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1. Calculate the standard free energy ∆Go for the following balanced reaction
Al(s) + Fe3+(aq) →Al3+(aq) + Fe(s)
If Eocell= 2.431 V, F = 96500 C/mol
a) - 7.04 x 105 J/mol
b) + 7.04 x 105 J/mol
c) 5.6 x 106 J/mol
d) - 56 x 103 J/mol
2. What is the kind of this electrode : Na/Na+
a) Metal/metal ions electrode
b) Nonmetal/nonmetal ions electrodes
c) Oxidation-reduction electrode
3. In a concentration cell with ion transference, the concentration of the
solutions are (1 M, 2 M), Cathode should be immersed in :
a) 1 M solution
b) 2 M solution
4. A concentration cell is constructed by placing identical Cd electrodes in
two Cd2+ solutions. If the concentrations of two Cd2+ solutions are 1.0 M
and 0.0010 M, calculate the potential of the cell, (E 0 Cd = - 0.400 V),
a) 1.20 V
b) – 0.0592 V
c) 0.0592 V
d) 0.0800 V
5. For a galvanic cell using Ag/Ag+ (1.0 M), and Zn/Zn2+ (1.0 M) half cells,
which of the following statements is incorrect (where EoAg = 0.799V, E0 Zn
= -0.762 V) :
a) The zinc electrode is the anode
b) Reduction occurs at the zinc electrode as the cell operates
c) The mass of the zinc electrode will decrease as the cell operates
d) The concentration of Ag+ will decease as the cell operates.
6. A process in which a substance accepts electrons is called:
a) Oxidation
b) Hydrogenation
c) Sublimation
d) Reduction
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a) Cu/Cu2+//Fe3+,Fe2+/Pt
b) Pt/Fe3+,Fe2+//Cu2+/Cu
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34. Hg,HgO/OH- is an
a) Electrode of the First kind
b) Electrode of the second kind
c) Oxidation- reduction electrode
35. In the electrolytic concentration cell :
a) The concentrations of the electrodes are different but the
electrolytes are the same
b) The concentrations of the electrodes are the same but the
electrolytes are different
36. The cell :
Hg, Zn(a1)/ZnSO4/Zn(a2),Hg
is classified as:
A) Concentration cell with transference
B) Concentration cell without transference
37. For the concentration cell with two chlorine gas electrodes (a = 0.04 atm)
and (0.2 atm) immersed into one solution of HCl (0.1 M)
determine the cathode and anode half reactions and overall
reaction?
a)
At anode: 2Cl → Cl2 (0.2 atm) + 2e
At cathode: Cl2 (0.04 atm) + 2e → 2Cl-
The cell can be represented as follows:
Pt, Cl2 (0.2atm) / HCl (0.1 M)/Cl2 (0.04 atm),Pt
The overall cell reaction is :
Cl2(0.04 atm) → Cl2 (0.2 atm)
b)
At anode: 2Cl- → Cl2 (0.04 atm) + 2e
At cathode: Cl2 (0.2 atm) + 2e → 2Cl-
The cell can be represented as follows:
Pt, Cl2 (0.04 atm) / HCl (0.1 M)/Cl2 (0.2 atm),Pt
The overall cell reaction is :
Cl2(0.2 atm) → Cl2 (0.04 atm)
38. For the concentration cell with two iron metal electrodes immersed into
two separated solutions of Fe2+(0.01 M) and Fe2+ (0.1 M) that are
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B)
Oxidation : Fe → Fe2+ (0.01 M)
Reduction Fe2+ (0.1 ) + 2e → Fe(s)
Cell line notation : Fe/Fe2+(0.01)//Fe2+(0. 1)/Fe
Overall cell reaction: Fe2+ (0. 1) → Fe2+(0.01)
39. Calculate the cell potential for a concentration cell with two silver
electrodes immersed in (0.2 M, 3 M) AgNO3(aq)
a) 0.0644 V
b) 0.644 V
c) 0.0348
d) 0.348
40. ……………………….is abattery that is designed to be used once and discarded,
and no recharged with electricity.
