Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II (including amendments) - United Kingdom (UK)

SAFETY DATA SHEET

Version
1
TRETOLITE* DMO86334

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Product name : TRETOLITE* DMO86334
Product code : DMO86334
Product type : Liquid.

1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Demulsifier

1.3 Details of the supplier of the safety data sheet

Baker Hughes
Kirkby Bank Road,
Knowsley Industrial Park,
Liverpool,
L33 7SY, UK

Tel: +44 (0)151 545 3899

Fax: +44 (0)151 547 3590

e-mail address of person : paul.chapman2@bakerhughes.com

responsible for this SDS

1.4 Emergency telephone number

Supplier
Telephone number : CHEMTREC Emergency Telephone within UK: 0870 820 0418
CHEMTREC Emergency Telephone outside UK: +44 870 820 0418

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Directive 1999/45/EC [DPD]
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : F; R11
Carc. Cat. 3; R40
T; R39/23/24/25
Xn; R20/21/22
Xi; R38
N; R51/53
Physical/chemical : Highly flammable.
hazards
Human health hazards : Limited evidence of a carcinogenic effect. Toxic: danger of very serious irreversible
effects through inhalation, in contact with skin and if swallowed. Harmful by
inhalation, in contact with skin and if swallowed. Irritating to skin.
Environmental hazards : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Date of issue/Date of revision : 25 November 2014 1/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
TRETOLITE* DMO86334

SECTION 2: Hazards identification

Flam. Liq. 2, H225
Acute Tox. 4, H302
Acute Tox. 4, H312
Acute Tox. 4, H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Carc. 2, H351
STOT SE 1, H370
STOT SE 3, H336
Aquatic Chronic 2, H411
See Section 16 for the full text of the R phrases or H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms :

GHS02 GHS08 GHS07 GHS09

Signal word : Danger
Hazard statements : Highly flammable liquid and vapour.
Harmful if swallowed, in contact with skin or if inhaled.
Causes serious eye irritation.
Causes skin irritation.
Suspected of causing cancer if inhaled.
Causes damage to organs.
May cause drowsiness or dizziness.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Prevention : Obtain special instructions before use. Wear protective gloves. Wear eye or face
protection. Wear protective clothing. Keep away from heat, sparks, open flames
and hot surfaces. - No smoking. Use explosion-proof electrical, ventilating, lighting
and all material-handling equipment. Avoid release to the environment. Do not
breathe vapour.
Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
Storage : Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazardous ingredients : Hydrocarbons, C10, aromatics, >1% naphthalene
methanol
naphthalene
Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs.

2.3 Other hazards

Substance meets the Not applicable.
criteria for PBT according P: Not available. B: Not available. T: Not available.
to Regulation (EC) No.
1907/2006, Annex XIII
Substance meets the Not applicable.
criteria for vPvB according vP: Not available. vB: Not available.
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : None known.
not result in classification

Date of issue/Date of revision : 25 November 2014 2/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
TRETOLITE* DMO86334

SECTION 2: Hazards identification

SECTION 3: Composition/information on ingredients

3.1 / 3.2 Substance/mixture : Mixture
Classification
% by
Product/ingredient Identifiers weight 67/548/EEC Regulation (EC) No. Type
name 1272/2008 [CLP]
Hydrocarbons, C10, REACH #: >=20, Xn; R65 STOT SE 3, H336 [1]
aromatics, >1% 01-2119463588-24 <25 R66, R67 Asp. Tox. 1, H304
naphthalene EC: 919-284-0 N; R51/53 Aquatic Chronic 2,
CAS: .64742-94-5 H411
(outside EU)
Index: 649-424-00-3
methanol REACH #: >=10, F; R11 Flam. Liq. 2, H225 [1] [2]
01-2119433307-44 <20 T; R23/24/25, Acute Tox. 3, H301
EC: 200-659-6 R39/23/24/25 Acute Tox. 3, H311
CAS: 67-56-1 Acute Tox. 3, H331
Index: 603-001-00-X STOT SE 1, H370
naphthalene EC: 202-049-5 >=1, Carc. Cat. 3; R40 Acute Tox. 4, H302 [1] [2]
CAS: 91-20-3 <2.5 Xn; R22 Carc. 2, H351
Index: 601-052-00-2 N; R50/53 Aquatic Acute 1, H400
Aquatic Chronic 1,
H410
Hydrocarbons, C9, REACH #: >=1, R10 Flam. Liq. 3, H226 [1]
aromatics 01-2119455851-35 <2.5 Xn; R65 STOT SE 3, H335 and
EC: 918-668-5 Xi; R37 H336
CAS: .64742-95-6 R66, R67 Asp. Tox. 1, H304
(outside EU) N; R51/53 Aquatic Chronic 2,
H411
Benzenesulfonic acid, REACH #: >=1, <3 Xn; R22 Acute Tox. 4, H302 [1]
4-C10-13-sec-alkyl 01-2119490234-40 C; R34 Skin Corr. 1C, H314
derivs. EC: 287-494-3 Aquatic Chronic 3,
CAS: 85536-14-7 H412

