Revision nr.

2 EN
VITEX - HERMES YANNIDIS BROS S.A. Dated 26/02/2015
Printed on 16/11/2015
ACRYLIC PUTTY Page n. 12/7
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4
5
6
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SECTION 16.
14. Other
Transport
information. ... / >>
information. ... / >>

14.7.R50/53 VERY TOXIC

Transport in bulk according TO AQUATIC
to Annex ORGANISMS,
II of MARPOL73/78 MAY
and the CAUSE
IBC Safety data sheet
Code.LONG-TERM ADVERSE EFFECTS IN THE AQUATIC
ENVIRONMENT.
SECTION 3.relevant.
6.
9.
12.
Information not Composition/information
Accidental
Physical
Ecological and
release
information.
chemical
measures.
properties.
on ingredients.
SECTION
9.1.
3.1.
6.1.No Information
specific data
Substances.
Personal 1. on Identification
precautions,are
basic available
physical
protective forand ofthis the
equipment
chemical substance/mixture
product. Handle
properties.
and it according
emergency and
to
procedures. goodofworkingthe company/undertaking
practices. Avoid littering. Do not contaminate soil and
LEGEND:
Appearance
waterways.
Block the leakage
Inform if there
the competent
is no hazard. authorities, should
pasty the
liquid product reach waterways or contaminate soil or vegetation. Please take all the proper
SECTION
1.1. Product
-measures
ADR: European 15.
identifier Regulatory
Agreement concerning information.
the carriage of Dangerous
Information
Colour
Wear suitabletonotreducerelevant.
protective
harmfulequipmenteffects on (including
aquifers. personal
white protectivegoods by Road
equipment referred to under Section 8 of the safety data sheet) to prevent any
-Odour
CAS NUMBER:ofChemical
contamination skin, eyes Abstract andServicepersonal Number clothing.
characteristic
These indications apply for both processing staff and those involved in emergency
-Product
3.2. CE50:
Odour
procedures.
15.1. Mixtures.
Safety,
name
Effective
threshold. health concentration
and environmental (requiredregulations/legislation
to induce aNot ACRYLIC
50%available.
effect) PUTTY
specific for the substance or mixture.
-pH.
12.1. CEToxicity.
NUMBER: Identifier in ESIS (European archive 7-9 of existing substances)
1.2. Relevant
-Contains:
CLP:
Seveso EC identified1272/2008
Regulation
category.
uses of theNone. substance or mixture and uses advised against
6.2.Melting point
Environmental / freezing point.
precautions. Not available.
-1,2-benziosothiazolin-3-one
DNEL:
Initial
The product Derived
boiling must
point. NonotEffect Levelinto the sewer >
penetrate system 100 or come °C.into contact with surface water or ground water.
Intended
-LC50
EmS:- for
Restrictions use
Emergency
relating to Schedule
the product or contained substances Acrylic puttyto Annex XVII to EC Regulation 1907/2006.
pursuant
Boiling
Identification.range. Fish. Conc. %. Classification Not
> 2,18available.
mg/l/96h
67/548/EEC. 1,2-benziosothiazolin-3-one Oncorhynchus
Classification mykiss
1272/2008 OECD Test Guideline
(CLP).
-None.
6.3. GHS:
FlashMethods Globally
point. andHarmonized
material forSystem containment of classification
and > cleaning93and labeling
203 up. °C. of chemicals
1.3.
-EC50 Details
IATA of International
the supplierAir of Transport
the safetyAssociation data sheet Dangerous Goods Regulation
Collect
Evaporation -DGR:
for
theCrustacea.
Rate
leaked product
1,2-benziosothiazolin-3-one into a suitable container. Not
> 2,94available.
Evaluate
mg/l/48h the1,2-benziosothiazolin-3-one
compatibility of the container Daphnia
to be used,
magna byOECD
checkingTestsection
Guideline
10. Absorb
202 the
-EC50
IC50:- Immobilization
Substances
remainder
Flammability
CAS. inof
for 2634-33-5
with
Algae Candidate
inert
solids
/ Aquatic Concentration
List
absorbent
and -(Art.
0gases
Plants.
0,05 59 REACH).
material. 50% T R23, Xn R22, >Xi0,11
Not R38, Xi
available.R41, Xi R43,
mg/l/72h N R50