a) Primary cell
b) Secondary cell
41. ………………………is an electric cell that is rechargeable because it converts
chemical energy into electrical energy by a reversible chemical reaction
a) Primary cell
b) Secondary cell
42. Write the oxidation reaction in dry cell and lead storage battery
a) Zn(s) → Zn2+ + 2e (lead storage battery)
Pb(s) → Pb2+ + 2e (dry cell)
b) Quinhydrone electrode
c) Glass electrode
d) A, b, c are correct
e) None of the above
44. The relationship between EH and pH at (1 atm) is
a) EH = - 0.0592 pH
b) EH = + 0.0592 pH
45. Calculate the EH at pH = 7 , (P = 1 atm)
a) – 0.414 V
b) + 0.414 V
c) + 0.342
d) – 0.342
e) None of the above
46. To calculate the pH according to the glass electrode, we use the following
relationship:
a) E = E0 + 0.0592 pH
b) E = E0 – 0.0592 pH
c) E = - 0.0592 pH
d) E = + 0.0592 pH
e) None of the above
47. Calculate the pH for a solution contains the hydrogen electrode and
calomel electrode and the average cell potential is 0.5164 V at 25 0C, the
pressure of hydrogen gas is 0.961 atm and the potential of calomel
electrode is 0.2800 V?
a) pH = 3
b) pH = 4
c) pH = 5
d) pH = 2.3
48. ……………………….is a process in which electrical energy is used to cause a
non-spontaneous chemical reaction to occur
a) Electrolysis
b) Hydrolysis
49. Write the oxidation and reduction for the electrolysis of water
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oxidation : …………………………………………………………….
Reduction…………………………………………………………..
50. Write the oxidation and reduction for the electrolysis of molten NaCl
oxidation : …………………………………………………………………….
Reduction…………………………………………………………………..
51. Write the oxidation and reduction for the electrolysis of NaCl solution
oxidation : ……………………………………………………………………….
Reduction…………………………………………………………
52. Electroplating can :
a) Increase corrosion resistance
b) Increase thickness of part
c) Increase tensile strength and hardness
d) A, b and c are correct
e) Non of the above
53. When plating a spoon with silver
a) Spoon is the anode and connected to the negative terminal of
the battery
b) Spoon is the anode and connected to the positive terminal of
the battery
c) Spoon is the cathode and connected to the negative terminal
of the battery
d) Spoon is the cathode and connected to the positive terminal of
the battery.
Oxidation………………………………………………………………………………………………..
Reduction……………………………………………………………………………………………….
57. The half – reaction that occurs at the anode during the electrolysis of
molten sodium bromide is :
a) 2Br - → Br2 + 2e
b) Br2 + 2e → 2Br-
c) Na+ + e → Na
d) Na → Na+ + e
e) 2H2O + 2e → 2OH- + H2
58. Which of the following represents the reaction that occurs at the negative
electrode in the following cell:
Pb/Pb(NO3)2 (1.0 M)//AgNO3 (1.0 M)/Ag
a) Pb2+ + 2e → Pb
b) Pb → Pb2+ + 2e
c) Ag+ + e → Ag
d) Ag → Ag+ + e
e) None of the above
59. For a voltaic (galvanic) cell using Ag, Ag+ (1.0 M) and Zn,Zn2+ (1.0 M) half-
cells, which of the following statements is incorrect (where E0Ag = 0.80 V,
E0Zn = -0.763 V)
a) The zinc electrode is the anode
b) Electrons will flow through the external circuit from the zinc
electrode to the silver electrode
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e) 10-72
64. In the standard notation for a voltaic cell, the double vertical line (//)
represents:
a) A phase boundary
b) Gas electrode
c) A wire (metal) connection
d) A salt bridge
e) A standard hydrogen electrode
65. In the electrolytic cell, flow of electrons is from:
a) Cathode to anode through internal supply
b) Cathode to anode in solution
c) Cathode to anode through external supply
d) Anode to cathode through internal supply
66. In Cu-Zn cell
