JAPANESE

INDUSTRIAL
STANDARD
Translated and Published by
Japanese Standards Association

JIS G 1314-2: 2011

(JFA/JSA)
Method for chemical analysis of
silicomanganese - Part 2: Determination
of silicon content

ICS 77.100
Reference number: JIS G 1314-2 : 2011 (E)

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G 1314-2 : 2011

Date of Establishment: 2011-10-20

Date of Public Notice in Official Gazette: 2011-10-20
Investigated by: Japanese Industrial Standards Committee
Standards Board
Technical Committee on Iron and Steel

JIS G 1314-2 : 2011, First English edition published in 2013-06

Translated and published by: Japanese Standards Association

4-1-24, Akasaka, Minato-ku, Tokyo, 107-8440 JAPAN

In the event of any doubts arising as to the contents,

the original JIS is to be the final authority.

© J5A 2013
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized
in any form or by any means, electronic or mechanical, including photocopying and microfilm, without
permission in writing from the publisher.

Printed in Japan HN

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 G 1314-2 : 2011

Contents

Page

Introduction································································································· 1
1 Scope ...................................................... ···········································1

2 Normative references············································································ 1
3 General ...................................................... ········································1
4 Classification of determination method ....................................... ·············1
5 Silicon dioxide gravimetric method ......................................................... 2
5.1 Summary···························································································· 2
5.2 Reagents ...................................................... ······································2
5.3 Amount of test portion·········································································· 2
5.4 Procedure ...................................................... ·····································2
5.5 Blank test················ ...................................................... ·····················4
5.6 Calculation ........................................................................ ·················4
5.7 Tolerances ...................................................... ····································4

6 Sodium hydroxide titration method after separation of precipitated

potassium hexafluorosilicate .................................................................. 5
6.1 Summary···························································································· 5
6.2 Reagents ...................................................... ······································5
6.3 Amount of test portion·········································································· 6
6.4 Procedure ...................................................... ·····································6
6.5 Blank test··························································································· 7
6.6 Calculation ........................................................................ ·················7
6.7 Tolerances· ......................................................................................... 8

Annex JA (informative) Comparison table between JIS and corresponding

International Standard ·············································9

(i)

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G 1314-2 : 2011

Foreword

This translation has been made based on the original Japanese Indus-
trial Standard established by the Minister of Economy, Trade and In-
dustry through deliberations at the Japanese Industrial Standards
Committee according to the proposal for establishment of Japanese In-
dustrial Standard submitted by the Japan Ferroalloy Association (JFA)I
Japanese Standards Association (JSA) with the draft being attached,
based on the provision of Article 12 Clause 1 of the Industrial Stan-
dardization Law.
Consequently JIS G 1314:1998 has been withdrawn and partially replaced
with this Standard.
This JIS document is protected by the Copyright Law.
Attention is drawn to the possibility that some parts of this Standard
may conflict with a patent right, application for a patent after opening to
the public or utility model right. The relevant Minister and the Japanese
Industrial Standards Committee are not responsible for identifying the
patent right, application for a patent after opening to the public or utility
model right.
JIS G 1314 series consists of the following 6 parts under the general title
"Method for chemical analysis ofsilicomanganese":
Part 1: Determina tion ofmanganese con ten t
Part 2: Determination ofsilicon content
Part 3: Determination of carbon content
Part 4: Determina tion ofphosphorus con ten t
Part 5: Determination ofsulfur content
Part 6: Determina tion of boron con ten t

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JAPANESE INDUSTRIAL STANDARD JIS G 1314-2 : 2011

Method for chemical analysis of silicomanganese -

Part 2 : Determination of silicon content

Introduction
This Japanese Industrial Standard has been prepared based on the first edition of
ISO 4158 published in 1978 with some modifications of the technical contents to corre-
spond to the progress in analysis technology.
The portions given sidelines or dotted underlines are the matters not given in the
corresponding International Standard. A list of modifications with the explanations is
given in Annex JA.

