(CHEMISTRY) ALDEHYDE & KETONE MMARKS: M.Time:_minutes ‘SUB: ° 1 CH;—CH = CH-CH = CH-C—H ALOHA, (a) (A)is " g 8 1 oy teteon tn oO 1H (c) on (0) oe (A) 25 eyanohydrin of (A) the eyanohydein is optically ative, then the possible structure of (A) is ' 2 @ (co) [>-on ) CP The cannizaro reaction of PhCOCHO forms the products} 2 (8) (A) PhCOCHZOH + PhCOCO a (c) PhCO; +PhCOCH,OH (0) both (A) and (c) oe CL onto ades oo i fee 4 GT. AM er a. 7 " q H “on (c) C- A (0) (mere a HH Acetone will be formed by the ozonolysis of (A) but-t-ene (B) but-2-ene (C)iso butene (0) but-2-yne Which of the following has minimum reactivity towards nucleophiles? (A) CHO (B) CHsCHO 9° 9 I I (C) GHy~ C~ CH (0) CHs~ C- CHe~CHs we te Where the organic product P is: mR oS a . ce ete | ie 1 Nao ® e In the Cannizzaro reection given below Ph—CHO. —9 4 Ph—CH,OH + PhCOo the slowest stop i (A) The attack of OH at the carbonyl group. (B) The transfer of hydride to the carbonyl group. (C) The abstraction of proton from carboxylic acid. (D) The deprotonation of Ph - COOH. Scanned with CamScannerQUIZ (CHEMISTRY) The product (s) obtained via Oxymercuration demurcuration (HgSO, +H,SQ,) of butyne -1 would be (A) CHy—CH,-COCH, (B) CHy—CH;-CH-CHO (©) CH;—CH,-CHO + cH,O (0) CHj—CH,-COOH + HCOOH ot sap (2 motes) Where X and ¥ are: 9% - % The products X, ¥ and Z of acid hydrolysis of P, @ and R; respectively, NT peo TP ee8 NY cee | oo can be distinguished by (A) Tollen’s reagent test for Y vs X or Zand Febiling solution test for X vs Z (B) Fehling solution test for Y vs Z or X and FeCl test for X vs Z (C) Tollen’s reagent test for Y vs X or Z and iodoform test for X vs Z (D) FeCls test for ¥ vs X or Z and iodoform test for X vs Z. (Me\Et)CHCOPh —%0/OH_, (Me) (E1)COCOPh + OD- + H20 If the reactant of this reaction is enantiomerically pure dexorotatory isomer, P will be (A) a racemic mixture (8) a meso product (C) dextro-rotatory isomer {D) laevo-rotatory isomer woe CO) ee The product X is: 6, *gtee OD 6 CQ, Which of the following will be most acidic? POC ROL te ‘ons by ons d son [mm 20 A, Band Care “58 00, (c) Scanned with CamScanner2 UIZ (CHEMISTRY) The most reactive compound towards cyanohydrin Formation is (A) Ph-CHO (3) on {po ©) we poe ()Ph-Chs- CHO A compound CsH:00(A) forms a phenylhydrazone and gives negative Tollens’ test and a positive iodoform reaction, It gives n-pentane on reduction, The compound (Ais (A) pentanal (8) 2-pentanone (C) 3-pentanone (0) amy! alcohol End product of the following sequence of reactions is mo och Aliphatic and aromatic aldehydes can be differentiated by the use of (A) Fehling solution (B) Tollen's regent (C) KMnO4/He/ A. (0) conc. HNQs/a Which of the following reduces Tollen’s reagent? ° (A) Hye (8) ‘ots 0) ‘on wd : Ces —CH-CH»—C-CHs —OM8_ product fie product will be OH tT (A) Gas ~CH-CH2~ COOH (B) Gos COOH, COOH - COOH and CHBrs 9° i (C) Gas ~C-CHs, CO and CHBrs (D) Only CHBrs Consider the following reaction CHsBr+Mg —S™*"» a "HO _, g MOM, ¢ compound C is (A) acetic acid (B) acetaldehyde (C) ethy! alcohol (D) formic acid When a mixture of calcium acetate + caloum formate is heated. It yields (A) acetone (8) acetaldehyde (C) formic acid (0) acetic acid Scanned with CamScannerQUIZ (CHEMISTRY) In the Baeyer Villiger oxidation of ketone to ester i.e. The rate of reaction depends upon the nature of R’ and Ar. The maximum rate of oxidation among the cases given below will be when: Identity the final product (Z) in the following sequence of reactions, ALKMOO4 ox) HO, cy OM) Identity the product C in the series CHCN MONON yA Mer yp moe 4 (a) CHsCOOH (8) CHsCHNHOH (C} CHsCONH (0) CHscHO In a cannizzaro reaction, the intermediate that will be best hydride donor is » oye » ore = H canada pee » ote Identity P in the reaction, O—ciHs ‘o_o yp (A) HOCH2CHeCHsCHaCH2CHzOH + CeHsOH (8) OHC.CH2CH2CHsCH2CHO (C) HOCH2CH2CH2C HCHO + CoHsOH (0) No reaction Among the following compounds, which will react with acetone to give product containing > = N ~ (A) GcHsNHCOCHs (B) (CHs)oN (C) GoHsNHGeHs (0) CoHsNHNH, Which of the following can be used for the preparation of chloroform? C\H,CHCI, CH,CHO—CD,COCH, —CCI,CHO 1 i tr iv (A) Land lv (8) only It (C) li, Wand tv {D) All the four HXOXOK OX. Scanned with CamScanner