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AS 4564—2005
natural gas
Australian Standard™
Australian Standard™
COPYRIGHT
© Standards Australia
All rights are reserved. No part of this work may be reproduced or copied in any form or by
any means, electronic or mechanical, including photocopying, without the written
permission of the publisher.
Published by Standards Australia, GPO Box 476, Sydney, NSW 2001, Australia
ISBN 0 7337 6880 6
AS 4564—2005 2
PREFACE
This Standard was prepared by the Committee AG-010, Natural Gas Quality Specifications
to supersede AS 4564—2003 (AG 864-2003). It serves as a specification for general
purpose natural gas, with an emphasis on the safety of the gas for use in natural gas
appliances and equipment and for use as fuel in natural gas vehicles.
The quality specification provided by this Standard defines the requirements for providing a
natural gas suitable for transportation and for general purpose use and provides the range of
gas properties consistent with safe operation of the natural gas appliance population.
The Standard provides certainty for appliance manufacturers who supply appliances for use
in the Australian market.
Natural gas conforming to this Standard is suitable for transportation through pipelines,
however operational problems have been reported in transmission systems with sulfur
concentrations in natural gas below the 50 mg/m3 specified in this Standard. Research on
this issue is continuing. The outcome of the research will be taken into account in
subsequent review of the Standard.
Certain limits defined in the specification may be temporarily departed from under some
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circumstances. The issue of such departures is not within the scope of this Standard and is
subject to and provided for under relevant gas sales contracts, legislation and/or
government guidelines.
The Standard is not intended to apply to gas supplies where no ‘general purpose’ users are
connected to the supply system, e.g., a dedicated supply to an industrial user.
Gas consumers who have specific needs that are not provided for by the specification would
need to nominate in appropriate commercial contracts with gas suppliers or retailers the gas
composition suitable for their particular use.
The term ‘informative’ has been used in this Standard and applies to appendices that are for
information and guidance only.
3 AS 4564—2005
CONTENTS
Page
SECTION 2 REQUIREMENTS
2.1 SAFETY FOR USE ..................................................................................................... 6
2.2 CONTAMINANTS...................................................................................................... 6
SECTION 3 COMPLIANCE
3.1 DEMONSTRATION OF COMPLIANCE ................................................................... 7
3.2 TESTING .................................................................................................................... 8
APPENDICES
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STANDARDS AUSTRALIA
Australian Standard
Specification for general purpose natural gas
1.1 SCOPE
1.1.1 General
This specification sets out requirements that ensure that general purpose natural gas that is
transported and supplied is safe for use in natural gas appliances and equipment and for use
as fuel in natural gas vehicles.
The specification applies to natural gas—
(a) from petroleum, landfill, biogas, coal seam and other sources where these sources
provide gas for direct or blended supply on a commercial basis through supply
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1.2 DEFINITIONS
For the purpose of this Standard the following definitions apply:
1.2.1 General purpose natural gas
That natural gas that is suitable for transportation in transmission and distribution systems,
and which is safe for use in the general population of natural gas appliances and equipment
in Australia.
1.2.2 Higher heating value
The amount of energy in MJ/m 3 released when one cubic metre of dry gas, at standard
conditions, is completely burnt in air with the products of combustion brought to standard
conditions, with the water produced by combustion condensed to the liquid state.
NOTE: Higher heating value is also known as gross heating value or superior heating value.
1.2.3 Inert gas
Means any material that exists predominantly in a gaseous state at standard conditions and
which does not contribute to energy release when the gas burns. Inert gas includes but is not
limited to carbon dioxide, nitrogen, oxygen and noble gases.
1.2.4 Limit
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The value beyond which the specified characteristic or concentration of the component shall
not be permitted to vary.
1.2.5 Maximum allowable operating pressure (MAOP)
The maximum pressure at which a pipeline may be operated.
1.2.6 Natural gas
A gaseous fuel consisting of a mixture of hydrocarbons of the alkane series, primarily
methane but which may also include ethane, propane and higher hydrocarbons in much
smaller amounts. It may also include some inert gases, plus minor amounts of other
constituents including odorizing agents. Natural gas remains in the gaseous state under the
temperature and pressure conditions normally found in service.
1.2.7 Relative density
Often called specific gravity, it is the mass of dry natural gas divided by the mass of an
equal volume of dry air, both at the same specified pressure and temperature (see
ISO 6976).
1.2.8 Standard conditions
A temperature of 15°C and an absolute pressure of 101.325 kPa.
1.2.9 Total sulfur
Sulfur from all sources including odorization of the gas.
