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WPE304 Lab Report
WPE304 Lab Report
Assignment On
Submitted By
S.N Name ID Batch
1 Md. Rasel Rana 1924205044 42nd
2 Morsheda akter 1924205069 42nd
3 Noor A Siam 1924205062 42nd
4 Md.Alamin 1924205056 42nd
5 Mehedi Hasan Rahat 1924205076 42nd
6 Md Mamun Hossain 1924205050 42nd
7 Khandakar Alinur 1924205045 42nd
8 Md.Ali Hossain Rajib 1924205096 42nd
9 Ismaiel Hossain Jahid 1924205101 42nd
10 Md. Samiul alim 1924205080 42nd
Experiment No: 01
Experiment name: layout of wet processing laboratory.
Introduction:
A wet lab is type of laboratory where it is necessary to handle various types of chemicals
and potential wet hazards. The room has to be carefully designed, constructed and controlled to avoid
spillage and contamination.
Objective:
1)To know about different machine used in wet lab.
2)To know about construction and instrumental layout of wet processing laboratory.
3)To know about different chemical and dyes.
Description:
Acid dye:
Water soluble anionic dyes that are applied to fibres such
as silk, wool, nylon and modified acrylic fibres from neutral to acid dyebaths. Attachment to the fibre is
attributed, at least partly, to salt formation between anionic groups in the dyes and cationic groups in the
fibre. Acid dyes are not substantive to cellulosic fibres.
Basic dye:
Water soluble cationic dyes that are mainly applied to acrylic fibres but find some use for wool,
and silk. Usually acetic acid is added to the dyebath to help the take up of the dye onto the fibre. Basic
dyes are also used in the coloration of paper.
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Vat dye:
These dyes are essentially insoluble in water and incapable of dyeing fibres directly. However,
reduction in alkaline liquor produces the water-soluble alkali metal salt of the dye. In this leuco form
these dyes have an affinity for the textile fibre. Subsequent oxidation reforms the original insoluble dye.
Reactive dye:
First appeared commercially in 1956, after their invention in 1954 by Rattee and Stephens
at the ICI Dyestuffs Division site in Blackley, Manchester, UK. They are used to dye cellulosic fibres.
The dyes contain a reactive group, either a haloheterocycle or an activated double bond, that, when
applied to a fibre in a weakly alkaline dyebath, forms a chemical bond with an hydroxyl group on the
cellulosic fibre. Reactive dyeing is now the most important method for the coloration of cellulsic fibres.
Reactive dyes can also be used to dye wool and nylon, in the latter case they are applied under weakly
acidic conditions.
Dyeing is normally carried out in a neutral or slightly alkaline dyebath, at or near the boil, with
the addition of either sodium chloride (NaCl) or sodium sulphate (Na2SO4). Direct dyes are used on cotton,
paper, leather, wool, silk and nylon. They are also used as pH indicators and as biological stains.
Chemicals:
Acid:
acid are highly water soluble, and have better light fastness than basic dyes.The textile acid dyes are
effective for protein fibers such as silk, wool, nylon and modified acrylics. They contain sulphonic acid
groups, which are usually present as sodium sulphonate salts. These increase solubility in water, and give
the dye molecules a negative charge. In an acidic solution, the -NH2 functionalities of the fibres are
protonated to give a positive charge: NH3+. This charge interacts with the negative dye charge, allowing
the formation of ionic interactions. As well as this, Van-der-Waals bonds, dipolar bonds and hydrogen
bonds are formed between dye and fibre. As a group, acid dyes can be divided into two sub-groups: acid-
leveling or acid-milling.
Salt:
Salt is necessary in three ways, firstly, to drive dye into textile during the dyeing process in textile.
Secondly, use of salt leads to maximum exhaustion of dye molecules during dyeing process in textiles.
Thirdly it is used as an electrolyte for migration, adsorption and fixation of the dyestuff to the cellulose
material.
