertion and Reason both are correct statements, but Reason is not the correct explanation of the Assertion. (C) Assertion is a correct statement, but Reason is a wrong statement. (D) Assertion is a wrong statement, but Reason is a correct statement. 12, Assertion: _Ortho-nitrophenol is more acidic than phenol. Reason : Nitro group is electron donating group and therefore stabilizes ortho-nitrophenoxide ion, 13, Assertion: F— F bond has lower bond dissociation enthalpy than Cl — Cl bond. Reason Fluorine forms only one oxoacid. oR Page 5 of 20 P.T.O.ae Assertion Noble gases form compounds mainly with Fluorine and Oxygen. Reason : Fluorine and Oxygen are the most electronegative elements. 1 14, Assertion: __ Iron on reaction with HCI gives FeCl, and not FeCl. Reason : Hydrogen gas produced from the reaction prevents the oxidation of FeCl, to FeCl, 1 15. Assertion Glucose is a reducing sugar. Reason : Despite having an aldehydic group, glucose does not give 2,4-DNP test. 1 16. Assertion: _Benzoic acid does not give Friedel-Crafts reaction. Reason The carboxyl group is deactivating and gets bonded to Lewis acid AICI, 1 SECTION B The following questions (Q. No. 17 to 26) are short answer type and carry 2 marks each : ox: 17. (a) _ Write structures of the products formed when 2x1=2 @ —__ Propan-2-0] is heated with Cu at 573 K. (i) Salicylic acid is treated with (CHCO),O/H*. OR (b) Carry out the following conversions : 2x1=2 @ Phenol to Anisole Gi Aniline to Phenol 18. What type of deviation from Raoult’s law is observed by mixing chloroform and acetone ? Why is a decrease in vapour pressure observed on mixing chloroform and acetone ? 2 19. (a) Write the hybridisation and magnetic behaviour of the following complex : 2x1=2 @ (CoF,)- @ — [NKCN), > [Atomic number of Co OR (b) — @_—Write the IUPAC name of [Mn(I,0),]80,. 27, Ni=28] (i) Why is [Fe(CN),]* diamagnetic while [FeF,]° is paramagnetic ? [At. No. Fe = 26] 2x1=2 20, The following reaction was carried out in water Br, +21 —> 2Br-+1, ‘The initial concentration of I” was 0-30 M and the concentration after 10 minutes reduced to 0-28 M. Calculate the rate of disappearance of I~ and production of 1. 2 Page 6 of 20or ai (a) Account for the following : 2x1=2 (@® Transition metals form large number of complex compounds. (i) Cris a strong reducing agent. oR (b) Why do transition elements show variable oxidation states ? How are transition metals different from p-block elements in terms of variability of oxidation states ? 2 22, Write the equations involved in the following reactions : 2x1=2 (@ ——Carbylamine reaction (ii) Hoffmann bromamide degradation reaction 28. In the following pairs of halogen compounds, which would undergo Sx2 reaction faster ? Give reason in support of your answer. 