Mathematics Tool 1

Mathematical Tool in Chemistry
ONLY ONE OPTION CORRECT TYPE
dsoy ,d lgh fodYi çdkj (ONLY ONE OPTION CORRECT TYPE)
Section (A) : Pressure, Volume and Temperature measurement

[k.M (A) : nkc] vk;ru rFkk rki ekiu
1. Which of the following is not a unit of pressure :
(1) Atmosphere (2) Pascal (3) Torr (4*) Newton
fuEu esa ls dkSulh] nkc dh bdkbZ ugha gS %
(1) ok;qeaMy (2) ikWLdy (3) VkWj (4) U;wVu
2. The SI unit of area is :

(1) Litre (2) hector (3*) m2 (4) dm2
{ks=kQy dh SI bdkbZ fuEu gS &
(1) Litre (2) hector (3) m2 (4) dm2
3. How many of the prefixes are correctly matched with their multiples :
(i) pico (p) – 10–12 (ii) tera (T) – 1012 (iii) giga (G) – 109
(iv) nano (n) – 10–9 (v) mega (M) – 106 (vi) micro () – 10–6
(vii) centi (D) – 10 –1 (viii) deci (D) – 10 (ix) milli (m) – 10–3
fuEu esa ls fdrus iwoZyXu (prefixes), vius xq.kd (multiples) ds lkFk lgh :i ls lqefs yr gSa %
(i) fidks (p) – 10–12 (ii) Vsjk (T) – 1012 (iii) xhxk (G) – 109
(iv) uSuks (n) – 10–9 (v) esxk (M) – 106 (vi) ekbØks () – 10–6
(vii) lsUVh (D) – 10–1 (viii) Mslh (D) – 10 (ix) feyh (m) – 10–3
(1) 5 (2) 6 (3*) 7 (4) 8
Sol. (vii) centi (3) – 10–2 (viii) deci (4) – 10–1
(vii) lsUVh (3) – 10–2 (viii) Mslh (4) – 10–1
4. In which of the following options, the units of pressure are not correctly related :
(1) 1 bar = 105 N/m2 (2) 1 torr = 1mm of Hg (3*) 1 atm = 105 Pa (4) 1 atm= 760 mm of Hg
fuEu esa ls dkSulk fodYi] nkc dh bdkb;ksa dk lgh lEcU/k ugha n'kkZrk gS %
(1) 1 bar = 105 N/m2 (2) 1 torr = 1mm of Hg (3) 1 atm = 105 Pa (4) 1 atm = 760 mm of Hg
5. Which of the following is the correct order of units of pressure :

nkc dh bdkb;ksa ds fy, fuEu esa ls dkSulk Øe lgh gS &
(1*) 1 atm > 1 bar > 1 cm of Hg > 1 torr > 1 pascal
(2) 1 bar > 1 atm > 1 pascal > 1 torr > 1 cm of Hg
(3) 1 pascal > 1 torr > 1 cm of Hg > 1 bar > 1 atm
(4) 1 torr < 1 pascal < 1 cm of Hg < 1 bar < 1 atm
6. Four persons P, Q, R and S are given a gas sample each. They reported the pressure of gas samples
to be 0.5 atm, 760 torr, 1×103 Pa & 0.5 bar respectively. Whose gas sample exerts maximum pressure:
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NEET MTC -1
(1) S (2) R (3*) Q (4) P

pkj O;fDr;ksa rFkk P, Q, R rFkk S dks ,d-,d xSlh; izkn'kZ fn;s x;sA mUgkasus] xSl izkn'kZ ds nkc Øe'k% 0.5 atm,
760 torr,1×103 Pa o 0.5 ckj izLrqr fd;sA fdl izkn'kZ dk nkc U;wure gS
(1) S (2) R (3) Q (4) P
7. In which of the following options, the units of volume are not correctly related :
(1) 1mL = 10–6 m3 (2) 1m3 = 1000 L (3) 1L = 1000 cm3 (4*) 1dm3 = 100 L
fuEu esa ls dkSulk fodYi] vk;ru dh bdkb;ksa dk lgh lEcU/k ugha n'kkZrk gS &
(1) 1mL = 10–6 m3 (2) 1m3 = 1000 L (3) 1L = 1000 cm3 (4) 1dm3 = 100 L
8. Three persons X, Y and Z are given a gas sample each. They reported the temperature of gas samples
to be 17ºC, 300 K and 96.4ºF. Whose gas sample exerts minimum temperature :
(1*) X (2) Y (3) Z (4) Both (X) and (Y)
rhu O;fDr;ksa X, Y rFkk Z dks ,d-,d xSlh; izkn'kZ fn;k x;kA mUgkasus xSl izkn'kZ ds rki Øe'k% 17ºC, 300 K rFkk
96.4ºF izLrqr fd;sA fdl izkn'kZ dk rki U;wure gS %
(1) X (2) Y (3) Z (4) (X) o (Y) nksuksa
9. Which of the prefixe is not correctly matched with their multiples :