1,2-benziosothiazolin-3-one Acute Tox. 4 H302, Acute Tox. 4 H332,
Pseudokirchneriella Eye Dam. 1 H318,
subcapitata OECD Test
Name
-None.
IMDG: International Maritime VITEX - HERMES YANNIDIS BROS S.A.
site Code foraired.
dangerousCheckgoods
Skin Irrit. 2 H315, Skin Sens. 1 H317, Aquatic Acute 1 H400 M=1
Make
Lower
EC. inflammability
sure the leakage
220-120-9 limit. is well incompatibility
Not
Guideline
available. 201for container material in section 7. Contaminated material should be disposed of
Full
-in IMO:
SubstancesaddressInternational
subject toMaritime
authorisarion Organization (Annex XIV REACH). IMEROS TOPOS
Upper
compliance
INDEX. inflammability with thelimit.
613-088-00-6 provisions set forth in point 13. Not available.
District and
-5-Chloro-2-methyl-
INDEX
None. CountryIdentifier in Annex VI of CLP
NUMBER: 19300 ASPROPYRGOS (ATTIKI)
Lower
5-Chloro-2-methyl-
explosive limit.3(2H)-isothiazolone 3(2H)-isothiazolone mixture with Not 2-Methyl-
available.
mixture 3(2H)-isothiazolonewith (3:1) 2-Methyl- 3(2H)-isothiazolone (3:1)
- LC50:
Substances Lethal subjectConcentration
to exportation 50% reporting pursuantT R23/24/25, toC(EC)R34, Reg.
Xi R43,
GREECE
649/2012:
N R50/53 Acute Tox. 3 H301+H311+H331, Skin Corr. 1B H314, Skin Sens. 1 H317,
6.4.Upper
EC50
CAS. -explosive
Reference for 55965-84-9
Crustacea.
to limit.
other sections.0 - 0,0015 Not
> 0,018
available.
mg/l/48h
-None.
LD50: Lethal dose 50% Tel. (0030) 2105589400 Aquatic Acute 1 H400 M=10, Aquatic Chronic 1 H410
AnyVapour
EC. information
pressure. on personal protection and disposal Not is given
available.
in sections 8 and 13.
- OEL: Occupational Exposure Level Fax (0030) 2105597859
Vapour
12.2.INDEX. density
Persistence 613-167-00-5 and degradability. Not available.
-e-mail
PBT: address
Substances
Relative
Information
subject
Persistent
density.
of bioaccumulative
the
not available.
competent
to the Rotterdam person
andConvention:
toxic as REACH Regulation
1,7-1,9 g/ml
SECTION
responsible
None.
-Note:
PEC:
Solubility Predicted 7.
for theHandling
Safety
environmental Data
Upper limit is not included into the range. and
Sheet storage.
Concentration vitexlab@vitex.gr
Not available.
-The
PEL: fullPredicted
Partition wording
coefficient: exposure
of level
12.3.
7.1.
Substances
Bioaccumulative
Precautions
Product
-Auto-ignition
PNEC: distribution
subject
Predicted forthesafe
toby
no
Risk
potential.
the
(R) and hazard (H) phrases
n-octanol/water
handling.
Stockholm
effect concentration Convention:
Notisavailable.
given in section 16 of the sheet.
YANNIDIS BROS S.A.
Information
Before not
temperature.
available. Not available.
T+ = Veryhandling
-None.
REACH: Tthe
EC Regulation
Toxic(T+), product,
= Toxic(T), consult
1907/2006
Xn = Harmful(Xn), all theC = other sections
Corrosive(C), of this material
Xi = Irritant(Xi), safety Edata
O = Oxidizing(O), sheet. Avoid
= Explosive(E), leakageFlammable(F+),
F+ = Extremely of the product into the
F = Highly environment.
Flammable(F), N=
Decomposition
Do
Dangerous notRegulation
eat,
for the drinktemperature.
or smoke
Environment(N) during use. Remove Not anyavailable.
contaminated clothes and personal protective equipment before entering places in which
1.4.
- Emergency
RID: telephone
concerning number the international transport of dangerous goods by train
Viscosity
12.4. Mobility in soil. 520.000 ± 150.000 cP
-people
Healthcare
Information
Explosive
eat.controls.
TLV: Threshold Limit Value
not available.
properties Not available.
Information
For urgent
-Oxidising
TLV CEILING: not
inquiries available.
refer to
Concentration that should not be exceeded (0030) 2105589400
during any time of occupational exposure.
SECTION
7.2. Conditions 4.for
properties First aid measures.
safe storage, including Not available.
any incompatibilities.
(0030) 2107793777
- TWA
12.5.
