Test 1 CBSE XI Date-04/12/21

Topics:
Marks-35 ALL THE BEST Time-1.5 hrs
SECTION A (answer any 20 questions from this section)
1. Which of the following represents largest number of particles?
(a) Atoms in 1 mole of CH4
(b) Atoms in 0.5 mole of SO 3
(c) Atoms in 0.5 mole of CO 2
(d) Atoms in 1 mole of CO
2. A hydrogen was found to contain 85.7% by mass of carbon and 14.3% by mass of hydrogen. Molar mass of
hydrocarbon is 56 mol−1. The formula for hydrocarbon is
(a) CH 4
(b) C 2 H 4
(c) C 4 H 8
(d) C 5 H 10
3. What will be the molarity of a solution which contains 5.85 g of NaCl(s) per 500 mL?
(a) 4 mol L−1
(b) 20 mol L−1
(c) 0.2 mol L−1
(d) 2 mol L−1
4. Which of the following pairs have the same number of atoms?

(a) I and II
(b) II and III
(c) III and IV
(d) I and IV
5. A mixture of 24 dm 3 of hydrogen and 100 dm 3 of oxygen was ignited and the reaction mixture was cooled to
room temperature and pressure. What will be volume of gases remaining of the end of the reaction?
(a) 24 dm 3
(b) 76 dm 3
(c) 88 dm 3
(d) 112 dm3
6. What is maximum number of orbitals that can be identified with the following quantum number?
n=3 ,l=1 ,m1=0
(a) 1
(b) 2
(c) 3
(d) 4
7. Which of the following options does not represent ground state electronic configuration of an atom?

8. The probability density plots of 1 s and 2 s orbitals are given in figure:

 The density of dots in a region represents the probability density of finding electrons in the region.
On the basis of above diagram which of the following statements is incorrect?
(a) 1 s and 2 s orbitals are spherical in shape.
(b) The probability of finding the electron is maximum near the nucleus.
(c) The probability of finding the electron at a given distance is equal in all directions.
(d) The probability density of electron for 2 s orbital decreases uniformly as distance from the nucleus
increases.
9. The pair of ions having same electronic configuration is ________________.
3+ ¿¿
(a) C r 3 +¿, F e ¿
2+¿ ¿
(b) F e 3+¿ , M n ¿
3+ ¿¿
(c) F e 3+¿ ,C o ¿
3+ ¿¿
(d) S c 3+¿ ,C r ¿
10. In the following question two or more options may be correct. Identify the pairs which are not of isotopes?
12 13
I. 6 X , 6Y
34 37
II. 17 X , 17Y
14 14
III. 6 X , 7Y
8 8
IV. 4 X , 5Y
(a) I and II
(b) II and III
(c) III and IV
(d) I and IV
11. Which of the following molecules all bonds not equal?
(a) PCl5
(b) SF6
(c) BF3
(d) AlF3
12. Which of the following pair consist of only paramagnetic species?
(a) O2 , NO
2−¿¿

(b) O +¿,
2
O ¿ 2

(c) CO, NO
−¿¿
2−¿, N ¿
(d) O 2 2

13. Which of the following isoelectronic and isostructural?

14. Decreasing order of stability.

15. Which of the following is polar molecule?
(a) SiF4
(b) XeF4
(c) BF3
(d) SF4
16. Which one of the following statements is incorrect in relation to ionization enthalpy?
(a) Ionization enthalpy increases for each successive electron.
(b) The greatest increase in ionization enthalpy is experiment on removal of electron from core noble gas
configuration.
(c) End of valence electrons is marked by a big jump in ionization enthalpy.
(d) Removal of electron from orbitals bearing lower n value is easier than from orbital having higher n value.
17. Considering the elements B, Al, Mg and K, the correct order of their metallic character is:
(a) B > Al > Mg > K
(b) Al > Mg > B > K
(c) Mg > Al > K > B
(d) K > Mg > Al > B
18. x KMnO4 + NH3 → y KNO3 + MnO2 + KOH + H2O
(a) x=4 , y=6
(b) x=8 , y=6
(c) x=3 , y=8
(d) x=8 , y=3
19. The reagent commonly used to determine hardness of water volumeterically (titrimetrically) is
(a) Oxalic acid.
(b) Disodium salt of EDTA.
(c) Sodium citrate.
(d) Sodium thiosulphate.
20. Why does H+ ion always get associated with other atoms or molecules?
(a) Ionisation enthalpy of hydrogen resembles that of alkali metals.
(b) Its reactivity is similar to halogens.
(c) It resembles both alkali metals and halogens
(d) Loss of an electron from hydrogen atom results in a nucleus of very small size as compared to other atoms
or ions. Due to small size it cannot exist free.
21. Interstitial hydride can be formed by
(a) Na
(b) K
(c) Fe
(d) Ca
22. Which of the following ion is most resonance stabilized?