(1) nano (n) – 10–9 (2) mega (M)–106 (3) micro () –10–6 (4*) centi (D)–10–1
fuEu esa ls dkSulk iwoZyXu vius xq.kd ds lkFk lgh :i ls lqesfyr ugha gSa %
(1) nano (n) – 10–9 (2) mega (M)–106 (3) micro () –10–6 (4) centi (D)–10–1
10. Unit of SI system are similar to the units in :

(1*) M.K.S. system (2) C.G.S. system (3) F.P.S. system (4) None of these
SI bdkb;k¡ fuEu eas ls fdldh bdkbZ;ksa ds leku gS
(1) M.K.S. system (2) C.G.S. system (3) F.P.S. system (4) buesa ls dksbZ ugha
11. 0.25 atm is not equal to

(1) 190 tors (2) 2.53 × 104 pascal (3) 19 cm of Hg (4*) 0.275 bar
0.25 atm fuEu esa ls fdlds leku ugh gS \
(1) 190 VkWj (2) 2.53 × 104 ikWLdy (3) 19 cm of Hg (4*) 0.275 ckj
12. Which pressure is largest

(1) 95 tors (2) 1.013 × 104 pascal (3*) 190 mm of Hg (4) 0.202 bar
dkSulk nkc vf/kdre gS \
(1) 95 VkWj (2) 1.013 × 104 ikLdy (3*) 190 mm of Hg (4) 0.202 ckj
95 1 1
Sol. (1) 95 tors = = atom (3) 190 mm = atom
760 8 4
1 1
(2) 1.013 × 104 pascal = atom (4) 0.2 atm =
10 5
13. 0.05 dm3 is equal to

0.05 dm3 fuEu esa ls fdlds leku gS \
(1) 50 ml (2) 0.05 lt (3) 5 × 10–5 m3 (4*) All of these (mijksDr lHkh)
NEET MTC -2
14. Which volume value is smallest

dkSulk vk;ru eku fuEure gS \
(1*) 0.3 lt (2) 2500 ml (3) 0.4 dm3 (4) 500 cm3
15. Which temperature is largest

dkSulk rki vf/kdre gS \
(1) 102ºF (2*) 45ºC (3) 310 K (4) All same (lHkh leku gS)
16. A general rule that for every 1000 feet of altitude the temperature falls 3.5 F. If the temperature at sea
level is 78 F, what would you expect the temperature to be at 1000 feet in ºc
(1) 43ºC (2*) 23.6ºC (3) 6.1ºF (4) None of these
izR;sd 1000 QhV dh ÅWpkbZ ij rkieku esa 3.5 F dh deh vkrh gSA ;fn leqnz ry ij rkieku 78 F gks rks 1000
QhV ij ºc esa rkieku gksxk \
(1) 43ºC (2*) 23.6ºC (3) 6.1ºF (4) mijksDr esa dksbZ ugha
17. If two moles of an ideal gas at 546 K occupy a volume of 44.8 litres, the pressure must be
;fn ,d vkn'kZ xSl ds nks eksy 546 K rki ij gSa vkSj mudk vk;ru 44.8 litres, gS rks mudk nkc gksxkA
(1*) 2 atm (2) 3 atm (3) 4 atm (4) 1 atm
nRT 2  0 .0821  546
Sol. (1) P    2 atm.
V 44.8 l
18. A sample of gas occupies 100 ml at 27°C and 740 mm pressure. When its volume is changed to 80 ml
at 740 mm pressure, the temperature of the gas will be
27°C o 740 mm nkc ij xSl dk ,d izkn'kZ 100 ml ?ksjrk gSA tc 740 mm nkc ij bldk vk;ru ifjofrZr
gksdj 80 ml gks tkrk gS rks xSl dk rkieku fuEu gksxkA
 (1) 21.6 °C (2) 240 °C (3*) – 33°C (4) 89.5 °C
Sol. V1 = 100 ml V2 = 80 ml
T1 = 300 K T2 = ?
P1 = 740 mm P2 = 740 mm
Applying charles law V  T ¼pkYlZ fu;e ykxw V  T)
V1 V
= 2
T1 T2
100 80
=
300 T2
300  80
T2 = = 240 K = 24 – 273 = 240 – 273ºC = – 33ºC.
100
19. A certain sample of gas has a volume of 0.2 litre measured at 1 atm. pressure and 0 o C . At the same
pressure but at 273 o C , its volume will be
;fn xSl ds uewus dk] 1 ok;qe.Myh; nkc vkSj 0°C rki ij vk;ru 0.2 yhVj ekik x;k gS] rks leku nkc ij
fdUrq 273°C rki ij vk;ru gksxkA
(1*) 0.4 litres (2) 0.8 litres (3) 27.8 litres (4) 55.6 litres
V T T o
546 K
(1) V  T  V2  T V1
1 1 2
Sol.   0 .2 L  0 .4 L.
2 2 1 273 o K
NEET MTC -3
20. How many moles of He gas occupy 22.4 litres at 30 o C and one atmospheric pressure
He xSl ds fdrus eksy 22.4 litres vk;ru] 30 o C o 1 atm ij ?ksjrs gS
(1*) 0.90 (2) 1.11 (3) 0.11 (4) 1.0
P1 V1 P2 V2 PVT
  n 2  2 2 1 n1
Sol. n1 T1 n 2 T2 P1 V1 T2
at STP n1  one mole. at T  273o  30 o  303o K
P1 = 1 atm. P2  1 atm
V2  22.4
V1 = 22.4 lt
T1 = 273oK
1 22.4 273
n2     1  0.9 moles
1 22.4 303
P1 V1 P2 V2 PVT
  n 2  2 2 1 n1
Sol. n1 T1 n 2 T2 P1 V1 T2
STP ij n1  1 mole. T  273o  30 o  303o K