9.2. Results
Other STEL: ofShort-term
information. PBT and exposure
vPvB limit
assessment.
-Store
VOC
4.1. TWA:
VOC
only
(Directive
Description
in 2004/42/EC)
Time-weighted
(Directive
the original
of first average
1999/13/EC)
: container.
: exposure
aid measures.
Storelimitthe containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away from
any
VOC:
EYES:
incompatible
-Primers. Volatile
Remove
materials,
organic Compounds
contact data,
see
lenses,
section 10 for details.
if present. Wash immediately with plentyinof water forgreater at least 30-60 minutes, opening the eyelids fully. Get
SECTION
On the
Information
-VOC
vPvB: givenbasis
Very in 2.
notof Hazards
available
available.
g/litre
Persistent of product
and very
identification.
the
in a product
ready-to-use
Bioaccumulative
does not contain
condition
as for REACH : any PBT or vPvB
Regulation
percentage than 0,1%.
medical advice/attention.
-Limit
7.3.
2.1.
12.6. WGK:
SKIN:
value:
Specific
Other Water
Remove
Classification
end
adverse
use(s).
hazard
contaminated classes
ofeffects.
the substance (German).
clothing. orRinse
mixture.
30,00 (2010)
skin with a shower immediately. Get medical advice/attention.
Information
VOC
SECTION of product not available.
: Stability 29,00
INGESTION: 10. Have the subject and drinkreactivity.
as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly
GENERAL
authorised
The productby
Information BIBLIOGRAPHY
isanot
not doctor.
classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP).
available.
10.1.
15.2.
1. Reactivity.
Chemical
Directive safety
1999/45/EC assessment.
andcontains
following amendments
INHALATION:
SECTION
However, since 8. Get
Exposure
the medical
product advice/attention
controls/personal
hazardous immediately.
substances inRemove
protection.
concentrationsvictim tosuch freshas toair,be away
declared from the accident
in section no. 3, itscene.
requiresIf a
the subject
safety datastops
There
2. Directive are no particular
67/548/EEC risks
and of reaction
following with other substances
amendments andprecautions
adjustmentsin normal conditions of use.
breathing,
sheet with administer
appropriate artificial
information, respiration. compliant Take tosuitable
EC Regulation for rescue
1907/2006 and workers.
subsequent amendments.
No
SECTION chemicalparameters.
3. Regulation
8.1. Control safety
13.
(EU)Disposalassessment
1907/2006 has been
considerations.
(REACH) of processed
the European for the mixture and the substances it contains.
Parliament
10.2. Chemical
4. Regulation stability.
(EU) 1272/2008 (CLP) of the European Parliament
4.2.
2.1.1. MostRegulationimportant symptoms
1272/2008 (CLP) andand effects,
following both amendments
acute and delayed. and adjustments.
The
13.1.
5. producttreatment
Waste is(EU)
stable inmethods.
normal conditions oftheuseEuropean
and storage.
ForRegulation
SECTION symptoms16. andOther790/2009
effects caused (I Atp.
information. by CLP) of
the contained substances,Parliament see chap. 11.
Reuse,
6. Regulation
Information when not possible.
(EU) 453/2010
available. Neat productof the European residues Parliament
should be considered special non-hazardous waste.
Hazard classification and indication: --
Disposal
10.3.
7.
Text Possibility
Regulation
of must(EU)
hazard be
(H)ofperformed
hazardous
286/2011
indications through
(II reactions.
Atp.
mentioned an authorised
CLP) inof the
section waste
European
2-3 management
Parliament
ofspecial
the sheet: firm, in compliance with national and local regulations.
4.3. Indication of any immediate medical attention and treatment needed.
No
8.
8.2. hazardous
CONTAMINATED
Regulation
Exposure reactions
(EU)
controls. 618/2012 (III Atp. CLP) of the European Parliament storage.
PACKAGING are foreseeable in normal conditions of use and
2.2.Information
Label elements. not available.
Contaminated
9. Regulation