1 Scope
This Standard specifies the determination method of silicon content in silicomanga-
nese.
NOTE: The International Standard corresponding to this Standard and the sym-
bol of degree of correspondence are as follows.
ISO 4158 : 1978 Ferrosilicon) ferrosilicomanganese and ferrosilicochro-
mium - Determination ofsilicon content - Gravimetric method (MOD)
In addition, symbols which denote the degree of correspondence in the
contents between the relevant International Standard and JIS are IDT
(identical), MOD (modified), and NEQ (not equivalent) according to
ISOIIEC Guide 21-1.

2 Normative references
The following standards contain provisions which, through reference in this text,
constitute provisions of this Standard. The most recent editions of the standards (in-
cluding amendments) indicated below shall be applied.
JJS_J!__19J)l ___ }i}!!:J;:Q!!JlQy§_~_G?lJ.?XEJIXl!}?§fQ~[lh~!!!jf;!!l/!-lJ.!Jlx~i~
J1SJ(_8_QQl ____ G~IJ.?XEJIXlJl~fQJ;:j;~~t!!!_f!_~.hQd$._Qfr..?_EJgf!!Jt~

3 General
.G-_~_1l~x~1_m_~_tt~x~ __GQm}:p.9}~~_JQ_Jh~ __ ~h~mj._G~1_~n~J.Y~5o~__ m_~thQd __ ~J~~ll_b~ __ in_~~~_Qxd~nG~
wj,th .JJS_ -'1 _l3-')t~
4 Classification of determination method
The determination method of silicon content shall be according to either of the fol-
lowing.
a) Silicon dioxide gravimetric method This method is applicable to the sample of

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G 1314-2 : 2011

which the silicon content rate is 10 % (mass fraction) or over up to and including
35 % (mass fraction).
p)____ SQdh~_m __ hy-cl:rQ~j.~~ ___tj.t:r~_ti~Ht __m~tbg~___ ~ft~J; ___~~p~~~t~QJJ:. __ Q( _J~r~~j.pj.t~t~~__ J~Qt~~~i~m,
b~~~tl~Q:rg~ili~~W____ Thif?__ m~thQsljf?__~F..Rli~9.:Rl~_t_Q__tb~_~mmI>Jg__Qf_wJli~h_tbg_f?51i~_Qn_~_Qn~
t~nt_r9.:t~_i~_14_%_~l).)._~_I?~_fr:9.:~_ti~H1tQX_9.Y:~X_llP__tQ_9.:!HtjJJgJJJdinK3Q_%_(m9.:f?_I?_f:t;~~tjQn.t

5 Silicon dioxide gravimetric method

5.1 Summary
Fuse the sample with sodium peroxide and sodium carbonate, add hydrochloric acid
and perchloric acid to make silicon insoluble silicon by generating white fume of per-
chloric acid, and dissolve soluble salts with hydrochloric acid. Filtrate the precipitate,
ignite it to obtain the constant mass, and weigh out the mass. Then, add hydrofluoric
acid and heat it to change silicon dioxide into silicon tetrafluoride for evaporation, ig-
nite it to obtain the constant mass, and weigh out the mass thereof.
5.2 Reagents
Reagents shall be as follows.
5.2.1 Hydrochloric acid (1 + 1, 1 + 2, 1 + 10)
5.2.2 Perchloric acid
5.2.3 Hydrofluoric acid
5.2.4 Sulfuric acid (1 + 1)
5.2.5 Fusing mixture (sodium peroxide 2 and sodium carbonate 1)
5.3 Amount of test portion
The test portion shall be _Q_._~_Q_g weighed out to the digit of 0.1 mg.
5.4 Procedure
Warning: The vapour of perchloric acid has a risk of explosion under presence of
ammonia, nitrite vapour or organic matters. The vapour shall be treated
at a place equipped with an exhaust equipment which ensures safety
under use of perchloric acid.
5.4.1 Decomposition of sample
The decomposition of sample shall be carried out according to the following proce-
dure.
a) Weigh out the sample and transfer it into a nickel crucible (30 mI) or a zirconium
crucible (35 ml or 45 mI).
b) Add 3 g of fusing mixture (5.2.5), mix them well and cover it with 0.5 g of fusing
mixture.
c) Place a nickel or zirconium cover, and heat mildly with lower temperature initially
by rotating the crucible until the content fuses.