P1 = 1 atm. P2  1 atm
V2  22.4
V1 = 22.4 lt
T1 = 273oK
1 22.4 273
n2     1  0.9 moles
1 22.4 303
21. The volume of a gas measured at 27°C and 1 atm pressure is 10 L. To reduce the volume to 2 L at 1
atm pressure, the temperature required is :
27°C rFkk 1 atm nkc ij ,d xSl dk vk;ru 10 L ekfir gqvk 1 atm nkc ij vk;ru dks 2 yhVj rd de djus
ds fy, vko';d rkieku fuEu gSA
(1*) 60 K (2) 75 K (3) 150 K (4) 225 K
Sol. Here (;gk¡) V1 = 10 L, V2 = 2 L
P1 = 1 atm, P2 = 1 atm
T1 = 300 K, T2 = ?
P1V1 PV
= 2 2
T1 T2
1 10 1 2
=
300 T2
300  2
T2 = = 60 K
10
22. Torr is unit of :

(1) Temperature (2*) Pressure (3) Volume (4) Density
Vksj fuEu dh bdkbZ gS %
(1) rki (2*) nkc (3) vk;ru (4) ?kuRo
Sol. 1 Torr = 1 mm.
NEET MTC -4
23. The atmospheric pressure on Mars is 0.61 kPa. What is the pressure in mm Hg ?
eaxy xzg ij ok;qe.Myh; nkc 0.61 kPa gSA bldk eku mm Hg esa fdruk gksxk \
(1) 0.63 (2*) 4.6 (3) 6.3 (4) 3.2
24. Centigrade and Fahrenheit scales are related as :

C F  32 C F  32 C F  32
(1*)  (2)  (3)  (4) None of these
5 9 9 5 8 5
lsfUVxzsM rFkk QkjsugkbV iSekus esa lEcU/k fuEu gS %
C F  32 C F  32 C F  32
(1*)  (2)  (3)  (4) buesa ls dksbZ ugha
5 9 9 5 8 5
Sol. This is the required relation in Centigrade and Fahrenheit scales.
Sol. uksV~l ns[ksaA
25. At what temperature, both Celsius and Fahrenheit scale read the same value :
fdl rki ij] lsfYl;l rFkk QkjsugkbV iSekus leku eku j[krs gSa %
(1) 100º (2) 130º (3) 60º (4*) –40º
F  32 C
Sol. (4)  ;
9 5
Let temperature be t, same on two scale (ekuk rki, t gSA)
9t
 t – 32 = or t = – 40
5
26. The value of universal gas constant R depends on :

(1) temperature of gas (2) volume of gas
(3) number of moles of gas (4*) units of volume and pressure
lkoZf=kd xSl fu;rkad R dk eku fuEu ij fuHkZj djrk gS %
(1) xSl dk rki (2) xSl dk vk;ru
(3) xSl ds eksyksa dh la[;k (4*) nkc rFkk vk;ru dh bdkbZ ij
27. The value of gas constant in calorie per degree temperature per mol is approximately :
R dk eku] dSyksjh izfr fMxzh rki izfr eksy esa yxHkx fuEu gS %
(1) 1 cal (2*) 2 cal (3) 3 cal (4) 4 cal
Sol. R = 2 can K mol = 8.314 JK mol = 8.314 × 10 erg K mol = 0.0821 litre atm K–1 mol–1.
–1 –1 –1 –1 7 –1 –1

28. The value of R in SI unit is :
R dk eku] SI bdkbZ esa fuEu gS %
–7 –1 –1
(1) 8.314 × 10 erg K mol (2*) 8.314 JK–1 mol–1
(3) 0.082 litre atm K–1 mol–1 (4) 2 cal K–1 mol–1
Sol. Follow answer 1 in SI units.
Section (B) : Relation between Mole, Mass and Gaseous volume.

[k.M (B) : eksy] nzO;eku o xSlh; vk;ru es laEc/k
1. If the atomic mass of Sodium is 23, the number of moles in 46 g of sodium is :

;fn lksfM;e dk ijek.kq nzO;eku 23 gS] rks lksfM;e ds 46 g esa eksyksa dh la[;k fuEu gS %
NEET MTC -5
(1) 1 (2*) 2 (3) 2.3 (4) 4.6

mass 46
Sol. mole  = = 2 mole.
at. wt. 23
nzO; eku 46
gy eksy = = = 2 eksy
ijek.kq Hkkj 23
2. Which of the following would contain 1 mole of particles :

(1) 0.5 mole of H2 (2) 2 g of H-atoms (3) 16 g of O-18 (4*) 16 g of methane
fuEu esa ls fduesa ,d eksy d.k gksaxs %
(1) H2 ds 0.5 eksy (2) H-ijek.kqvksa dk 2 g (3) O-18 ds 16 g (4*) esFksu ds 16 g
3. How many atoms are there in 100 amu of He ?