Acute Tox.(EU) packaging
3 487/2013 must
Acute (IVbeAtp. recovered
toxicity,CLP) of or
categorythedisposed
European
3 of Parliament
in compliance with national waste management regulations.
10.4.
10. Conditions
Acute
Regulation Tox.
use of(EU) 4 to avoid.
944/2013 Acute toxicity,
(VRegulation
Atp. equipment
CLP) category
of themust4 always
European
As Hazard the labelling adequate
pursuant to technical
EC 1272/2008 (CLP)Parliament
takesubsequent
and priority overamendments
personal protective equipment, make sure that the workplace is well
and supplements.
SECTION
None
11.
airedSkin
Regulation
throughCorr.5.
in particular. 1B
(EU)Firefighting
effective HoweverlocalSkin
605/2014 the (VI usual
aspiration. measures.
corrosion,
Atp. precautions
CLP) of the used
category 1B for chemical
European Parliament products should be respected.
SECTION EyePROTECTION
Dam. 1
14. Transport Serious --
information.
eye damage, category 1
HAND
Hazard pictograms:media.
5.1.
10.5. Extinguishing
Skin Irrit.Index.
Incompatible 2 Skin irritation, category 2
-Protect
14.1. The UN Merckhands
number. with materials.
- 10th Edition
category III work gloves (see standard EN 374).
SUITABLE
Skin Sens.
Information EXTINGUISHING
1available. Skin
notshould EQUIPMENT
sensitization, category 1
-Signal
Handling
The following
words: Chemical Safety
be considered-- when choosing work glove material: compatibility, degradation, failure time and permeability.
TheAquatic
extinguishing Acute 1equipment should be
Hazardous toofthe the conventional
aquatic environment,kind: carbon dioxide,category
acute toxicity, foam, powder 1 and water spray.
-Not
Niosh
The work - Registry
applicable. gloves'ofresistance
Toxic Effects of Chemical
to chemical agents Substances
should be checked before use, as it can be unpredictable. The gloves' wear time depends on the
UNSUITABLE
10.6. Aquatic
Hazardous EXTINGUISHING
Chronic 1
decomposition Hazardous EQUIPMENT
products. to the aquatic environment, chronic toxicity, category 1
-Hazard
INRS -statements:
duration Fiche
and typeToxicologique
of use. Toxic (toxicological sheet)
None H301+H311+H331
Information in particular.
not available. if swallowed, in contact with skin or if inhaled.
-SKIN
14.2. PattyUN
EUH210
H302 - proper
Industrial
PROTECTION Hygienename.
shipping and Toxicology
Safety
Harmful data sheet available on request.
if swallowed.
-Wear
N.I.
EUH208
H332 Sax - Dangerous
category properties
I professional Contains:
Harmful ofifIndustrial
long-sleeved
inhaled. Materials-7, and1989
overalls5-Chloro-2-methyl-
safety Edition 3(2H)-isothiazolone
footwear mixture with 2-Methyl-
(see Directive 89/686/EEC and standard3(2H)-isothiazolone
EN ISO 20344). (3:1) Wash body
5.2. Special hazards arising from the substance or mixture.
-Not
withECHA
SECTION soap
H314 website
applicable. and11. water after removing
Toxicological Causes protective
severe information.
skin clothing.
burns 1,2-benziosothiazolin-3-one
and eye damage.
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
EYE PROTECTION May produce an eyeallergic reaction.
Do H318 not breathe combustionCauses products. serious damage.
Wear
11.1.
14.3. H315 airtight protective
Information
Transport hazard goggles
on toxicological Causes
class(es). (see skin standard
effects.irritation. EN 166).
Note H317
RESPIRATORY
In the for users: ofPROTECTION
absence experimental May cause data for antheallergic
product skinitself,
reaction.
health hazards are evaluated according to the properties of the substances it contains,
5.3. Advice for firefighters.
The
If H400 information
Precautionary
using
Not theapplicable.
thethreshold
criteria contained
statements:
specified
value Very
in in
(e.g. the toxic
the
TLV-TWA) to aquatic
present
applicable sheetlife.arefor
isregulation
exceeded based theon our own knowledge
forclassification.