1.2.10 Wobbe Index
The number expressed in MJ/m3 produced when the higher heating value of the gas is
divided by the square root of the relative density of that same gas.
S E C T I O N 2 RE Q U IRE M E N T S
2.2 CONTAMINANTS
The gas shall not contain—
(a) materials, dust, and other solid or liquid matter, waxes, gums, gum forming
constituents, and unsaturated or aromatic hydrocarbons to an extent which might
cause damage to, or interfere with the proper operation of, pipes, meters, regulators,
control systems, equipment or appliances;
(b) unsaturated or aromatic hydrocarbons to an extent which causes unacceptable sooting;
(c) other substances to the extent that they cause damage to, or problems in operation of,
pipelines or appliances or that cause the products of combustion to be toxic, or
hazardous to health, other than substances that are usually found in natural gas
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combustion products.
S E C T I O N 3 CO M P L I A NCE
TABLE 3.1
SPECIFICATION LIMITS
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3.2 TESTING
Determination of the value of the properties of the gas shall be at a frequency that
reasonably confirms compliance at all times.
To meet this requirement, the measurement methods and equipment shall have acceptable
and sufficiently low uncertainty, traceable to certified Standards. However, this Standard
does not prescribe particular methods for any specific test.
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APPENDIX A
DERIVATION OF SPECIFICATION
(Informative)
A1 BACKGROUND
The specification encompasses the range of Australian natural gases in use at the time of
publication.
In order to retain the greatest flexibility of supply no attempt has been made to detail the
composition of the gas beyond those compounds normally regarded as gas contaminants and
which have a detrimental effect on the properties of the gas. Specification limits are
generally consistent with overseas practice. Australian gas appliance manufacturers and
most overseas manufacturers including those in Canada, Japan, New Zealand, the UK and
the USA, design appliances to operate safely with gases within the range of this
specification. In this respect the specification is intended to cover only those gases that are
primarily methane. This specification does not cover other gases such as LPG/air mixtures
and synthetic natural gas.
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A2 LIMITS
In any natural gas specification a balance must be achieved between optimum performance,
which requires the narrowest possible combustion limits, and cost of supply that, if
possible, requires no limits at all so that any available gas can be used. In an endeavour to
resolve this issue the limits are set as wide as possible while still maintaining safe
combustion performance in gas burning appliances certified for use in Australia. If the
specification of gas deviates outside the limits both safety and performance may be
compromised. This is dependent on the duration, and extent of the excursion.
Although rate of change of variables within the limits is not addressed in this specification,
it is a matter that may be addressed in gas supply contracts. It is relevant to the performance
of combustion control systems particularly in lean burn and low NOx applications. In
addition, rapid changes in Wobbe Index, for example, may lead to customer complaints, as
there may be a noticeable change in performance with some appliances.
Corrosion products from oxidation in steel pipelines have the effect of stripping the injected
odorant from gas.
A3.3 Hydrogen sulfide
The limitation on hydrogen sulfide in the gas is necessary because of its corrosive effects.
In the presence of water, hydrogen sulfide can cause hydrogen induced cracking and sulfide
stress cracking in high tensile steels at high pressure. This is of particular importance for
transportation of gas in steel pipes and for the use of natural gas in vehicles where natural
gas is typically stored at pressures up to 25 MPa.
Further information on the effects of hydrogen sulfide is contained in Appendix H of
AS 2885.1:1997.
A3.4 Total sulfur
A maximum permitted sulfur concentration of 50 mg/m3 includes sulfur from all sources
including odorization of the gas. Odorants commonly used in Australia contribute to the
sulfur level in the gas. In setting the sulfur limit, the use of flueless heating in Australia has
been taken into account.
Sulfur deposition is an operating issue in some transmission systems. This has occurred in
some systems with sulfur concentrations below 50 mg/m 3 and further research is required.
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A3.5 Water
This specification covers water content by nominating the dewpoint at maximum
transmission pressures. Additionally, an absolute limit (mg/m 3) is stated. Figure A1 defines
the water content in mg/m3 producing a dewpoint of 0°C for a range of transmission
pressures.
Liquid phase water can cause corrosion and the formation of gas hydrates in transmission
systems. In combination with hydrogen sulfide and carbon dioxide, water can also lead to
stress corrosion cracking and hydrogen embrittlement.
The stated limits are designed to ensure that hydrate formation and excessive corrosion do
not occur in transmission systems.