Scouring agent:
Scouring agent in textile refers to a large number of auxiliaries with functions of
emulsifying, penetrating, washing, dispersing and wetting in the scouring process before dyeing and
printing, in order to remove oil stains and impurities from the textile fibers.
Washing agent:
soaping is used for washing in textile material.
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Brightening agent:
This agent is used to increase the brightness of textile materials.
Anti-creasing agent:
usually used in dye bath on finishing stage to prevent creasing fabric.
Conclusion:
wet processing lab plays a vital role in the quality control of wet processing department.
Dyes and chemicals are one of the major components in wet lab. From this experiment we can learn about
chemicals, dyes and other major knowledge of wet processing laboratory.
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Experiment no: 02
Experiment name: Experiment on singeing machine.
Introduction:
Singeing is a part of the pretreatment processes carried out in textile processing, and is usually the first
step carried out after weaving. It is the process of burning off of protruding fibers from the surface of yarn
or fabric in order to improve the luster and smoothness of the material. The ‘fuzz’, as the protruding fibers
also tends to scatter incident light on the yarn or fabric surface and contributes to a dull appearance of the
textile material. Removal of ‘fuzz’ results in a smoother and more uniform surface that reflects more light
and therefore gives a brighter appearance.
Objectives:
Description:
singeing is process of removal of projectile fibers from the surface of fabric using thermal
and mechanical energy.
There are three main types of singeing machine-
1. Gas singeing machine
2. Plate singeing machine
Rotary cylinder or roller singeing machine.
In this type of singeing machine, the fabric passes over a burning gas flame at such a speed that only the
protruding fibers burn and the main body of the fabric is not damaged by the flame. This is the most
common type of machine used for singeing fabrics as well yarns.
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Singeing procedure:
1. The speed of the fabric must be consistent with the flame height otherwise fabric may be burnt.
2. Synthetic blend must be operated carefully. Otherwise uneven dyeing may occur during dyeing
process.
3. Fabric may be burnt due to power failure. So automatic gas burner stopping must necessary.
4. Burner should be clean, otherwise singed fabric will be faulty and as a result stripe found during
dyeing.
5. The fabric must be evenly dried before singeing.
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Conclusion:
singeing is done in order to obtain a smooth clean fabric surface which allows the structure of
the fabric to be clearly seen. It is done to minimize the pilling. Singeing is important for wet processing
section.
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Experiment no: 03
Experiment name: Experiment on desizing machine.
Objects of Desizing:
The factors, on which the efficiency of size removal depends, are as follows:
▪ Type and amount of size applied
▪ Viscosity of the size in solution
▪ Ease of dissolution of the size film on the yarn
▪ Nature and the amount of the plasticizers
▪ Fabric construction
▪ Method of desizing, and
▪ Method of washing-off
Methods of Desizing:
1. Hydrolytic Method
2. Oxidative Method
1. Hydrolytic Method
▪ Rot Stepping
▪ Alkali Stepping
▪ Acid Stepping
▪ Enzymatic Stepping
2. Oxidative Method
▪ Bromide Desizing
▪ Chlorite Desizing
▪ Ammonium per Sulphate Desizin
Description:
▪ Cloth is taken from the batch into the entry J-scray and through the guiders to the desizing
chamber.
▪ The fabric is arranged inside the desizing chamber in S-threading. Temperature is maintained at
65°c-70°c. There are 7 rollers above and 8 rollers below the chamber. The length of fabric inside
the desizing chamber is 24m, which have a capacity of holding 1000L of liquor.
▪ he fabric is then passed into the steamer using a squeezer and bow roll/expander to remove
crease. The capacity of steamer is 350 kg. The threading length is 84m arranged in a double S-
threading.
▪ The dwell time varies from 8min for yarn dyed fabric to 12min for bleached fabric. The
temperature is maintained at 95°c-100°c. The temperature at lower compartment of steamer is
slightly less to avoid formation of cloud.
▪ The fabric is then passed through a metallic guider to washing chamber having water holding
capacity of 1000L.