2x 1=2 @ NT, n~ CH, (i) CHy— b-a, CH, — CH, — Cl cut, 24, Write equations of the following reactions 2x1=2 (@ Friedel-Crafts reaction — alkylation of anisole Gi) _Nitration of Phenol with concentrated nitric aci 25. Anclement with molar mass 27 g mol“ forms a cubic unit cell with edge length 300 pm. If its density is 6-6 g em, identify the nature of cubic unit cell. 2 SECTION C Q. No. 26 to 30 are long answer type-I questions carrying 3 marks each. 5x3=15 26. (a) Why is E°(Cu*|Cu) exceptionally positive ? Although Cu* ion has 3d!° configuration, yet it is unstable in an aqueous solution. Why ? What is the reason for the stability of Cu®* over Cut ion ? 3 oR (b) Give reasons for the following : x1=3 (@) Transition metals form alloys. Gi) Zine has lowest enthalpy of atomization. (ii) Manganese shows higher oxidation state of +4 with Fluorine but shows +7 with Oxygen. Page 7 of 20 P.T.O.28, 29, Q. No, 31 to 33 are long answer type-II questions carrying 5 marks each. 31. ee a (@) Differentiate the following ax1=3 (@ Fibrous protein and Globular protein Gi) Essential amino acids and Non-essential amino acids Gi) DNAand RNA OR (b) Write the reaction of Glucose with 3x1=3 @ HEN (i) Bry ii) HI Following data were obtained for the given reaction X+Y —> Product Exp. c/M (yI/M ina 1 o1M 02M 005 2 02M 02M 0-10 3 o1M O1M 0-05 @ Find the order of reaction with respect to X and Y. (ii) Write the rate law expression. (iii) Find the rate constant. 3xt: Vapour pressure of water at 293 K is 17536 mm Hg. Calculate the vapour pressure of aqueous solution when 20 g of glucose (Molar mass = 180 g mol“) is dissolved in 500 g of water, 3 Give reasons for the following 3x1=3 () _Eleetrophilic substitution in haloarenes occurs slowly Gi) Sulphuric acid is not used during the reaction of alcohols with KI. (ii) Alkyl halides give nitrile with KCN and isonitrile with AgCN. SECTION D (a) (i) Account for the following : () Tendency to show -2 oxidation state decreases from Oxygen to Polonium in Group-16. (I) Among the noble gases, only Xenon is known to form chemical compounds. (I) Axial Br - F bonds are slightly bent in the structure of BrF,. Page 8 of 2032, (b) (a) (b) Gi) @ Gi) w aw @ i) Gi) (iv) © oye & Si) Draw the structures of KeF, and XeF., Be OR When MnO, is heated with conc, HCl a pungent coloured gas (A) is evolved. (A) reacts with excess NH, to give a colourless gas (B). However, when excess (A) is reacted with NH, it gives an explosive (C), Identify (A), (B), (C), with equations. Arrange the following in the increasing order of the property indicated () Xe, Kr, Ar, Ne, He — Boiling point () HF, HCl, HBr, HI— Thermal stability 34225 Identify A, B and C in the following reactions : Br © Mg, dry Ether, Gi) CO, PCls, Gi) H,O CrOs, , dil. NaOH 4, A (0) CH;—CH,OH Bsc By what tests will you distinguish between : @) Ethanol and Benzaldehyde (1) Acetone and Acetic acid 342-5 OR Name the reagents used in the following reactions 0 ee ap CH, COO7 K* CH-CH,-OH Write the structure of oxime of propanal. Why does carboxylic acid not give reactions of aldehydes and ketones ? Arrange the following in the increasing order of their reactivity towards nucleophilic addition reaction COCH, CH;CHO, HCHO, CH, -G-CH, oO 241414155 Page 9 of 20 P.T.O.