For applications such as natural gas vehicles requiring compression to higher pressure than
the maximum transmission pressure it may be necessary to use a gas dryer to remove
moisture from the gas to prevent liquid water or hydrate formation.
140
120
WATER CONTENT IN mg/m3
100
80
60
40
20
0
0 5 10 15 20 25
APPENDIX B
MATTERS THAT MAY BE CONSIDERED IN CONTRACTS
(Informative)
The following gas quality matters that are outside the scope of this gas specification may be
considered, if relevant, in gas transportation and supply contracts.
(a) The rate of change of critical parameters.
(b) Frequency of agreed tests for verification of compliance.
(c) Exchange of results of all monitoring/testing undertaken.
(d) Retention period for records of the tests carried out to verify compliance.
(e) Excursions and their duration outside the absolute limits set out in Table 3.1.
(f) Response actions to be taken relating to excursions, emergencies, etc.
(g) Commissioning activities, such as hydrostatic testing and drying of pipelines and
initial odorant injection activities.
NOTE: This is not an exhaustive list.
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APPENDIX C
DEMONSTRATION OF COMPLIANCE WITH THIS SPECIFICATION
(Informative)
C1 TEST METHODS
Table C1 below sets out details of methods that meet the requirements for analysis of
methane based gases to identify characteristic and components and confirm compliance
with this specification.
TABLE C1
TEST METHODS
Reference to a
Characteristics and suggested
Range
components test/calculation
method
Wobbe Index — ISO 6974
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ISO 6975
ISO 6976
Heating value — ISO 6974
ISO 6975
ISO 6976
Relative density — ISO 6974
ISO 6975
ISO 6976
ASTM D1070
Oxygen 0.001% to 0.5% ISO 6974
3
Hydrogen sulfide 0.1 to 100 mg/m ISO 6326
3
Total sulfur (as S) 0.5 to 1000 mg/m ISO 6326
ASTM D1072
Water 5 mg/m 3 to 5000 mg/m 3 if ISO 10101
concentration of sulfur compounds
in the gas is less than 20% of the
water content
Calculation of water vapour ISO 6327
content based on dewpoint ASTM D1142
measurement
Hydrocarbon dewpoint −40°C to +10°C See C1.1(b)
C1.1
Further details of some of the test methods referenced in Table C1 are provided in the
following:
(a) FLYNN, N. and DE LAPPE, B. Trace constituents in landfill gas. Task Report on
sampling and analysis. GRI-87/0018, 1988.
(b) DODDS, D.E. Determination of water vapor content and hydrocarbon dewpoint in
gas. 71st Proceedings of the International School of Hydrocarbon Measurement,
pp 541-543, 1996.
(c) ISO 5725-1.
C1.2
As Standards are subject to revision from time to time the most recent editions of the
Standards listed should always be used.
C1.3
More appropriate methods for testing may become available and these should be used
provided that the results of the tests are of known accuracy and reproducibility.
C2 PRECISION OF MEASUREMENT
To demonstrate compliance with this Standard it is necessary to show, at the accepted levels
of precision of the test/calculation methods, that the value of a characteristic or
concentration of a component is not beyond the specified limit.
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APPENDIX D
LIST OF REFERENCED STANDARDS
(Informative)
AS
2885 Pipelines—Gas and liquid petroleum
2885.1:1997 Part 1: Design and construction
ISO
4259 Petroleum products—Determination and application of precision data in
relation to methods of test
5725 Accuracy (trueness and precision) of measurement methods and results
5725-1 Part 1: General principles and definitions
6326 Natural gas— Determination of sulfur compounds
6327 Gas analysis—Determination of the water dew point of natural gas—Cooled
surface condensation hygrometers
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APPENDIX E
SUGGESTED READING
(Informative)
Specialist text should be consulted for detailed discussion of natural gas characteristics in
this Standard. Some examples are given below.
DUTTON, B.C. A new dimension to gas interchangeability, Inst. Gas Eng communication
number 1246, 1984.
GILBERT, M.G. and PRIGG, J.A. The prediction of combustion characteristics of town
gas, Trans Inst. Gas Eng. 106, p 503, 1956.
HARRIS, J.A. and LOVELACE, D.E. Combustion characteristics of natural gas and
manufactured substitutes, Inst. Gas Eng. Journal, pp 169-185, 1968.
WU, H.L. and JASIEWICZ, J. The influence of higher hydrocarbons and inert gases on the
stability of natural gas flames, Journal of the Institute of Fuel, Vol. 45 (December 1972),
pp 609-614.
FRANCE, D.H. Combustion interchangeability of second-family gases, Journal of the
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