▪ After three consecutive hot wash at 95°c, the fabric is cold washed or washed with oxalic acid at
55°c (if online route is taken) and passed to the exit J-scray
▪ From where it is taken through the guiders and guide rollers to the winding roller and finally
batching is done.
Remarks:
From this experiment we learned about scouring and its methods that will need in future at textile sector.
12
Experiment No: 04
Experiment name: Experiment on scouring.
Introduction:
The term ‘scouring’ applies to the removal of impurities such as oils, was, gums, soluble impurities
and sold dirt commonly found in textile material and produce a hydrophilic and clean cloth.
Objectives:
• To remove natural as well as added impurities of essentially hydrophobic character as
completely as possible.
• To increase absorbency of textile material.
• To leave the fabric in a highly hydrophilic condition without undergoing chemical or
physical damage significantly.
Recipe:
▪ Alkali (NaOH) - 2 to 5 gm per litre.
▪ Soda ash - x gm per litre to adjust PH (PH required for scouring is 10.5).
▪ Wetting agent - 1 gm per litre.
▪ Sequestering agent - 1 gm per litre.
▪ Detergent - 1 to 2 gm per litre.
▪ Temperature - 100 to 1250c.
▪ Time - 6 hours (close vessel) and 8 hours (open vessel) § M : L - 1 : 10
Description:
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Kier boiler is a long mild steel or cast-iron cylindrical vessel provided with two perforated tube sheets
(disc with a number of holes). One is placed at the bottom and another is top. These discs are connected
by a number of tunes which carry the liquor from the bottom compartment to the upper one. In the middle
compartment steam is passed.
Thus, the tubes carrying the liquor are surrounded by steam which heats them.
The hot liquor from the multitublar heater is sprayed over the cloth, packed in the kier, through a hollow
perforated ring. The liquid passes slowly over the packed cloth, collects below the false bottom, from
where it is pumped into the auxiliary heater by a centrifugal pump and the cycle repeats.
Precaution:
Experiment No: 05
Introduction:
Bleaching is a chemical process which removes the natural color from textile fibers. The fiber, yarn, fabric
become permanent white. Bleaching is the second step of pre-treatment.
Objective:
• Increase whiteness.
• Bleaching is process to make the fabric or yarn look brighter and whiter.
Recipe:
NaOH - 17ml/kg
SOAP (DTC) - 2ml/kg
STABILIZER - 5ml/kg
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H2O2 - 30ml/kg
Reaction time - 25min.
Speed - 50-70m/min
Working Procedure:
4) For 10 minutes steam and liquor turned off to remove air from kier.
5) Again, temperature raised up to 80oC and flow of steam and liquor turned off for 10 minutes.
6) After that, kier is completely closed and raised the temp. 110oC and kept it 1-3 hours.
7) After 3hours checking is done and thus bleaching id done.
Conclusion:
Bleaching is must needed for whiting the fabric. For dark shade of dyeing we can reduce our cost
removing of this process.
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Experiment no: 06
Experiment name: Beck Dyeing Machine
Introduction :
Beck dyeing is a continuous process used to dye long pieces of fabric, up to several thousand yards. The
fabric is loaded open width in rope form, and then passed over a pony reel and through the dye bath in a
constant circular motion until the fabric dyeing process is complete.
Objective:
The primary objective of dyeing is to apply uniform color to the substrate (fiber, yarn, or fabric) with
required color fastness. Tie-dye and printing are the methods where the color is applied in a localized
manner.
Working procedure:
Dye becks are a more economical piece of equipment found in most dye houses, they are used for wet
process atmospheric dyeing of piece goods. A typical function of the dye beck would be to start the dye
bath at 120 degrees F., then slowly raise the temperature to 160 degrees F. or higher through steam heat,
and dye the fabric for a few hours. The reason steam heat is used rather than by adding hot water is to
ensure an exact consistency in the pre formulated dye bath. If you added water, the viscosity as well as
the dye bath would change. Used in a multitude of dye houses for fabric dyeing.