(b) @ Gi) @ a ae Caleulate emf of the following cell at 298 K : AL (s) | AlS* (0-1 MD || Cu?* (0-01 M) | Cu (s) Given : Ez.) = 2-00 V (log 10 = 1) Define molar conductivity. On dilution, why does the molar conductivity of HCOOH increase drastically, while that of HCOONa increases gradually ? 34225 OR The electrical resistance of a column of 0:02 M NaOH solution of diameter 1-40 cm and length 44 cm is 5-00 x 10? ohm. Calculate its resistivity, conductivity and molar conductivity. Depict the galvanic cell in which the reaction takes place : Ni (s) + 2Ag* (aq) ——> Ni®* (aq) + 2Ag (s) Further show : (1) Which of the electrodes is positively charged ? (1) The carriers of the current in the outer circuit. 34225 Page 10 of 20oe Set~1 Series 1HKPQ6/C asa. 56/1/1 aad ater ats A oeyer } ge « . raga fered | © gra ate a oi fi ga wera Fi afga ye 102 1 + weewa a qfet wa ft it Re me as FER HT oa TR- ger & yas H fir | + grote a di fe ga wea 33 wee «Bea rea er ae feraet Ye wet Ses, Wes a ei saree fre | © sea a agt & fore 15 five ar ae fear war 2 | weave ar faa gate 10.15 aa fT STET | 10.15 FS 4 10.30 aS oH ora Fae wea BT TSA ott ge Hale & dhe 4 oe-gferaT WH get we feral | Aratita ara: 3 qe ares Fear: rcrber het FER at Ee ATTA a TET SIR TTT AE A TTT ITE w@ (ii) Gi) (iv) @ (vi) (vii) (viii) ae wed a gust H fasta Fear wen 2 — a, G, 1 ed I ge Med HBS sed E | are eH oitiart @ 1 Gus & FH wer Fe 1 a 16 ae sift oy-THIN VaR % wer 8, Were yer MTT 1 ate HTB | WRT BT TH Oh HG A TH aT HATE | US HH WET HOTT QE TH TY-THIT VOR Wes B, Mobs eT Tat Te | Us 7H eT HOT 26 430 TH PETA VERT H Wer B, Mea VETS sat HTB | wus oF ved HE 81 B33 ae Pls VEN-M % WEI w, Voda MEAS sey eT 2 | a Ha rae eB | ae, cee-wm oi AH sat wi, aah stead a iach sieht & a eat # rer aaah arate # ome Fr me @ | Oe meat tt ae Om ah aay a Te BATE | sa sift, sirazrwargen, Wes aus sik wer a rer weiter Fee fee ae & | Repeier area aii Bact wai Ht spat TEE | 56/1/1 | Page 11 of 20 P.T.O.ee wes 1 are feu ne aged at ofgu cen Prefefad weil & ser fie 4x1=4 eid @ onifen eyea ey Farr on waa 8 ae gre: A aE, aE, Bares, tune, wo & are we 21 a aegis odes aad Bot fe ae vif oT a TT wm 2 | tates test A gtagia cn (Peet) a etagin sre wR eT atta aot sore: af Ua Ba HUA E | fiat ahem a atte, feces cen qlee teil A gear ae fag vee fear Stee 1 reafetira wea wefteeca wea @ Caer tea LAIN, are fees are finer HH sa aT THT ze? (A) CH,NO, (B) CH, CN (©) CH,-Ne (D) CH, ~CH, -CONH, Gi) Peafettaa