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G 1314-2 : 2011

d) Raise its temperature, heat it at about 700°C (dark red colour state) for about 5
min by swirling the crucible until it completely fuses, then allow it to cool.
e) Place the crucible and the cover into a beaker (500 m!) in which 60 ml of hydro-
chloric acid (1 + 2) has been put, dissolve the melt, and remove the crucible and the
cover after being rinsed with water.
5.4.2 Dehydration of silicon dioxide
The dehydration of silicon dioxide shall be carried out according to the following pro-
cedure.
a) Add 60 ml ofperchloric acid into the solution obtained in 5.4.1 e).
b) Heat it on a hot plate for evaporation and for generation of the dense white fume of
perchloric acid, then cover it with a watch glass.
c) Continue heating for about 15 min under the condition where the perchloric acid
vapour is refluxed along the inside wall of the beaker, then allow it to cool.
d) Add 20 ml of hydrochloric acid (1 + 1) and heat, decompose precipitated manganese
oxides, etc., and add about 100 ml of warm water to dissolve soluble salts.
e) Immediately filter the solution through filter paper (Class 5A), and put the filtrate
into another beaker (500 m!).
f) Transfer the precipitate stuck on the inside wall of the beaker and the watch glass
by rubbing it with a rubber-tipped stirring rod onto the filter paper, wash it with
warm hydrochloric acid (1 + 10) five times, wash it with warm water until no iron
(III) ion can be detected 1), then put the washings together with the filtrate. Pre-
serve this precipitate and filter paper.
N9_t~_~~ ____ J]}~$ __G~n_h~__ ~_9nfi~m~d_pY-_t~~~ng_~_p_QXti9_n_Qfw~J~bing~__ ~!1~l_QP_$~~~d!1g__it
.n9.t_t~king_gn_x~dQ.j_$h __Qx~rrg~ __ ~9.l9.1-!~ __wll&rr __ ~dQ.j_ng_'p'9.t~~~i~m___thjg~y-=
.~rr~ t~__$Qlll_tiQ!1_ {lQQ _g~L} JQ _jt~

5.4.3 Recovery of silicon from filtrate and washings

The recovery of silicon from the filtrate and washings shall be carried out according
to the following procedure.
a) Add 10 ml of perchloric acid to the solution obtained in 5.4.2 £).
b) Carry out the procedures of 5.4.2 b) to 5.4.2 d).
c) Immediately filter the precipitation through filter paper (Class 5B), and transfer
the precipitate stuck on the inside wall of the beaker and the watch glass by rub-
bing it with a rubber-tipped stirring rod onto the filter paper, wash it with warm
hydrochloric acid (1 + 10), wash it with hydrochloric acid (1 + 10) warmed to about
40°C to 60 °C five times, and wash it with warm water until no iron (III) ion can be
detected 1). Discard the filtrate and washings.
5.4.4 Ashing of filter paper and weighing of precipitate
Ashing of filter paper and weighing of precipitate shall be carried out according to

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G 1314-2 : 2011

the following procedure.