See Section 16 for See Section 16 for the

the full text of the R- full text of the H
phrases declared statements declared
above. above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this
section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
Occupational exposure limits, if available, are listed in Section 8.

Date of issue/Date of revision : 25 November 2014 3/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
TRETOLITE* DMO86334

SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention.
Continue to rinse for at least 15 minutes. Chemical burns must be treated promptly
by a physician.
Inhalation : Move exposed person to fresh air. Keep person warm and at rest. If not breathing,
if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Skin contact : Get medical attention immediately. Flush contaminated skin with plenty of water.
Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves. Continue to rinse for at least 15
minutes. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Wash out mouth with water. If material has
been swallowed and the exposed person is conscious, give small quantities of water
to drink. If vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May
cause drowsiness or dizziness.
Skin contact : Harmful in contact with skin. Causes skin irritation.
Ingestion : Harmful if swallowed. Can cause central nervous system (CNS) depression.
Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to medical doctor : No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
Specific treatments : Not available.

Date of issue/Date of revision : 25 November 2014 4/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
TRETOLITE* DMO86334

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable
Not suitable
5.2 Special hazards arising from the substance or mixture
Special exposure hazards
Hazardous thermal
decomposition products
5.3 Advice for fire-fighters
Special protective
equipment for fire-fighters
Additional information
: Use dry chemical, CO₂, water spray (fog) or foam.
: Do not use water jet.
: Highly flammable liquid and vapour. In a fire or if heated, a pressure increase will
occur and the container may burst, with the risk of a subsequent explosion. Runoff
to sewer may create fire or explosion hazard. This material is toxic to aquatic life
with long lasting effects. Fire water contaminated with this material must be
contained and prevented from being discharged to any waterway, sewer or drain.
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
: Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
: Not available.

SECTION 6: Accidental release measures

6.1 Personal precautions,
protective equipment and
emergency procedures
6.2 Environmental
precautions
6.3 Methods and materials for containment and cleaning up
Small spill
Large spill
6.4 Reference to other
sections
: If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials.
: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities. Collect spillage.
: Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble or absorb with an inert dry material and place in an appropriate
waste disposal container. Use spark-proof tools and explosion-proof equipment.
Dispose of via a licensed waste disposal contractor.
: Stop leak if without risk. Move containers from spill area. Approach the release
from upwind. Prevent entry into sewers, water courses, basements or confined
areas. Wash spillages into an effluent treatment plant or proceed as follows.
Contain and collect spillage with non-combustible, absorbent material e.g. sand,
earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations. Use spark-proof tools and explosion-proof
equipment. Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilt product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
: Note: see section 8 for personal protective equipment and section 13 for waste
disposal.

Date of issue/Date of revision : 25 November 2014 5/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
TRETOLITE* DMO86334

SECTION 7: Handling and storage

7.1 Precautions for safe : Eating, drinking and smoking should be prohibited in areas where this material is
handling handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
7.2 Conditions for safe storage, including any incompatibilities
Storage : Store in accordance with local regulations. Store in a segregated and approved
area. Store in original container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see Section 10) and food and
drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not
store in unlabelled containers. Use appropriate containment to avoid environmental
contamination.
Recommended Packaging : Use original container.
materials
7.3 Specific end use(s) : Demulsifier
Not available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limits
Product/ingredient name
methanol
naphthalene
Recommended monitoring
procedures
8.2 Exposure controls
Occupational exposure
controls
Hygiene measures
Respiratory protection
Exposure limit values
EH40/2005 WELs (United Kingdom (UK), 12/2011). Absorbed
through skin.
STEL: 333 mg/m³ 15 minutes.
STEL: 250 ppm 15 minutes.
TWA: 266 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
EU OEL (Europe, 12/2009). Notes: list of indicative
occupational exposure limit values
TWA: 10 ppm, 0 times per shift, 8 hours.
TWA: 50 mg/m³, 0 times per shift, 8 hours.
: If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for
methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous
substances.
: Use only with adequate ventilation. Use process enclosures, local exhaust
ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapour or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
: Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and
the safe working limits of the selected respirator.