HS ater aires Daath adler FE sepa Ren are & 2 (A) C,H,COC (B) CH, Coc! (©) CgH;-SOjH ) — C,H,-S0,C1 Gi) Prerferftza 4 8 srefta faeraa A vercrae ae 8 (A) (CH,),NH (B) (CH,)sN (© CH,-NH, (©) — C,H,-NH, Gv) anita fi aiftifen CH, - C1% snftas Farle yer: TAT (A) CH, (B) (CH,),NH (©) (CH,),N*cr (D) CH,-NH, aaa frafafisa tit 3 a fear gaara faeron ortferd & 2 (A) C,H;-NH, (B) — (C,H,)N (© C,H,),NH (0) CH,-NH, Page 12 of 20AS Rome aged a fee cen Praferttad weit & sex dif, 4x=4 aot & aren & oman w Braise froas arate faa wa fieiar H mea ot feof 1 oH aie fa 4 a weet at & — ohare ween wg afer mre | ahr sae we uftdao mer 3 de sreeaBien A wept S ore we Betis a wen Fe Bd E— gakeerht we yar aeigs | staiget aot we ater freq order we @ | eteiget fae Ft ones aT safes (stra) fren are 8 1 Freaferfeaa 194 (797 HET 2 (i) - (iv) 7 va afreRad Tar sae a wT war fear wate | Rreafertean Pracat #8 at om GAT I (A) after sik aro dai ad war @ at ar, afta A ae ore F | (8) aftmes sit are det adi wer %, veg are, siftrwers Ht at caret ae? I (©) aftmert ad wee 2, eg ST Tea ST? | (D) after wea wer 8, eg aT aA eT 2 | @) ofr: areata facrrt sere ar wath carter 2 eT areata faces 4 facras ail a sian sam war & creed @ aga aH Bare Gi) emer: aunt ate, safer ate ft gern HF afte ear aa 2 1 aR FaOh aie frees Forfa frerratind (Previa aanita) tt | Gi) sme: Bieigdt faerem arian % ara Ufsepa (ifr) fa sre 2 | FR, anites 9 atetigdt aor wa see ferech HS frac aa & | (iv) siftraa7; Fa AgNO, # KT sre rat 2 va UH eaTafia Get SAAT 2 | eT ae Agt arerti % saftey onftreitror 3 arer erat 2 erat iret: areiigdh rota ars fe aartar @ | are wiaigs ww verde 8 yeg Vers I sraeAT eI Aivatediiad ed (994 HON 3 B11) aelrarda Wed B: 3. SFT at Berra aicaar % ara ear ae 8 1 1 (A) fers erie (B) RENE aa (©) SRaPERS oie 0) wet ae act Page 13 of 20 P.T.O.frafefsd 4 8 am vac aida 8 ? (Fey HATH Mn = 25, Zn = 30, Cr (A) Mn3+ B) Zn? © oF @) se Paar Q adi a wa unite eiccer Grecettgpa Rese a ares aren @ set P uO] aH aT we Ter Q Te wer Hes oe E | ate wae: (A) PzQ, PQ, © PQ ©) P,Q argdiora Wrertergs aa) Harem 8 ali ; (A) star p wari Ai safeata ae 21 (BR) pwnd eet waa H aqaieata a 2 | (©) d-maret A arqufeafa act 21 © awh erat ‘Freaferfiad # 8 ata eregisr tangs walt avettat @ 7 () H-F @®) H-I (Cc) H-Br @) H-c [Colen),],(SO,), % Co A sitaefrare emt & (A) 42 (By +3 O +4 ©) +6 ‘Freafefad ferret 4 & ate erg sis & ara rete’ dpe sara 2? (A) HO (B) CNT © coo Oo co arat [CrCl,(ox),|- 9 Cr A soe Hem 2 : @ 6 @) 5 oO 4 @ 3 Page 14 of 20 aeae sreedaias tifa Qgricfiaaeiisrrsfeal-N-wraree II DFANISE I Yaz : (A) [Co(NH,),CKONO)ICL, (B) — [Co(NH,),C1,(NO,)]C1 (©) — [Co(NH,),CICNO,)ICL ) — [Co(NH,),(NO,)ICl, 10. 