a) Put the precipitate and filter paper preserved in 5.4.2 :fj and those obtained in 5.4.3
c) together into a platinum crucible (No. 30).
b) Dry the filter paper by heating at low temperature and ash the filter paper by ig-
niting.
c) Ignite the platinum crucible at about 1 100°C for about 30 min, allow it to cool in a
desiccator to the ordinary temperature, and weigh the mass of the crucible.
d) Repeat the procedure of c) to obtain the constant mass (Q!~l.m_g_9X_JX!Hl~r..J~:n~Jh~__gjf~
f~K~n~~_jn_m_~_~~~~_1~~Jw~~X!_b~fQr..~_J~\nd_~ft~r_ignit.i9.nl.
5.4.5 Treatment on precipitate with hydrofluoric acid and weighing
Treatment on the precipitate with hydrofluoric acid and weighing shall be carried
out according to the following procedure.
a) Moisten the precipitate in the platinum crucible obtained in 5.4.4 d) with 2 or 3
drops of sulfuric acid (1 + 1), add 3 ml to 5 ml of hydrofluoric acid, and heat it so as
to evaporate silicon dioxide and sulfuric acid.
b) Ignite the platinum crucible at about 1 100°C for about 30 min, allow it to cool in a
desiccator to the ordinary temperature, and weigh the mass of the crucible.
c) Repeat the procedure of b) to obtain the constant mass (Q!.3 __mgJ)x__lJnd~r..JQr..Jh~__gjf~
f~K~n~~_jn_m_~_~~~~__b.~Jw~~X!_b~fQr..~_J~\nd_~ft~r_ignit.i9.nl.

5.5 Blank test

The same operation as the sample shall be carried out without using the sample in
parallel with the sample.
5.6 Calculation
The silicon content rate in the sample shall be calculated from the mass obtained in
5.4.4 d) for the sample, the mass obtained in 5.4.5 c) for the sample, the mass obtained
in 5.4.4 d) in the blank test and the mass obtained in 5.4.5 c) in the blank test accord-
ing to the following formula .
. [(m2 -m3)-(m4 -m s )]x0.4674
Sz = xlOO
m1

where, Si: silicon content rate in sample [% (mass fraction)]

ml: amount of test portion (g)
m2: mass obtained in 5.4.4 d) for sample (g)
m3: mass obtained in 5.4.5 c) for sample (g)
m4: mass obtained in 5.4.4 d) in blank test (g)
ms: mass obtained in 5.4.5 c) in blank test (g)
5. 7 TQ1~J'~n<;~~

The tolerances on this method shall be in accordance with table 1.

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G 1314-2 : 2011

Table 1 Tolerances
Unit: % (mass fraction)
Silicon content rate Within -laboratory-reproducibility limit Reproducibility limit
17.21 0.120 0.526
16.18 0.140 0.554
NQrE__:___ r.b_~_~ili9_Qn~9D_t~_ntx~t~_giy~p.:.ip.:_thi~_t~Rl~.if?_tb&_~ili~9D__G9.P.:t~P.:t.K~_t~__in_th~_f?~n:ml~_
:tJ_~~<i.iP.:_tb~_~Q9.P_~K~tiY~_~~:R~:rj_I)J._~ntJQK_<i~_t~xminin.Kt.b.~_t.Ql~:r_~)J._G~_I?_h~~gg_QP.:_JJS_Z_
~~Q~_:_U)_~_L

6 Sodium hydroxide titration method after separation of precipitated potassium

hexafluorosilicate
6.1 Summary
Decompose the sample with nitric acid and hydrofluoric acid coexisting with potas-
sium fluoride, or fuse the sample with sodium peroxide and sodium carbonate and dis-
solve it in nitric acid. Thereafter, add hydrofluoric acid and potassium nitrate, and
precipitate potassium hexafluorosilicate. Filter this precipitate, dissolve in warm water,
and titrate with sodium hydroxide solution.
6.2 Reagents
Reagents shall be as follows.
6.2.1 Hydrochloric acid
6.2.2 Nitric acid (1 + 1)
6.2.3 Hydrofluoric acid
6.2.4 Potassium nitrate
6.2.5 Potassium nitrate solution (50 gIL)
6.2.6 Potassium fluoride solution Dissolve 200 g of potassium fluoride in hydroflu-
0ric acid and make the liquid amount 1 000 ml with hydrofluoric acid. Reserve this so-
lution in a polyethylene container.
6.2.7 Fusing mixture (sodium peroxide 1 and potassium carbonate 5)
6.2.8 0.5 mollL sodium hydroxide standard solution The solution of 0.5 mollL so-
dium hydroxide shall be as follows.
a) Preparation 500 ml of 1 mollL sodium hydroxide solution prepared in accordance
with r) 1) 1.1) of JA.5.2 in JIS K 8001 shall be taken into a volumetric flask of 1
000 ml, water not containing carbon dioxide is added to the marked line, and it is
preserved in an airtight polyethylene bottle with soda -lime tube.
b) Standardization In accordance with r) 1) 1.2) of JA.5.2 in JIS K 8001. In this case,
1.2 g to 1.3 g of amidosulfuric acid shall be weighed out to the digit of 0.1 mg.
c) Calculation The factor shall be calculated according to the following formula.

