16/2/22, 19:12 Introduction to Chemical Engineering Thermodynamics - 9780073104454 - Exercise 13 | Quizlet

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Explanations Introduction to Chemical Engineering Thermodynamics

Exercise 13
Chapter 11 | Page 422

Introduction to Chemical Engineering Thermodynamics

ISBN: 9780073104454

Table of contents

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1 of 11
Step 1

Known

V = 120x1 + 70x2 + (15x1 + 8x2 )x1 x2

​ ​ ​ ​ ​ ​

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2 of 11
Step 2

a) Start by applying liquid phase mole fraction summation

expression into the given molar volume expression

x1 + x2 = 1
​ ​

V = 120 ⋅ x1 + 70 ⋅ (1 − x1 ) + (15 ⋅ x1 + 8 ⋅ (1 − x1 ))x

​ ​ ​ ​

V = −7 ⋅ x31 − x21 + 58 ⋅ x1 + 70
​ ​ ​

3 of 11
Step 3

Partial molar volumes can be found using Equation 11.15

and Equation 11.16

dV
Vˉ1 = V + x1 ​ ​

dx1 ​

ˉ dV
V2 = V + x1 ​ ​

dx1 ​

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16/2/22, 19:12 Introduction to Chemical Engineering Thermodynamics - 9780073104454 - Exercise 13 | Quizlet

4 of 11
Step 4

Derivation of the volume yields

dV
= −21 ⋅ x21 − 2 ⋅ x1 + 58
​ ​ ​

dx1
​

5 of 11
Step 5

Substitute given volume and derivation of it expressions

into the previously set up partial molar volumes equations

Vˉ1 = 14 ⋅ x31 − 20 ⋅ x21 − 2 ⋅ x1 + 128

​ ​ ​ ​

Vˉ2 = 14 ⋅ x31 + x21 + 70

​ ​

​ ​ ​

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16/2/22, 19:12 Introduction to Chemical Engineering Thermodynamics - 9780073104454 - Exercise 13 | Quizlet

6 of 11
Step 6

b) Summability expression is given by Equation 11.11 as

V = ∑ xi ⋅ Vˉi ​ ​ ​

V = x1 ⋅ (14 ⋅ x31 − 20 ⋅ x21 − 2 ⋅ x1 + 128) + (1 − x1 ) ⋅ (

​ ​ ​ ​ ​

V = −7x31 − x21 + 58 ⋅ x1 + 70 ​ ​ ​

7 of 11
Step 7
c) Gibbs/Duhem expression for this case can be written as

∑ xi dVˉi = 0 ​ ​ ​ x1 ⋅ dVˉ1 + x2 ⋅ dVˉ = 0

​ ​ ​

​ ​ ​

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16/2/22, 19:12 Introduction to Chemical Engineering Thermodynamics - 9780073104454 - Exercise 13 | Quizlet

8 of 11
Step 8

Derivation of volume over species 1 expression can be

found from the case a) results

Vˉ1 = 14 ⋅ x31 − 20 ⋅ x21 − 2 ⋅ x1 + 128

​ ​ ​ ​

Vˉ2 = 14 ⋅ x31 + x21 + 70

​ ​ ​

Vˉ1
= 42 ⋅ x21 − 40 ⋅ x1 − 2
​ ​

→
​

​ ​ ​

x1 ​

Vˉ2
→ = 42 ⋅ x21 − 2 ⋅ x1
​

​ ​ ​

x1 ​

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16/2/22, 19:12 Introduction to Chemical Engineering Thermodynamics - 9780073104454 - Exercise 13 | Quizlet

9 of 11
Step 9
Divide the Gibbs/Duhem expression for this case with dx
and with it, substitute the derivation of volume previously
set up

dVˉ1 dVˉ
x1 ⋅ + x2 ⋅ =0
​

​ ​ ​ ​

x1 x1
​ ​

x1 ⋅ 42 ⋅ x21 − 40 ⋅ x1 − 2 + (1 − x1 ) ⋅ (42 ⋅ x21 − 2 ⋅ x1 )

​ ​ ​ ​ ​ ​

42 ⋅ x31 − 40 ⋅ x21 − 2 ⋅ x1 + 42 ⋅ x21 − 2 ⋅ x1 − 42 ⋅ x31 − 2

​ ​ ​ ​ ​ ​

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16/2/22, 19:12 Introduction to Chemical Engineering Thermodynamics - 9780073104454 - Exercise 13 | Quizlet

10 of 11
Step 10

d) Required derivations are already calculated, therefore

just substitute the given values for the liquid mole fraction

x1 = 1  x1 = 0
​ ​

42 ⋅ x21 − 40 ⋅ x1 − 2 = 42 ⋅ x21 − 2 ⋅ x1 = 0
​ ​ ​ ​

42 ⋅ 1 − 40 ⋅ 1 − 2 = 42 ⋅ 02 − 2 ⋅ 0 = 0
0 = 0 = 0   ✓

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16/2/22, 19:12 Introduction to Chemical Engineering Thermodynamics - 9780073104454 - Exercise 13 | Quizlet

11 of 11
Step 11

e) As suggested in the problem use the given expression

and the ones found in the case a) to plot the graphs and
plot the points.

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16/2/22, 19:12 Introduction to Chemical Engineering Thermodynamics - 9780073104454 - Exercise 13 | Quizlet

Exercise 12 Exercise 16

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