Chapter 26

Aldehydes, Ketones and Carboxylic Acids

1. Answer (3) CH3 COOH COCl CHO
H
Liquid + ethanol   Fruity smell compound
KMnO4 SOCl2 H2/Pd
  BaSO4
Carboxylic acid Must be ester
H  (A) (B) (C)
CH3COOH + C2H5OH  CH3COOC2H5
11. Answer (3)
2. Answer (3)
OH CH3
aq. KOH
CH3CHCl2 CH3CH + –
Na O C CH3
gem-dihalide OH
unstable O
CH3
–H2O Br

CH3CHO CH3
3. Answer (1)
In Cannizzaro reaction, the transfer of hydride to O O C CH3
the carbonyl group is the rate determining step.
4. Answer (1) CH3
CH3 H (Product)

O3 The above product does not have any C = C or

CH3 C C CH2 CH3 C  C bond, so, it will not give Br2-water test.
Zn/H2O
CH3 O 12. Answer (4)
DIBAL — H reduces esters and carboxylic acids
CH3 C O + CH3 CH2 C H into aldehydes
acetone
5. Answer (4) O O OH H O
6. Answer (3)
7. Answer (4) DIBAL-H
CH3CH2COOH + NH3 CH3CH2CO2NH4
(A) (B)  COOH CHO
KOH + Br2
CH3CH2NH2 CH3CH2CONH2 + H2O 13. Answer (3) O
(C) –
8. Answer (4) OH3 O O – C – O – CH3
O
PCC is mild oxidising agent, it will convert OH –
Cl – C – O – CH3
R  CH2  OH R  CHO
9. Answer (3)
Ethylene Br2
LiAlH4
CH3COOH CH3CH2OH 'A' O
PCl5 O – C – O – CH3

CH3CH2Cl 'B'
Alc. KOH
Br
CH2 = CH2 'C' Hence, option (3) is correct.
10. Answer (4)
‰‰‰
Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-47623456