a) Oxidation occurs at the copper cathode
b) Chemical energy is converted to light energy
c) Reduction occurs at the copper cathode
d) Reduction occurs at the anode
67. Corrosion kinetics is used to :
a) Calculate cell potential
b) Corrosion rate
c) Standard free energy
68. Polarization is the :
a) Deviation from a standard potential while corrosion
b) Value of deviation from a standard potential
69. Overpotential is the :
a) Deviation from a standard potential while corrosion
b) Value of deviation from a standard potential
70. Calculate the overpotential of cathode if : EoCu = 0.34 V, Ecu = 0.29 V
a) – 0.11
b) 0.63 V
c) + 0.11 V
d) 0.29 V
e) 0.34 V
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71. Rate of reduction of hydrogen ions at different metal surfaces (Hg, Fe, Pt)
at the same hydrogen standard potential (Eo = 0.000) have :
a) Different I0 values
b) Similar I0 values
c) Unpredicted I0 values
d) None of the above
72. When the Corrosion is under anodic polarization control:
a) Polarization of anode is smaller than of that of cathode
b) Polarization of cathode is greater than of that of anode
c) Corrosion potential will decrese
d) Corrosion potential will increase
e) Non of the above
73. Exchange current density (I0) is dependent on :
a) Nature of the redox reaction
b) Surface area
c) Electrode composition
d) A, b and c are correct
e) None of the above
74. What will happen if a Pt electrode is added to an acid solution containing a
Zn electrode :
a) The rate of hydrogen evolution on Zn (H on Zn) increases
b) The rate of hydrogen evolution on platinum surface (H on Pt)
increases vigorously
c) The rate of oxidation of zinc in the acid solution decreases
d) A, b and c are correct
e) None of the above
a) A
b) B
77. (Two dissimilar materials are coupled in a corrosive electrolyte. The less
noble material will become the anode and corrodes faster).
The previous definition relates to :
a) Uniform corrosion
b) Galvanic corrosion
c) Pitting corrosion
d) Erosion corrosion
78. (Formation of holes or pits on metal surface where passive film breaks
down).
The previous definition relates to :
a) Uniform corrosion
b) Galvanic corrosion
c) Pitting corrosion
d) Erosion corrosion
a) Inhibitors
b) Design
c) Coatings
d) Anodic protection
e) Cathodic protection
81. External power supply (potentiostat) is applied to keep a protective
passive film on a metal or alloy surface:
A) Anodic protection
B) Cathodic protection
82. ……………………………involves supplying, from an external source, electrons
to the metal to be protected, making it a cathode.
a) Anodic protection
b) Cathodic protection
83. Which of these represents one of the methods of cathodic protection:
a) Externally DC Supply
b) Galvanic coupling with more anodic metal (Sacrificial anode)
c) Hot-dip Galvanizing
d) A, b, c are correct
e) None of the above
84. Explain one of the methods of cathodic protection with illustrations and
equations
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85. Write net ionic equations describing the reaction between:
Aluminum metal and Fe3+ ions in solution that products dissolved Al3+ and
Fe2+ ions
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86. Write net ionic equations describing the reaction between:
Tin (Sn) and Ag+ ions in solution that produces dissolved Sn2+ ions and
silver metal
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87. An electrochemical cell with an aqueous electrolyte is based on the
reaction between Ni2+(aq) and Cd(s), producing Ni(s) and Cd2+(aq)
a) Write half-reactions for the anode and cathode
Oxidation: ………………………………………………………………………..
Reduction:………………………………………………………………………..