substance or one of the onsubstances
the date of presentthe last in
version. Users use
the product, musta verify
mask the
withsuitability
a type B
GENERALH410 INFORMATIONVery toxic to aquatic life with long lasting effects.
and thoroughness
It isP102
filter therefore
whose class necessaryof(1,provided
2toorKeep
take 3) out
information
into
must of reach
account of
thechildren.
be according
chosen to each specific
concentration
according to ofthethe use
limit ofofuse
theconcentration.
individual product.
hazardous substances (see standard indicated in section
EN 14387). 3, topresence
In the evaluateofthegases or
UseEUH210 jets of water to cool the containers
Safety data to
sheet prevent
available productonany decomposition
request. and the development of substances potentially hazardous for health.
This P273document
toxicological
vapours
14.4. Packing must
effects
of variousgroup. ofnot
kinds be Avoid
exposure
and/orregarded torelease
gases theas orato
product.the
vapours environment.
guarantee on
containing specific
particulate product property.
(aerosol sprays, fumes, mists, etc.) combined filters are required.
Always wear full fire prevention IF gear. Collect extinguishing water /todoctor prevent . . .it/fromyoudraining into the sewer system. Dispose of contaminated
TheP301+P312
Respiratory use of protection this product is SWALLOWED:
devices notmust subject be usedto Call a POISON
our ifdirect
the control;
technicalCENTER
therefore,
measures users / must,
adopted ifunder
are feel unwell.
their
not own responsibility,
suitable comply
for restricting with theexposure
the worker's current health
to the
water
Text ofusedrisk for
(R) extinction
phrases and
mentioned the remains
in sectionof the
2-3 fire
of according
the sheet: to applicable regulations.
and
Not
This safety
applicable.
thresholdproduct laws
values and
contains regulations.
sensitizing
considered. TheThe producer
substance/s
protection is relieved
and
provided maybycause fromallergic
masks any
is inliability arising
reactions.
any case from improper uses.
limited.
SPECIAL
2.3. Other PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
hazards.
Provide
If the appointed
substance staff with adequate
considered is odourless trainingoronitshow to usethreshold
olfactory chemical isproducts.
higher than the corresponding TLV-TWA and in the case of an emergency,
Normal R22 fire fighting clothing HARMFUL i.e. fireIFkitSWALLOWED. (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
wearEnvironmental
14.5. open-circuit compressed hazards. air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in
self-contained
On R23the basis ofopen circuitdata,
available positive
TOXIC theBY pressure
INHALATION.
product compressed
does not contain air any
breathing
PBT or apparatus (BS EN 137).
vPvB in percentage
Changes
1,2-benziosothiazolin-3-one
compliance to with
previous standardreview: EN 138). For a correct choice of respiratory protection device, see greater
standard than
EN0,1%.
529.
R23/24/25 TOXIC BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
The
Not
LD50 following
applicable.
ENVIRONMENTAL (Oral). sections were modified:
EXPOSURE > 2,175 mg/Kg 1,2-benziosothiazolin-3-one
CONTROLS.
R34 CAUSES BURNS.
01
The
LD50 / 02 / 03 / 08 /generated
emissions
(Dermal). 11 / 12 / 16. by manufacturing> 1,221
R38 IRRITATING TOmg/KgSKIN. processes,
1,2-benziosothiazolin-3-one
including those generated by ventilation equipment, should be checked to ensure
LC50
compliance
14.6. (Inhalation).
Special
R41 with environmental
precautions for user. 0,5
standards. mg/L
RISK OF SERIOUS DAMAGE TO EYES.
R43 MAY CAUSE SENSITISATION BY SKIN CONTACT.
NotR50
applicable. VERY TOXIC TO AQUATIC ORGANISMS.
EPY 9.1.6 - SDS 1003
 Revision nr.2 EN
VITEX - HERMES YANNIDIS BROS S.A. Dated 26/02/2015
Printed on 16/11/2015
ACRYLIC PUTTY Page n. 2 / 7