Date of issue/Date of revision : 25 November 2014 6/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
TRETOLITE* DMO86334

SECTION 8: Exposure controls/personal protection

Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary.
Eye protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
Skin protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
DNELs
Ingredient name Exposure DNELs Population Effects
Hydrocarbons, C10, aromatics, >1% Long term 12.5 mg/ Workers Systemic
naphthalene Dermal kg bw/day
Long term 151 mg/m³ Workers Systemic
Inhalation
methanol Long term 260 mg/m³ Workers Systemic
Inhalation
Short term 260 mg/m³ Workers Local
Inhalation
Long term 260 mg/m³ Workers Local
Inhalation
Short term 260 mg/m³ Workers Systemic
Inhalation
Long term 40 mg/kg Workers Systemic
Dermal bw/day
Short term 40 mg/kg Workers Systemic
Dermal bw/day
naphthalene Long term 25 mg/m³ Workers Systemic
Inhalation
Long term 3.57 mg/ Workers Systemic
Dermal, kg bw/day
Inhalation
Long term 25 mg/m³ Workers Local
Inhalation
Hydrocarbons, C9, aromatics Long term 25 mg/kg Workers Systemic
Dermal bw/day
Long term 150 mg/m³ Workers Systemic
Inhalation
DEL Summary : Not available.
PNECs
Ingredient name Compartment Detail PNECs Method Detail
methanol Fresh water 20.8 mg/l Assessment Factors
Marine 2.08 mg/l Assessment Factors
Sewage Treatment 100 mg/l Assessment Factors
Plant
Fresh water sediment 77 mg/kg -
Soil 3.18 mg/kg dwt -
Marine water sediment 7.7 mg/kg -
naphthalene Fresh water 2.4 μg/l Assessment Factors
Marine water sediment 2.4 μg/l Assessment Factors
Sewage Treatment 2.9 mg/l Assessment Factors
Plant
Fresh water sediment 67.2 μg/kg dwt -
Marine water sediment 67.2 μg/kg dwt -
Soil 53.3 μg/kg dwt -
PEC Summary : Not available.

Date of issue/Date of revision : 25 November 2014 7/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
TRETOLITE* DMO86334

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid.
Colour : Brown.
Odour : Aromatic.
Odour threshold : Not available.
pH : Not available.
Boiling point : >=65°C (>=149°F)
Melting point/freezing : <-30°C (<-22°F)
point
Flammability (solid, gas) : May be combustible at high temperature.
Flash point : Closed cup: >11°C (>51.8°F)
Explosive properties : Not available.
Explosion limits : Not available.
Oxidising properties : Not available.
Vapour pressure : Not available.
Density : Not available.
Relative density : 0.952 to 0.98 (16°C)
Solubility : Insoluble in the following materials: cold water.
Partition coefficient: n- : Not available.
octanol/water
Viscosity : Kinematic (40°C): 15 to 50 cSt
Vapour density : Not available.
Evaporation rate (butyl : Not available.
acetate = 1)
Decomposition : Not available.
temperature
Auto-ignition temperature : Not available.
9.2 Other information
Pour point : Not available.

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : The product is stable.
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid
release to the environment.
10.5 Incompatible :
materials
10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.

Date of issue/Date of revision : 25 November 2014 8/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
TRETOLITE* DMO86334

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Potential acute health effects
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May
cause drowsiness or dizziness.
Ingestion : Harmful if swallowed. Can cause central nervous system (CNS) depression.
Irritating to mouth, throat and stomach.
Skin contact : Harmful in contact with skin. Causes skin irritation.
Eye contact : Causes serious eye irritation.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Hydrocarbons, C10, LD50 Oral Rat 3200 mg/kg -
aromatics, >1% naphthalene
LD50 Oral Rat >2000 mg/kg -
methanol LC50 Inhalation Vapour Rat 128.2 mg/l 4 hours
LD50 Dermal Rabbit 17100 mg/kg -
LD50 Oral Rat >=2528 mg/kg -
naphthalene LD50 Oral Rat 490 mg/kg -
Benzenesulfonic acid, LD50 Oral Rat 1470 mg/kg -
4-C10-13-sec-alkyl derivs.