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Experiment no: 07
Experiment name: Cotton Fabric Dyeing By Vat Dyes
Introduction :
Cotton can be dyed with many natural colours extracted from natural sources and synthetic dyes (Thakare
et al, 2006). The original vat dye is indigo, once obtained from plants but now produced synthetically
(Burch Paula, 2013).
Vat dye is the most popular dye used for coloration of cotton, particularly when high fastness is required
(Philips et al, 1996). The coloration of cellulose fibres about 120 000 tons of vat dyes are being used
annually (Mojca Bozic and Vanja Kokol, 2008). Vat dye is not soluble in water, but can be solubilized by
reaction with a reducing agent, e.g., sodium hydrosulfite ("hydros", Na2S2O4) in dilute NaOH (Philips,
1996).
Once it has been converted to its soluble (LEUCO) form, the vat dye can penetrate into the cotton fibers.
pad
hydros Vat dye
(insol) → on fabric surface → LEUCO
form (soluble) NaOH
This accounts for their good wash fastness. This is because they can be applied, solubilized by reduction,
and finally re-oxidized when inside the cotton (Baumgarte et al, 1987). Although fabric preparation
involving desizing and mercerization treatment of the cotton fabrics can definitely increase and improves
the dye uptake and ensures more shelve life of the vat dyed cotton fabrics as compared to the untreated
ones.
Materials :
• Vat dyes
• Sodium Hydrosulphite
• Caustic Soda
• Stirrer
• Nose mask
• Beakers
• Hand gloves
• Weighing balance.
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• Basic laboratory glass wares, such as, conical flasks, measuring cylinders, thermometer, stirring
rod, and volumetric flask
Method:
Fabric preparation
The cotton fabrics were obtained in its grey state, desizing and mercerization operation was carried out on
the fabrics. It was then weighed and wetted out before immersion into the dye liquor.
Desizing operation:
The cloth was impregnated with water only and stored for 48 hours at room temperature. During this
period, the starch becomes degraded by enzymes naturally present in the medium, it was then washed off.
This is necessary to allow easy penetration of the dye into the cotton fabrics as compared to the un-
desized materials.
Mercerization operation:
Mercerization process was carried out by treating the cotton fabrics in a concentrated solution of 25%
caustic soda for 2 minutes at room temperature. The material was then thoroughly washed in water, rinsed
to remove the alkali, and dried. This increases the colour yield on dyeing and significantly increases the
dye affinity of the cloth relative to that of an untreated material.
An aspect of fabrics which is always of interest to consumer is how fast the colour is. This is because the
beauty of a fabric is of no value unless the dye is fast under the conditions in which the fabric is to be
used. The colour fastness tests used for this analysis are the colour fastness to light and washing. The
results are displayed in tables 1 and 2
.
Results Of The Dyed Fabrics (Untreated And Treated)
The results of the dyed untreated and treated fabrics is displayed below
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Plate1 Plate2
Plate 1 shows the sample of the untreated dyed fabrics while plate 2 shows the samples of the treated
dyed fabrics (desizing and mercerization treatment). They both indicate the level of dye absorption during
vat dyeing of the fabrics.
It can be seen that plate 2 which is the treated fabric is darker in colour under the same dyeing conditions
with the untreated fabrics. This is attributable to the fact that treated fabrics readily absorb dyes easily as
compared to the untreated fabrics.
The colour fastness tests carried out are: colour fastness to light and washing.
LOW MODERATE
LOW MODERATE
Table 1b :
LOW MODERATE
LOW MODERATE
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Table 1c :
LOW HIGH
LOW HIGH
Table 2a
LOW MODERATE
LOW MODERATE
Table 2b
LOW MODERATE
LOW MODERATE
Table 2c
LOW HIGH
LOW HIGH
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Tables 1a To C, Show That The Untreated Fabric Gave Low Colour Fastness (Resistance) To Light. This
Can Be Attributed To The Fact That The Untreated Cotton Fabric Does Not Readily Retain The Vat Dyes.