SECTION 3. Composition/information on ingredients.

3.1. Substances.

Information not relevant.

3.2. Mixtures.

Contains:

Identification. Conc. %. Classification 67/548/EEC. Classification 1272/2008 (CLP).

1,2-benziosothiazolin-3-one
CAS. 2634-33-5 0 - 0,05 T R23, Xn R22, Xi R38, Xi R41, Xi R43, N R50 Acute Tox. 4 H302, Acute Tox. 4 H332, Eye Dam. 1 H318,
Skin Irrit. 2 H315, Skin Sens. 1 H317, Aquatic Acute 1 H400 M=1
EC. 220-120-9
INDEX. 613-088-00-6
5-Chloro-2-methyl- 3(2H)-isothiazolone mixture with 2-Methyl- 3(2H)-isothiazolone (3:1)
CAS. 55965-84-9 0 - 0,0015 T R23/24/25, C R34, Xi R43, N R50/53 Acute Tox. 3 H301+H311+H331, Skin Corr. 1B H314, Skin Sens. 1 H317,
Aquatic Acute 1 H400 M=10, Aquatic Chronic 1 H410
EC.
INDEX. 613-167-00-5

Note: Upper limit is not included into the range.

The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet.
T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N =
Dangerous for the Environment(N)

SECTION 4. First aid measures.

4.1. Description of first aid measures.
EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get
medical advice/attention.
SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention.
INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly
authorised by a doctor.
INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops
breathing, administer artificial respiration. Take suitable precautions for rescue workers.

4.2. Most important symptoms and effects, both acute and delayed.
For symptoms and effects caused by the contained substances, see chap. 11.

4.3. Indication of any immediate medical attention and special treatment needed.
Information not available.

SECTION 5. Firefighting measures.

5.1. Extinguishing media.
SUITABLE EXTINGUISHING EQUIPMENT
The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.

5.2. Special hazards arising from the substance or mixture.

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products.

5.3. Advice for firefighters.

GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health.
Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated
water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

EPY 9.1.6 - SDS 1003

 Revision nr.2 EN
VITEX - HERMES YANNIDIS BROS S.A. Dated 26/02/2015
Printed on 16/11/2015
ACRYLIC PUTTY Page n. 3 / 7

SECTION 6. Accidental release measures.

6.1. Personal precautions, protective equipment and emergency procedures.
Block the leakage if there is no hazard.
Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any
contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency
procedures.

6.2. Environmental precautions.

The product must not penetrate into the sewer system or come into contact with surface water or ground water.

6.3. Methods and material for containment and cleaning up.

Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the
remainder with inert absorbent material.
Make sure the leakage site is well aired. Check incompatibility for container material in section 7. Contaminated material should be disposed of
in compliance with the provisions set forth in point 13.

6.4. Reference to other sections.

Any information on personal protection and disposal is given in sections 8 and 13.

SECTION 7. Handling and storage.

7.1. Precautions for safe handling.
Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment.
Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which
people eat.

7.2. Conditions for safe storage, including any incompatibilities.

Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away from
any incompatible materials, see section 10 for details.

7.3. Specific end use(s).

Information not available.

SECTION 8. Exposure controls/personal protection.

8.1. Control parameters.

Information not available.