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G 1314-2 : 2011

f= m6 x_A_
0.04855 x VI 100

where, f: factor of 0.5 mollL sodium hydroxide solution

m6: mass of amidosulfuric acid weighed out (g)
A: purity of amidosulfuric acid [% (mass fraction)]
0.048 55: mass of amidosulfuric acid corresponding to 1 ml of 0.5
mollL sodium hydroxide solution (g)
VI: used amount of 0.5 mollL sodium hydroxide solution re-
quired for titration (m!)
6.2.9 Phenolphthalein solution 0.5 g of phenolphthalein shall be dissolved in 90 ml
of ethanol (95) and made 100 ml with water.
6.3 Amount of test portion
The test portion shall be 0.20 g weighed out to the digit of 0.1 mg.
6.4 Procedure
6.4.1 Decomposition of sample and generation of potassium hexatluorosilicate pre-
cipitation
The decomposition of sample and the generation of potassium hexafluorosilicate pre-
cipitation shall be according to either of the following.
a) Case of decomposition of decomposable sample by acid
1) Weigh out the sample and transfer it into a polyethylene beaker (300 m!) and
place a polyethylene cover.
2) Add 30 ml of nitric acid (1 + 1), place a polyethylene cover and add 10 ml of pot as-
sium fluoride solution (6.2.6) little by little shaking the beaker to decompose the
sample.
3) Add 5 ml of hydrochloric acid and add water to make the liquid amount about 80
ml, and heat it on a water bath for about 15 min.
4) Add small amount of filter paper pulp, allow it to stand for about 30 min while
being cooled to 15°C or lower, and precipitate potassium hexafluorosilicate.

b) Case of decomposition by fusing mixture

1) Weigh out the sample and transfer it into a nickel crucible (30 m!) or a zirconium
crucible (35 ml or 45 m!).
2) Add 3 g of fusing mixture (6.2.7), mix them well and place a nickel or zirconium
cover.
3) Initially heat mildly until the content fuses, then raise the temperature and heat
it at about 700°C (dark red colour state) for about 5 min by swirling the crucible
to fuse.
4) After allowing it to cool, add a little amount of warm water, and heat it gently to
dissolve the melt.

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G 1314-2 : 2011

5) Transfer the solution by using warm water into a polyethylene beaker (300 mn in
which 50 ml of nitric acid (1 + 1) has been put.
6) Add 3 ml of hydrochloric acid into the crucible to dissolve the melt stuck on the
inside wall of the crucible, wash the crucible and the cover with water sufficiently,
then put this solution and washings together with the solution of 5).
7) Heat the solution on a water bath to completely dissolve the melt, and add water
to make the liquid amount about 80 ml.
8) Add 10 ml of hydrofluoric acid and 3 g of potassium nitrate, mix them, and heat it
for about 15 min on a water bath.
9) Add small amount of filter paper pulp, allow it to stand for about 30 min while
being cooled to 15°C or lower, and precipitate potassium hexafluorosilicate.
6.4.2 Filtration of precipitate
The filtration of precipitate shall be carried out according to the following procedure.
a) Filter the precipitate obtained in a) 4) or b) 9) of 6.4.1 while being cooled to 15°C or
lower by using a polyethylene funnel attached with a filter paper (Class 5A).
b) Wash sufficiently the precipitate and the filter paper with potassium nitrate solu-
tion (50 giL) (6.2.5) cooled to 15°C or lower until blue litmus paper gives no change
to red colour when the washings are dripped. Discard the filtrate and washings.
6.4.3 Titration
The titration shall be carried out acording to the following procedure.
a) Transfer the precipitate obtained in 6.4.2 b) together with filter paper into an Er-
lenmeyer flask (200 mn.
b) Add about 50 ml of warm water, sufficiently mix by shaking, and crush the filter
paper.
c) After boiling the solution by heating, add several drops of phenolphthalein solution
(6.2.9), and add 0.5 mollL sodium hydroxide solution (6.2.8) at once approximate to
the end point.
d) Add several drops of phenolphthalein solution (6.2.9), titrate again with 0.5 mollL
sodium hydroxide solution (6.2.8), and stop the titration for a while when the solu-
tion turns faint pink colour.
e) Stopper the Erlenmeyer flask, mix sufficiently the solution by shaking, continue
titration when the faint pink colour vanishes, take the point where the solution has
turned again to faint pink colour as the end point, and obtain the amount of 0.5
mollL sodium hydroxide solution (6.2.8) used.
6.5 Blank test
The same operation as the sample shall be carried out without using the sample in
parallel with the sample.
6.6 Calculation