23. Homolytic fission leads to formation of

(a) Nucleophile
(b) Carbanion
(c) Free radical
(d) Carbocation
24. The order of priority in IUPAC system
25. The IUPAC name of the molecule

(a) 4-oxo-2,3-diinethyl pent-2-en-1-oic acid

(b) 2-carboxy-3-methyl pent-2-en -3-one
(c) 4-carboxy-3-methyl pent-3-en-2-one
(d) 2,3-Dimethyl-4-oxo-pent-2-en-1-oic acid

SECTION B (answer any 20 questions from this section)

In the following questions the Assertion and Reason have been put forward. Read the statements
carefully and choose the correct alternative from the following:
(a) Assertion and reason both are correct statements and reason is correct explanation for assertion.
(b) Assertion and reason both are correct statements but reason is not correct explanation for
assertion.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
26. Assertion: 3° free radical is most stable.
Reason: It is due to ––I effect of alkyl groups.
27. Assertion: IUPAC name of ICH 2 CH 2 HC 2-COOH is 4-iodobutanoic acid.
Reason: Iodine is preferred over ––COOH in IUPAC system.
28. Assertion: Allyl free radical is more stable than n-propyl free radical.
Reason: Allyl free radical is stabilised by resonance.
29. Assertion: Ionic compounds usually have high melting and boiling points.
Reason: A large amount of energy is needed to overcome the strong interionic electrostatic attractive forces.
30. Assertion: Sodium chloride formed by the action of chlorine gas on sodium metal is a stable compound.
Reason: This is because sodium and chloride ions acquire octet in sodium chloride formation.
31. Assertion: In the reaction between potassium permanganate and potassium iodide, permanganate ions act as
oxidising agent.
Reason': Oxidation state of manganese changes from +2 to +7 during the reaction.
32. Assertion: The decomposition of hydrogen peroxide to form water and oxygen is an example of
disproportionation reaction.
Reason: The oxygen of peroxide is in – 1 oxidation state and it is converted to zero oxidation state in O 2 and –
2 oxidation state in H2O.
33. Assertion: −¿ OH group is less preferred over double bond.
Reason: IUPAC name of C 6 H 5 −CH =CH −COOH is 3-phenyl-prop-2-enoic acid.
34. Assertion: Combustion of 16 g of methane gives 18 g of water.
Reason: In the combustion of methane, water is one of the products.
Read the given passage and answer the questions that follow:
Redox reactions are reactions in which oxidation and reduction takes place simultaneously. Oxidation
number are assigned in accordance with the set of rules. Oxidation number and ion electron methods
both are used in balancing ionic equations. Redox reactions are classified as combination,
decomposition, displacement and disproportionation reactions.
35. The oxidation states of Br in Br3O8 are
(a) +6, +4, +6
(b) +6, +6, +4
(c) +4, +6, +6
 (d) +4, +6, +4
36. The oxidation state of ‘S’ in CuSO4 is
(a) +2
(b) +4
(c) +6
(d) – 2
+ ¿→¿
−¿+ MnO +2 H O ¿
37. x MnO−¿+ 4
yH ¿
‘z’ MnO4 2 2