100 amu He esa ijek.kqvksa dh la[;k Kkr dhft,A
(1*) 25 (2) 50 (3) 75 (4) 100
1
Sol. We know that, 1 amu = × weight of one 12C atom
12
or weight of one 12C atom = 12 amu (at. wt. of C = 12 amu).
Similarly, as the atomic weight of He is 4 amu,
weight of one He atom = 4 amu.
100
Thus, the number of atoms in 100 amu of He = = 25.
4
1
Sol. ge tkurs gS fd] 1 amu = × ,d 12C ijek.kq dk Hkkj
12
;k ,d 12C ijek.kq dk Hkkj = 12 amu (C dk ijek.kq Hkkj = 12 amu).
blh çdkj] He dk ijek.kq Hkkj 4 amu gSA
,d He ijek.kq dk Hkkj = 4 amu.
100
vr%] He ds 100 amu esa ijek.kqvksa dh la[;k = = 25.
4
4. Number of molecules of water in a drop of water weighing 0.09 g are :
ty dh ,d cw¡n] ftldk Hkkj 0.09 xzke gS] blesa v.kqvksa dh la[;k ifjdfyr dhft,A
(1*) 3.01 × 1021 (2) 6.02 × 1021 (3) 3.01 × 1022 (4) 3.01 × 1020
Sol. In 18 g, no. of molecules = NA
NA NA
so in 0.09 g no. of molecules = × 0.09 = = 3.01 × 1021 .
18 2  100
gy- 18 g esa] v.kqvksa dh la[;k = NA
NA NA
blfy, 0.09 g esa v.kqvksa dh la[;k = × 0.09 = = 3.01 × 1021
18 2  100
5. The largest number of molecules is present in 1 g of
fuEu eas ls fdlds v.kqvksa ds 1 xzke esa mifLFkr v.kqvksa dh la[;k vf/kdre gS&
(1) CO2 (2*) H2O (3) C2H5OH (4) N2O5.
w 1
Sol. mole = 
m m
for largest no. of molecule m should be lowest.
vf/kdre v.kqvksa dh la[;k ds fy, m fuEure gksuk pkfg,A
NEET MTC -6
6. The total number of g-molecules of SO2Cl2 in 13.5 g of sulphuryl chloride is

13.5g lY¶;wfjy DyksjkbM esa SO2Cl2 ds xzke v.kqvksa dh dqy la[;k gS
(1*) 0.1 (2) 0.2 (3) 0.3 (4) 0.4
7. The number of molecules of CO2 present in 44 g of CO2 is :

44g CO2 esa CO2 ds v.kqvksa dh la[;k fuEu gS :
(1*) 6.0  1023 (2) 3  1023 (3) 12  1023 (4) 3  1010
8. The number of mole of ammonia in 4.25 g of ammonia is :

4.25 g veksfu;k esa veksfu;k ds eksyksa dh la[;k fuEu gS %
(1) 0.425 (2*) 0.25 (3) 0.236 (4) 0.2125
Sol. 17 g NH3 = NA molecules
9. One mole of P4 molecules contain :

(1) 1 molecule (2) 4 molecules
1
(3)  6.022  1023 atoms (4*) 24.088 × 1023 atoms
4
P4 v.kqdk ,d eksy fuEu dks j[krk gS %
(1) 1 v.kq (2) 4 v.kq
1
(3)  6.022  1023 ijek.kq (4*) 24.088 × 1023 ijek.kq
4
Sol. 1 mole P4 = N molecules of P4 = 4 N atoms of P4.
10. 1.0 g of hydrogen contains 6×1023 atoms. The atomic weight of helium is 4. It follows that the number of
atoms in 1 g of He is :
1.0 g gkbMªkstu 6 ×1023 ijek.kq j[krk gSA ghfy;e dk ijek.kq Hkkj 4 gSA bl izdkj 1 g He esa ijek.kqvksa dh la[;k
fuEu gksxh %
1
(1*)  6  1023 (2) 4 × 6 × 1023 (3) 6 × 1023 (4) 12 × 1023
4
Sol. 4 g He = NA atoms
11. A sample of aluminium has a mass of 54.0 g. What is the mass of the same number of magnesium
atoms? (At. wt. Al = 27, Mg = 24)
(1) 12 g (2) 24 g (3*) 48 g (4) 96 g.
,Y;qfefu;e ds ,d uewus dk nzO;eku 54.0 g gSA ,Y;qfefu;e ds leku ijek.kq la[;k j[kus ij] eSXuhf'k;e
ijek.kqvksa dk nzO;eku D;k gksxk \ (ijek.kq Hkkj Al = 27, Mg = 24)
(1) 12 g (2) 24 g (3*) 48 g (4) 96 g.
54
Sol. Mole of Aluminium = = 2 mole.
27
Al and Mg have same number of atoms (given). Hence same moles also.
 Mass of magnesium = 2 × 24 = 48 g.
54
gy ,Y;qfefu;e ds eksy = = 2 eksy
27
NEET MTC -7
Al o Mg ds fy, ijek.kqvksa dh la[;k leku nh xbZ gSA vr% eksy Hkh leku jgsxsaA
 eSXuhf'k;e dk nzO;eku = 2 × 24 = 48 g.
12. The number of atoms in 558.5 g of Fe (at wt.= 55.85) is :