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G 1314-2 : 2011

The silicon content rate in the sample shall be calculated from the used amounts (m!)
of 0.5 mollL sodium hydroxide solution for the sample and in the blank test according
to the following formula.
(V2 - V3 ) x F x 0.003 511
Si= x100
m7

where, Si: silicon content rate in sample [% (mass fraction)]

V2 : used amount of 0.5 mollL sodium hydroxide solution in
6.4.3 for sample (m!)
V3: used amount of 0.5 mollL sodium hydroxide solution in
6.4.3 in blank test (m!)
F: factor of 0.5 mollL sodium hydroxide solution
m7: amount of test portion (g)
6.7 Tolerances
The tolerances shall be in accordance with table 2.

Table 2 Tolerances
Unit: % (mass fraction)
Silicon content rate Wi thin -labora tory-reprod ucibility limit Reproducibility limit
17.14 0.280 0.669
16.14 0.244 0.596
NOTE: The silicon content rate given in this table is the silicon content rate in the sample
used in the cooperative experiment for determining the tolerances based on JIS Z
8402 : 1991.

Bibliography
JIS Z 8402 : 1991 General rules for permissible tolerance of chemical analyses and
physical tests

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 Annex JA (informative)
Comparison table between JIS and corresponding International Standard
JIS G 1314-2 : 2011 Method foI' chemical analysis ofs11icomanganese - PaI't 2 : ISO 4158 : 1978 FeITosilicon, feI'I'osilicomanganese and fen'osili-
DeteI'mination ofsilicon content cochI'omium - DeteI'mination ofsilicon content- GI'avimetI'ic method
(I) Requirements in JIS (II) Inter- (III) Requirements in (IV) Classification and details of technical (V) Justification for the
national International Standard deviation between JIS and the Interna- technical deviation and
Standard tional Standard by clause future measures
number
No. and Content No. of Content Classifica - Detail of technical deviation
title of clause tion by
clause clause
1 Scope Determination method 1 Determina tion Addition In ISO Standard, only sili- Proposal of addition of the
"'d of silicon content in method of silicon con dioxide gravimetric sodium hydroxide titration
~
o silicomanganese is content of ferrosili- method is specified. In JIS, method after separation of
~
t:rj
specified. con, ferrosilicoman- sodium hydroxide titration precipitated potassium
o
~ ganese and ferrosili- method after separation of hexafluorosilicate to ISO
t:rj
U cochromium is precipitated potassium will be studied.
to
~ specified. hexafluorosilicate is added.
o
o 2 Norma-
~ tive refer-
o
"""" ences
~
~
3 General In accordance with JIS - - Addition Not specified in ISO Stan- Proposal to ISO will be
G 130l. dard. studied.

