Chemical Equilibrium

Beginner’s Box - 1
Solutions

Ans has the reaction

QI CC ) :
Dynamicboth equilibrium
-

the directions and

going radioactive
in
therefore
the Iz can be
found in both
reactants and products .

- ' 5
h G
QI Kc
°

: = . x to

observe small value

of
'
We a Kc
very very
-
. -

and since

Kc = [Product
[ Reactant ]
r
: [ Product ] case [ Reactant ]

}Au
Reaction
-
:
is
shifted towards
left
of product relatively smalls
and conc . is

Ans CA ) On
equilibrium concentration
reaching
03 -
the
,
=

of
becomes
" '

constant
'

C .

Qu ( is Calo
,
→
Cao t
coz ; Ks =
Pco ,
=
Latin
=

Cii ) CO, t C →
20 ; Kz = Gath

( ist Lii ) Cacozt C → Cao t 20

; Ks = K, -
Kz

t.kz = 12 atm
'

AIS By :
ANKIT GAUR Sir
 6.3×10-5
EI ( i) GHS Coon
H2O Gtf Coo
thot Kz
-

t f t
j
⇐

6.3×109
( ii ) Gtf Cg Hs Coo H2O ;
-

T
-

Coon t on + Kz =

( i) Lii ) Hz Ot Kfz
-

H2O t H2O F t OH
; K
,
=

←
: K
,
= 6.3×10-5 = 10-14
6.3×7 Ans
=

QE ( it Mtlzaz F MU ; kz -
-

Pz

Cii ) MU t
Iza ,
T Maz ; Kz =
Pz

Ciii ) Ma, MU
the Az F
, ; K
,
=
Pz

( ist
3- K K K
) Ciii ) M t
Uz F Maz ; K2
-

+
,
.
-
-

i . K -
-

Ps -

Pz .

Ps

Taking leg on both sides

Azs lagk -

log Pst by Pz +
bgp ,

Et ke
a÷B, i ke i 's
;pf÷
-
-

'
CK ) ka )
=f÷ =
'S
-

,
.
, ,

bus
=

By :
ANKIT GAUR Sir
 5- TSE SI
-

08 ( is
; ke -
-
12
=
( ii 5- +25 F
Sj 132
Kz
-

) ;
o
=

522 Sj ¥
-
-

Cii ) t s = j Kz =

-
lis

: .

Kz =

1,322 =
11
AIS

0¥ Nzoucg , = 2 Noa
cg , ; Kp
-

¥1
[
Pray ]
Dng = 2-1=1
'

Kc =
Coz ]
-

Kc ( RT ) AT
'
°o° [ Nzou ]
Kp =

then
if
'

RT= I
Kp Kc
- -
-
-

In ¥0821
T -
-

-1=12.18 K Ans
=

"
(RT) '
0¥ X :
Dng I
KI
o
-
-
-
: =

Y t1
Dng
: = ,

Z :
Ang
-
-
O o
.

.
XLZCY {for RT > I }
Ans
=

'"
8 and
Ey
o

:
Kp -
- K
,
(A) Joe Pasig ,
F
Pasig ,
+
Uscg,
Ang =L

Kp kn
.
-

. . -

when PT = I

-
: at f- Iatm By :
Ans ANKIT GAUR Sir
=
 For
50292cg
012
= ,
←
502cg , t
42cg , ; Ang =L

-
'

KI =
( RT ) 1=3
Kc

RT = 3

T=
I =

03%2 = 36.54K
AID
,

013 ( i)
Iz Nz t
Iz Hz = Nth ; Kp 6 Kz
= =

Cii )
2MHz = Nz 1--3112 ; Kp =
Kz =

I
: Cii Cis multiplied with (2)
-

) is inverse
of
Kz I
'

. . =

142
Ans
=) Kz =
# =
O - 028
=

By :
ANKIT GAUR Sir