Product name Carcinogenic Mutagenic effects Developmental Fertility effects

effects effects
naphthalene Carc. 2, H351

General : No known significant effects or critical hazards.

Carcinogenicity : Suspected of causing cancer if inhaled. Risk of cancer depends on duration and
level of exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Inhalation : Adverse symptoms may include the following:

nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Ingestion : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness

Date of issue/Date of revision : 25 November 2014 9/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
TRETOLITE* DMO86334

SECTION 12: Ecological information

12.1 Toxicity : Water polluting material. May be harmful to the environment if released in large
quantities. This material is toxic to aquatic life with long lasting effects.
Aquatic ecotoxicity
Product/ingredient name Result Species Exposure
Hydrocarbons, C10, Acute LC50 2 to 5 mg/l Fish 96 hours
aromatics, >1% naphthalene
methanol Acute EC50 10000 ppm Fresh water Algae - Prorocentrum minimum 96 hours
Acute EC50 >10000 mg/l Fresh water Daphnia 48 hours
Acute EC50 10000000 μg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 15400 mg/l Fresh water Fish 96 hours
Acute LC50 100 mg/l Fresh water Fish - Pimephales promelas - 96 hours
Juvenile (Fledgling, Hatchling,
Weanling)
naphthalene Acute EC50 1.96 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute EC50 1.6 ppm Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 2800 μg/l Marine water Crustaceans - Elasmopus 48 hours
pectenicrus - Adult
Acute LC50 315 μg/l Fresh water Fish - Melanotaenia fluviatilis - 96 hours
Larvae
Chronic NOEC 0.67 ppm Fresh water Fish - Oncorhynchus kisutch 40 days

Conclusion/Summary : Not available.

12.2 Persistence and degradability
Conclusion/Summary : Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Hydrocarbons, C10, aromatics, >1% - - Not readily
naphthalene
naphthalene - - Not readily
12.3 Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Hydrocarbons, C10, aromatics, >1% 2.8 to 6.5 99 to 5780 high
naphthalene
methanol -0.77 <10 low
naphthalene 3.4 36.5 to 168 low
Benzenesulfonic acid, 4-C10-13-sec- 3.2 - low
alkyl derivs.
12.4 Mobility in soil : Not available.
12.5 Results of PBT and vPvB assessment
PBT : Not applicable.
P: Not available. B: Not available. T: Not available.
vPvB : Not applicable.
vP: Not available. vB: Not available.
12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Empty
containers or liners may retain some product residues. This material and its
container must be disposed of in a safe way. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Disposal of this product,
solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local
authority requirements. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.
Date of issue/Date of revision : 25 November 2014 10/14
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
TRETOLITE* DMO86334

SECTION 13: Disposal considerations

Hazardous waste
Packaging
Methods of disposal
13.2 Additional information
Special precautions
: The classification of the product may meet the criteria for a hazardous waste.
: The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
: This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Vapor from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.

SECTION 14: Transport information

International transport regulations
Regulatory 14.1 UN 14.2 Proper shipping name 14.3 Transport 14.4 PG* Label
information number hazard class(es)
ADR/RID Class UN1993 FLAMMABLE LIQUID, N.O.S. 3 II
(contains methanol)

ADN Class UN1993 FLAMMABLE LIQUID, N.O.S. 3 II

(contains methanol)

IMDG Class UN1993 FLAMMABLE LIQUID, N.O.S. 3 II

(contains methanol)

IATA Class UN1993 FLAMMABLE LIQUID, N.O.S. 3 II

(contains methanol)

PG* : Packing group

Regulatory 14.5 14.6 Special precautions for user Additional
information Environmental information
hazards
ADR/RID Class Yes. Special provisions UK Hazchem: 3YE
640 (C)

Tunnel code
(D/E)
ADN Class Yes. - -

Date of issue/Date of revision : 25 November 2014 11/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
TRETOLITE* DMO86334

SECTION 14: Transport information

IMDG Class Yes. - -

IATA Class No. - -

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Proper shipping name : Not available.
Ship type : Not available.
Pollution category : Not available.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Other EU regulations
Europe inventory : Not determined.
Black List Chemicals : Not listed
Priority List Chemicals : Not listed

15.2 Chemical Safety : This product contains substances for which Chemical Safety Assessments are still
Assessment required.