(1*) Twice that in 60 g carbon (2) 6.022 × 1022
(3) Half in 8 g He (4) 558.5 × 6.023 × 1023
558.5 g Fe (ijek.kq Hkkj = 55.85) esa ijek.kqvksa dh la[;k fuEu gS :
(1*) 60 g dkcZu esa ijek.kqvksa dh la[;k dh nqxquh (2) 6.022 × 1022
(3) 8 g He esa ijek.kqvksa dh la[;k dh vk/kh (4) 558.5 × 6.023 × 1023
558.5
Sol. 558.5 g Fe = mole Fe = 10 mole Fe
55.85
60
= 2×5 mole C = 2× mole C
12
13. The weight of 1  1022 molecules of CuSO4. 5H2O is :

(1) 41.59 g (2) 415.9 g (3*) 4.159 g (4) None of these
CuSO4. 5H2O ds 1  1022 v.kqvksa dk nzO;eku fuEu gS %
(1) 41.59 g (2) 415.9 g (3*) 4.159 g (4) buesa ls dksbZ ugha
14. 5.6 litre of oxygen at STP contains :

(1) 6.02 × 1023 atoms (2*) 3.01 × 1023 atoms (3) 1.505 × 1023 atoms (4) 0.7525 × 1023 atoms
STP ij 5.6 yhVj vkWDlhtu esa gksxsa :
(1) 6.02 × 1023 ijek.kq (2*) 3.01 × 1023 ijek.kq (3) 1.505 × 1023 ijek.kq (4) 0.7525 × 1023 ijek.kq
15. If 1 dm3 of a gas weights 2.5 g at STP, its gram-molecular weight is :

STP ij 1 dm3 xSl dk Hkkj 2.5 g gS] bldk xzke v.kqHkkj gksxk&
(1*) 56 g (2) 11.2 g (3) 22.4 g (4) 224 g
16. Which one of the following pairs of gases contains the same number of molecules :
(1*) 16 g of O2 and 14 g of N2 (2) 8 g of O2 and 22 g of CO2
(3) 28 g of N2 and 22 g of CO2 (4) 32 g of O2 and 32 g of N2
fuEu esa ls fdl xSlh; ;qXe esa v.kqvksa dh la[;k leku gS %
(1*) 16 g O2 rFkk 14 g N2 (2) 8 g O2 rFkk 22 g CO2
(3) 28 g N2 rFkk 22 g CO2 (4) 32 g O2 rFkk 32 g N2
17. 1.5 × 1022 atoms of an element weigh about 0.9 g. The atomic mass of the element (in amu) is :
,d rRo ds 1.5 × 1022 ijek.kqvksa dk nzO;eku yxHkx 0.9 g gSA rRo dk ijek.kq nzO;eku (amu esa) D;k gksxk %
(1*) 36 (2) 18 (3) 54 (4) 72
Sol. Mole of element  At. Mass of element = Mass of element
 1.5  1022 
 
 NA   At. Mass of element = 0.9
 
 At. Mass of element = 36 u.
NEET MTC -8
gy- rRo ds eksy  rRo dk ijek.kq nzO;eku = rRo dk nzO;eku

 1.5  1022 
 
 NA   rRo dk ijek.kq nzO;eku = 0.9
 
 rRo dk ijek.kq nzO;eku = 36 u.
18. The least number of molecules are contained in

fuEu esa ls fdlesa v.kqvks es lcls de la[;k gS %
(1) 2 g Hydogen (2) 8 g oxygen (3*) 4 g Nitrogen (4) 16 g CO2
Section (C) : Log calculation

[k.M (C) : Log dh x.kuk
1. What is pH of 2× 10–4 M H3O+ :

2× 10–4 M H3O+ dh pH D;k gksxh \
(1) 4.3 (2*) 3.7 (3) 4.7 (4) None
2. Which have highest conc. of H3O+ in solution

fdl pH ij foy;u esa H3O+ dh lkUnzrk vf/kdre gksxhA
(1) pH = 4.3 (2) pH = 5.7 (3*) pH = 2.4 (4) pH = 8
3. What is conc. of OH– with pOH = 4.4 :

pOH = 4.4 ds lkFk OH– dh lkUnzrk gksxh \
10 –5 10 –4
(1) 4 × 10–4 (2*) 4 × 10–5 (3) (4)
4 4
4. Complete the table of pH (pH + pOH = 14) [H+] [OH–] = 10–14

fuEu pH lkj.kh dks iwjk dhft, (pH + pOH = 14) [H+] [OH–] = 10–14
H3O+ pH OH pOH
(1) 3 × 10–2 - - -
(2) - 6.3 - -
(3) 2 × 10–4
(4) 4.7
10 –12
Ans. (1) 3 × 10–2 1.52 = 3.3 × 10–13 12.48
3
10 –7
(2) 5 × 10–7 6.3 = 2 × 10–8 7.7
5
10 –10
(3) = 5 × 10–11 10.3 2 × 10–4 3.7
2
(4) 5 × 10–10 9.3 2 × 10–5 4.7
5. What is addition value of 10–2 , 10–3 , 10–4