48 ang sifitieen 1 Cl CH, weet & (A) ads aifiBear (8) aa — feten often (©) fefen after (D) sade 8 a ate at erat frofetad aftiensi #2 aa ear aes i dia ert 2 1 (A) C,H,OH + HI —> C,H,1+H,0 (B) C,H,OH + HCl —> C,H,Cl+H,0 (© C,H,OH + HBr —> C,H,Br + 11,0 ) C,H,OH + HF —> C,H,F + 1,0 11. Fam oven & thet ar rte fifas agers ‘are fern rat & | 1 (A) ACB ACB ACB... (B) ABABAB... (©) ABC ABC ABC... (D) ABACACAB Preaferfeas ser (oer ear 12 16) Fas atfraers Ten see are ar were fear rate | Preaferfeare Prenoal & argh aan at Ae | (A) aaftert site aro at adh ae & atte aire, siftrmers At wet caret 8 | (B) afteer sit aro ai wai aor , og are, saftree A ah oe Te BI (©) after ae wert 8, 9g OT Tea we BL (D) afters yea wer @, Tey aT ae aT? 12, onfireerr Gria A gen 4 siaiangehisia aftr acta 8 | PRT: areal aye getagia crt aye 8 ott fe aidisnedfitaess orem aH cenfired Sar al 1 138. oifireer: Cl- Clady ft gern # F— Fara Farry Rete aed we 2 | aT: agit Sac op stfedtora warm 2 | 1 sera Page 15 of 20 P.T.O.sage (faa) 88 gor: aaeite Gi sieetas & ara hits aa eI agit ud stfeetion walfire freq aeomens aa € 1 1 are i afta HC) a eH FeCl, fat 27 FH FeCl, | after Far arefi eregis tha FeCl, #1 FeCl, stiaettarer wi Ta @ | 1 rae saree whe 2 | Tenia Wf Ufeserefees eae GAH sued Hh 2,4-DNP war vel Bar 31 1 Saige aa bse-arvee stifiear ae Sar 2 | araifaere ang fattram 8 wear Gea sree AICI, & aera at TAT? | 1 wee Feiteatea ea (TFT BET 17 & 25) cys eT & ait We WET 2 sTeF Te 9x2=18 17. (a) Seat At dead ferfiae ra: 2x12 @ —MH-2-aifet FY Cu wry 573 K ed Hed EL Gi) Aferfefera: seat At fire (CH,CO),O/H* 8 aarg are 2 1 were (>) Reaferftsn eae at Afar: 2x1=2 @ Fae a trate Gi) Uefa a fata 18, -eehitehd ud tear & ftom & asec fem a fee wae am fare Bar wer? acted ea tela % for & aver ra H ant ail dict 8? 2 19. (a) Aefefed age A deer a gerdia vafa fefer, 2x1=2 @ [Cor J G — [NKCN),> [etHTy HHI Co = 27, Ni = 28] erat oo) [Mn(H,0),|S0, #1 TUPAC a14 ferfaae, 1 Gi) [Fe(CN),|* sRrgearhta @ safe [FeF, | aggeacta 2, aa? [rere ants Fe = 26) 2x1=2 20, Preaferftsc siftifivar ster Hf ah ng 2: Br, +21 ——> 2Br-+1, Tt arf Bigat 0-30 M at aa 10 fire Tard Big HH aR 0-28 MME | TH Pra aA aT LF a A a A oT Fhe | 2 Page 16 of 20(a) Freiferftad & fare are die 2x1=2 @ tam agt afte deat age ate arte | @ Cr WH yee srs F| ora (>) Sar oa ahead aia sacar sai auld % 2 Gea uTgd, poate ai @ uate stadia saemsit % dav 3 G8 fae 2 2 22, Preaferfs sififearsit 4 afaifera ate at ferfae 2x1=2 @ —-aifdetel sire Gi) RRA tage Fete afte 23, Preaferfisa Qeftom afte & anit Fa eta So aafiefseen Goh @ Qe 2 sea sae a gat Taare “aifire 2x1s2 I cl @ “NT, NS i Gi) CHy~G—Cl, Clg CH, ~ Cl CHy 24, Preaferftsa sftifiearsit & fore anftarer ferftae : 2x1=2 @) Siar afiira — tata ar tesctaer G@) Sate ar aregieen aig aif ore % are, 25. we aed firaet thet ZMH 27 g mol}, 300 pm HR eras Al erfla wea afer sera B 1 ale FH Tel 6-6 gem @, at ata Uae ait A wena at Teer | 2 wen Wer Hear 26 3 30 Gel-seta ware] & wed & site vote WET 3 ater wre | 5X3=15 26. (a) E°(Cu**| Cu) arargeaey saree Fa 2? Cut area ar 3d!