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Solar Cooling Report
Solar Cooling Report
Solar Cooling Report
Solar Cooling
Introduction
The core idea is to use the solar energy directly to produce chilled water.
The high temperature required by absorption chillers is provided by
solar troughs. The system doesn’t require “strategic” materials (like in
PV systems) and has peak production in the moment of peak demand.
Desiccant Cooling
Energy is transferred through latent heat processes.
“The cooling capacity is based on the physical properties of the cooling
fluid that will change phases. At different temperatures, depending on its
pressure.”
Absorption Cooling
Heat Driven Systems
Absorption Refrigerator-
The absorption refrigerator is a refrigerator that uses a heat source (e.g.,
solar, kerosene-fueled flame) to provide the energy needed to drive the
cooling system. Absorption refrigerators are a popular alternative to
regular compressor refrigerators where electricity is unreliable, costly, or
unavailable, where noise from the compressor is problematic, or where
surplus heat is available (e.g., from turbine exhausts or industrial
processes). Absorption refrigerators powered by heat from the
combustion of liquefied petroleum gas are often used for food storage in
recreational vehicles.
Adsorption Refrigeration
Adsorption refrigeration and heat pump cycles rely on the adsorption of
a refrigerant gas into an adsorbent at low pressure and subsequent
desorption by heating. The adsorbent acts as a "chemical compressor"
driven by heat and is, from this point of view, the "pump" of the system.
It consists of a solar collector, a condenser or heat-exchanger and an
evaporator that is placed in a refrigerator box. The inside of the collector
is lined with an adsorption bed packed with activated carbon adsorbed
with methanol. The refrigerator box is insulated filled with water. The
activated carbon can adsorb a large amount of methanol vapours in
ambient temperature and desorb it at a higher temperature (around 100
degrees Celsius). During the daytime, the sunshine irradiates the
collector, so the collector is heated up and the methanol is desorbed from
the activated carbon. In desorption, the liquid methanol adsorbed in the
charcoal heats up and vaporizes. The methanol vapour condenses and is
stored in the evaporator.
Helium gas can also be 'pumped' by thermally cycling activated carbon
'sorption pumps' between 4 kelvins and higher temperatures. An
example of this is to provide the cooling power for the Oxford
Instruments AST series dilution refrigerators. 3He vapour is pumped
from the surface of the dilute phase of a mixture of liquid 4He and its
isotope 3He. The 3He is adsorbed onto the surfaces of the carbon at low
temperature (typically <4K), the regeneration of the pump between 20
and 40 K returns the 3He to the concentrated phase of the liquid mixture.
Cooling occurs at the interface between the two liquid phases as 3He
'evaporates' across the phase boundary. If more than one pump is present
in the system a continuous flow of gas and hence constant cooling power
can be obtained, by having one sorption pump regenerating while the
other is pumping. Systems such as this allow temperatures as low as 10
mK (0.01 kelvin) to be obtained with very few moving parts.
Desiccant system
A desiccant is a hygroscopic substance that induces or sustains a state of
dryness (desiccation) in its local vicinity in a moderately well-sealed
container.
Commonly encountered pre-packaged desiccants are solids, and work
through absorption or adsorption of water, or a combination of the two.
Desiccants for specialized purposes may be in forms other than solid,
and may work through other principles, such as chemical bonding of
water molecules.
Pre-packaged desiccant is most commonly used to remove excessive
humidity that would normally degrade or even destroy products sensitive
to moisture. Drierite, Silica gel, calcium sulfate, calcium chloride,
montmorillonite clay, and molecular sieves are commonly used as
desiccants.
Rice is a common "low-tech" alternative frequently used, for example, in
salt-shakers to maintain granularity of table-salt for effective pouring or
shaking. Rice, however, is not a good general purpose desiccant since,
unless immersed in an organism-hostile environment like pure salt, over
time may be eaten by creatures that might in turn contaminate the
product that is being preserved. Salt itself is another effective desiccant,
used for millennia in preparation of dried food and also to mummify
corpses.
Solar Cooling Path and Local
Conditions
Refrigerants
A vapor-compression chiller uses a refrigerant internally as its working
fluid. Many refrigerants options are available; when selecting a chiller,
the application cooling temperature requirements and refrigerant's
cooling characteristics need to be matched. Important parameters to
consider are the operating temperatures and pressures.
There are several environmental factors that concern refrigerants, and
also affect the future availability for chiller applications. This is a key
consideration in intermittent applications where a large chiller may last
for 25 years or more. Ozone depletion potential (ODP) and global
warming potential (GWP) of the refrigerant need to be considered. ODP
and GWP data for some of the more common vapor-compression
refrigerants:
"Freon" is a trade name for a family of haloalkane refrigerants
manufactured by DuPont and other companies. These refrigerants were
commonly used due to their superior stability and safety properties: they
were not flammable nor obviously toxic as were the fluids they replaced,
such as sulfur dioxide. Unfortunately, these chlorine-bearing refrigerants
reach the upper atmosphere when they escape. In the stratosphere, CFCs
break up due to UV-radiation, releasing their chlorine atoms. These
chlorine atoms act as catalysts in the breakdown of ozone, which does
severe damage to the ozone layer that shields the Earth's surface from
the Sun's strong UV radiation. The chlorine will remain active as a
catalyst until and unless it binds with another particle, forming a stable
molecule. CFC refrigerants in common but receding usage include R-11
and R-12. Newer refrigerants that have reduced ozone depletion effect
include HCFCs (R-22, used in most homes today) and HFCs (R-134a,
used in most cars) have replaced most CFC use. HCFCs in turn are
being phased out under the Montreal Protocol and replaced by
hydrofluorocarbons (HFCs), such as R-410A, which lack chlorine.
However, CFCs, HCFCs, and HFCs all have large global warming
potential.
Newer refrigerants are currently the subject of research, such as
supercritical carbon dioxide, known as R-744. These have similar
efficiencies compared to existing CFC and HFC based compounds, and
have many orders of magnitude lower global warming potential.
CONCLUSIONS
The thermodynamics of the vapor compression cycle can be analyzed on
a temperature versus entropy diagram. At point 1 in the diagram, the
circulating refrigerant enters the compressor as a saturated vapor. From
point 1 to point 2, the vapor is isentropically compressed (i.e.,
compressed at constant entropy) and exits the compressor as a
superheated vapor.
From point 2 to point 3, the superheated vapor travels through part of the
condenser which removes the superheat by cooling the vapor. Between
point 3 and point 4, the vapor travels through the remainder of the
condenser and is condensed into a saturated liquid. The condensation
process occurs at essentially constant pressure.
Between points 4 and 5, the saturated liquid refrigerant passes through
the expansion valve and undergoes an abrupt decrease of pressure. That
process results in the adiabatic flash evaporation and auto-refrigeration
of a portion of the liquid (typically, less than half of the liquid flashes).
The adiabatic flash evaporation process is isenthalpic.
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