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The Penex Process For Pentane Isomerisation: by L. E. H. R. D. H. Belden
The Penex Process For Pentane Isomerisation: by L. E. H. R. D. H. Belden
The Penex Process For Pentane Isomerisation: by L. E. H. R. D. H. Belden
Type 1-3 Penex catalyst employed also tible to many of the same metallic poisons
overcomes many of the problems associated which adversely affect other noble metal
with more highly acidic isomerisation systems catalysts. Fortunately, however, the con-
by permitting operation under non-carbon- taminants have not been identified in sufficient
ising and non-sludging conditions. This is quantities in virgin pentane fractions to cause
achieved by hydrogenation of coke and any concern.
sludge precursors by the use of a hydrogen One of the unique features of the 1-3
atmosphere and a hydrogenation component Penex catalyst is its ability to cope with
in the catalyst. limited amounts of contaminants such as
The relatively low operating temperatures sulphur or water, which may frequently be
give a more favourable iso- to normal pentane found in reactor feed and make-up hydrogen
equilibrium in the product. The close streams. Such contaminants exhibit only a
approach to this equilibrium means a higher temporary inhibiting effect on the catalyst,
quality product for a once-through operation, this effect readily disappearing once the
or less fractionating capacity for a recycle contaminant is removed from the entering
operation. These factors, together with the stream. Further, their continued presence can
high efficiency of the isomerisation reaction, be overcome by moderate changes in opera-
are achieved by careful formulation and ting conditions without any significant sacri-
manufacture of the platinum-containing fice in product yields or efficiencies. The
catalyst. remarkable characteristics of the 1-3 catalyst
The processing of a pentane fraction in a were shown by pilot plant runs of up to 100
Penex unit has presented no particular bbl. per lb. duration with very low carbon
problems not readily handled in the plant levels on the spent catalyst of 0.10 per cent
design. Olefins are not normally present but, or less.
if they should exist in the feed, they are Late in 1956 engineers of UOP and Phillips
completely saturated in the Penex reactor at started the final design of the Borger Penex
the expense only of the hydrogen required for Unit. Process design of the reaction area,
saturation. The 1-3 Penex catalyst is suscep- including the product stabiliser, was handled
The synthesis of hydrocyanic acid by the by-product and easily separable from hydro-
exothermic reaction between methane, am- cyanic acid.
monia and air-the Andrussow process-has The synthesis reaction occurs in sintered
been extensively developed during recent alumina tubes 2 metres long and 20 mm in
years (Platinum Metals Rev., 1958, 2, 7-11). external diameter, lined on their inner surface
The energy requirements of this process are with a layer, 15 p thick, of catalyst containing
low, and it has proved to be a practicable about 70 per cent platinum. This catalyst,
commercial method, but the yield is com- which was specially developed for the process,
paratively poor and separation of hydrocyanic suffered no apparent loss in activity in a test
acid from the reaction products is difficult. lasting nine months. The reaction between
A modified process has now been developed ammonia and methane, in the ratio 105 : TOO,
in Germany by Degussa in which the direct takes place a t about 1200°C and the gases,
endothermic reaction between methane and on leaving the reaction chamber, are im-
ammonia is utilised and heat is supplied from mediately cooled to below 300°C to prevent
an external source. This BMA process dissociation of the hydrocyanic acid. The
(Blausaure aus Methan und Ammoniak) has unreacted ammonia is removed as ammonium
been described in a paper by F. Endter sulphate by washing with sulphuric acid and
(Chem.-1ng.-Techn., 1958, 30, (s), 305-310). the hydrocyanic acid is separated from the
I n a plant with a capacity of 100 tons per hydrogen by absorption in sodium hydroxide.
day, hydrocyanic acid is produced in 83 per Some heat can be recovered from the
cent yield based on ammonia, compared with effluent gas as process steam, but the need to
65 per cent for the Andrussow process and supply heat for the endothermic reaction is
the concentration in the outlet gas is more the main item of cost, so that the process will
than 20 per cent, the only other major con- be most economic where fuel gas is available
stituent being hydrogen which is a valuable cheaply.