SECTION 16: Other information

16.1 Revision comments : Not available.
Indicates information that has changed from previously issued version.
16.2 Abbreviations and : ATE = Acute Toxicity Estimate
acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
16.3 Key literature : Not available.
references and sources for
data
16.4 Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 2, H225
Acute Tox. 4, H302
Acute Tox. 4, H312
Acute Tox. 4, H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Carc. 2, H351
STOT SE 1, H370
STOT SE 3, H336
Aquatic Chronic 2, H411

Date of issue/Date of revision : 25 November 2014 12/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
TRETOLITE* DMO86334
SECTION 16: Other information
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification
Flam. Liq. 2, H225
Acute Tox. 4, H302
Acute Tox. 4, H312
Acute Tox. 4, H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Carc. 2, H351
STOT SE 1, H370
STOT SE 3, H336
Aquatic Chronic 2, H411
16.5 Full text of abbreviated
H statements
Full text of classifications
[CLP/GHS]
Date of issue/Date of revision : 25 November 2014
Justification
On basis of test data
Calculation method
Calculation method
Calculation method
Calculation method
Calculation method
Calculation method
Calculation method
Calculation method
Calculation method
: H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation. May cause drowsiness or dizziness.
and
H336
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer if inhaled.
H370 Causes damage to organs.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
: Acute Tox. 3, H301 ACUTE TOXICITY: ORAL - Category 3
Acute Tox. 3, H311 ACUTE TOXICITY: SKIN - Category 3
Acute Tox. 3, H331 ACUTE TOXICITY: INHALATION - Category 3
Acute Tox. 4, H302 ACUTE TOXICITY: ORAL - Category 4
Acute Tox. 4, H312 ACUTE TOXICITY: SKIN - Category 4
Acute Tox. 4, H332 ACUTE TOXICITY: INHALATION - Category 4
Aquatic Acute 1, H400 ACUTE AQUATIC HAZARD - Category 1
Aquatic Chronic 1, H410 LONG-TERM AQUATIC HAZARD - Category 1
Aquatic Chronic 2, H411 LONG-TERM AQUATIC HAZARD - Category 2
Aquatic Chronic 3, H412 LONG-TERM AQUATIC HAZARD - Category 3
Asp. Tox. 1, H304 ASPIRATION HAZARD - Category 1
Carc. 2, H351 CARCINOGENICITY: INHALATION - Category 2
Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Flam. Liq. 2, H225 FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3
Skin Corr. 1C, H314 SKIN CORROSION/IRRITATION - Category 1C
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2
STOT SE 1, H370 SPECIFIC TARGET ORGAN TOXICITY (SINGLE
EXPOSURE) - Category 1
STOT SE 3, H335 and SPECIFIC TARGET ORGAN TOXICITY (SINGLE
H336 EXPOSURE) [Respiratory tract irritation and Narcotic
effects] - Category 3
STOT SE 3, H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE
EXPOSURE) [Narcotic effects] - Category 3
13/14
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
TRETOLITE* DMO86334

SECTION 16: Other information

16.5 Full text of abbreviated : R11- Highly flammable.
R phrases R10- Flammable.
R40- Limited evidence of a carcinogenic effect.
R23/24/25- Toxic by inhalation, in contact with skin and if swallowed.
R39/23/24/25- Toxic: danger of very serious irreversible effects through inhalation,
in contact with skin and if swallowed.
R22- Harmful if swallowed.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R65- Harmful: may cause lung damage if swallowed.
R34- Causes burns.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapours may cause drowsiness and dizziness.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Full text of classifications : F - Highly flammable
[DSD/DPD] Carc. Cat. 3 - Carcinogen category 3
T - Toxic
C - Corrosive
Xn - Harmful
Xi - Irritant
N - Dangerous for the environment
16.6 Training advice : Not available.
16.7 Further information
Date of issue/ Date of : 25 November 2014
revision
Date of previous issue : No previous validation
Version : 1
Notice to reader
This information relates only to the specific material designated and may not be valid for such material used
in combination with any other materials or in any process. Such information is, to the best of the company's
knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or
representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy
himself as to the suitability of such information for his own particular use.

Date of issue/Date of revision : 25 November 2014 14/14