10–2 , 10–3 , 10–4 ds ;ksxkRed eku D;k gksxs \
(1) 10–9 (2) 11 × 10–2 (3) 1.1 × 10–4 (4*) 1.11 × 10–2
NEET MTC -9
6. What is new pH when 0.1 mole H+ added into 1 ltr solution of pH = 1

0.1 eksy H+ dks 2 yhVj foy;u pH = 1 feykus ij ubZ pH D;k gksxh \
(1) 1.3 (2*) 0.7 (3) 1.7 (4) none
7. What is sum of 0.2, 0.3 and 0.4 in term of log

0.2, 0.3 rFkk 0.4 dks ;ksx log esa D;k gksxk
9
(1) log 9 (2) log (3*) log 8 (4) log 4
10
8. What is sum of 0.3, 0.48 and 0.6 in term of log

0.3, 0.48 rFkk 0.6 dk ;ksx log esa D;k gksxkA
(1) log 9 (2) log 6 (3) log 12 (4*) log 24
9. What is x value if x = log 18 – 2 log3

x dk eku D;k gksxk tc x = log 18 – 2 log3 gksA
(1*) 0.3 (2) 0.6 (3) 0.48 (4) 1.3
10. What is y value if logy = log5 + ½ log4

y dk eku D;k gksxk = log5 + ½ log4
(1) 20 (2) 1010 (3*) 10 (4) 20
11. What is x value if x = –log10–2 – log10–3 – log10–4

x dk eku Kkr dhft, tc x = –log10–2 – log10–3 – log10–4
1
(1) 10–9 (2*) 9 (3) 109 (4)
9
Section (D) : Energy, wavelength calculation

[k.M (D) : ÅtkZ] rjaxnS/;Z dh x.kuk
1. Which work value is equal with W = 20 atm×lt

dkSulk dk;Z dk eku W = 20 atm×lt ds leku gS
(1) 2026 J (2) 482.38 cal (3*) both 1 & 2 (4) None of these
2. Which is correct R (gas constant) value according to given relation.

dkSuls R (xSl fu;rkad) dk eku fuEufyf[kr lehdj.k ds vk/kkj ij lgh gSA
(1) Gº = – 2.3 RT log K, R = 0.082
K 2 H  1 1 
(2) log    , R = 2 for H = xKJ
K1 2.3R  T1 T2 
(3*) K  Ae–Ka / RT , R = 8.31, Ea = xKJ

MP
(4) d(g / lt)  , R=2
RT
3. How many no of waves present having wavelength 400 m.

(1) 2.5 × 103m–1 (2) 2.5 × 101m–1 (3) 2.5 × 105cm–1 (4*) Both (1) and (3)
NEET MTC -10
400 m rjaxnS/;Z esa mifLFkr rjxksa dh la[;k gS \

(1) 2.5 × 103m–1 (2) 2.5 × 101m–1 (3) 2.5 × 105cm–1 (4*) nksuks (1) rFkk (3)
4. What is wavelength if 4 × 103 waves are present in 10 m

;fn 10 m esa 4 × 103 rjaxs mifLFkr gS rks rjaxnZ/;Z D;k gksxh \
(1) 2.5 × 10–4 m (2) 4 × 10–3 m (3*) 2.5 × 10–3 m (4) none
5. What is approximate energy of one photon having wavelength 6.62 Å

,d QksVksu ftldh rjaxnS/;Z 6.62 Å gS mldh ÅtkZ yxHkx D;k gksxh \
(1) 3 × 10–24 J (2*) 3 × 10–16 J (3) 10–16 J (4) none
–34 8
6.62  10  3  10
Sol. E= =3 × 10–16 J
6.62  10–10
6. What is approxe energy of each quantum having wavelength 310 nm

izR;sd DokUVe dh rjaxnZ/;Z 310 nm gS ÅtkZ dk eku yxHkx D;k gksxk \
(1*) 4 ev (2) 3 ev (3) 40 ev (4) 0.4 ev
12400ev
Sol. E=
3100Å
7.
 (wave no.) E no. of photon
  (rjax la[;k) E (QksVksu dh la[;k)
(1) - - 6.62 × 10–16J 1

(2) 3000 Pm - - 10
(3) - 2 × 109 - NA
Ans.
1010
(1) 3Å =3.3×109 6.62 × 10–16J 1
3
 hc 
(2) 30Å=3000 Pm 3.3 × 108 6.62 × 10–16J  n  10
  
