PRAGYAN PUBLIC SCHOOL, Jewar (UP)

www.pragyanpublicschool.com

DPP No. 1 Date : 15-02-2022 Subject: CHEMISTRY

Topic : IUPAC/GOC Student Name : Class : XII
Sub Topics :
1.
(d) CH3 – NH – CH3
1. Which of the following resonance structure is
the major contributor to the resonance hybrid?

5. Consider the following species:

a) I
b) II
c) Both have equal contribution
d) They are not resonance structures
+
CH 3 C HCH 3
2. The species is less stable than:
+
(CH 3 )3 C Arrange these species in their decreasing order
a) of nucleophilicity.
+ a) C > D > A > B
CH 3 CH 2 C H 2 b) B > A > C > D
b) c) A > B > C > D
+
CH 3 C H 2 d) C > A > B > D
6. Consider the following carbanions:
c)
+
CH 3
d)
3. Arrange in the order of decreasing Ka.
(P) F−CH 2 CH 2 COOH

(Q)

(R) F−CH 2 −COOH

(S) Br −CH 2 −CH 2 −COOH
Correct answer is:
a) Q>S>P>R Correct decreasing order of stability is:
b) P>R>S>Q a) II > III > IV > I
c) R>Q>P>S b) III > IV > I >II
d) S>Q>P>R c) IV > I > II > III
4. The strongest base is d) I > II > III > IV

7. CH2 = CHCH2 – COOH

(II)

CH3CH2COOH
(III)
 Arrange the following acids in decreasing
order of [ H ] conc.
+

a) I > II > III

b) II > III > I
c) II > I > III
d) III > II > I
8. Arrange the following in decreasing order of
the basicity.
CH 2 =CHCH 2 NH 2 , CH 3 CH 2 CH 2 NH 2 ,
CH≡CCH 2 NH 2
a) I > II >III
b) II > I > III
c) III > II > I
d) II < III < I
9. Arrange the following in increasing order of
basicity.

a) I < II < III

b) III < I < II
c) III < II < I
d) II < III < I
10. Arrange the following in decreasing order of
basicity.

a) I > II < III > IV < V

b) V > IV > II > III > I
c) I > II > III > IV > V
d) V > IV > III > II > I
ANSWER KEY –DPP-1
1. B 2. A 3.C 4. B 5. A
6. A 7. A 8.B 9. C 10. D