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88. A voltaic cell is based on the reaction between Cu2+(aq) and Ni(s),
producing Cu(s) and Ni2+(aq)
a) Write the anode and cathode half-reactions
Oxidation: ………………………………………………………………………..
Reduction:………………………………………………………………………..
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89. A voltaic cell is based on the reduction of Ag+(aq) to Ag(s) and the
oxidation of Sn(s) to Sn2+(aq)
Oxidation: ………………………………………………………………………..
Reduction:………………………………………………………………………..
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90. What is the function of platinum in the standard hydrogen electrode?
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91. Which is a stronger oxidizer under standard conditions :
oxygen or chlorine?
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92. Which is the strongest reducing agent: Li, K and Na
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93. Calculate the values of ∆G0 and Eocell of the following reactions:
Cu(s) + 2Fe3+(aq) ----------Cu2+(aq) + 2Fe2+(aq)
EoCu = 0.337 V, E0Fe3+/Fe2+ = 0.771 V
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94. If a piece of silver is placed in a solution in which [Ag +] = [Cu2+] = 1.00M,
will the following reaction proceed spontaneously?
EoCu = 0.337 V, E0Ag = 0.799 V
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95. A piece of cademium (Cd) is placed in a solution in which [Cd 2+] = [Sn2+] =
1.00 M. Will the following reaction proceed spontaneously?
E0Cd = - 0.403 V, E0Sn = - 0.136 V
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97. Under standard conditions are H+ ions capable of oxidizing :
a) Zn to Zn2+ (EoZn = - 0.763 V)
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101. Determine the equilibrium constant for the following reaction at 298 K :
Fe3+ (aq) + Cr2+(aq) → Fe2+(aq) + Cr3+(aq)
R = 8.314, F = 96500 C/mol,
E0Fe3+/Fe2+ = 0.771 V, EoCr3+/Cr2+ = - 0.408 V
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106. Pt,H2(1 atm)/H+(a2)…H+(a1)/H2(1 atm),Pt
- What type of the previous cell
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109. A cell whose reaction is as follows
NiO2 + 2Ag + 4H+ → Ni2+ + 2Ag+ + 2H2O
And its standard potential is 2.48 V
Calculate the cell potential at the following concentrations :
[Ni2+]= [Ag+] = 0.01 M
And pH for the solution is 5
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110. Cl2 + 2I- → 2Cl- + I2
What is the effect of dissolving more iodide in solution on the cell
potential ?
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111. Calculate the change in standard free energy ∆G0 and equilibrium constant
for the following reaction at standard conditions
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114. Calculate the potential of the following cell, the change in free energy of
its reaction and the equilibrium constant
Sn/Sn2+(1 M)//Pb2+(0.001 M/Pb
R = 8.314, 1 F = 96500 C/mol
E0Sn2+/Sn = -0.136 V E0Pb2+/Pb = - 0.126 V V
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115. At standard conditions, will chromium(III) ions Cr3+, oxidize metallic copper
to copper(II) ions, Cu2+, or will Cu2+ oxidize metallic chromium to Cr3+ ions?
E0Cu2+/Cu = 0.337 V, Eo Cr3+/Cr = - 0.744 V
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116. Calculate the reduction potential for the Fe3+/Fe2+ electrode if the
concentration of Fe2+ is five times that of Fe3+
E0Fe3+/Fe2+ = + 0.771 V
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117. Calculate the potential of the chlorine/chloride ion, Cl2/Cl-, electrode when
the partial pressure of Cl2 is 10.0 atm and [Cl-] = 1.00 x 10-3 M
Cl2+ 2e → 2Cl-
E0Cl2/Cl- = + 1.360 V
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118. Calculate ∆G0 in J/mole and K at 25 0C for the following reaction from
standard electrode potentials :
3Sn4+ + 2Cr → 3Sn2+ + 2Cr3+
following reaction
2Cu + PtCl6- → 2Cu+ + PtCl42- + 2Cl-