However In Table 1a Only The De-Sized Samples Were Analysed And They Have Moderate Fastness To
Light. This Is Attributable To The Fact That The Desizing Treatment Gave A Better Dye Absorption And
Retention Though Moderately As Compared To The Untreated Samples.
In Table 1b, Only The Mercerized Samples Were Analysed, And It Gave Moderate Fastness To Light. This
Is Also Attributable To The Fact That Only Mercerized Treatment Gave A Better Dye Absorption As
Compared To The Un-Mercerized Samples.
Table 1c, However Showed A Complete Pre-Treatment Of Both The Desizing And Mercerizing Treatment
On The Cotton Fabrics. This Gave A Relative High Colour Fastness To Light As Compared To Desizing
Or Mercerization Alone. This Is Also Attributable To The Fact That Desizing And Mercerization Treatment
Combined Gave The Most Efficient Form Of Cotton Fabric Pre-Treatment Prior To Dyeing Which Account
For The Excellent High Light Fastness Indicating That The Cotton Fabric Readily Absorbs The Vat Dyes
And Retains It.
Tables 2a To C Which Show The Result Of The Colour Fastness To Washing, Gave Similar Result Like
That Of Tables 1a To C, Indicating That Both The Desized And Mercerized Cotton Combined, Gave A
Better Wash Fastness Because It Has Better Efficiency In Dye Absorption Compared To Each Alone, And
By Far Better Than The Untreated Samples As Far As The Preparation Of Cotton Fabrics For Vat Dyeing
Is Concerned.
Conclusion:
It Is A Common Experience That Cotton Fabrics Fades With Time When Dyed With Vat Dyes. This
Research However, Has Shown That Pre-Treatment Of Such Fabrics Using Desizing And Mercerization,
Gave A Better And More Durable Fabrics Due To Imparting On The Fabrics The High Absorption And
Retention Ability That Would Not Have Been Possible If Not Pre-Treated, As Assessed By The Colour
Fastness Test Especially To Light And Washing.
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Experiment no: 08
Experiment name: Experiment On Dyeing Machine
Introduction:
It was found that in using Winch dyeing machines, there were some inherent problems. So the Jet dyeing
machines when they came up in the 1970’s were specifically designed to overcome those shortcomings. In
the Jet dyeing machine the reel is completely eliminated. A closed tubular system exists where the fabric is
placed. For transporting the fabric through the tube a jet of dye liquor is supplied through a venturi. The Jet
creates turbulence. This helps in dye penetration along with preventing the fabric from touching the walls
of the tube. As the fabric is often exposed to comparatively higher concentrations of liquor within the
transport tube, so little dye bath is needed in the bottom of the vessel. This is just enough for the smooth
movement from rear to front. Aqueous jet dyeing machines generally employs a driven winch reel along
with a jet nozzle.
fabric circulation for usual drain and fill steps. The principle working behind the technique is very unique.
There is a system for fresh water to enter the vessel via a heat exchanger to a special interchange zone. At
the same time the contaminated liquor is allowed channel out through a drain without any sort of contact
with the fabric or for that matter the new bath in the machine.
There are several versions of both jet dyeing and soft flow
dyeing machines. Some designs have two or more tubes, mounted side by side, which share a common dye
liquor. The speed of the rollers, the circumference of the tube and the force of the jets can be altered to
accommodate different fabrics and reduce potential issues of fabric creasing and any stretching of the fabric,
thereby making the machines versatile in the range of fabrics that can be processed.
14. All safety device required for a pressure vessel is incorporated with the machine.
Textile material can be dyed using batch, continuous or semi continuous process. Batch processes are the
most common method used to dye textile materials. There are three general types of batch dyeing
machines:
Soft flow dyeing machine is the best example of a machine that circulated both the fabric and the dyebath.
It is used for knitted fabrics. For Terry-towels soft flow dyeing is use.
Conclusion:
The countless advantages of dyeing include not only being cost effective but one easy way of transforming
your fabrics to look new. It is also a great way to renew the fabrics you currently have and enjoy each one
year after year. Dyeing fabric has to do with the process of textile colouring using pigments