8.2. Exposure controls.

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well
aired through effective local aspiration.
HAND PROTECTION
Protect hands with category III work gloves (see standard EN 374).
The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability.
The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the
duration and type of use.
SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body
with soap and water after removing protective clothing.
EYE PROTECTION
Wear airtight protective goggles (see standard EN 166).
RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type B
filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases or
vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the
threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency,
wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in
compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.
ENVIRONMENTAL EXPOSURE CONTROLS.
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure
compliance with environmental standards.

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SECTION 9. Physical and chemical properties.

9.1. Information on basic physical and chemical properties.
Appearance pasty liquid
Colour white
Odour characteristic
Odour threshold. Not available.
pH. 7-9
Melting point / freezing point. Not available.
Initial boiling point. > 100 °C.
Boiling range. Not available.
Flash point. > 93 °C.
Evaporation Rate Not available.
Flammability of solids and gases Not available.
Lower inflammability limit. Not available.
Upper inflammability limit. Not available.
Lower explosive limit. Not available.
Upper explosive limit. Not available.
Vapour pressure. Not available.
Vapour density Not available.
Relative density. 1,7-1,9 g/ml
Solubility Not available.
Partition coefficient: n-octanol/water Not available.
Auto-ignition temperature. Not available.
Decomposition temperature. Not available.
Viscosity 520.000 ± 150.000 cP
Explosive properties Not available.
Oxidising properties Not available.
9.2. Other information.
VOC (Directive 1999/13/EC) :
Information not available.

SECTION 10. Stability and reactivity.

10.1. Reactivity.
There are no particular risks of reaction with other substances in normal conditions of use.

10.2. Chemical stability.

The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions.

No hazardous reactions are foreseeable in normal conditions of use and storage.

10.4. Conditions to avoid.

None in particular. However the usual precautions used for chemical products should be respected.

10.5. Incompatible materials.

Information not available.

10.6. Hazardous decomposition products.

Information not available.

SECTION 11. Toxicological information.

11.1. Information on toxicological effects.
In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it contains,
using the criteria specified in the applicable regulation for classification.
It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the
toxicological effects of exposure to the product.

This product contains sensitizing substance/s and may cause allergic reactions.

1,2-benziosothiazolin-3-one
LD50 (Oral). > 2,175 mg/Kg 1,2-benziosothiazolin-3-one
LD50 (Dermal). > 1,221 mg/Kg 1,2-benziosothiazolin-3-one
LC50 (Inhalation). 0,5 mg/L

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SECTION 12. Ecological information.

No specific data are available for this product. Handle it according to good working practices. Avoid littering. Do not contaminate soil and
waterways. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation. Please take all the proper
measures to reduce harmful effects on aquifers.

12.1. Toxicity.

1,2-benziosothiazolin-3-one
LC50 - for Fish. > 2,18 mg/l/96h 1,2-benziosothiazolin-3-one Oncorhynchus mykiss OECD Test Guideline
203
EC50 - for Crustacea. > 2,94 mg/l/48h 1,2-benziosothiazolin-3-one Daphnia magna OECD Test Guideline 202
EC50 - for Algae / Aquatic Plants. > 0,11 mg/l/72h 1,2-benziosothiazolin-3-one Pseudokirchneriella subcapitata OECD Test
Guideline 201

5-Chloro-2-methyl- 3(2H)-isothiazolone mixture with 2-Methyl- 3(2H)-isothiazolone (3:1)

EC50 - for Crustacea. > 0,018 mg/l/48h

12.2. Persistence and degradability.

Information not available.

12.3. Bioaccumulative potential.

Information not available.

12.4. Mobility in soil.

Information not available.

12.5. Results of PBT and vPvB assessment.

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.

12.6. Other adverse effects.

Information not available.

SECTION 13. Disposal considerations.

13.1. Waste treatment methods.
Reuse, when possible. Neat product residues should be considered special non-hazardous waste.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

SECTION 14. Transport information.

14.1. UN number.

Not applicable.

14.2. UN proper shipping name.

Not applicable.

14.3. Transport hazard class(es).

Not applicable.

14.4. Packing group.

Not applicable.

14.5. Environmental hazards.

Not applicable.

14.6. Special precautions for user.

Not applicable.
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SECTION 14. Transport information. ... / >>

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code.

