1.

Penentuan Konsentrasi (normalitas) Larutan Standar Natrium Tiosulfat

Dik : Volume Na2S2O3
V1 = 26 ml
V2 = 24 ml
V3 = 22,5 ml
Vrata-rata = 24,16 ml
N K2Cr2O7 = 0,1 N
V K2Cr2O7 = 25,00 ml

Dit : Normalitas Na2S2O3 ….??

Penyelesaan :
( V × N ) K2 Cr 2 O7
N Na2S2O3 =
V Na2 S2 O3
( 25,00 ml ) × (0,1 N)
=
24,16 ml
= 0,103 N
2. Penentuan Kadar Cu Dalam CuSO4
Dik : Volume Na2S2O3
V1 = 19 ml
V2 = 17 ml
V3 = 14 ml
Vrata-rata = 16,67 ml
N Na2S2O3 = 0,103 N
Ar Cu = 63,5 mg/mmol
V Sampel = 25,00 ml
Cu2+ + 2e- → Cu, sehingga 1 mol Cu= 2ek
Ek Cu = 2 mek/mmol
BM Cu = 63, 546 mg/mmol
N Na2S2O3 = 0, 103 N
Dit : Kadar Cu (mg/ml) ….??
Penyelesaan :
BE Cu = Cu2+ + 2e- → Cu
Sehinga, 2 mg/mmol = 1 mg/mek
1 mg/mmol = ½ mg/mek
 1/2 mg/ mek
BM Cu = 63, 546 mg/mmol x
1 mg/mmol
63, 54 6
BE Cu = mg/mek
2
( V × N ) Na2 S2 O3
Kadar Cu = × BECu
V Sampel
( 16,67 ml ) × (0,1 03 N) mek/mg 63, 54 6
= × mg/ mek
25,00 ml 2
= 2, 25 mg/mL