4 Classifi- Silicon dioxide gra- Silicon dioxide gra- Addition In ISO Standard, only sili- Proposal of addition of the
cation of vimetric method vimetric method con dioxide gravimetric sodium hydroxide titration
determina- Sodium hydroxide ti- method is specified. In JIS, method after separation of
tion tration method after sodium hydroxide titration precipitated potassium
method separation ofprecipi- method after separation of hexafluorosilicate to ISO 0
I--'
tated potassium precipitated potassium will be studied. CA:l
I--'
hexafl uorosilica te hexafluorosilicate is added. *:'"
t-.:l

t-.:l
0
I--'
1--'\.0
 o~
o
~
CJJ
~
~
(I) Requirements in JIS (II) Inter- (III) Requirements in (IV) Classification and details of technical (V) J ustifica tion for the I

~
national International Standard deviation between JIS and the Interna- technical deviation and
~
Standard tional Standard by clause future measures o
~
number
No. and Content No. of Content Classifica - Detail of technical deviation ~

title of clause tion by

clause clause
5.1 Sum- Summary of silicon 3 Principle Identical - -
mary dioxide gravimetric
method is specified.
"'d 5.2 Re- Reagents are specified. 4 Reagents are speci- Deletion Ammonia solution and sil- In ISO Standard, ammo-
~
o agents fied. ver nitrate are specified. nia solution is specified,
~
t:rj
o but this procedure is not
~
t:rj used in Japan. As silver
U nitrate cannot be used for
to
~ the confirmation of exis-
o tence of perchloric acid,
o
~
proposal of deletion to ISO
will be studied.
o
""""
~
~ 5.3 Amount Specified as 0.20 g. 7.3.1 0.50 g for sample of Alteration There is difference in As the amount of test por-
of test por- which silicon content amount of test portion. tion in ISO Standard is
tion ra te is less than not suitable by considering
50 %, and 0.25 g for the precipitation amount
not less than 50 %. of silicon dioxide, proposal
to ISO will be studied.

5.4 Proce- Procedure is specified. 7.3 Procedure is speci- Addition There is difference in con- Proposal to ISO will be
dure fied. firmation method of wash- studied.
ing.

5.5 Blank Method of blank test is 7.2 Identical with JIS. Identical - -
test specified.

5.6 Calcu- Calculation formula is 8 Identical with JIS. Identical - -

lation specified.
 (I) Requirements in JIS (II) Inter- (III) Requirements in (IV) Classification and details of technical (V) J ustifica tion for the
national International Standard deviation between JIS and the Interna- technical deviation and
Standard tional Standard by clause future measures
number
No. and Content No. of Content Classifica - Detail of technical deviation
title of clause tion by
clause clause
5.7 Toler- Tolerances are speci- 9 Reproducibility Alteration In JIS, they are determined Proposal to ISO will be
ances tied. from cooperative experi- studied.
ment.

6 Sodium Sodium hydroxide ti- - - Addition Sodium hydroxide titration Proposal of addition of so-
hydroxide tration method after method after separation of dium hydroxide titration
"'d titration separation ofprecipi- precipitated potassium method after separation of
~
o method af- tated potassium hexafluorosilicate is added. precipitated potassium
~
t:rj ter separa- hexafl uorosilica te hexafluorosilicate to ISO
o
~ tion of pre- will be studied.
t:rj
U cipitated
to potassium
~
o hexafluoro-
o
silicate
~
o
""""
~
~
Overall degree of correspondence between JIS and International Standard (ISO 4158 : 1978): MOD

NOTE 1 Symbols in sub-columns of classification by clause in the above table indicate as follows:

- Identical: Identical in technical contents.

- Deletion: Deletes the specification item(s) or content(s) of International Standard.

- Addition: Adds the specification item(s) or content(s) which are not included in International Standard.
0
I--'
- Alteration: Alters the specification content(s) which are included in International Standard. CA:l
I--'
NOTE 2 Symbol in column of overall degree of correspondence between JIS and International Standard in the above table indicates as follows: *:'"
t-.:l
- MOD: Modifies International Standard. t-.:l
0
I--' I--'
I--' I--'
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