° faerra eta ea Mi ett face 9 arent 2 | Fah? Cu? &1 Cut ae @ efits eanfirca wr ae are 8? 3 are (o) Prferftan & fare are fare, 3x1=3 @ ae eng frengd wart & 1 Gi) fre Fawr Tae aa? | Gi) aris aside & aa +4 A se ailedior sae quia @ sah sien & wa +7 Rar 2 | Page 17 of 20 PTO.(a) Revferftaa 3 fate Ffare ; 3x1=3 @ War wa wer tifereran wae sree OF sre wer orraeae GAT oiret (iii) DNA a RNA’ at (bo) eater & are after fee ax1=3 @ HEN Gi) Bry Gi) 28. aig after & fee fesferfad Sar sea ee X+Y¥ —> 39 art (xi/M (yl /M REI M minv 1 o1M 02M 0-05 2 02M 02M 0-10 3 o1M o1M 0-05 @ XwryS ana sittin A ae are Fre | @) Rem aise fear Gi) a feats ara Fifa | 3x1=3 29. Fe HI 293 KW aM Ga 17536 mm Hg @ | Fa 20 g TATA (HER ZIM = 180 g mol!) i 500 g ae a facta freer oer @, at acta fares & arr cre A oT ifr | 3 30, Fieaferfiad & fare ere Afire : Sx1=8 @ Re A eetaginertt sfceeraa oR erat 8 1 i) Beater AKL after & Shor eRe are aT se aE Par TAT a Gi) Usa tangs KCN % ara age TH AgCN & aa sigan 23 Z| wea WRT HOM BL AIS Teh sere WAL H wed & aie Ve METS THF BT F | Bx5=15 31. (a) Gi) Raffa & fery aren difire (Fhe 4 afer @ dicifas ce -2 siete sae quit ft waft wedi @ 1 septa Ae aa dae sais carafe alfre aar & fore art ore 2 1 (I) BrF, $1 ert F Br—F seta orate ats & gw ara @ | Page 18 of 2032, (b) (a) (b) Gi) @ Gi) wi (ii) a (ii) Gi) (iv) S oe & Si XeF, Wd XeF, #1 Head TAT | 3H arat Wa MnO, #1 arg HCl % ae ef fear sre 2, at um ater Gia Ata (A) Freeri 8 1 (A) A siftifear onftiey NH, @ sant w Grd Ate (B) aT 2 af NH, # saftraa (A) & sififisar arard @, dt ww faeries (C) aa 2 | (A), (B) Fa (C) Br TeaTe TE aa ata ferfaT, | rattan a fee me a & ome we age EE a HT ora aT, i} Xe, Kr, Ar, Ne, He — #aeraié (i) HF, HCl, HBr, HI — arta enti 34255 Pafefad afibensi 7 A, Baa Ca Teaae Br o Cy Meme, , BO, y Pb (iD CH,—CH,OH 8a, 4, MMOH AL fra ude @ freaferfiad 4 fate wah; Drie cr Aafeses Ueda en Belew ara B42=5 aaa restora fitment & weg 3 are afta & orm fre CH,CH, 9 COO” K* 7 2 (i) CH, =cH-cHo —+ cn, = cH-cH,- on atte & afar A der ferfiae 1 Yesers ud Fata ft afiinant erciftetern sea wil val 2a 82 Pretea aA aReaert) aera (eee) ARB sf saRiBaefera 3 ag Ba A orale Ai : COCH, CH;CHO, HCHO, CH, G- CH, 241414125 Page 19 of 20 P.T.O.(b) @ (ii) w aw ae freaferfiad Get % fore 298 K 4 fa-at.act (emf) A ORT ifSre, AL(s) | AIS* (0-1 M) || Cu?* (0-01 M) | Cu (s) fen man @ : Bg = 2:00 V (log 10 = 1) Tet area Ht oferta Sifae | aq Se HK HCOOH 1 tet aera aha weil aged &, safs HCOONa A HR aad @ 2 34225 aeeat 0-02 M NaOH face % stem = qa whee 5-00 x 109 ohm @ | Fae ATE 1-40 cm Ud Tae 44 om 2 | gah wfcdeaeT, reTaAT ae Aree Tea FAT ufcrert Fie | va teat daw caige fret Pevferfad after at 2 Ni (s) + 2Ag* (aq) —> Ni? (aq) + 2Ag (8) ora Forage, (Beem geagte eres srafira & 2 aD wet sive 4 fgg oro & ores F | 34225 Page 20 of 20