(3) 5 ×10–10 Pm 2 × 109 2.38 ×108 J NA
8. What is wavelength obtained when 2000Å and 4000Å wave are merged :
2000Å rFkk 4000Å okyh rjaxsa dks feykus ij izkIr rjaxnS/;Z gksxh \
4000 2000
(1) 600Å (2*) Å (3) Å (4) none
3 3
1 1 1 2 1 4000
Ans.    = 
 2000 4000 4000 3
9. What is total energy when 4ev and 3.2 ×10–19J are merged in form of single photon ?
tc 4ev rFkk 3.2 ×10–19J dks ,d QksVksu ds :I esa feyk;k tk, rks dqy ÅtkZ D;k gksxh ?
(1*) 6ev (2) 6.4 × 10–19J (3) 3.2 × 10–19J (4) 2ev
NEET MTC -11
10. Wavelength of a photon having an energy of 2 eV. will be :

2 eV dh ÅtkZ j[kus okys ,d QksVksu dh rjaxnS/;Z gksxhsA
(1*) 6.2  10–7 m (2) 6.2  10–6 m (3) 6.2  10–9 m (4) 6.2  10–8 m
12400
Sol. = Aº = 6200 Aº
2
11. The frequency of yellow light having wavelength 600 nm is : [MP PET 2002]
600nm rjaxns?;Z ds ihys izdk'k dh vko`fr D;k gksxha
(1*) 5.0 × 1014 Hz (2) 2.5 × 107 Hz (3) 5.0 × 107 Hz (4) 2.5 × 1014 Hz
1
c 3  10 ms 8
Sol.    5.0  1014 Hz
 600  109 m
12. Wave number of radiations having frequency of 4 × 104 Hz will be :

4 × 104 Hz vko`fr okys fofdj.k dh rjax la[;k fuEu gksxh %
(1*) 1.33 × 10–6 cm–1 (2) 1.33 × 10–7 cm–1 (3) 9 × 10–11 cm–1 (4) 4 × 10–5 cm–1
Section (E) : Concentration, Solvent, solute calculation

[k.M (E) : lkUnzrk] foyk;d] foys; x.kuk
1. What is amount of solute present in 4% w/w solution of 500 gm weight ?
500 gm Hkkj ds 4% w/w foy;u esa mifLFkr foys; dh ek=kk D;k gksxh \
(1) 4gm (2*) 20 gm (3) 40 gm (4) 2000 gm
2. What is amount of solvent present in 10% w/w solution having 50 gm solute

50 gm Hkkj 10% w/w foy;u esa mifLFkr foyk;d dh ek=kk D;k gksxh \
(1) 10 gm (2) 500 gm (3*) 450 gm (4) None
Sol. 10 gm solute ……………… Solution 100 gm
50 gm ………….. 500 gm
Solvent = 500 – 50 = 450
3. What is mass of solute present in 2ltr solution of molarity 2M (Molar mass solute = 50 g
2M eksyjrk ds 2ltr foy;u esa mifLFkr foyk;d dk nzO;eku D;k gksxk \ (foys; dk eksyj nzO;eku= 50 g)
(1*) 200 g (2) 4 gm (3) 400 gm (4) none
4. 2.5 mole/ltr solution is not equal to (Molar mass solute = 40)

2.5 eksy/lyhVj foy;u fuEu esa ls fdlds leku ugh gSA (foys; dk eksyj nzO;eku = 40)
mole
(1) 100 g/lt (2) 0.1 g/ml (3*) 2.5 × 10–3 (4) 105 g/m3
m3
5. Which solution contain highest solute when solution have equal amount will same solute ? (d=1.5 g/ml)
dkSuls foy;u esa foys; vf/kdre gksxk tc foy;u esa mlh foys; dh leku ek=kk gksxh \ (d=1.5 g/ml)
(1) 10 % w/v (2*) 10 % w/w (3) equal in both (4) none
6. Calculate volume of following gases at STP and arrange in increasing order of volume
fuEu xSlks ds STP ij vk;ru dh x.kuk dhft, rFkk vk;ru ds c<+rs gq, Øe esa O;ofLFkr dhft,A
(i) 1.20 mol O2 (ii) 8.40 × 1023 atoms of Ne
(iii) 50 g Ar (iv) 2.60 mol C2H6
(1) iii < I < ii < iv (2*) I < iii < ii , iv (3) iv < ii < i < iii (4) i < ii < iii < iv
NEET MTC -12
7. An alcoholic solution is prepared by adding 50 mL ethanol in 150 mL water of calculate