x , y , z respectively in balanced ionic equation will be

(a) 2, 4, 3
(b) 3, 4, 2
(c) 4, 3, 2
(d) 4, 2, 3
38. Which of the following is correct oxidation number of Cr in CrO5?
(a) +5
(b) +10
(c) +6
(d) +3
39. Cu+ undergoes disproportionation reaction to form
(a) Cu
(b) Cu2+
(c) Both (a) and (b)
(d) None of these
40. Anything that influences the valence electrons will affect the chemistry of the element. Which one of the
following factors does not affect the valence shell?
(a) Valence principal quantum number ( n )
(b) Nuclear charge ( Z )
(c) Nuclear mass
(d) Number of core electrons
41. Metal hydride on treatment with water give
(a) Acid
(b) Hydrogen peroxide
(c) metal hydroxide + H2
(d) Metal oxide.
42. Natural gas contains
(a) CO + H2
(b) CH4 + H2
(c) H2 only
(d) CO + N2
43. Mg3N2 reacts with D2O to form
(a) Mg(OH)2 + ND3
(b) Mg(OD)2 + ND3
(c) Mg(OD)2 + 6D2O
(d) None of these
44. The formula of deuterium sulphate is
(a) D2SO4
(b) D3SO4
(c) DSO4
(d) D4(SO4)3
45. Pick out the wrong statement.
46. Which of the following carbocation is most stable?

47. Match Column I with Column II.

48. A mixture of 24 dm 3 of hydrogen and 100 dm 3 of oxygen was ignited and the reaction mixture was cooled to
room temperature and pressure. What will be volume of gases remaining of the end of the reaction?
(e) 24 dm 3
(f) 76 dm 3
(g) 88 dm 3
(h) 112 dm3
49. Which of the following terms are unitless?
I. Molality
II. Molarity
III. Mole fraction
IV. Mass percent
(a) I and II
(b) II and III
(c) III and IV
(d) I and IV

SECTION C
Read the given passage and answer the questions that follow based on passage and related studied concepts.
Orbitals are region or space where there is maximum probability of finding electrons. Qualitatively, these
orbitals can be distinguished by their size, shape and orientation. An orbital of small size means there is more
 chance of finding the electron near the nucleus. Shape and orientation means the direction in which
probability of finding electron is maximum. Atomic orbitals can be distinguished by quantum numbers. Each
orbital is designated by three quantum numbers n , l and ml (magnetic quantum number) which define energy,
shape and orientation but these are not sufficient to explain spectra of multi-electrons atoms. Spin quantum
number ( ms ) determines the spin of electron. Spin angular momentum of electron has two orientations relative
to chosen axis which are distinguished by spin quantum numbers ms which can take values +1/2 and −1/2.

Value of ‘l ’ 0 1 2 3 4
Notation for subshell s p d f g

50. The number of orbitals in 3rd shell are equal to –

(a) 2
(b) 6
(c) 9
(d) 12
51. n=2 ,l=1, n=4 ,l=0 respectively represent –
(a) 2 d , 4 s
(b) 2 p , 4 s
(c) 2 s , 4 p
(d) 2 s , 4 d
52. An orbital can have maximum electrons equal to –
(a) 2
(b) 6
(c) 10
(d) 14
53. Shape of ‘s’ and ‘p’ orbitals respectively are –
(a) spherical, dumb-bell
(b) both are spherical
(c) Both are dumb-bell
(d) dumb-bell, spherical
54. The d -orbitals on the axis are –
(a) d xy
(b) d yz
(c) d xz
(d) d x − y and d z
2 2 2

55. Which of the following has maximum difference in 1st and 2nd ionization enthalpy.
(a) 1 s2 2 s2 2 p 6 3 s1
(b) 1 s2 2 s2 2 p 6 3 s2
(c) 1 s2 2 s2 2 p1
(d) 1 s2 2 s2 26

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ANSWERS:
1. Ans. A
2. Ans. C
3. Ans. C
4. Ans. C
5. Ans. C
6. Ans. A
7. Ans. B
8. Ans. D
9. Ans. B
10. Ans. C
11. Ans. A
12. Ans. A
13. Ans. A
14. Ans. C
15. Ans. D
16. Ans. D
17. Ans. D
18. Ans. D
19. Ans. B
20. Ans. D
21. Ans. C
22. Ans. B
23. Ans. C
24. Ans. B
25. Ans. D
26. Ans. C
27. Ans. C
28. Ans. A
29. Ans. A
30. Ans. A
31. Ans. C
32. Ans. A
33. Ans. D
34. Ans. D
35. Ans. A
36. Ans. C
37. Ans. B
38. Ans. C
39. Ans. C
40. Ans. C
41. Ans. C
42. Ans. B
43. Ans. B
44. Ans. A
45. Ans. A
46. Ans. B
47. Ans. A
48. Ans. C
49. Ans. C
50. Ans. C
51. Ans. B
52. Ans. A
53. Ans. A
54. Ans. D
55. Ans. A