Information not relevant.

SECTION 15. Regulatory information.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture.

Seveso category. None.

Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006.
None.

Substances in Candidate List (Art. 59 REACH).

None.
Substances subject to authorisarion (Annex XIV REACH).
None.
Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012:
None.

Substances subject to the Rotterdam Convention:

None.

Substances subject to the Stockholm Convention:

None.

Healthcare controls.
Information not available.

VOC (Directive 2004/42/EC) :

Primers.
VOC given in g/litre of product in a ready-to-use condition :
Limit value: 30,00 (2010)
VOC of product : 29,00

15.2. Chemical safety assessment.

No chemical safety assessment has been processed for the mixture and the substances it contains.

SECTION 16. Other information.

Text of hazard (H) indications mentioned in section 2-3 of the sheet:

Acute Tox. 3 Acute toxicity, category 3

Acute Tox. 4 Acute toxicity, category 4
Skin Corr. 1B Skin corrosion, category 1B
Eye Dam. 1 Serious eye damage, category 1
Skin Irrit. 2 Skin irritation, category 2
Skin Sens. 1 Skin sensitization, category 1
Aquatic Acute 1 Hazardous to the aquatic environment, acute toxicity, category 1
Aquatic Chronic 1 Hazardous to the aquatic environment, chronic toxicity, category 1
H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled.
H302 Harmful if swallowed.
H332 Harmful if inhaled.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
EUH210 Safety data sheet available on request.

Text of risk (R) phrases mentioned in section 2-3 of the sheet:

R22 HARMFUL IF SWALLOWED.

R23 TOXIC BY INHALATION.
R23/24/25 TOXIC BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
R34 CAUSES BURNS.
R38 IRRITATING TO SKIN.
R41 RISK OF SERIOUS DAMAGE TO EYES.
R43 MAY CAUSE SENSITISATION BY SKIN CONTACT.
R50 VERY TOXIC TO AQUATIC ORGANISMS.
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SECTION 16. Other information. ... / >>

R50/53 VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC
ENVIRONMENT.

LEGEND:
- ADR: European Agreement concerning the carriage of Dangerous goods by Road
- CAS NUMBER: Chemical Abstract Service Number
- CE50: Effective concentration (required to induce a 50% effect)
- CE NUMBER: Identifier in ESIS (European archive of existing substances)
- CLP: EC Regulation 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: Immobilization Concentration 50%
- IMDG: International Maritime Code for dangerous goods
- IMO: International Maritime Organization
- INDEX NUMBER: Identifier in Annex VI of CLP
- LC50: Lethal Concentration 50%
- LD50: Lethal dose 50%
- OEL: Occupational Exposure Level
- PBT: Persistent bioaccumulative and toxic as REACH Regulation
- PEC: Predicted environmental Concentration
- PEL: Predicted exposure level
- PNEC: Predicted no effect concentration
- REACH: EC Regulation 1907/2006
- RID: Regulation concerning the international transport of dangerous goods by train
- TLV: Threshold Limit Value
- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
- TWA STEL: Short-term exposure limit
- TWA: Time-weighted average exposure limit
- VOC: Volatile organic Compounds
- vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation
- WGK: Water hazard classes (German).

GENERAL BIBLIOGRAPHY
1. Directive 1999/45/EC and following amendments
2. Directive 67/548/EEC and following amendments and adjustments
3. Regulation (EU) 1907/2006 (REACH) of the European Parliament
4. Regulation (EU) 1272/2008 (CLP) of the European Parliament
5. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament
6. Regulation (EU) 453/2010 of the European Parliament
7. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament
8. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament
9. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament
10. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament
11. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament

- The Merck Index. - 10th Edition

- Handling Chemical Safety
- Niosh - Registry of Toxic Effects of Chemical Substances
- INRS - Fiche Toxicologique (toxicological sheet)
- Patty - Industrial Hygiene and Toxicology
- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
- ECHA website

Note for users:

The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability
and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health
and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.

Changes to previous review:

The following sections were modified:
01 / 02 / 03 / 08 / 11 / 12 / 16.

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