(1) Volume percent of the solution ?
(2) What is the volue of ethanol present 100 mL of the solution ?
(3) What is the new volume percent when 50 mL of ethanol is further added ?
50 mL ,FksukWy rFkk 150 mL ty dks feykdj ,d ,Ydksgy ;qDr foy;u cuk;k x;k gS fuEu dh x.kuk dhft,%
(1) foy;u dk vk;ru izfr'kr
(2) 100 mL foy;u dsa mifLFkr ,FksukWy dh ek=kk gksxh \
(3) 50 mL ,FksukWy vksj feyk nsus ij u;k vk;ru izfr'kr gksxk \
Ans. (1) 25%
(2) 25 ml
(3) 50 %
8. By Application of PV = nRT. Fill the table (PV = nRT ds mi;ksx djrs gq, Vscy Hkjs)
P V N T
(i) atom 2.5 L 3 mol 400 K
(ii) Pa 4.0 m3 2 mol 57ºC
(iii) 380 mm L 1.5 mol 87ºC
(iv) 2 bar 60 L 4.8 mol
(v) 1.5 atm 3.0 L –23ºC
Ans.
(i) 40 atm
(ii) 1.375 KPa
(iii) 90 L
(iv) 300 K
(v) 0.216 mol
9. Fill the table
Substance Moles Mass No. of particles

CO2 0.25
NaOH 10g
He 7.8 × 1022 atoms
CaCO3 1.50 mol
C8H18 22.8g
Ca3(PO4)2 2.50 mol
Vscy Hkjs
inkFkZ Eksy nzO;eku v.kqvksa dh la[;k
CO2 0.25
NaOH 10g
He 7.8 × 1022 atoms
CaCO3 1.50 mol
C8H18 22.8g
Ca3(PO4)2 2.50 mol
Ans.
NEET MTC -13
Substance Moles Mass No. of particles

CO2 0.25 11 g 1.5 × 1023
NaOH 0.25 10g 1.5 × 1023
He 0.13 0.52 7.8 × 1022 atoms
CaCO3 1.50 mol 150 gm 9 × 1023
C8H18 0.2 22.8g 1.2 × 1023
Ca3(PO4)2 2.50 mol 775 gm 15 × 1023
NEET MTC -14

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Mathematical Tool in Chemistry

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dsoy ,d lgh fodYi çdkj (ONLY ONE OPTION CORRECT TYPE)

Section (A) : Pressure, Volume and Temperature measurement

2. The SI unit of area is :

5. Which of the following is the correct order of units of pressure :

(1) S (2) R (3*) Q (4) P

9. Which of the prefixe is not correctly matched with their multiples :

10. Unit of SI system are similar to the units in :

11. 0.25 atm is not equal to

12. Which pressure is largest

13. 0.05 dm3 is equal to

14. Which volume value is smallest

15. Which temperature is largest

STP ij n1  1 mole. T  273o  30 o  303o K

22. Torr is unit of :

24. Centigrade and Fahrenheit scales are related as :

26. The value of universal gas constant R depends on :

Section (B) : Relation between Mole, Mass and Gaseous volume.

1. If the atomic mass of Sodium is 23, the number of moles in 46 g of sodium is :

(1) 1 (2*) 2 (3) 2.3 (4) 4.6

2. Which of the following would contain 1 mole of particles :

3. How many atoms are there in 100 amu of He ?

6. The total number of g-molecules of SO2Cl2 in 13.5 g of sulphuryl chloride is

7. The number of molecules of CO2 present in 44 g of CO2 is :

8. The number of mole of ammonia in 4.25 g of ammonia is :

9. One mole of P4 molecules contain :

12. The number of atoms in 558.5 g of Fe (at wt.= 55.85) is :

13. The weight of 1  1022 molecules of CuSO4. 5H2O is :

14. 5.6 litre of oxygen at STP contains :

15. If 1 dm3 of a gas weights 2.5 g at STP, its gram-molecular weight is :

gy- rRo ds eksy  rRo dk ijek.kq nzO;eku = rRo dk nzO;eku

18. The least number of molecules are contained in

Section (C) : Log calculation

1. What is pH of 2× 10–4 M H3O+ :

2. Which have highest conc. of H3O+ in solution

3. What is conc. of OH– with pOH = 4.4 :

4. Complete the table of pH (pH + pOH = 14) [H+] [OH–] = 10–14

5. What is addition value of 10–2 , 10–3 , 10–4

6. What is new pH when 0.1 mole H+ added into 1 ltr solution of pH = 1

7. What is sum of 0.2, 0.3 and 0.4 in term of log

8. What is sum of 0.3, 0.48 and 0.6 in term of log

9. What is x value if x = log 18 – 2 log3

10. What is y value if logy = log5 + ½ log4

11. What is x value if x = –log10–2 – log10–3 – log10–4

Section (D) : Energy, wavelength calculation

1. Which work value is equal with W = 20 atm×lt

2. Which is correct R (gas constant) value according to given relation.

(3*) K  Ae–Ka / RT , R = 8.31, Ea = xKJ

3. How many no of waves present having wavelength 400 m.

400 m rjaxnS/;Z esa mifLFkr rjxksa dh la[;k gS \

4. What is wavelength if 4 × 103 waves are present in 10 m

5. What is approximate energy of one photon having wavelength 6.62 Å

6. What is approxe energy of each quantum having wavelength 310 nm

(1) - - 6.62 × 10–16J 1

10. Wavelength of a photon having an energy of 2 eV. will be :

12. Wave number of radiations having frequency of 4 × 104 Hz will be :

Section (E) : Concentration, Solvent, solute calculation